Deck 6: Some Processes Are Irreversible Thermal Physics

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سؤال
Consider a rectangular book. The book is (approximately) symmetric for rotations around an axis that goes diagonally from one corner to the other
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سؤال
Consider a system consisting of two Einstein solids PP and QQ in thermal contact. Assume that we know the number of atoms in each solid and ε\varepsilon . What do we know about the system if we also know the total energy in each of the two objects?

A) Its macrostate
B) Its microstate
C) Its macropartition
D) Its microstate and macropartition
E) Its macrostate and macropartition
F) Its macrostate and microstate
G) Its macrostate, microstate, and macropartition
سؤال
Consider a system consisting of two Einstein solids PP and QQ in thermal contact. Assume that we know the number of atoms in each solid and ε\varepsilon . What do we know about the system if we also know the total energy of the combined system?

A) Its macrostate
B) Its microstate
C) Its macropartition
D) Its microstate and macropartition
E) Its macrostate and macropartition
F) Its macrostate and microstate
G) Its macrostate, microstate, and macropartition
سؤال
What is the crucial characteristic of an Einstein solid that makes it easier to analyze in the context of this chapter than most other kinds of thermodynamic systems?

A) The atoms are arranged in a regular, cubic lattice.
B) The atoms are identical.
C) Its microstates are comparatively easy to count.
D) Each atom's energy levels are equally spaced.
E) Ω(U,N)\Omega(U, N) is always reasonably small.
F) Other (specify).
سؤال
We can ignore an Einstein solid's zero-point energy because

A) it is zero.
B) it never changes in any thermal interaction.
C) it is insignificant compared to the solid's total energy.
D) it is just a quantum-mechanical effect.
E) other (specify).
سؤال
Which of the following statements is true?

A) There are always many microstates in a macrostate.
B) All accessible macrostates are equally probable.
C) All microstates of a system are equally probable.
D) All accessible macropartitions are equally probable.
E) When two objects in thermal contact are isolated from everything else, their macrostates cannot change.
F) None of the above.
سؤال
Suppose that we increase an NN -atom Einstein solid's value of q=U/εq=U / \varepsilon from qq to q+1q+1 . By what factor does the value of its multiplicity Ω\Omega increase? (Choose whichever result is the closest, assuming that q>>1q>>1 and N>>1N>>1 .)

A) qq
B) 3N3 N
C) q/3Nq / 3 N
D) 3N/q3 N / q
E) (q+3N)/q(q+3 N) / q
F) (q+3N)/(qN)(q+3 N) /(q N)
سؤال
In the situation shown in figure T2.5c, the width of the bell curve at half its peak value is 0.021U0.021 U . If we multiply NAN_{A} , NBN_{B} , and UU by a factor of 100 , then the peak's width (as you can check) is about 0.0021U0.0021 U . Suppose that we increase each solid's NN and the system's total energy by another factor of 101810^{18} to create solids containing 1/61 / 6 of a mole of atoms (still pretty small objects by everyday standards). Assuming that the trend continues, what will be the approximate width of the combined system's probability bell curve as a fraction of UU ?
 <strong>In the situation shown in figure T2.5c, the width of the bell curve at half its peak value is  0.021 U . If we multiply  N_{A} ,  N_{B} , and  U  by a factor of 100 , then the peak's width (as you can check) is about  0.0021 U . Suppose that we increase each solid's  N  and the system's total energy by another factor of  10^{18}  to create solids containing  1 / 6  of a mole of atoms (still pretty small objects by everyday standards). Assuming that the trend continues, what will be the approximate width of the combined system's probability bell curve as a fraction of  U  ?  </strong> A)  2 \times 10^{-20}  (c) 0.0 B)  2 \times 10^{-22}  Figure T2.5 C)  2 \times 10^{-10}  D)  \mathbf{2} \times \mathbf{1 0}^{-12}  E)  2 \times 10^{-40}  F)  2 \times 10^{-42}   \mathrm{T} . Some other factor (specify). <div style=padding-top: 35px>

A) 2×10202 \times 10^{-20}
(c) 0.0
B) 2×10222 \times 10^{-22}
Figure T2.5
C) 2×10102 \times 10^{-10}
D) 2×1012\mathbf{2} \times \mathbf{1 0}^{-12}
E) 2×10402 \times 10^{-40}
F) 2×10422 \times 10^{-42}
T\mathrm{T} . Some other factor (specify).
سؤال
Suppose that you use a super-fast computer to measure a system's macropartition a billion times a second. What is the approximate probability of the least-probable macropartition that you might plausibly see in your lifetime? Select the closest response.

A) 1 chance in a million (106)\left(10^{6}\right)
B) 1 chance in a billion (109)\left(10^{9}\right)
C) 1 chance in a trillion (1012)\left(10^{12}\right)
D) 1 chance in 101510^{15}
E) 1 chance in 101810^{18}
F) 1 chance in 102110^{21}
سؤال
Consider the system where NA=NB=1000,U=5999εN_{A}=N_{B}=1000, U=5999 \varepsilon (see figure T2.6). Suppose that we can measure each object's energy to within 0.01U60ε0.01 U \approx 60 \varepsilon (the size of one bin). Once the system has reached a macropartition in the most probable bin, it will never spontaneously move to a macropartition outside that bin.
سؤال
Which of the systems listed below is the largest, having NA=NBN_{A}=N_{B} and U=6NAεU=6 N_{A} \varepsilon for which there is a better than 1 in a billion chance of seeing one or the other solid having zero energy? (Hint: Using StatMech to check cases is probably the easiest approach.)

A) NA=6N_{A}=6
B) NA=8N_{A}=8
C) NA=10N_{A}=10
D) NA=12N_{A}=12
E) NA=15N_{A}=15
سؤال
A hot object is placed in contact with a cold object. We observe that heat flows spontaneously from the hot object to the cold object, but not in the other direction. According to the argument in this chapter, this is so because

A) this increases the entropies of both objects.
B) this decreases the entropy of the combined system.
C) the system will tend to evolve toward macropartitions that have more microstates.
D) AA and CC
E) BB and CC
سؤال
Consider an object (object AA ) whose multiplicity is always 1 , no matter how much energy you put into it. If you put a very large amount of energy into such an object, and place it into thermal contact with an Einstein solid (object BB ) having the same number of atoms but much less energy, what will happen? (Hint: Imagine a macropartition table for such a pair of objects.)

A) Energy flows from AA to BB until AA has very little energy.
B) Energy flows from BB to AA until BB has very little energy.
C) Energy flows from AA to BB until both objects have the same energy.
D) No energy will flow between AA and BB at all.
E) Something else happens (describe).
سؤال
In a given macropartition, the total entropy of a system comprised of two or more parts is always equal to the sum of the entropies of those parts.
سؤال
1062/1060=10010^{62} / 10^{60}=100 . What is ln1062/\ln 10^{62} / In 106010^{60} ? (Select the closest response.)

A) 100
B) 10
C) 4.6
D) 1.0\mathbf{1 . 0}
سؤال
The entropy of a certain macropartition of a combined system is 102kB102 \mathrm{k}_{\mathrm{B}} . The entropy of another macropartition is 204kB204 \mathrm{k}_{\mathrm{B}} . How much more likely is the system to be in the second macropartition than the first? (Select the closest response.)

A) 2 times
B) e2=7.4\mathrm{e}^{2}=7.4 times
C) 102=10010^{2}=100 times
D) e102=2×1044\mathrm{e}^{102}=2 \times 10^{44} times
E) e102kBe0e^{102 k_{B}} \approx e^{0} ; so the two macropartitions have basically the same probability
سؤال
Which system has the greater entropy, a puddle of water sitting on a table next to a chaotic scattering of salt crystals or the same amount of salt dissolved in an evenly distributed way in the puddle? Be prepared to describe your reasoning.

A) The puddle and the scattered crystals.
B) The puddle with the dissolved salt.
C) Both have the same entropy.
D) One needs detailed models of water and salt to say.
سؤال
Object A's entropy increases quite a bit when we give it a certain tiny amount of energy, whereas object B's entropy increases by a much smaller amount with the same gift. Which has the higher temperature?

A) Object AA
B) Object BB
C) One cannot say without more information.
سؤال
As a normal object's thermal energy UU goes to zero, the slope of a graph of its entropy SS versus UU

A) approaches infinity.
B) approaches some positive value less than infinity.
C) approaches zero.
D) approaches some finite negative value.
E) approaches negative infinity.
F) depends entirely on the object's properties.
سؤال
Consider a system whose multiplicity is 1 , no matter how much energy one puts into it. What is such a system's temperature?

A) Zero
B) Positive
C) Negative
D) Undefined
سؤال
Suppose that an object's entropy increases from zero when its thermal energy is U=0U=0 to some maximum value when U=12Umax U=\frac{1}{2} U_{\text {max }} , and then goes back to zero when U=UmaxU=U_{\max } (as shown in the drawing below). The greatest thermal energy UU that such an object could have when in thermal equilibrium with a normal object is closest to which of the following?
 <strong>Suppose that an object's entropy increases from zero when its thermal energy is  U=0  to some maximum value when  U=\frac{1}{2} U_{\text {max }} , and then goes back to zero when  U=U_{\max }  (as shown in the drawing below). The greatest thermal energy  U  that such an object could have when in thermal equilibrium with a normal object is closest to which of the following?  </strong> A) 0 B)  \frac{1}{4} U_{\max }  C)  \frac{1}{2} U_{\max }  D)  \frac{3}{4} U_{\max }  E)  U_{\max }  F) Other (specify) <div style=padding-top: 35px>

A) 0
B) 14Umax\frac{1}{4} U_{\max }
C) 12Umax\frac{1}{2} U_{\max }
D) 34Umax\frac{3}{4} U_{\max }
E) UmaxU_{\max }
F) Other (specify)
سؤال
If an object has a multiplicity Ω\Omega that decreases as its thermal energy UU increases, its temperature would

A) be always zero.
B) be always positive (and nonzero).
C) be negative (and nonzero).
D) increase as UU increases.
E) decrease as UU increases.
سؤال
Suppose that an atom has two energy levels separated by an energy difference ΔE\Delta E . When such atoms are in thermal contact with a reservoir at temperature TT , there is roughly 1 atom in the higher state for every 4 in the lower state. What is the approximate ratio of ΔE\Delta E to kBTk_{B} T ?

A) 14\frac{1}{4}
B) 4
C) In 4
D) ln4-\ln 4
E) e1/4e^{-1 / 4}
F) e4e^{-4}
G) Other (specify)
سؤال
Suppose that an atom has exactly two energy levels separated by an energy difference ΔE\Delta \mathrm{E} . When such atoms are in contact with a reservoir at a temperature T1T_{1} , the ratio of the number of atoms in the higher level to the number in the lower level is 14\frac{1}{4} . If we increase the temperature to T2T_{2} , the numerical value of this ratio

A) increases.
B) decreases.
C) remains the same.
سؤال
The quantity ZZ in the expression Pr(E)=Z1eE/kBT\operatorname{Pr}(\mathrm{E})=\mathrm{Z}^{-1} \mathrm{e}^{-\mathrm{E} / \mathrm{k}_{\mathrm{B}} \mathrm{T}} depends on the temperature TT of the reservoir.
سؤال
The quantity ZZ in the expression Pr(E)=Z1eE/kBT\operatorname{Pr}(E)=Z^{-1} e^{-E / k_{B} T} must be

A) always greater than 1 .
B) always less than 1 .
C) It could be either greater than or less than 1.
سؤال
As temperatures become large, the denominator in equation T4.36\mathrm{T} 4.36 becomes
Equation T4.36\mathrm{T} 4.36
U=3NEavg =3Nεeε/kBT1eε/kBT=3Nεeε/kBT1U=3 N E_{\text {avg }}=\frac{3 N \varepsilon e^{-\varepsilon / k_{B} T}}{1-e^{-\varepsilon / k_{B} T}}=\frac{3 N \varepsilon}{e^{\varepsilon / k_{B} T}-1}

A) very large.
B) very small.
C) approximately 1.
D) approximately -1 .
سؤال
Suppose that the energy difference between adjacent energy levels for an oscillator in an Einstein solid is ε=\varepsilon= 0.005eV0.005 \mathrm{eV} . At room temperature, the value of T/TET / T_{E} is

A) quite a bit smaller than 1
B) about equal to 0.5 .
C) about equal to 1 .
D) about equal to 2 .
E) quite a bit larger than 2.
F) (One doesn't have enough information to tell.)
سؤال
Suppose that the energy difference between adjacent energy levels for an oscillator in an Einstein solid is ε=\varepsilon= 0.005eV0.005 \mathrm{eV} . We would expect the average energy of this oscillator when it is in contact with a reservoir at room temperature to be

A) negligible.
B) smaller than 12kBT\frac{1}{2} k_{B} T .
C) about equal to 12kBT\frac{1}{2} k_{B} T .
D) about equal to kBTk_{B} T .
E) significantly larger than kBTk_{B} T .
F) One doesn't have enough information to tell.
سؤال
To calculate an object's heat capacity, we take its specific heat and

A) multiply by the object's mass MM .
B) divide by the object's mass MM .
C) multiply by the molar mass MAM_{A} of the object's molecules.
D) divide by the molar mass MAM_{A} of the object's molecules.
E) multiply by the mass mm of one molecule in the object.
F) divide by the mass mm of one molecule in the object.
G) do something else (specify).
سؤال
Suppose that the temperature TT is about TE/9T_{E} / 9 for a certain Einstein solid. The probability that an oscillator in that solid will have one unit of energy is closest to
(Hint: See equation T4.32T 4.32 for how to calculate ZZ .)
Equation T4.32:
1+x+x2+=11x1+x+x^{2}+\ldots=\frac{1}{1-x}

A) 1
B) 1/91 / 9
C) 1/811 / 81
D) 1/80001 / 8000
E) 1/1091 / 10^{9}
سؤال
TET_{E} is much smaller for lead than for iron. Which therefore has the greater heat capacity per atom at

-(a) T=100 KT=100 \mathrm{~K} ?

A) Lead
B) Iron
C) Both should be about the same.
سؤال
TET_{E} is much smaller for lead than for iron. Which therefore has the greater heat capacity per atom at

-(b) T=400 KT=400 \mathrm{~K} ?

A) Lead
B) Iron
C) Both should be about the same.
سؤال
At a sufficiently high temperature, an oscillator in an Einstein solid is more likely to have one unit of energy than no energy at all.
سؤال
Suppose that the forces holding an atom in its position in a crystal are the same for two different monatomic solids, but the mass of an atom mm is larger for solid BB than for solid AA . Which has the larger value of TET_{E} ?

A) Solid AA
B) Solid BB
C) Both have about the same value of TET_{E} .
سؤال
If we increase a one-dimensional container's length LL by a factor of 100 , by what factor does the value of ε/kBT\varepsilon / k_{B} T change at room temperature?

A) 10
B) 100
C) 10,000
D) 1/101 / 10
E) 1/1001 / 100
F) 1/10,0001 / 10,000
سؤال
Using an integral to calculate a sum over f(n)f(n) (where nn is an integer) is a good approximation when

A) the summed values f(n)f(n) are individually small.
B) the value of f(n)\boldsymbol{f}(\boldsymbol{n}) varies only very slowly with n\boldsymbol{n} .
C) the value of f(n)f(n) goes to zero as nn goes to infinity.
D) the value of f(n)f(n) goes to zero as nn goes to zero.
E) All of the conditions above are true.
سؤال
Which of the following energy storage modes for a gas molecule "switch on" fully at

-(a) the lowest temperature?

A) The molecule's kinetic energy
B) The molecule's rotational energy
C) The molecule's vibrational energy
سؤال
Which of the following energy storage modes for a gas molecule "switch on" fully at

-(b) the highest temperature?

A) The molecule's kinetic energy
B) The molecule's rotational energy
C) The molecule's vibrational energy
سؤال
The heat capacity of any energy storage mode with quantized energy levels goes to zero as the temperature TT goes to zero.
سؤال
An atom of helium can store energy by bumping an electron from its lowest orbital energy state to a higher orbital energy level. In particular, moving an electron from the lowest state to the next-lowest state would store an energy of 24.6eV24.6 \mathrm{eV} . Why can we ignore this energy storage mode when calculating the heat capacity of helium gas?

A) This mode is "frozen" out at normal temperatures.
B) Collisions between atoms can't influence the energy levels of electrons inside the atoms.
C) This storage mode is completely independent of the kinetic and/or rotational energy modes.
D) Only modes involving helium molecules count.
E) We have ignored this mode only for simplicity's sake.
F) Some other reason (specify).
سؤال
(a) The average xx -velocity of molecules in a container of gas at rest is zero.
سؤال
(b) The average molecular speed is zero.
سؤال
If the speed of a molecule in a container doubles (other things remaining the same), the average pressure that this molecule exerts on the container wall

A) remains the same.
B) doubles.
C) quadruples.
D) One does not have enough information to say.
سؤال
Suppose that when we add 20.8 J20.8 \mathrm{~J} to 1 mol of a certain gas, its temperature is observed to increase by 1 K1 \mathrm{~K} . Which of the following statements is true?

A) This gas is monatomic.
B) This gas is diatomic.
C) This gas is polyatomic.
D) One cannot determine the type of gas without information that we are not given.
E) The results described are impossible.
سؤال
The ideal gas model assumes that molecules have infinitesimal size. Consider one molecule bouncing around in the container. As the molecule's size increases relative to the size of the container, how will the average pressure PP that it exerts change, other things being held constant?

A) P\boldsymbol{P} increases.
B) PP does not change.
C) PP decreases.
D) One does not have enough information to say.
سؤال
Two identical rooms, AA and BB , are sealed except for an open doorway between them. Room AA is warmer than BB . Which room has the greater number of molecules? (Hint: How will the pressures in the two rooms compare?)

A) Room A
B) Room B
C) Both have the same number of molecules.
سؤال
One mole of hydrogen gas and 12\frac{1}{2} mole of helium gas are mixed in a container and maintained at a fixed temperature TT . How does the total pressure PHP_{\mathrm{H}} exerted by the hydrogen molecules compare to the total pressure PHeP_{\mathrm{He}} exerted by the helium molecules? Note that a molecule (atom) of helium has twice the mass of an H2\mathrm{H}_{2} molecule.

A) PH=2PHeP_{\mathrm{H}}=2 P_{\mathrm{He}}
B) PH=2PHeP_{\mathrm{H}}=\sqrt{2} P_{\mathrm{He}}
C) PH=PHeP_{\mathrm{H}}=P_{\mathrm{He}}
D) PH=12PHeP_{\mathrm{H}}=\sqrt{\frac{1}{2}} P_{\mathrm{He}}
E) PH=12PHeP_{\mathrm{H}}=\frac{1}{2} P_{\mathrm{He}}
F) Other (specify)
سؤال
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(a) the greater value of [v2]avg \left[v^{2}\right]_{\text {avg }} ,

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
سؤال
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(b) the greater average kinetic energy per molecule,

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
سؤال
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(c) the greater total thermal energy UU , and

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
سؤال
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(d) the greater pressure PP ?

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
سؤال
When counting particle-in-a-box quantum states in three dimensions, why do we divide the "volume" of only one eighth of a full spherical shell by the "volume" per quantum state? Why not the full shell's volume?

A) Molecules in a gas can only have positive momentum components.
B) A single quantum energy state embraces both positive and negative values for each momentum component.
C) A particle's momentum magnitude must be positive.
D) The factor of 2 in the expression h/2Lh / 2 L already counts both possible momentum signs.
E) We really do include the full shell: the diagram only shows 1/81 / 8 of the shell to make it easier to draw.
F) Some other reason (specify).
سؤال
Physically, why is a gas molecule's speed vv more likely to be near vpv_{p} than near zero?

A) There are fewer quantum states with smaller speeds than larger speeds.
B) The Boltzmann factor has a larger value near v=vp\mathrm{v}=\mathrm{v}_{\mathrm{p}} than near v=0v=0 .
C) We know that 12m[v2]avg =32kBT\frac{1}{2} m\left[v^{2}\right]_{\text {avg }}=\frac{3}{2} k_{B} T , and vpv_{p} is closer to [vavg 2]1/2\left[v_{\text {avg }}^{2}\right]^{1 / 2} than zero is.
سؤال
Physically, why is a gas molecule's speed vv more likely to be near vpv_{p} than near 2vp2 v_{p} ?

A) There are fewer quantum states for larger speeds than there are at speeds near vpv_{p} .
B) The Boltzmann factor is larger at vp\mathbf{v}_{\mathbf{p}} than at 2vp\mathbf{2} \mathbf{v}_{\mathbf{p}} .
C) We know that 12m[v2]avg =32kBT\frac{1}{2} m\left[v^{2}\right]_{\text {avg }}=\frac{3}{2} k_{B} T , and vp\mathrm{v}_{\mathrm{p}} is closer to [vavg 2]1/2\left[v_{\text {avg }}^{2}\right]^{1 / 2} than 2vp2 \mathrm{v}_{\mathrm{p}} is.
سؤال
How should ([v3]avg )1/3\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3} compare to ([v2]avg )1/2\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2} for an ideal gas?

A) ([v3]avg )1/3>([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}>\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
B) ([v3]avg )1/3=([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}=\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
C) ([v3]avg )1/3<([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}<\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
D) One cannot tell without careful calculation.
سؤال
Which of the speeds vv listed below is the lowest speed where the probability of a gas molecule having that speed is negligible compared to that for v=vpv=v_{p} ("negligible" meaning less than 1/1001 / 100 of its value at v=vpv=v_{p} ).

A) v0.2vpv \approx 0.2 v_{p}
B) v=2vpv=2 v_{p}
C) v=3vpv=3 v_{p}
D) v=5vpv=5 v_{p}
سؤال
How would the values of vp\mathrm{v}_{\mathrm{p}} for carbon dioxide gas compare to that of nitrogen gas at a given temperature? (Hint: Carbon dioxide gas has a molar mass of 44 g/mole44 \mathrm{~g} / \mathrm{mole} ; nitrogen has a molar mass of 28 g/mole28 \mathrm{~g} / \mathrm{mole} .)

A) vpv_{p} will be larger for carbon dioxide.
B) vpv_{p} will be larger for nitrogen.
C) vpv_{p} will be equal in both cases.
D) One does not have enough information to tell for sure.
سؤال
How does the number of molecules with speed vvPv\left\langle v_{P}\right. compare to the number having speed v>vPv>v_{P} ?

A) Fewer molecules have v>vPv>v_{P} .
B) The same number of molecules are in each range.
C) More molecules have v>vPv>v_{P} .
D) The answer depends on the temperature.
سؤال
The number of photons per second radiated by a blackbody is proportional to what power of TT ?

A) TT
B) T2T^{2}
C) T3T^{3}
D) T4T^{4}
E) T5T^{5}
سؤال
Doubling a blackbody's temperature doubles the number of photons it emits per second.
سؤال
Will a blackbody at temperature TT emit more photons per second with energy 0.5kBT0.5 k_{B} T or with energy 1.5kBT1.5 k_{B} T ? (Note: The amount of energy emitted per time is not the same as the number of photons emitted per time, though these quantities are related.)

A) It will emit more photons with the lower energy.
B) It will emit more photons with the higher energy.
C) The number of photons emitted will be the same.
D) One has no way of telling.
سؤال
Will a blackbody at temperature TT emit more photons-perBsecond with energy kBTk_{B} T or with energy 6kBT6 k_{B} T ? (Note: The amount of energy emitted per time is not the same as the number of photons emitted per time, though these quantities are related.)

A) It will emit more photons with the lower energy.
B) It will emit more photons with the higher energy.
C) The number of photons emitted will be the same.
D) One has no way of telling.
سؤال
A perfectly reflective piece of metal at room temperature would not radiate any photons,
سؤال
An object strongly reflects red light, but readily absorbs all other colors of light. Relative to the number of thermal photons of red light emitted by a black body at the same temperature TT , our object's thermal emission rate of photons of red light will be

A) enhanced.
B) Suppressed.
C) unchanged.
D) The answer depends on the value of TT .
سؤال
Suppose that a star has twice the surface temperature of the sun and also twice the radius. How many times larger is the rate at which this star emits energy compared to the rate at which the sun emits energy?

A) The star radiates at the same rate as the sun.
B) 2 times
C) 4 times
D) 8 times
E) 16 times
F) 32 times
G) 64 times
سؤال
Suppose that we double the electrical power flowing into the filament of an incandescent bulb. By what factor will the most probable photon energy εp\varepsilon_{p} increase?

A) 21/42^{1 / 4}
B) 21/32^{1 / 3}
C) 21/22^{1 / 2}
D) 2
E) 4
F) 8
G) 16
سؤال
A gas with a pressure of 100kPa100 \mathrm{kPa} is in a container that is a cube measuring 10 cm10 \mathrm{~cm} on a side. If we move one wall in 1 millimeter ( mm\mathrm{mm} ), does work flow into (A) or out of (B) the gas? What is the magnitude of W?

A) 1000 J1000 \mathrm{~J}
B) 100 J100 \mathrm{~J}
C) 10 J10 \mathrm{~J}
D) 1 J1 \mathrm{~J}
E) 0.001 J0.001 \mathrm{~J}
F) Other (specify)
سؤال
Which of the following triplets of macroscopic variables would not adequately specify a gas's macrostate?

A) U,V,TU, V, T
B) P,T,NP, T, N
C) U,N,TU, N, T
D) M,V,TM, V, T
E) M,P,VM, P, V
F) M,P,UM, P, U
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -The process  B \rightarrow C  shown is</strong> A) an isochoric process. B) an isothermal process. C) an isobaric process. D) an adiabatic process. E) an isometric process. F) none of the above. <div style=padding-top: 35px>

-The process BCB \rightarrow C shown is

A) an isochoric process.
B) an isothermal process.
C) an isobaric process.
D) an adiabatic process.
E) an isometric process.
F) none of the above.
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  A \rightarrow B  ?</strong> A)  0,-,-  B)  0,+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify) <div style=padding-top: 35px>

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process ABA \rightarrow B ?

A) 0,,0,-,-
B) 0,+,+0,+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  B \rightarrow C  ?</strong> A)  0,-,-  B)  0,+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify) <div style=padding-top: 35px>

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process BCB \rightarrow C ?

A) 0,,0,-,-
B) 0,+,+0,+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  C \rightarrow A  ?</strong> A)  0,-,-  B)  \mathbf{0},+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify) <div style=padding-top: 35px>

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process CAC \rightarrow A ?

A) 0,,0,-,-
B) 0,+,+\mathbf{0},+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -In static equilibrium, any excess charge on a conductor is uniformly spread on its surface.<div style=padding-top: 35px>

-In static equilibrium, any excess charge on a conductor is uniformly spread on its surface.
سؤال
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -When an object slides down a frictionless incline, The interaction does not change the object's momentum<div style=padding-top: 35px>

-When an object slides down a frictionless incline, The interaction does not change the object's momentum
سؤال
Suppose that a bubble of helium (a monatomic gas) rising from the bottom of the ocean expands in volume by a factor of 8 by the time it reaches the surface [where the pressure is 1 atmosphere (atm)]. Assume that the bubble rises so fast that it expands essentially adiabatically. What was the pressure on the gas at the depth where it formed (in atmospheres)?

A) 3.5 atm3.5 \mathrm{~atm}
B) 8 atm8 \mathrm{~atm}
C) 16 atm16 \mathrm{~atm}
D) 18 atm18 \mathrm{~atm}
E) 32 atm
F) Other (specify)
سؤال
If the temperature of the bubble described in problem T7T. 8 was 320 K320 \mathrm{~K} when it formed, what is its approximate final temperature when it reaches the surface?

A) 40 K40 \mathrm{~K}
B) 80 K80 \mathrm{~K}
C) 320 K320 \mathrm{~K}
D) 1280 K1280 \mathrm{~K}
E) 2560 K2560 \mathrm{~K}
F) Other (specify)
سؤال
During an adiabatic compression, does a gas's temperature increase, decrease, or remain the same?

A) It increases.
B) It decreases.
C) It remains the same.
سؤال
Does the pressure of a gas decrease more rapidly or less rapidly when expanding adiabatically than it would when expanding isothermally?

A) More rapidly.
B) Less rapidly.
C) The pressure decreases at the same rate in both cases.
D) The pressure increases in an adiabatic expansion.
E) The pressure increases in an isothermal expansion.
سؤال
Water actually contracts when it is warmed near its freezing point. In this range, is water's heat capacity at constant volume (A) greater than, (B) less than, or (C) equal to its heat capacity at constant pressure?

A) greater than
B) less than
C) equal to
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Deck 6: Some Processes Are Irreversible Thermal Physics
1
Consider a rectangular book. The book is (approximately) symmetric for rotations around an axis that goes diagonally from one corner to the other
T
2
Consider a system consisting of two Einstein solids PP and QQ in thermal contact. Assume that we know the number of atoms in each solid and ε\varepsilon . What do we know about the system if we also know the total energy in each of the two objects?

A) Its macrostate
B) Its microstate
C) Its macropartition
D) Its microstate and macropartition
E) Its macrostate and macropartition
F) Its macrostate and microstate
G) Its macrostate, microstate, and macropartition
Its macrostate and macropartition
3
Consider a system consisting of two Einstein solids PP and QQ in thermal contact. Assume that we know the number of atoms in each solid and ε\varepsilon . What do we know about the system if we also know the total energy of the combined system?

A) Its macrostate
B) Its microstate
C) Its macropartition
D) Its microstate and macropartition
E) Its macrostate and macropartition
F) Its macrostate and microstate
G) Its macrostate, microstate, and macropartition
Its macrostate
4
What is the crucial characteristic of an Einstein solid that makes it easier to analyze in the context of this chapter than most other kinds of thermodynamic systems?

A) The atoms are arranged in a regular, cubic lattice.
B) The atoms are identical.
C) Its microstates are comparatively easy to count.
D) Each atom's energy levels are equally spaced.
E) Ω(U,N)\Omega(U, N) is always reasonably small.
F) Other (specify).
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5
We can ignore an Einstein solid's zero-point energy because

A) it is zero.
B) it never changes in any thermal interaction.
C) it is insignificant compared to the solid's total energy.
D) it is just a quantum-mechanical effect.
E) other (specify).
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6
Which of the following statements is true?

A) There are always many microstates in a macrostate.
B) All accessible macrostates are equally probable.
C) All microstates of a system are equally probable.
D) All accessible macropartitions are equally probable.
E) When two objects in thermal contact are isolated from everything else, their macrostates cannot change.
F) None of the above.
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7
Suppose that we increase an NN -atom Einstein solid's value of q=U/εq=U / \varepsilon from qq to q+1q+1 . By what factor does the value of its multiplicity Ω\Omega increase? (Choose whichever result is the closest, assuming that q>>1q>>1 and N>>1N>>1 .)

A) qq
B) 3N3 N
C) q/3Nq / 3 N
D) 3N/q3 N / q
E) (q+3N)/q(q+3 N) / q
F) (q+3N)/(qN)(q+3 N) /(q N)
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8
In the situation shown in figure T2.5c, the width of the bell curve at half its peak value is 0.021U0.021 U . If we multiply NAN_{A} , NBN_{B} , and UU by a factor of 100 , then the peak's width (as you can check) is about 0.0021U0.0021 U . Suppose that we increase each solid's NN and the system's total energy by another factor of 101810^{18} to create solids containing 1/61 / 6 of a mole of atoms (still pretty small objects by everyday standards). Assuming that the trend continues, what will be the approximate width of the combined system's probability bell curve as a fraction of UU ?
 <strong>In the situation shown in figure T2.5c, the width of the bell curve at half its peak value is  0.021 U . If we multiply  N_{A} ,  N_{B} , and  U  by a factor of 100 , then the peak's width (as you can check) is about  0.0021 U . Suppose that we increase each solid's  N  and the system's total energy by another factor of  10^{18}  to create solids containing  1 / 6  of a mole of atoms (still pretty small objects by everyday standards). Assuming that the trend continues, what will be the approximate width of the combined system's probability bell curve as a fraction of  U  ?  </strong> A)  2 \times 10^{-20}  (c) 0.0 B)  2 \times 10^{-22}  Figure T2.5 C)  2 \times 10^{-10}  D)  \mathbf{2} \times \mathbf{1 0}^{-12}  E)  2 \times 10^{-40}  F)  2 \times 10^{-42}   \mathrm{T} . Some other factor (specify).

A) 2×10202 \times 10^{-20}
(c) 0.0
B) 2×10222 \times 10^{-22}
Figure T2.5
C) 2×10102 \times 10^{-10}
D) 2×1012\mathbf{2} \times \mathbf{1 0}^{-12}
E) 2×10402 \times 10^{-40}
F) 2×10422 \times 10^{-42}
T\mathrm{T} . Some other factor (specify).
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9
Suppose that you use a super-fast computer to measure a system's macropartition a billion times a second. What is the approximate probability of the least-probable macropartition that you might plausibly see in your lifetime? Select the closest response.

A) 1 chance in a million (106)\left(10^{6}\right)
B) 1 chance in a billion (109)\left(10^{9}\right)
C) 1 chance in a trillion (1012)\left(10^{12}\right)
D) 1 chance in 101510^{15}
E) 1 chance in 101810^{18}
F) 1 chance in 102110^{21}
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10
Consider the system where NA=NB=1000,U=5999εN_{A}=N_{B}=1000, U=5999 \varepsilon (see figure T2.6). Suppose that we can measure each object's energy to within 0.01U60ε0.01 U \approx 60 \varepsilon (the size of one bin). Once the system has reached a macropartition in the most probable bin, it will never spontaneously move to a macropartition outside that bin.
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11
Which of the systems listed below is the largest, having NA=NBN_{A}=N_{B} and U=6NAεU=6 N_{A} \varepsilon for which there is a better than 1 in a billion chance of seeing one or the other solid having zero energy? (Hint: Using StatMech to check cases is probably the easiest approach.)

A) NA=6N_{A}=6
B) NA=8N_{A}=8
C) NA=10N_{A}=10
D) NA=12N_{A}=12
E) NA=15N_{A}=15
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12
A hot object is placed in contact with a cold object. We observe that heat flows spontaneously from the hot object to the cold object, but not in the other direction. According to the argument in this chapter, this is so because

A) this increases the entropies of both objects.
B) this decreases the entropy of the combined system.
C) the system will tend to evolve toward macropartitions that have more microstates.
D) AA and CC
E) BB and CC
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13
Consider an object (object AA ) whose multiplicity is always 1 , no matter how much energy you put into it. If you put a very large amount of energy into such an object, and place it into thermal contact with an Einstein solid (object BB ) having the same number of atoms but much less energy, what will happen? (Hint: Imagine a macropartition table for such a pair of objects.)

A) Energy flows from AA to BB until AA has very little energy.
B) Energy flows from BB to AA until BB has very little energy.
C) Energy flows from AA to BB until both objects have the same energy.
D) No energy will flow between AA and BB at all.
E) Something else happens (describe).
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14
In a given macropartition, the total entropy of a system comprised of two or more parts is always equal to the sum of the entropies of those parts.
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15
1062/1060=10010^{62} / 10^{60}=100 . What is ln1062/\ln 10^{62} / In 106010^{60} ? (Select the closest response.)

A) 100
B) 10
C) 4.6
D) 1.0\mathbf{1 . 0}
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16
The entropy of a certain macropartition of a combined system is 102kB102 \mathrm{k}_{\mathrm{B}} . The entropy of another macropartition is 204kB204 \mathrm{k}_{\mathrm{B}} . How much more likely is the system to be in the second macropartition than the first? (Select the closest response.)

A) 2 times
B) e2=7.4\mathrm{e}^{2}=7.4 times
C) 102=10010^{2}=100 times
D) e102=2×1044\mathrm{e}^{102}=2 \times 10^{44} times
E) e102kBe0e^{102 k_{B}} \approx e^{0} ; so the two macropartitions have basically the same probability
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17
Which system has the greater entropy, a puddle of water sitting on a table next to a chaotic scattering of salt crystals or the same amount of salt dissolved in an evenly distributed way in the puddle? Be prepared to describe your reasoning.

A) The puddle and the scattered crystals.
B) The puddle with the dissolved salt.
C) Both have the same entropy.
D) One needs detailed models of water and salt to say.
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18
Object A's entropy increases quite a bit when we give it a certain tiny amount of energy, whereas object B's entropy increases by a much smaller amount with the same gift. Which has the higher temperature?

A) Object AA
B) Object BB
C) One cannot say without more information.
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19
As a normal object's thermal energy UU goes to zero, the slope of a graph of its entropy SS versus UU

A) approaches infinity.
B) approaches some positive value less than infinity.
C) approaches zero.
D) approaches some finite negative value.
E) approaches negative infinity.
F) depends entirely on the object's properties.
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20
Consider a system whose multiplicity is 1 , no matter how much energy one puts into it. What is such a system's temperature?

A) Zero
B) Positive
C) Negative
D) Undefined
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21
Suppose that an object's entropy increases from zero when its thermal energy is U=0U=0 to some maximum value when U=12Umax U=\frac{1}{2} U_{\text {max }} , and then goes back to zero when U=UmaxU=U_{\max } (as shown in the drawing below). The greatest thermal energy UU that such an object could have when in thermal equilibrium with a normal object is closest to which of the following?
 <strong>Suppose that an object's entropy increases from zero when its thermal energy is  U=0  to some maximum value when  U=\frac{1}{2} U_{\text {max }} , and then goes back to zero when  U=U_{\max }  (as shown in the drawing below). The greatest thermal energy  U  that such an object could have when in thermal equilibrium with a normal object is closest to which of the following?  </strong> A) 0 B)  \frac{1}{4} U_{\max }  C)  \frac{1}{2} U_{\max }  D)  \frac{3}{4} U_{\max }  E)  U_{\max }  F) Other (specify)

A) 0
B) 14Umax\frac{1}{4} U_{\max }
C) 12Umax\frac{1}{2} U_{\max }
D) 34Umax\frac{3}{4} U_{\max }
E) UmaxU_{\max }
F) Other (specify)
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22
If an object has a multiplicity Ω\Omega that decreases as its thermal energy UU increases, its temperature would

A) be always zero.
B) be always positive (and nonzero).
C) be negative (and nonzero).
D) increase as UU increases.
E) decrease as UU increases.
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23
Suppose that an atom has two energy levels separated by an energy difference ΔE\Delta E . When such atoms are in thermal contact with a reservoir at temperature TT , there is roughly 1 atom in the higher state for every 4 in the lower state. What is the approximate ratio of ΔE\Delta E to kBTk_{B} T ?

A) 14\frac{1}{4}
B) 4
C) In 4
D) ln4-\ln 4
E) e1/4e^{-1 / 4}
F) e4e^{-4}
G) Other (specify)
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24
Suppose that an atom has exactly two energy levels separated by an energy difference ΔE\Delta \mathrm{E} . When such atoms are in contact with a reservoir at a temperature T1T_{1} , the ratio of the number of atoms in the higher level to the number in the lower level is 14\frac{1}{4} . If we increase the temperature to T2T_{2} , the numerical value of this ratio

A) increases.
B) decreases.
C) remains the same.
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25
The quantity ZZ in the expression Pr(E)=Z1eE/kBT\operatorname{Pr}(\mathrm{E})=\mathrm{Z}^{-1} \mathrm{e}^{-\mathrm{E} / \mathrm{k}_{\mathrm{B}} \mathrm{T}} depends on the temperature TT of the reservoir.
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26
The quantity ZZ in the expression Pr(E)=Z1eE/kBT\operatorname{Pr}(E)=Z^{-1} e^{-E / k_{B} T} must be

A) always greater than 1 .
B) always less than 1 .
C) It could be either greater than or less than 1.
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27
As temperatures become large, the denominator in equation T4.36\mathrm{T} 4.36 becomes
Equation T4.36\mathrm{T} 4.36
U=3NEavg =3Nεeε/kBT1eε/kBT=3Nεeε/kBT1U=3 N E_{\text {avg }}=\frac{3 N \varepsilon e^{-\varepsilon / k_{B} T}}{1-e^{-\varepsilon / k_{B} T}}=\frac{3 N \varepsilon}{e^{\varepsilon / k_{B} T}-1}

A) very large.
B) very small.
C) approximately 1.
D) approximately -1 .
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28
Suppose that the energy difference between adjacent energy levels for an oscillator in an Einstein solid is ε=\varepsilon= 0.005eV0.005 \mathrm{eV} . At room temperature, the value of T/TET / T_{E} is

A) quite a bit smaller than 1
B) about equal to 0.5 .
C) about equal to 1 .
D) about equal to 2 .
E) quite a bit larger than 2.
F) (One doesn't have enough information to tell.)
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29
Suppose that the energy difference between adjacent energy levels for an oscillator in an Einstein solid is ε=\varepsilon= 0.005eV0.005 \mathrm{eV} . We would expect the average energy of this oscillator when it is in contact with a reservoir at room temperature to be

A) negligible.
B) smaller than 12kBT\frac{1}{2} k_{B} T .
C) about equal to 12kBT\frac{1}{2} k_{B} T .
D) about equal to kBTk_{B} T .
E) significantly larger than kBTk_{B} T .
F) One doesn't have enough information to tell.
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30
To calculate an object's heat capacity, we take its specific heat and

A) multiply by the object's mass MM .
B) divide by the object's mass MM .
C) multiply by the molar mass MAM_{A} of the object's molecules.
D) divide by the molar mass MAM_{A} of the object's molecules.
E) multiply by the mass mm of one molecule in the object.
F) divide by the mass mm of one molecule in the object.
G) do something else (specify).
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31
Suppose that the temperature TT is about TE/9T_{E} / 9 for a certain Einstein solid. The probability that an oscillator in that solid will have one unit of energy is closest to
(Hint: See equation T4.32T 4.32 for how to calculate ZZ .)
Equation T4.32:
1+x+x2+=11x1+x+x^{2}+\ldots=\frac{1}{1-x}

A) 1
B) 1/91 / 9
C) 1/811 / 81
D) 1/80001 / 8000
E) 1/1091 / 10^{9}
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32
TET_{E} is much smaller for lead than for iron. Which therefore has the greater heat capacity per atom at

-(a) T=100 KT=100 \mathrm{~K} ?

A) Lead
B) Iron
C) Both should be about the same.
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33
TET_{E} is much smaller for lead than for iron. Which therefore has the greater heat capacity per atom at

-(b) T=400 KT=400 \mathrm{~K} ?

A) Lead
B) Iron
C) Both should be about the same.
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34
At a sufficiently high temperature, an oscillator in an Einstein solid is more likely to have one unit of energy than no energy at all.
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35
Suppose that the forces holding an atom in its position in a crystal are the same for two different monatomic solids, but the mass of an atom mm is larger for solid BB than for solid AA . Which has the larger value of TET_{E} ?

A) Solid AA
B) Solid BB
C) Both have about the same value of TET_{E} .
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36
If we increase a one-dimensional container's length LL by a factor of 100 , by what factor does the value of ε/kBT\varepsilon / k_{B} T change at room temperature?

A) 10
B) 100
C) 10,000
D) 1/101 / 10
E) 1/1001 / 100
F) 1/10,0001 / 10,000
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37
Using an integral to calculate a sum over f(n)f(n) (where nn is an integer) is a good approximation when

A) the summed values f(n)f(n) are individually small.
B) the value of f(n)\boldsymbol{f}(\boldsymbol{n}) varies only very slowly with n\boldsymbol{n} .
C) the value of f(n)f(n) goes to zero as nn goes to infinity.
D) the value of f(n)f(n) goes to zero as nn goes to zero.
E) All of the conditions above are true.
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38
Which of the following energy storage modes for a gas molecule "switch on" fully at

-(a) the lowest temperature?

A) The molecule's kinetic energy
B) The molecule's rotational energy
C) The molecule's vibrational energy
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39
Which of the following energy storage modes for a gas molecule "switch on" fully at

-(b) the highest temperature?

A) The molecule's kinetic energy
B) The molecule's rotational energy
C) The molecule's vibrational energy
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40
The heat capacity of any energy storage mode with quantized energy levels goes to zero as the temperature TT goes to zero.
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41
An atom of helium can store energy by bumping an electron from its lowest orbital energy state to a higher orbital energy level. In particular, moving an electron from the lowest state to the next-lowest state would store an energy of 24.6eV24.6 \mathrm{eV} . Why can we ignore this energy storage mode when calculating the heat capacity of helium gas?

A) This mode is "frozen" out at normal temperatures.
B) Collisions between atoms can't influence the energy levels of electrons inside the atoms.
C) This storage mode is completely independent of the kinetic and/or rotational energy modes.
D) Only modes involving helium molecules count.
E) We have ignored this mode only for simplicity's sake.
F) Some other reason (specify).
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42
(a) The average xx -velocity of molecules in a container of gas at rest is zero.
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43
(b) The average molecular speed is zero.
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44
If the speed of a molecule in a container doubles (other things remaining the same), the average pressure that this molecule exerts on the container wall

A) remains the same.
B) doubles.
C) quadruples.
D) One does not have enough information to say.
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45
Suppose that when we add 20.8 J20.8 \mathrm{~J} to 1 mol of a certain gas, its temperature is observed to increase by 1 K1 \mathrm{~K} . Which of the following statements is true?

A) This gas is monatomic.
B) This gas is diatomic.
C) This gas is polyatomic.
D) One cannot determine the type of gas without information that we are not given.
E) The results described are impossible.
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46
The ideal gas model assumes that molecules have infinitesimal size. Consider one molecule bouncing around in the container. As the molecule's size increases relative to the size of the container, how will the average pressure PP that it exerts change, other things being held constant?

A) P\boldsymbol{P} increases.
B) PP does not change.
C) PP decreases.
D) One does not have enough information to say.
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47
Two identical rooms, AA and BB , are sealed except for an open doorway between them. Room AA is warmer than BB . Which room has the greater number of molecules? (Hint: How will the pressures in the two rooms compare?)

A) Room A
B) Room B
C) Both have the same number of molecules.
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48
One mole of hydrogen gas and 12\frac{1}{2} mole of helium gas are mixed in a container and maintained at a fixed temperature TT . How does the total pressure PHP_{\mathrm{H}} exerted by the hydrogen molecules compare to the total pressure PHeP_{\mathrm{He}} exerted by the helium molecules? Note that a molecule (atom) of helium has twice the mass of an H2\mathrm{H}_{2} molecule.

A) PH=2PHeP_{\mathrm{H}}=2 P_{\mathrm{He}}
B) PH=2PHeP_{\mathrm{H}}=\sqrt{2} P_{\mathrm{He}}
C) PH=PHeP_{\mathrm{H}}=P_{\mathrm{He}}
D) PH=12PHeP_{\mathrm{H}}=\sqrt{\frac{1}{2}} P_{\mathrm{He}}
E) PH=12PHeP_{\mathrm{H}}=\frac{1}{2} P_{\mathrm{He}}
F) Other (specify)
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49
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(a) the greater value of [v2]avg \left[v^{2}\right]_{\text {avg }} ,

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
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50
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(b) the greater average kinetic energy per molecule,

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
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51
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(c) the greater total thermal energy UU , and

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
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52
NN molecules of a monatomic gas AA are mixed with the same number of molecules of a diatomic gas BB in a container, and the mixture is held at a constant temperature TT (which is about equal to room temperature). The molecules of gas AA have mass mAm_{A} , and the molecules of gas BB have mass mB>mAm_{B}>m_{A} Which gas has In each case, choose from one of the four answers below.

-(d) the greater pressure PP ?

A) The quantity is greater for gas AA .
B) The quantity is greater for gas BB .
C) The quantity is the same for both gases.
D) One does not know enough to compare the quantities.
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53
When counting particle-in-a-box quantum states in three dimensions, why do we divide the "volume" of only one eighth of a full spherical shell by the "volume" per quantum state? Why not the full shell's volume?

A) Molecules in a gas can only have positive momentum components.
B) A single quantum energy state embraces both positive and negative values for each momentum component.
C) A particle's momentum magnitude must be positive.
D) The factor of 2 in the expression h/2Lh / 2 L already counts both possible momentum signs.
E) We really do include the full shell: the diagram only shows 1/81 / 8 of the shell to make it easier to draw.
F) Some other reason (specify).
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54
Physically, why is a gas molecule's speed vv more likely to be near vpv_{p} than near zero?

A) There are fewer quantum states with smaller speeds than larger speeds.
B) The Boltzmann factor has a larger value near v=vp\mathrm{v}=\mathrm{v}_{\mathrm{p}} than near v=0v=0 .
C) We know that 12m[v2]avg =32kBT\frac{1}{2} m\left[v^{2}\right]_{\text {avg }}=\frac{3}{2} k_{B} T , and vpv_{p} is closer to [vavg 2]1/2\left[v_{\text {avg }}^{2}\right]^{1 / 2} than zero is.
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55
Physically, why is a gas molecule's speed vv more likely to be near vpv_{p} than near 2vp2 v_{p} ?

A) There are fewer quantum states for larger speeds than there are at speeds near vpv_{p} .
B) The Boltzmann factor is larger at vp\mathbf{v}_{\mathbf{p}} than at 2vp\mathbf{2} \mathbf{v}_{\mathbf{p}} .
C) We know that 12m[v2]avg =32kBT\frac{1}{2} m\left[v^{2}\right]_{\text {avg }}=\frac{3}{2} k_{B} T , and vp\mathrm{v}_{\mathrm{p}} is closer to [vavg 2]1/2\left[v_{\text {avg }}^{2}\right]^{1 / 2} than 2vp2 \mathrm{v}_{\mathrm{p}} is.
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56
How should ([v3]avg )1/3\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3} compare to ([v2]avg )1/2\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2} for an ideal gas?

A) ([v3]avg )1/3>([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}>\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
B) ([v3]avg )1/3=([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}=\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
C) ([v3]avg )1/3<([v2]avg )1/2\left(\left[v^{3}\right]_{\text {avg }}\right)^{1 / 3}<\left(\left[v^{2}\right]_{\text {avg }}\right)^{1 / 2}
D) One cannot tell without careful calculation.
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57
Which of the speeds vv listed below is the lowest speed where the probability of a gas molecule having that speed is negligible compared to that for v=vpv=v_{p} ("negligible" meaning less than 1/1001 / 100 of its value at v=vpv=v_{p} ).

A) v0.2vpv \approx 0.2 v_{p}
B) v=2vpv=2 v_{p}
C) v=3vpv=3 v_{p}
D) v=5vpv=5 v_{p}
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58
How would the values of vp\mathrm{v}_{\mathrm{p}} for carbon dioxide gas compare to that of nitrogen gas at a given temperature? (Hint: Carbon dioxide gas has a molar mass of 44 g/mole44 \mathrm{~g} / \mathrm{mole} ; nitrogen has a molar mass of 28 g/mole28 \mathrm{~g} / \mathrm{mole} .)

A) vpv_{p} will be larger for carbon dioxide.
B) vpv_{p} will be larger for nitrogen.
C) vpv_{p} will be equal in both cases.
D) One does not have enough information to tell for sure.
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59
How does the number of molecules with speed vvPv\left\langle v_{P}\right. compare to the number having speed v>vPv>v_{P} ?

A) Fewer molecules have v>vPv>v_{P} .
B) The same number of molecules are in each range.
C) More molecules have v>vPv>v_{P} .
D) The answer depends on the temperature.
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60
The number of photons per second radiated by a blackbody is proportional to what power of TT ?

A) TT
B) T2T^{2}
C) T3T^{3}
D) T4T^{4}
E) T5T^{5}
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61
Doubling a blackbody's temperature doubles the number of photons it emits per second.
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62
Will a blackbody at temperature TT emit more photons per second with energy 0.5kBT0.5 k_{B} T or with energy 1.5kBT1.5 k_{B} T ? (Note: The amount of energy emitted per time is not the same as the number of photons emitted per time, though these quantities are related.)

A) It will emit more photons with the lower energy.
B) It will emit more photons with the higher energy.
C) The number of photons emitted will be the same.
D) One has no way of telling.
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63
Will a blackbody at temperature TT emit more photons-perBsecond with energy kBTk_{B} T or with energy 6kBT6 k_{B} T ? (Note: The amount of energy emitted per time is not the same as the number of photons emitted per time, though these quantities are related.)

A) It will emit more photons with the lower energy.
B) It will emit more photons with the higher energy.
C) The number of photons emitted will be the same.
D) One has no way of telling.
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64
A perfectly reflective piece of metal at room temperature would not radiate any photons,
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65
An object strongly reflects red light, but readily absorbs all other colors of light. Relative to the number of thermal photons of red light emitted by a black body at the same temperature TT , our object's thermal emission rate of photons of red light will be

A) enhanced.
B) Suppressed.
C) unchanged.
D) The answer depends on the value of TT .
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66
Suppose that a star has twice the surface temperature of the sun and also twice the radius. How many times larger is the rate at which this star emits energy compared to the rate at which the sun emits energy?

A) The star radiates at the same rate as the sun.
B) 2 times
C) 4 times
D) 8 times
E) 16 times
F) 32 times
G) 64 times
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67
Suppose that we double the electrical power flowing into the filament of an incandescent bulb. By what factor will the most probable photon energy εp\varepsilon_{p} increase?

A) 21/42^{1 / 4}
B) 21/32^{1 / 3}
C) 21/22^{1 / 2}
D) 2
E) 4
F) 8
G) 16
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68
A gas with a pressure of 100kPa100 \mathrm{kPa} is in a container that is a cube measuring 10 cm10 \mathrm{~cm} on a side. If we move one wall in 1 millimeter ( mm\mathrm{mm} ), does work flow into (A) or out of (B) the gas? What is the magnitude of W?

A) 1000 J1000 \mathrm{~J}
B) 100 J100 \mathrm{~J}
C) 10 J10 \mathrm{~J}
D) 1 J1 \mathrm{~J}
E) 0.001 J0.001 \mathrm{~J}
F) Other (specify)
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69
Which of the following triplets of macroscopic variables would not adequately specify a gas's macrostate?

A) U,V,TU, V, T
B) P,T,NP, T, N
C) U,N,TU, N, T
D) M,V,TM, V, T
E) M,P,VM, P, V
F) M,P,UM, P, U
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70
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -The process  B \rightarrow C  shown is</strong> A) an isochoric process. B) an isothermal process. C) an isobaric process. D) an adiabatic process. E) an isometric process. F) none of the above.

-The process BCB \rightarrow C shown is

A) an isochoric process.
B) an isothermal process.
C) an isobaric process.
D) an adiabatic process.
E) an isometric process.
F) none of the above.
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71
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  A \rightarrow B  ?</strong> A)  0,-,-  B)  0,+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify)

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process ABA \rightarrow B ?

A) 0,,0,-,-
B) 0,+,+0,+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
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72
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  B \rightarrow C  ?</strong> A)  0,-,-  B)  0,+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify)

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process BCB \rightarrow C ?

A) 0,,0,-,-
B) 0,+,+0,+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
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73
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
 <strong>Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -What are the signs of  Q, W , and  \Delta U  for the process  C \rightarrow A  ?</strong> A)  0,-,-  B)  \mathbf{0},+,+  C),,+- 0 D),,++ 0 E),,-+ 0 F) Other (specify)

-What are the signs of Q,WQ, W , and ΔU\Delta U for the process CAC \rightarrow A ?

A) 0,,0,-,-
B) 0,+,+\mathbf{0},+,+
C),,+- 0
D),,++ 0
E),,-+ 0
F) Other (specify)
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74
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -In static equilibrium, any excess charge on a conductor is uniformly spread on its surface.

-In static equilibrium, any excess charge on a conductor is uniformly spread on its surface.
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75
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:
Problems T7T. 3 through T7T. 7 refer to the following cyclic gas process:    -When an object slides down a frictionless incline, The interaction does not change the object's momentum

-When an object slides down a frictionless incline, The interaction does not change the object's momentum
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76
Suppose that a bubble of helium (a monatomic gas) rising from the bottom of the ocean expands in volume by a factor of 8 by the time it reaches the surface [where the pressure is 1 atmosphere (atm)]. Assume that the bubble rises so fast that it expands essentially adiabatically. What was the pressure on the gas at the depth where it formed (in atmospheres)?

A) 3.5 atm3.5 \mathrm{~atm}
B) 8 atm8 \mathrm{~atm}
C) 16 atm16 \mathrm{~atm}
D) 18 atm18 \mathrm{~atm}
E) 32 atm
F) Other (specify)
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77
If the temperature of the bubble described in problem T7T. 8 was 320 K320 \mathrm{~K} when it formed, what is its approximate final temperature when it reaches the surface?

A) 40 K40 \mathrm{~K}
B) 80 K80 \mathrm{~K}
C) 320 K320 \mathrm{~K}
D) 1280 K1280 \mathrm{~K}
E) 2560 K2560 \mathrm{~K}
F) Other (specify)
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78
During an adiabatic compression, does a gas's temperature increase, decrease, or remain the same?

A) It increases.
B) It decreases.
C) It remains the same.
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79
Does the pressure of a gas decrease more rapidly or less rapidly when expanding adiabatically than it would when expanding isothermally?

A) More rapidly.
B) Less rapidly.
C) The pressure decreases at the same rate in both cases.
D) The pressure increases in an adiabatic expansion.
E) The pressure increases in an isothermal expansion.
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80
Water actually contracts when it is warmed near its freezing point. In this range, is water's heat capacity at constant volume (A) greater than, (B) less than, or (C) equal to its heat capacity at constant pressure?

A) greater than
B) less than
C) equal to
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