Deck 20: Electrochemistry

ملء الشاشة (f)
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سؤال
Table 20.2 <strong>Table 20.2   Which of the following reactions will occur spontaneously as written?</strong> A)3Fe<sup>2+</sup> (aq) + Cr<sup>3+ </sup>(aq) → Cr (s) + 3Fe<sup>3+</sup> (aq) B)2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq) → 3Sn<sup>4+</sup> (aq) + 2Cr (s) C)Sn<sup>4+</sup> (aq) + Fe<sup>2+</sup> (s) → Sn<sup>2+</sup> (aq) + Fe (s) D)Sn<sup>2+</sup> (aq) + Fe<sup>2+</sup> (s) → Sn<sup>4+</sup> (aq) + Fe<sup>3+</sup> (aq) E)2Cr (s) + 3Fe<sup>2+</sup> (s) → 3Fe (s) + 2Cr<sup>3+</sup> (aq) <div style=padding-top: 35px>
Which of the following reactions will occur spontaneously as written?

A)3Fe2+ (aq) + Cr3+ (aq) → Cr (s) + 3Fe3+ (aq)
B)2Cr3+ (aq) + 3Sn2+ (aq) → 3Sn4+ (aq) + 2Cr (s)
C)Sn4+ (aq) + Fe2+ (s) → Sn2+ (aq) + Fe (s)
D)Sn2+ (aq) + Fe2+ (s) → Sn4+ (aq) + Fe3+ (aq)
E)2Cr (s) + 3Fe2+ (s) → 3Fe (s) + 2Cr3+ (aq)
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سؤال
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which one of the following is the best oxidizing agent?

A)H2
B)Na
C)O2
D)Li
E)Ca
سؤال
Which element is reduced in the reaction below? Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A)Fe
B)Cr
C)O
D)H
سؤال
Which transformation could take place at the anode of an electrochemical cell?

A)NO → NO3-
B)CO2 → C2O42-
C)VO2+ → VO2+
D)H2AsO4 → H3AsO3
E)O2 → H2O2
سؤال
Which element is reduced in the reaction below? Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A)Fe
B)C
C)O
D)H
E)I
سؤال
Which substance is the oxidizing agent in the following reaction? Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A)HNO3
B)S
C)NO2
D)Fe2S3
E)H2O
سؤال
The purpose of the salt bridge in an electrochemical cell is to ________.

A)maintain electrical neutrality in the half-cells via migration of ions
B)provide a source of ions to react at the anode and cathode
C)provide oxygen to facilitate oxidation at the anode
D)provide a means for electrons to travel from the anode to the cathode
E)provide a means for electrons to travel from the cathode to the anode
سؤال
Which transformation could take place at the anode of an electrochemical cell?

A)Cr2O72- → Cr2+
B)F2 to F-
C)O2 to H2O
D)HAsO2 to As
E)None of the above could take place at the anode.
سؤال
Which one of the following reactions is a redox reaction?

A)NaOH + HCl → NaCl + H2O
B)Pb2+ + 2Cl- → PbCl2
C)AgNO3 + HCl → HNO3 + AgCl
D)None of the above is a redox reaction.
سؤال
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which one of the following types of elements is most likely to be a good oxidizing agent?

A)alkali metals
B)lanthanides
C)alkaline earth elements
D)transition elements
E)halogens
سؤال
Consider an electrochemical cell based on the reaction: 2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)
Which of the following actions would change the measured cell potential?

A)increasing the pH in the cathode compartment
B)lowering the pH in the cathode compartment
C)increasing the [Sn2+] in the anode compartment
D)increasing the pressure of hydrogen gas in the cathode compartment
E)Any of the above will change the measure cell potential.
سؤال
What is the coefficient of the permanganate ion when the following equation is balanced? MnO4- + Br- → Mn2+ + Br2 (acidic solution)

A)1
B)2
C)3
D)5
E)4
سؤال
Which of the following reactions is a redox reaction? (a) K2CrO4 + BaCl2 → BaCrO4 + 2KCl
(b) Pb22+ + 2Br- → PbBr
(c) Cu + S → CuS

A)(a)only
B)(b)only
C)(c)only
D)(a)and (c)
E)(b)and (c)
سؤال
Which transformation could take place at the cathode of an electrochemical cell?

A)MnO2 → MnO4-
B)Br2 → BrO3-
C)NO → HNO2
D)HSO4- → H2SO3
E)Mn2+ → MnO4-
سؤال
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which of the halogens in Table 20.1 is the strongest oxidizing agent?

A)Cl2
B)Br2
C)F2
D)I2
E)All of the halogens have equal strength as oxidizing agents.
سؤال
Consider an electrochemical cell based on the reaction: 2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)
Which of the following actions would not change the measured cell potential?

A)lowering the pH in the cathode compartment
B)addition of more tin metal to the anode compartment
C)increasing the tin (II)ion concentration in the anode compartment
D)increasing the pressure of hydrogen gas in the cathode compartment
E)Any of the above will change the measured cell potential.
سؤال
What is the coefficient of Fe3+ when the following equation is balanced? CN- + Fe3+ → CNO- + Fe2+ (basic solution)

A)1
B)2
C)3
D)4
E)5
سؤال
Table 20.2 <strong>Table 20.2   Which of the following reactions will occur spontaneously as written?</strong> A)Sn<sup>4+</sup> (aq) + Fe<sup>3+</sup> (aq) → Sn<sup>2+</sup> (aq) + Fe<sup>2+</sup> (aq) B)3Fe (s) + 2Cr<sup>3+</sup> (aq) → 2Cr (s) + 3Fe<sup>2+</sup> (aq) C)Sn<sup>4+</sup> (aq) + Fe<sup>2+</sup> (aq) → Sn<sup>2+</sup> (aq) + Fe (s) D)3Sn<sup>4+</sup> (aq) + 2Cr (s) → 2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq) E)3Fe<sup>2+</sup> (aq) → Fe (s) + 2Fe<sup>3+</sup> (aq) <div style=padding-top: 35px>
Which of the following reactions will occur spontaneously as written?

A)Sn4+ (aq) + Fe3+ (aq) → Sn2+ (aq) + Fe2+ (aq)
B)3Fe (s) + 2Cr3+ (aq) → 2Cr (s) + 3Fe2+ (aq)
C)Sn4+ (aq) + Fe2+ (aq) → Sn2+ (aq) + Fe (s)
D)3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)
E)3Fe2+ (aq) → Fe (s) + 2Fe3+ (aq)
سؤال
What is the coefficient of the dichromate ion when the following equation is balanced? Fe2+ + Cr2O72- → Fe3+ + Cr3+ (acidic solution)

A)1
B)2
C)3
D)5
E)6
سؤال
Which element is reduced in the reaction below? I- + MnO4- + H+ → I2 + MnO2 + H2O

A)I
B)Mn
C)O
D)H
سؤال
What is the oxidation number of oxygen in H2O2?

A)-1
B)-2
C)+1
D)+2
E)-1/2
سؤال
What is the oxidation number of manganese in MnO2?

A)+3
B)+2
C)+1
D)+4
E)+7
سؤال
________ is the oxidizing agent in the reaction below. Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr2O72-
B)S2O32-
C)H+
D)Cr3+
E)S4O62-
سؤال
The gain of electrons by an element is called ________.

A)reduction
B)oxidation
C)disproportionation
D)fractionation
E)sublimation
سؤال
Cathodic protection of a metal pipe against corrosion usually entails ________.

A)attaching an active metal to make the pipe the anode in an electrochemical cell
B)coating the pipe with another metal whose standard reduction potential is less negative than that of the pipe
C)attaching an active metal to make the pipe the cathode in an electrochemical cell
D)attaching a dry cell to reduce any metal ions which might be formed
E)coating the pipe with a fluoropolymer to act as a source of fluoride ion (since the latter is so hard to oxidize)
سؤال
Which substance is the reducing agent in the reaction below? Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A)Pb
B)H2SO4
C)PbO2
D)PbSO4
E)H2O
سؤال
Which substance is serving as the reducing agent in the following reaction? 14H+ + Cr2O72- + 3Ni → 3Ni2+ + 2Cr3+ + 7H2O

A)Ni
B)H+
C)Cr2O72-
D)H2O
E)Ni2+
سؤال
What is the oxidation number of potassium in KMnO4?

A)0
B)+1
C)+2
D)-1
E)+3
سؤال
________ is reduced in the following reaction: Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62 + 7H2O

A)Cr6+
B)S2+
C)H+
D)O2-
E)S4O62-
سؤال
________ is the reducing agent in the reaction below. Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr2O72-
B)S2O32-
C)H+
D)Cr3+
E)S4O62-
سؤال
What is the cathode in the hydrogen fuel cell?

A)O2
B)KOH
C)Li
D)H2
E)Pt
سؤال
What is the cathode in an alkaline battery?

A)MnO2
B)KOH
C)Zn powder
D)Mn2O3
E)Pt
سؤال
Which substance is serving as the oxidizing agent in the following reaction? 14H+ + Cr2O72- + 3Ni → 3Ni2+ + 2Cr3+ + 7H2O

A)Ni
B)H+
C)Cr2O72-
D)H2O
E)Ni2+
سؤال
What is the oxidation number of manganese in the MnO41- ion?

A)+1
B)+2
C)+5
D)+4
E)+7
سؤال
Which substance is the oxidizing agent in the reaction below? Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A)Pb
B)H2SO4
C)PbO2
D)PbSO4
E)H2O
سؤال
What is the anode in an alkaline battery?

A)MnO2
B)KOH
C)Zn powder
D)Mn2O3
E)Pt
سؤال
In a lead-acid battery, the electrodes are consumed. In this battery, ________.

A)the anode is Pb
B)the anode is PbSO4
C)the anode is PbO2
D)the cathode is PbSO4
E)the cathode is Pb
سؤال
One of the differences between a voltaic cell and an electrolytic cell is that in an electrolytic cell, ________.

A)an electric current is produced by a chemical reaction
B)electrons flow toward the anode
C)a nonspontaneous reaction is forced to occur
D)O2 gas is produced at the cathode
E)oxidation occurs at the cathode
سؤال
________ is oxidized in the following reaction: Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr6+
B)S2+
C)H+
D)O2-
E)S4O62-
سؤال
What is the oxidation number of chromium in Cr2O72- ion?

A)+3
B)+12
C)+7
D)+6
E)+14
سؤال
In a voltaic cell, electrons flow from the ________ to the ________.

A)salt bride, anode
B)anode, salt bridge
C)cathode, anode
D)salt bridge, cathode
E)anode, cathode
سؤال
1V = ________.

A)1 amp ∙ s
B)1 J/s
C)96485 C
D)1 J/C
E)1 C/J
سؤال
The electrode at which oxidation occurs is called the ________.

A)oxidizing agent
B)cathode
C)reducing agent
D)anode
E)voltaic cell
سؤال
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. Cr (s) + 3Fe<sup>3+</sup> (aq) → 3Fe<sup>2+</sup> (aq) + Cr<sup>3+</sup> (aq)</strong> A)-1.45 B)+2.99 C)+1.51 D)+3.05 E)+1.57 <div style=padding-top: 35px>
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. Cr (s) + 3Fe3+ (aq) → 3Fe2+ (aq) + Cr3+ (aq)

A)-1.45
B)+2.99
C)+1.51
D)+3.05
E)+1.57
سؤال
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. 2Cr (s) + 3Fe<sup>2+</sup> (aq) → 3Fe (s) + 2Cr<sup>3+</sup> (aq)</strong> A)+0.30 B)+2.80 C)+3.10 D)+0.83 E)-0.16 <div style=padding-top: 35px>
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. 2Cr (s) + 3Fe2+ (aq) → 3Fe (s) + 2Cr3+ (aq)

A)+0.30
B)+2.80
C)+3.10
D)+0.83
E)-0.16
سؤال
The balanced half-reaction in which sulfate ion is reduced to sulfite ion is a ________ process.

A)four-electron
B)one-electron
C)two-electron
D)three-electron
E)six-electron
سؤال
The half-reaction occurring at the anode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A)MnO4- (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (l)
B)2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C)Fe (s) → Fe3+ (aq) + 3e-
D)Fe (s) → Fe2+ (aq) + 2e-
E)Fe2+ (aq) → Fe3+ (aq) + e-
سؤال
The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.

A)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =   <div style=padding-top: 35px>
B)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =   <div style=padding-top: 35px>
C)ΔG = -nFE
D)ΔG = -nRTF
E)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =   <div style=padding-top: 35px>
سؤال
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. 3Sn<sup>4+</sup> (aq) + 2Cr (s) → 2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq)</strong> A)+1.94 B)+0.89 C)+2.53 D)-0.59 E)-1.02 <div style=padding-top: 35px>
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. 3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)

A)+1.94
B)+0.89
C)+2.53
D)-0.59
E)-1.02
سؤال
The standard cell potential (E°cell)of the reaction below is -0.34 V. The value of ΔG° for the reaction is ________ kJ/mol. Cu (s) + 2H+ (aq) → Cu2+ (aq) + H2 (g)

A)-0.34
B)+66
C)-130
D)+130
E)none of the above
سؤال
The more ________ the value of E°red, the greater the driving force for reduction.

A)positive
B)negative
C)exothermic
D)endothermic
E)extensive
سؤال
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. Sn<sup>2+</sup> (aq) + 2Fe<sup>3+</sup> (aq) → 2Fe<sup>2+</sup> (aq) + Sn<sup>4+</sup> (aq)</strong> A)+0.46 B)+0.617 C)+1.39 D)-0.46 E)+1.21 <div style=padding-top: 35px>
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. Sn2+ (aq) + 2Fe3+ (aq) → 2Fe2+ (aq) + Sn4+ (aq)

A)+0.46
B)+0.617
C)+1.39
D)-0.46
E)+1.21
سؤال
The standard cell potential (E°cell)of the reaction below is -0.55 V. The value of ΔG° for the reaction is ________ J/mol. I2 (s) + 2Br- (aq) → 2I- (aq) + Br2 (l)

A)0.54
B)0.55
C)5.5 × 10-6
D)1.1 × 105
E)none of the above
سؤال
The reduction half reaction occurring in the standard hydrogen electrode is ________.

A)H2 (g, 1 atm) → 2H+ (aq, 1M) + 2e-
B)2H+ (aq) + 2OH- → H2O (l)
C)O2 (g) + 4H+ (aq)+ 4e- → 2H2O (l)
D)2H+ (aq, 1M) + 2e- → H2 (g, 1 atm)
E)2H+ (aq, 1M) + Cl2 (aq) → 2HCl (aq)
سؤال
________ electrons appear in the following half-reaction when it is balanced. S4O62- → 2S2O32-

A)6
B)2
C)4
D)1
E)3
سؤال
The standard cell potential (E°cell)of the reaction below is +0.126 V. The value of ΔG° for the reaction is ________ kJ/mol. Pb (s) + 2H+(aq) → Pb2+ (aq) + H2 (g)

A)-24.3
B)+24.3
C)-12.6
D)+12.6
E)-50.8
سؤال
The balanced half-reaction in which chlorine gas is reduced to the aqueous chloride ion is a ________ process.

A)one-electron
B)two-electron
C)four-electron
D)three-electron
E)six-electron
سؤال
The half-reaction occurring at the cathode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A)MnO4- (aq) + 8H+ (aq) + 5 <strong>The half-reaction occurring at the cathode in the balanced reaction shown below is ________. 3MnO<sub>4</sub><sup>-</sup> (aq) + 24H<sup>+</sup> (aq) + 5Fe (s) → 3Mn<sup>2+</sup> (aq) + 5Fe<sup>3+</sup> (aq) + 12H<sub>2</sub>O (l)</strong> A)MnO<sub>4</sub><sup>-</sup> (aq) + 8H<sup>+</sup> (aq) + 5   → Mn<sup>2+</sup> (aq) + 4H<sub>2</sub>O (l) B)2MnO<sub>4</sub><sup>-</sup> (aq) + 12H<sup>+</sup> (aq) + 6e<sup>-</sup> → 2Mn<sup>2+</sup> (aq) + 3H<sub>2</sub>O (l) C)Fe (s) → Fe<sup>3+</sup> (aq) + 3e<sup>-</sup> D)Fe (s) → Fe<sup>2+</sup> (aq) + 2e<sup>-</sup> E)Fe<sup>2+</sup> (aq) → Fe<sup>3+</sup> (aq) + e<sup>-</sup> <div style=padding-top: 35px> → Mn2+ (aq) + 4H2O (l)
B)2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C)Fe (s) → Fe3+ (aq) + 3e-
D)Fe (s) → Fe2+ (aq) + 2e-
E)Fe2+ (aq) → Fe3+ (aq) + e-
سؤال
The balanced half-reaction in which dichromate ion is reduced to chromium (III)ion is a ________ process.

A)four-electron
B)twelve-electron
C)three-electron
D)six-electron
E)two-electron
سؤال
The balanced half-reaction in which dichromate ion is reduced to chromium metal is a ________ process.

A)two-electron
B)six-electron
C)three-electron
D)four-electron
E)twelve-electron
سؤال
What is the oxidation number of phosphorous in the PH3 molecule?

A)-3
B)-4
C)-5
D)+1
E)0
سؤال
Which element is oxidized in the reaction below? I- + MnO4- + H+ → I2 + MnO2 + cO

A)I
B)Mn
C)O
D)H
سؤال
Which substance is the oxidizing agent in the reaction below? Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A)HI
B)Fe(CO)5
C)Fe(CO)4I2
D)CO
E)H2
سؤال
The standard cell potential (E° cell)for the reaction below is +0.63 V. The cell potential for this reaction is ________ V when [ Zn2+] = 3.0 M and [Pb2+] = 2.0 × 10-4 M. Pb2+ (aq) + Zn (s) → Zn2+ (aq) + Pb (s)

A)0.51
B)0.86
C)0.40
D)0.75
E)0.63
سؤال
What is the oxidation number of sulfur in the S2O32- ion?

A)+2
B)+1
C)0
D)-1
E)-2
سؤال
In the galvanic cell using the redox reaction below, the reduction half-reaction is ________. Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s)

A)Cu2+ + 2e- → Cu
B)Zn → Zn2+ + 2e-
C)Cu2+ → Cu + 2e-
D)Zn + 2e- → Zn2+
سؤال
What is the correct coefficient for the electrons in the following half-reaction: Ni6+ + ___e- → Ni

A)6
B)1
C)2
D)3
E)5
سؤال
What is the oxidation number of bromine in the HBrO molecule?

A)+1
B)+2
C)0
D)-1
E)-2
سؤال
Which element is reduced in the following reaction? Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A)N
B)S
C)H
D)O
E)NO2
سؤال
What is the oxidation number of nitrogen in the NH2OH molecule?

A)-1
B)-2
C)-3
D)0
E)+1
سؤال
A voltaic cell is constructed with two silver-silver chloride electrodes, where the half-reaction is AgCl (s) + e- → Ag (s) + Cl- (aq)E° = +0.222 V
The concentrations of chloride ion in the two compartments are 0.0100 M and 1.55 M, respectively. The cell emf is ________ V.

A)0.216
B)0.130
C)0.00143
D)34.4
E)0.228
سؤال
In the electrochemical cell using the redox reaction below, the oxidation half reaction is ________. Sn4+ (aq) + Fe (s)→ Sn2+ (aq) + Fe2+ (aq)

A)Sn4+ + 2e- → Sn2+
B)Fe → Fe2+ + 2e-
C)Sn4+ → Sn2+ + 2e-
D)Fe + 2e- → Fe2+
E)Fe + 2e- → Sn2+
سؤال
In the electrochemical cell using the redox reaction below, the cathode half-reaction is ________. 2H+ (s) + Sn (s) → Sn2+ (aq) + H2 (g)

A)2H+ + 2e- → H2
B)Sn → Sn2+ + 2e-
C)2H+ → H2 + 2e-
D)Sn + 2e- → Sn2+
E)Sn + 2e- → H2
سؤال
Galvanized iron is iron coated with ________.

A)magnesium
B)zinc
C)chromium
D)phosphate
E)iron oxide
سؤال
Which element is reduced in the reaction below? Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A)Cr
B)Fe
C)H
D)O
سؤال
The standard cell potential (E° cell)for the reaction below is +1.10 V. The cell potential for this reaction is ________ V when the concentration of [Cu2+] = 1.0 × 10-5 M and [Zn2+] = 3.0 M. Zn (s) + Cu2+ (aq) → Cu (s) + Zn2+ (aq)

A)1.42
B)1.26
C)0.94
D)0.78
E)1.10
سؤال
The standard cell potential (E°cell)of the reaction below is +1.34 V. The value of ΔG° for the reaction is ________ kJ/mol. 3 Cu (s) + 2 MnO4- (aq)+ 8H+ (aq) → 3 Cu2+ (aq)+ 2 MnO2 (s) + 4 H2O (l)

A)-24.3
B)+259
C)-259
D)+776
E)-776
سؤال
The lead-containing reactant(s)consumed during recharging of a lead-acid battery is/are ________.

A)Pb (s)only
B)PbO2 (s)only
C)PbSO4 (s)only
D)both PbO2 (s)and PbSO4 (s)
E)both Pb (s)and PbO2 (s)
سؤال
The standard cell potential (E°)of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g)
With PH2 = 1.0 atm and [Zn2+] = 1.0 M, the cell potential is 0.53 V. The concentration of H+ in the cathode compartment is ________ M.

A)1.3 × 10-4
B)1.7 × 10-8
C)1.1 × 10-2
D)7.7 × 103
E)1.3 × 10-11
سؤال
Corrosion of iron is retarded by ________.

A)the presence of salts
B)high pH conditions
C)low pH conditions
D)both the presence of salts and high pH conditions
E)both the presence of salts and low pH conditions
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Deck 20: Electrochemistry
1
Table 20.2 <strong>Table 20.2   Which of the following reactions will occur spontaneously as written?</strong> A)3Fe<sup>2+</sup> (aq) + Cr<sup>3+ </sup>(aq) → Cr (s) + 3Fe<sup>3+</sup> (aq) B)2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq) → 3Sn<sup>4+</sup> (aq) + 2Cr (s) C)Sn<sup>4+</sup> (aq) + Fe<sup>2+</sup> (s) → Sn<sup>2+</sup> (aq) + Fe (s) D)Sn<sup>2+</sup> (aq) + Fe<sup>2+</sup> (s) → Sn<sup>4+</sup> (aq) + Fe<sup>3+</sup> (aq) E)2Cr (s) + 3Fe<sup>2+</sup> (s) → 3Fe (s) + 2Cr<sup>3+</sup> (aq)
Which of the following reactions will occur spontaneously as written?

A)3Fe2+ (aq) + Cr3+ (aq) → Cr (s) + 3Fe3+ (aq)
B)2Cr3+ (aq) + 3Sn2+ (aq) → 3Sn4+ (aq) + 2Cr (s)
C)Sn4+ (aq) + Fe2+ (s) → Sn2+ (aq) + Fe (s)
D)Sn2+ (aq) + Fe2+ (s) → Sn4+ (aq) + Fe3+ (aq)
E)2Cr (s) + 3Fe2+ (s) → 3Fe (s) + 2Cr3+ (aq)
2Cr (s) + 3Fe2+ (s) → 3Fe (s) + 2Cr3+ (aq)
2
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which one of the following is the best oxidizing agent?

A)H2
B)Na
C)O2
D)Li
E)Ca
O2
3
Which element is reduced in the reaction below? Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A)Fe
B)Cr
C)O
D)H
Cr
4
Which transformation could take place at the anode of an electrochemical cell?

A)NO → NO3-
B)CO2 → C2O42-
C)VO2+ → VO2+
D)H2AsO4 → H3AsO3
E)O2 → H2O2
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5
Which element is reduced in the reaction below? Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A)Fe
B)C
C)O
D)H
E)I
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6
Which substance is the oxidizing agent in the following reaction? Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A)HNO3
B)S
C)NO2
D)Fe2S3
E)H2O
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7
The purpose of the salt bridge in an electrochemical cell is to ________.

A)maintain electrical neutrality in the half-cells via migration of ions
B)provide a source of ions to react at the anode and cathode
C)provide oxygen to facilitate oxidation at the anode
D)provide a means for electrons to travel from the anode to the cathode
E)provide a means for electrons to travel from the cathode to the anode
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8
Which transformation could take place at the anode of an electrochemical cell?

A)Cr2O72- → Cr2+
B)F2 to F-
C)O2 to H2O
D)HAsO2 to As
E)None of the above could take place at the anode.
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9
Which one of the following reactions is a redox reaction?

A)NaOH + HCl → NaCl + H2O
B)Pb2+ + 2Cl- → PbCl2
C)AgNO3 + HCl → HNO3 + AgCl
D)None of the above is a redox reaction.
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10
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which one of the following types of elements is most likely to be a good oxidizing agent?

A)alkali metals
B)lanthanides
C)alkaline earth elements
D)transition elements
E)halogens
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11
Consider an electrochemical cell based on the reaction: 2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)
Which of the following actions would change the measured cell potential?

A)increasing the pH in the cathode compartment
B)lowering the pH in the cathode compartment
C)increasing the [Sn2+] in the anode compartment
D)increasing the pressure of hydrogen gas in the cathode compartment
E)Any of the above will change the measure cell potential.
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12
What is the coefficient of the permanganate ion when the following equation is balanced? MnO4- + Br- → Mn2+ + Br2 (acidic solution)

A)1
B)2
C)3
D)5
E)4
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13
Which of the following reactions is a redox reaction? (a) K2CrO4 + BaCl2 → BaCrO4 + 2KCl
(b) Pb22+ + 2Br- → PbBr
(c) Cu + S → CuS

A)(a)only
B)(b)only
C)(c)only
D)(a)and (c)
E)(b)and (c)
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14
Which transformation could take place at the cathode of an electrochemical cell?

A)MnO2 → MnO4-
B)Br2 → BrO3-
C)NO → HNO2
D)HSO4- → H2SO3
E)Mn2+ → MnO4-
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15
Table 20.1
Half Reaction E°(V)
F2 (g) + 2e- → 2F- (aq)+2.87
Cl2 (g) + 2e- → 2Cl- (aq)+1.359
Br2 (l) + 2e- → 2Br- (aq)+1.065
O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23
Ag+ + e- → Ag (s)+0.799
Fe3+ (aq) + e- → Fe2+ (aq)+0.771
I2 (s) + 2e- → 2I- (aq)+0.536
Cu2+ + 2e- → Cu (s)+0.34
2H+ + 2e- → H2 (g) 0
Pb2+ + 2e- → Pb (s)-0.126
Ni2+ + 2e- → Ni (s)-0.28
Li+ + e- → Li (s)-3.05
Which of the halogens in Table 20.1 is the strongest oxidizing agent?

A)Cl2
B)Br2
C)F2
D)I2
E)All of the halogens have equal strength as oxidizing agents.
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16
Consider an electrochemical cell based on the reaction: 2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)
Which of the following actions would not change the measured cell potential?

A)lowering the pH in the cathode compartment
B)addition of more tin metal to the anode compartment
C)increasing the tin (II)ion concentration in the anode compartment
D)increasing the pressure of hydrogen gas in the cathode compartment
E)Any of the above will change the measured cell potential.
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17
What is the coefficient of Fe3+ when the following equation is balanced? CN- + Fe3+ → CNO- + Fe2+ (basic solution)

A)1
B)2
C)3
D)4
E)5
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18
Table 20.2 <strong>Table 20.2   Which of the following reactions will occur spontaneously as written?</strong> A)Sn<sup>4+</sup> (aq) + Fe<sup>3+</sup> (aq) → Sn<sup>2+</sup> (aq) + Fe<sup>2+</sup> (aq) B)3Fe (s) + 2Cr<sup>3+</sup> (aq) → 2Cr (s) + 3Fe<sup>2+</sup> (aq) C)Sn<sup>4+</sup> (aq) + Fe<sup>2+</sup> (aq) → Sn<sup>2+</sup> (aq) + Fe (s) D)3Sn<sup>4+</sup> (aq) + 2Cr (s) → 2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq) E)3Fe<sup>2+</sup> (aq) → Fe (s) + 2Fe<sup>3+</sup> (aq)
Which of the following reactions will occur spontaneously as written?

A)Sn4+ (aq) + Fe3+ (aq) → Sn2+ (aq) + Fe2+ (aq)
B)3Fe (s) + 2Cr3+ (aq) → 2Cr (s) + 3Fe2+ (aq)
C)Sn4+ (aq) + Fe2+ (aq) → Sn2+ (aq) + Fe (s)
D)3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)
E)3Fe2+ (aq) → Fe (s) + 2Fe3+ (aq)
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19
What is the coefficient of the dichromate ion when the following equation is balanced? Fe2+ + Cr2O72- → Fe3+ + Cr3+ (acidic solution)

A)1
B)2
C)3
D)5
E)6
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20
Which element is reduced in the reaction below? I- + MnO4- + H+ → I2 + MnO2 + H2O

A)I
B)Mn
C)O
D)H
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21
What is the oxidation number of oxygen in H2O2?

A)-1
B)-2
C)+1
D)+2
E)-1/2
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22
What is the oxidation number of manganese in MnO2?

A)+3
B)+2
C)+1
D)+4
E)+7
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23
________ is the oxidizing agent in the reaction below. Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr2O72-
B)S2O32-
C)H+
D)Cr3+
E)S4O62-
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24
The gain of electrons by an element is called ________.

A)reduction
B)oxidation
C)disproportionation
D)fractionation
E)sublimation
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25
Cathodic protection of a metal pipe against corrosion usually entails ________.

A)attaching an active metal to make the pipe the anode in an electrochemical cell
B)coating the pipe with another metal whose standard reduction potential is less negative than that of the pipe
C)attaching an active metal to make the pipe the cathode in an electrochemical cell
D)attaching a dry cell to reduce any metal ions which might be formed
E)coating the pipe with a fluoropolymer to act as a source of fluoride ion (since the latter is so hard to oxidize)
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26
Which substance is the reducing agent in the reaction below? Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A)Pb
B)H2SO4
C)PbO2
D)PbSO4
E)H2O
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27
Which substance is serving as the reducing agent in the following reaction? 14H+ + Cr2O72- + 3Ni → 3Ni2+ + 2Cr3+ + 7H2O

A)Ni
B)H+
C)Cr2O72-
D)H2O
E)Ni2+
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28
What is the oxidation number of potassium in KMnO4?

A)0
B)+1
C)+2
D)-1
E)+3
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29
________ is reduced in the following reaction: Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62 + 7H2O

A)Cr6+
B)S2+
C)H+
D)O2-
E)S4O62-
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30
________ is the reducing agent in the reaction below. Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr2O72-
B)S2O32-
C)H+
D)Cr3+
E)S4O62-
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31
What is the cathode in the hydrogen fuel cell?

A)O2
B)KOH
C)Li
D)H2
E)Pt
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32
What is the cathode in an alkaline battery?

A)MnO2
B)KOH
C)Zn powder
D)Mn2O3
E)Pt
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33
Which substance is serving as the oxidizing agent in the following reaction? 14H+ + Cr2O72- + 3Ni → 3Ni2+ + 2Cr3+ + 7H2O

A)Ni
B)H+
C)Cr2O72-
D)H2O
E)Ni2+
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34
What is the oxidation number of manganese in the MnO41- ion?

A)+1
B)+2
C)+5
D)+4
E)+7
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35
Which substance is the oxidizing agent in the reaction below? Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A)Pb
B)H2SO4
C)PbO2
D)PbSO4
E)H2O
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36
What is the anode in an alkaline battery?

A)MnO2
B)KOH
C)Zn powder
D)Mn2O3
E)Pt
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37
In a lead-acid battery, the electrodes are consumed. In this battery, ________.

A)the anode is Pb
B)the anode is PbSO4
C)the anode is PbO2
D)the cathode is PbSO4
E)the cathode is Pb
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38
One of the differences between a voltaic cell and an electrolytic cell is that in an electrolytic cell, ________.

A)an electric current is produced by a chemical reaction
B)electrons flow toward the anode
C)a nonspontaneous reaction is forced to occur
D)O2 gas is produced at the cathode
E)oxidation occurs at the cathode
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39
________ is oxidized in the following reaction: Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A)Cr6+
B)S2+
C)H+
D)O2-
E)S4O62-
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40
What is the oxidation number of chromium in Cr2O72- ion?

A)+3
B)+12
C)+7
D)+6
E)+14
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41
In a voltaic cell, electrons flow from the ________ to the ________.

A)salt bride, anode
B)anode, salt bridge
C)cathode, anode
D)salt bridge, cathode
E)anode, cathode
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42
1V = ________.

A)1 amp ∙ s
B)1 J/s
C)96485 C
D)1 J/C
E)1 C/J
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43
The electrode at which oxidation occurs is called the ________.

A)oxidizing agent
B)cathode
C)reducing agent
D)anode
E)voltaic cell
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44
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. Cr (s) + 3Fe<sup>3+</sup> (aq) → 3Fe<sup>2+</sup> (aq) + Cr<sup>3+</sup> (aq)</strong> A)-1.45 B)+2.99 C)+1.51 D)+3.05 E)+1.57
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. Cr (s) + 3Fe3+ (aq) → 3Fe2+ (aq) + Cr3+ (aq)

A)-1.45
B)+2.99
C)+1.51
D)+3.05
E)+1.57
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45
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. 2Cr (s) + 3Fe<sup>2+</sup> (aq) → 3Fe (s) + 2Cr<sup>3+</sup> (aq)</strong> A)+0.30 B)+2.80 C)+3.10 D)+0.83 E)-0.16
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. 2Cr (s) + 3Fe2+ (aq) → 3Fe (s) + 2Cr3+ (aq)

A)+0.30
B)+2.80
C)+3.10
D)+0.83
E)-0.16
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46
The balanced half-reaction in which sulfate ion is reduced to sulfite ion is a ________ process.

A)four-electron
B)one-electron
C)two-electron
D)three-electron
E)six-electron
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47
The half-reaction occurring at the anode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A)MnO4- (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (l)
B)2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C)Fe (s) → Fe3+ (aq) + 3e-
D)Fe (s) → Fe2+ (aq) + 2e-
E)Fe2+ (aq) → Fe3+ (aq) + e-
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48
The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.

A)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =
B)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =
C)ΔG = -nFE
D)ΔG = -nRTF
E)ΔG = <strong>The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.</strong> A)ΔG =   B)ΔG =   C)ΔG = -nFE D)ΔG = -nRTF E)ΔG =
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49
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. 3Sn<sup>4+</sup> (aq) + 2Cr (s) → 2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq)</strong> A)+1.94 B)+0.89 C)+2.53 D)-0.59 E)-1.02
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. 3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)

A)+1.94
B)+0.89
C)+2.53
D)-0.59
E)-1.02
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50
The standard cell potential (E°cell)of the reaction below is -0.34 V. The value of ΔG° for the reaction is ________ kJ/mol. Cu (s) + 2H+ (aq) → Cu2+ (aq) + H2 (g)

A)-0.34
B)+66
C)-130
D)+130
E)none of the above
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51
The more ________ the value of E°red, the greater the driving force for reduction.

A)positive
B)negative
C)exothermic
D)endothermic
E)extensive
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52
Table 20.2 <strong>Table 20.2   The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. Sn<sup>2+</sup> (aq) + 2Fe<sup>3+</sup> (aq) → 2Fe<sup>2+</sup> (aq) + Sn<sup>4+</sup> (aq)</strong> A)+0.46 B)+0.617 C)+1.39 D)-0.46 E)+1.21
The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. Sn2+ (aq) + 2Fe3+ (aq) → 2Fe2+ (aq) + Sn4+ (aq)

A)+0.46
B)+0.617
C)+1.39
D)-0.46
E)+1.21
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53
The standard cell potential (E°cell)of the reaction below is -0.55 V. The value of ΔG° for the reaction is ________ J/mol. I2 (s) + 2Br- (aq) → 2I- (aq) + Br2 (l)

A)0.54
B)0.55
C)5.5 × 10-6
D)1.1 × 105
E)none of the above
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54
The reduction half reaction occurring in the standard hydrogen electrode is ________.

A)H2 (g, 1 atm) → 2H+ (aq, 1M) + 2e-
B)2H+ (aq) + 2OH- → H2O (l)
C)O2 (g) + 4H+ (aq)+ 4e- → 2H2O (l)
D)2H+ (aq, 1M) + 2e- → H2 (g, 1 atm)
E)2H+ (aq, 1M) + Cl2 (aq) → 2HCl (aq)
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55
________ electrons appear in the following half-reaction when it is balanced. S4O62- → 2S2O32-

A)6
B)2
C)4
D)1
E)3
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56
The standard cell potential (E°cell)of the reaction below is +0.126 V. The value of ΔG° for the reaction is ________ kJ/mol. Pb (s) + 2H+(aq) → Pb2+ (aq) + H2 (g)

A)-24.3
B)+24.3
C)-12.6
D)+12.6
E)-50.8
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57
The balanced half-reaction in which chlorine gas is reduced to the aqueous chloride ion is a ________ process.

A)one-electron
B)two-electron
C)four-electron
D)three-electron
E)six-electron
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58
The half-reaction occurring at the cathode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A)MnO4- (aq) + 8H+ (aq) + 5 <strong>The half-reaction occurring at the cathode in the balanced reaction shown below is ________. 3MnO<sub>4</sub><sup>-</sup> (aq) + 24H<sup>+</sup> (aq) + 5Fe (s) → 3Mn<sup>2+</sup> (aq) + 5Fe<sup>3+</sup> (aq) + 12H<sub>2</sub>O (l)</strong> A)MnO<sub>4</sub><sup>-</sup> (aq) + 8H<sup>+</sup> (aq) + 5   → Mn<sup>2+</sup> (aq) + 4H<sub>2</sub>O (l) B)2MnO<sub>4</sub><sup>-</sup> (aq) + 12H<sup>+</sup> (aq) + 6e<sup>-</sup> → 2Mn<sup>2+</sup> (aq) + 3H<sub>2</sub>O (l) C)Fe (s) → Fe<sup>3+</sup> (aq) + 3e<sup>-</sup> D)Fe (s) → Fe<sup>2+</sup> (aq) + 2e<sup>-</sup> E)Fe<sup>2+</sup> (aq) → Fe<sup>3+</sup> (aq) + e<sup>-</sup> → Mn2+ (aq) + 4H2O (l)
B)2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C)Fe (s) → Fe3+ (aq) + 3e-
D)Fe (s) → Fe2+ (aq) + 2e-
E)Fe2+ (aq) → Fe3+ (aq) + e-
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59
The balanced half-reaction in which dichromate ion is reduced to chromium (III)ion is a ________ process.

A)four-electron
B)twelve-electron
C)three-electron
D)six-electron
E)two-electron
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60
The balanced half-reaction in which dichromate ion is reduced to chromium metal is a ________ process.

A)two-electron
B)six-electron
C)three-electron
D)four-electron
E)twelve-electron
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61
What is the oxidation number of phosphorous in the PH3 molecule?

A)-3
B)-4
C)-5
D)+1
E)0
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62
Which element is oxidized in the reaction below? I- + MnO4- + H+ → I2 + MnO2 + cO

A)I
B)Mn
C)O
D)H
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63
Which substance is the oxidizing agent in the reaction below? Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A)HI
B)Fe(CO)5
C)Fe(CO)4I2
D)CO
E)H2
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64
The standard cell potential (E° cell)for the reaction below is +0.63 V. The cell potential for this reaction is ________ V when [ Zn2+] = 3.0 M and [Pb2+] = 2.0 × 10-4 M. Pb2+ (aq) + Zn (s) → Zn2+ (aq) + Pb (s)

A)0.51
B)0.86
C)0.40
D)0.75
E)0.63
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65
What is the oxidation number of sulfur in the S2O32- ion?

A)+2
B)+1
C)0
D)-1
E)-2
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66
In the galvanic cell using the redox reaction below, the reduction half-reaction is ________. Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s)

A)Cu2+ + 2e- → Cu
B)Zn → Zn2+ + 2e-
C)Cu2+ → Cu + 2e-
D)Zn + 2e- → Zn2+
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67
What is the correct coefficient for the electrons in the following half-reaction: Ni6+ + ___e- → Ni

A)6
B)1
C)2
D)3
E)5
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68
What is the oxidation number of bromine in the HBrO molecule?

A)+1
B)+2
C)0
D)-1
E)-2
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69
Which element is reduced in the following reaction? Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A)N
B)S
C)H
D)O
E)NO2
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70
What is the oxidation number of nitrogen in the NH2OH molecule?

A)-1
B)-2
C)-3
D)0
E)+1
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71
A voltaic cell is constructed with two silver-silver chloride electrodes, where the half-reaction is AgCl (s) + e- → Ag (s) + Cl- (aq)E° = +0.222 V
The concentrations of chloride ion in the two compartments are 0.0100 M and 1.55 M, respectively. The cell emf is ________ V.

A)0.216
B)0.130
C)0.00143
D)34.4
E)0.228
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72
In the electrochemical cell using the redox reaction below, the oxidation half reaction is ________. Sn4+ (aq) + Fe (s)→ Sn2+ (aq) + Fe2+ (aq)

A)Sn4+ + 2e- → Sn2+
B)Fe → Fe2+ + 2e-
C)Sn4+ → Sn2+ + 2e-
D)Fe + 2e- → Fe2+
E)Fe + 2e- → Sn2+
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73
In the electrochemical cell using the redox reaction below, the cathode half-reaction is ________. 2H+ (s) + Sn (s) → Sn2+ (aq) + H2 (g)

A)2H+ + 2e- → H2
B)Sn → Sn2+ + 2e-
C)2H+ → H2 + 2e-
D)Sn + 2e- → Sn2+
E)Sn + 2e- → H2
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74
Galvanized iron is iron coated with ________.

A)magnesium
B)zinc
C)chromium
D)phosphate
E)iron oxide
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75
Which element is reduced in the reaction below? Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A)Cr
B)Fe
C)H
D)O
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76
The standard cell potential (E° cell)for the reaction below is +1.10 V. The cell potential for this reaction is ________ V when the concentration of [Cu2+] = 1.0 × 10-5 M and [Zn2+] = 3.0 M. Zn (s) + Cu2+ (aq) → Cu (s) + Zn2+ (aq)

A)1.42
B)1.26
C)0.94
D)0.78
E)1.10
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77
The standard cell potential (E°cell)of the reaction below is +1.34 V. The value of ΔG° for the reaction is ________ kJ/mol. 3 Cu (s) + 2 MnO4- (aq)+ 8H+ (aq) → 3 Cu2+ (aq)+ 2 MnO2 (s) + 4 H2O (l)

A)-24.3
B)+259
C)-259
D)+776
E)-776
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78
The lead-containing reactant(s)consumed during recharging of a lead-acid battery is/are ________.

A)Pb (s)only
B)PbO2 (s)only
C)PbSO4 (s)only
D)both PbO2 (s)and PbSO4 (s)
E)both Pb (s)and PbO2 (s)
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79
The standard cell potential (E°)of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g)
With PH2 = 1.0 atm and [Zn2+] = 1.0 M, the cell potential is 0.53 V. The concentration of H+ in the cathode compartment is ________ M.

A)1.3 × 10-4
B)1.7 × 10-8
C)1.1 × 10-2
D)7.7 × 103
E)1.3 × 10-11
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80
Corrosion of iron is retarded by ________.

A)the presence of salts
B)high pH conditions
C)low pH conditions
D)both the presence of salts and high pH conditions
E)both the presence of salts and low pH conditions
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