Deck 14: Chemical Kinetics

ملء الشاشة (f)
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سؤال
Determine the rate law and the value of k for the following reaction using the data provided. CO(g)+ Cl2(g)→ COCl2(g)[CO]i (M)[Cl2]i (M)Initial Rate (M-1s-1)
0)25 0.40 0.696
0)25 0.80 1.97
0)50 0.80 3.94

A) Rate = 11 M-3/2s-1 [CO][Cl2]3/2
B) Rate = 36 M-1.8s-1 [CO][Cl2]2.8
C) Rate = 17 M-2s-1 [CO][Cl2]2
D) Rate = 4.4 M-1/2s-1 [CO][Cl2]1/2
E) Rate = 18 M-3/2s-1 [CO]2[Cl2]1/2
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سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]0[B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
Give the characteristic of a second-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
سؤال
Give the characteristic of a first-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
سؤال
Give the characteristic of a zero-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
سؤال
A gas chromatograph can be used to determine the relative amounts of reactants and products by

A) measuring the changes in pressure as the reaction proceeds.
B) analyzing the intensity of the transmitted light.
C) separating the components of the mixture, which results in an individual peak for each component and the peaks are quantified.
D) measuring the degree of the polarization of light.
E) measuring the change in temperature of the reaction.
سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]1,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
What is the overall order of the following reaction,given the rate law? NO(g)+ O3(g)→ NO2(g)+ O2(g)Rate = k[NO][O3]

A) 1st order
B) 2nd order
C) 3rd order
D) 1 <strong>What is the overall order of the following reaction,given the rate law? NO(g)+ O<sub>3</sub>(g)→ NO<sub>2</sub>(g)+ O<sub>2</sub>(g)Rate = k[NO][O<sub>3</sub>]</strong> A) 1st order B) 2nd order C) 3rd order D) 1   order E) 0th order <div style=padding-top: 35px> order
E) 0th order
سؤال
Identify the CFC with the longest atmospheric lifetime.

A) CFC-113
B) CFC-12
C) CFC-114
D) CFC-11
E) CFC-115
سؤال
Write a balanced reaction for which the following rate relationships are true. Rate = <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> = <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> = - <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px>

A) <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> N2 + O2

<strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> N2O
B) 2 N2O → 2 N2 + O2
C) N2O → N2 + 2 O2
D) <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> N2O →
<strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <div style=padding-top: 35px> N2 + O2
E) 2 N2 + O2 → 2 N2O
سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]0,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
Determine the rate law and the value of k for the following reaction using the data provided. NO2(g)+ O3(g)→ NO3(g)+ O2(g)[NO2]i (M)[O3]i (M)Initial Rate (M-1s-1)
0)10 0.33 1.42
0)10 0.66 2.84
0)25 0.66 7.10

A) Rate = 1360 M-2.5s-1[NO2]2.5[O3]
B) Rate = 227 M-2.5s-1[NO2][O3]2.5
C) Rate = 43 M-1s-1[NO2][O3]
D) Rate = 430 M-2s-1[NO2]2[O3]
E) Rate = 130 M-2s-1[NO2][O3]2
سؤال
Determine the rate law and the value of k for the following reaction using the data provided. 2 NO(g)+ O2(g)→ 2 NO2(g)[NO]i (M)[O2]i (M)Initial Rate (M-1s-1)
0)030 0.0055 8.55 × 10-3
0)030 0.0110 1.71 × 10-2
0)060 0.0055 3.42 × 10-2

A) Rate = 57 M-1s-1[NO][O2]
B) Rate = 3.8 M-1/2s-1[NO][O2]1/2
C) Rate = 3.1 × 105 M-3s-1[NO]2[O2]2
D) Rate = 1.7 × 103 M-2s-1[NO]2[O2]
E) Rate = 9.4 × 103 M-2s-1[NO][O2]2
سؤال
Identify the CFC with the shortest atmospheric lifetime.

A) CFC-113
B) CFC-12
C) CFC-114
D) CFC-11
E) CFC-115
سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A][B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
Write a balanced reaction for which the following rate relationships are true. Rate = - <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> = <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> = <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px>

A) 2 N2O5 → 4 NO2 + O2
B) 4 NO2 + O2 2 N2O5
C) 2 N2O5 → NO2 + 4 O2
D) <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> NO2 + O2

<strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> N2O5
E) <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> N2O5

<strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <div style=padding-top: 35px> NO2 + O2
سؤال
Identify the methods used to monitor a reaction as it occurs in the reaction flask.

A) polarimeter
B) spectrometer
C) pressure measurement
D) none of the above
E) all of the above
سؤال
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]2[B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
سؤال
Determine the rate law and the value of k for the following reaction using the data provided. S2O82⁻(aq)+ 3 I⁻(aq)→ 2 SO42⁻(g)+ I3⁻(aq)[S2O82⁻]i (M)[I⁻]i (M)Initial Rate (M-1s-1)
0)30 0.42 4.54
0)44 0.42 6.65
0)44 0.21 3.33

A) Rate = 120 M-2s-1 [S2O82]2[I⁻]
B) Rate = 36 M-1s-1 [S2O82⁻][I⁻]
C) Rate = 86 M-2s-1 [S2O82⁻][I⁻]2
D) Rate = 195 M-3s-1 [S2O82⁻]2[I⁻]2
E) Rate = 23 M-1/2s-1 [S2O82⁻][I⁻]1/2
سؤال
The second-order decomposition of HI has a rate constant of 1.80 × 10-3 M-1s-1.How much HI remains after 27.3 s if the initial concentration of HI is 4.78 M?

A) 4.55 M
B) 0.258 M
C) 3.87 M
D) 2.20 M
E) 2.39 M
سؤال
The first-order decomposition of N2O5 at 328 K has a rate constant of 1.70 × 10-3 s-1.If the initial concentration of N2O5 is 2.88 M,what is the concentration of N2O5 after 12.5 minutes?

A) 0.124 M
B) 0.805 M
C) 2.82 M
D) 0.355 M
E) 0.174 M
سؤال
The first-order decomposition of N2O at 1000 K has a rate constant of 0.76 s-1.If the initial concentration of N2O is 10.9 M,what is the concentration of N2O after 9.6 s?

A) 7.4 × 10-3 M
B) 1.0 × 10-3 M
C) 1.4 × 10-3 M
D) 3.6 × 10-3 M
E) 8.7 × 10-3 M
سؤال
What data should be plotted to show that experimental concentration data fits a second-order reaction?

A) ln[reactant] vs. time
B) [reactant] vs. time
C) ln(k) vs. 1/T
D) 1/[reactant] vs. time
E) ln(k) vs. Ea
سؤال
The second-order decomposition of NO2 has a rate constant of 0.255 M-1s-1.How much NO2 decomposes in 4.00 s if the initial concentration of NO2 (1.00 L volume)is 1.33 M?

A) 1.8 mol
B) 0.85 mol
C) 0.48 mol
D) 0.77 mol
E) 0.56 mol
سؤال
The rate constant for the first-order decomposition of N2O is 3.40 s-1.What is the half-life of the decomposition?

A) 0.491 s
B) 0.204 s
C) 0.236 s
D) 0.424 s
E) 0.294 s
سؤال
Which of the following statements is FALSE?

A) The average rate of a reaction decreases during a reaction.
B) It is not possible to determine the rate of a reaction from its balanced equation.
C) The rate of zero-order reactions is not dependent on concentration.
D) The half-life of a first-order reaction is dependent on the initial concentration of reactant.
E) None of the statements is FALSE.
سؤال
What data should be plotted to show that experimental concentration data fits a first-order reaction?

A) 1/[reactant] vs. time
B) [reactant] vs. time
C) ln[reactant] vs. time
D) ln(k) vs. 1/T
E) ln(k) vs. Ea
سؤال
The first-order decomposition of cyclopropane has a rate constant of 6.7 × 10-4 s-1.If the initial concentration of cyclopropane is 1.33 M,what is the concentration of cyclopropane after 644 s?

A) 0.43 M
B) 0.15 M
C) 0.94 M
D) 0.86 M
E) 0.67 M
سؤال
Identify the rate-determining step.

A) the slowest step
B) the faster step
C) the fast step
D) always the last step
E) always the second step
سؤال
The half-life for the second-order decomposition of HI is 15.4 s when the initial concentration of HI is 0.67 M.What is the rate constant for this reaction?

A) 1.0 × 10-2 M-1s-1
B) 4.5 × 10-2 M-1s-1
C) 9.7 × 10-2 M-1s-1
D) 2.2 × 10-2 M-1s-1
E) 3.8 × 10-2 M-1s-1
سؤال
The first-order decay of radon has a half-life of 3.823 days.How many grams of radon decompose after 5.55 days if the sample initially weighs 100.0 grams?

A) 83.4 g
B) 16.6 g
C) 50.0 g
D) 36.6 g
E) 63.4 g
سؤال
Which of the following statements is FALSE?

A) The half-life of a zero-order reaction is dependent on concentration.
B) The half-life of a second-order reaction is not dependent on concentration.
C) The rate of second-order reactions is dependent on concentration.
D) The rate of a first-order reaction is dependent on concentration.
E) None of the statements is FALSE.
سؤال
The first-order rearrangement of CH3NC is measured to have a rate constant of 3.61 × 10-15 s-1 at 298 K and a rate constant of 8.66 × 10-7 s-1 at 425 K.Determine the activation energy for this reaction.

A) 160. kJ/mol
B) 240. kJ/mol
C) 417 kJ/mol
D) 127 kJ/mol
E) 338 kJ/mol
سؤال
The first-order decay of radon has a half-life of 3.823 days.How many grams of radon remain after 7.22 days if the sample initially weighs 250.0 grams?

A) 4.21 g
B) 183 g
C) 54.8 g
D) 76.3 g
E) 67.5 g
سؤال
Carbon-14 has a half-life of 5720 years and this is a first-order reaction.If a piece of wood has converted 75% of the carbon-14,then how old is it?

A) 11440 years
B) 2375 years
C) 4750 years
D) 4290 years
E) 1430 years
سؤال
What data should be plotted to show that experimental concentration data fits a zeroth-order reaction?

A) ln[reactant] vs. time
B) 1/[reactant] vs. time
C) ln(k) vs. 1/T
D) ln(k) vs. Ea
E) [reactant] vs. time
سؤال
Carbon-14 has a half-life of 5720 years and this is a first-order reaction.If a piece of wood has converted 25% of the carbon-14,then how old is it?

A) 11440 years
B) 2375 years
C) 4750 years
D) 4290 years
E) 1430 years
سؤال
The half-life for the decay of radium is 1620 years.What is the rate constant for this first-order process?

A) 4.28 × 10-4 yr-1
B) 1.12 × 10-4 yr-1
C) 2.33 × 10-4 yr-1
D) 8.91 × 10-4 yr-1
E) 6.17 × 10-4 yr-1
سؤال
For a reaction,what generally happens if the temperature is increased?

A) A decrease in k occurs, which results in a faster rate.
B) A decrease in k occurs, which results in a slower rate.
C) An increase in k occurs, which results in a faster rate.
D) An increase in k occurs, which results in a slower rate.
E) There is no change with k or the rate.
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [O2]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Identify an heterogeneous catalyst.

A) CFCs with ozone
B) Pd in H2 gas
C) KI dissolved in H2O2
D) H2SO4 with concentrated HCl
E) H3PO4 with an alcohol
سؤال
If the activation energy for a given compound is found to be 42.0 kJ/mol,with a frequency factor of 8.0 × 1010 s-1,what is the rate constant for this reaction at 298 K?

A) 2.9 × 10-4 s-1
B) 7.4 × 10-4 s-1
C) 1.4 × 109 s-1
D) 4.6 × 105 s-1
E) 3.5 × 103 s-1
سؤال
Which rate law has a molecularity of three?

A) Rate = k[A]0
B) Rate = k[A][B]2
C) Rate = k[A][B]
D) Rate = k[A]
E) Rate = k[A]2
سؤال
Biological catalysts that increase the rates of biochemical reactions are known as

A) substrates.
B) inhibitors.
C) enzymes.
D) binders.
E) trumanettes.
سؤال
If the activation energy for a given compound is found to be 103 kJ/mol,with a frequency factor of 4.0 × 1013 s-1,what is the rate constant for this reaction at 398 K?

A) 1.2 s-1
B) 8.2 s-1
C) 3.9 × 1010 s-1
D) 1.7 × 1010 s-1
E) 2.5 × 107 s-1
سؤال
In the hydrogenation of double bonds,a catalyst is needed.In the third step,the reactants react to form the product.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
سؤال
A reaction is followed and found to have a rate constant of 3.36 × 104 M-1s-1 at 344 K and a rate constant of 7.69 M-1s-1 at 219 K.Determine the activation energy for this reaction.

A) 23.8 kJ/mol
B) 42.0 kJ/mol
C) 11.5 kJ/mol
D) 12.5 kJ/mol
E) 58.2 kJ/mol
سؤال
In the hydrogenation of double bonds,a catalyst is needed.In the first step,the reactants must come into contact with a metal surface.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
سؤال
Which rate law has a molecularity of one?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]2
سؤال
In the hydrogenation of double bonds,a catalyst is needed.In the second step,the reactants diffuse on the surface until they approach each other.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
سؤال
In the hydrogenation of double bonds,a catalyst is needed.In the last step,the reactants must escape from the surface into the gas phase.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [SO2]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
A reaction is found to have an activation energy of 108 kJ/mol.If the rate constant for this reaction is 4.60 × 10-6 s-1 at 275 K,what is the rate constant at 366 K?

A) 12 s-1
B) 1.7 s-1
C) 0.58 s-1
D) 5.4 × 10-5 s-1
E) 1.9 × 10-4 s-1
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [SO3]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Which of the following statements is TRUE?

A) The rate constant does not depend on the activation energy for a reaction where the products are lower in energy than the reactants.
B) A catalyst raises the activation energy of a reaction.
C) Rate constants are temperature dependent.
D) The addition of a homogeneous catalyst does not change the activation energy of a given reaction.
E) None of the above is true.
سؤال
Which rate law has a molecularity of three?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]2
سؤال
Which rate law is unimolecular?

A) Rate = k[A]2
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]3
سؤال
Which rate law has a molecularity of two?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]3
سؤال
A reaction is found to have an activation energy of 38.0 kJ/mol.If the rate constant for this reaction is 1.60 × 102 M-1s-1 at 249 K,what is the rate constant at 436 K?

A) 2.38 × 105 M-1s-1
B) 1.26 × 103 M-1s-1
C) 7.94 × 104 M-1s-1
D) 4.20 × 105 M-1s-1
E) 3.80 × 104 M-1s-1
سؤال
What are the units of k in the following rate law? Rate = k[X] [Y]3

A) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
B) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
C) M s2
D) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
سؤال
What are the units of k in a zero-order reaction?

A) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)   <div style=padding-top: 35px>
B) M
C) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)   <div style=padding-top: 35px>
D) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)   <div style=padding-top: 35px>
سؤال
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of appearance of O2 is equal to 3.00 mol/min at a particular moment,what is the rate of disappearance of N2O5 at that moment?

A) 0.750 mol/min
B) 1.50 mol/min
C) 6.00 mol/min
D) 12.0 mol/min
سؤال
What are the units of k in a second-order reaction?

A) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
B) M2s2
C) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
D) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
سؤال
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of disappearance of N2O5 is equal to 1.80 mol/min at a particular moment,what is the rate of appearance of NO2 at that moment?

A) 0.900 mol/min
B) 1.80 mol/min
C) 3.60 mol/min
D) 7.20 mol/min
E) 1.50 mol/min
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [O2]. 2 O3(g)→ 3 O2(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [Cl2].If the rate of Cl2 loss is 4.24 × 10-2 M/s,what is the rate of formation of NOCl? 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) 4.24 × 10-2 M/s
B) 2.12 × 10-2 M/s
C) 1.06 × 10-1 M/s
D) 8.48 × 10-2 M/s
E) 1.61 × 10-2 M/s
سؤال
What are the units of k in the following rate law? Rate = k[X]2[Y]

A) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
B) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
C) M2s2
D) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)   <div style=padding-top: 35px>
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H2(g)+ Cl2(g)→ 2 HCl(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [O2].If the rate of formation of O2 is 7.78 × 10-1 M/s,what is the rate of the loss of O3? 2 O3(g)→ 3 O2(g)

A) 0.519 M/s
B) 1.56 M/s
C) 2.34 M/s
D) 1.17 M/s
E) 7.78 M/s
سؤال
What are the units of k in the following rate law? Rate = k[X][Y]

A) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
B) M s2
C) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
D) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)   <div style=padding-top: 35px>
سؤال
Determine the rate law and the value of k for the following reaction using the data provided. 2 N2O5(g)→ 4 NO2(g)+ O2(g)[N2O5]i (M)Initial Rate (M-1s-1)
0)093 4.84 × 10-4
0)084 4.37 × 10-4
0)224 1.16 × 10-3

A) Rate = 5.6 × 10-2 M-1s-1[N2O5]2
B) Rate = 6.0 × 10-1 M-2s-1[N2O5]3
C) Rate = 1.6 × 10-3 M1/2s-1[N2O5]1/2
D) Rate = 1.7 × 10-2 M-1/2s-1[N2O5]3/2
E) Rate = 5.2 × 10⁻3 s-1[N2O5]
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [H2]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of appearance of NO2 is equal to 0.560 mol/min at a particular moment,what is the rate of appearance of O2 at that moment?

A) 0.140 mol/min
B) 0.280 mol/min
C) 1.12 mol/min
D) 2.24 mol/min
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [NH3]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [O2].If the rate of O2 loss is 2.64 × 10-3 M/s,what is the rate of formation of SO3? 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) 2.64 × 10-3 M/s
B) 1.19 × 10-3 M/s
C) 1.32 × 10-3 M/s
D) 6.60 × 10-2 M/s
E) 5.28 × 10-3 M/s
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [Cl2].If the rate of disappearance of Cl2 is 4.24 × 10-2 M/s,what is the rate of formation of NO? 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) 4.24 × 10-2 M/s
B) 2.12 × 10-2 M/s
C) 1.06 × 10-1 M/s
D) 8.48 × 10-2 M/s
E) 1.61 × 10-2 M/s
سؤال
Given the following balanced equation,determine the rate of reaction with respect to [N2]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
<strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information. <div style=padding-top: 35px>
E) It is not possible to determine without more information.
سؤال
What are the units of k in a first-order reaction?

A) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)   <div style=padding-top: 35px>
B) M2s
C) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)   <div style=padding-top: 35px>
D) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)   <div style=padding-top: 35px>
E) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)   <div style=padding-top: 35px>
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Deck 14: Chemical Kinetics
1
Determine the rate law and the value of k for the following reaction using the data provided. CO(g)+ Cl2(g)→ COCl2(g)[CO]i (M)[Cl2]i (M)Initial Rate (M-1s-1)
0)25 0.40 0.696
0)25 0.80 1.97
0)50 0.80 3.94

A) Rate = 11 M-3/2s-1 [CO][Cl2]3/2
B) Rate = 36 M-1.8s-1 [CO][Cl2]2.8
C) Rate = 17 M-2s-1 [CO][Cl2]2
D) Rate = 4.4 M-1/2s-1 [CO][Cl2]1/2
E) Rate = 18 M-3/2s-1 [CO]2[Cl2]1/2
Rate = 11 M-3/2s-1 [CO][Cl2]3/2
2
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]0[B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
0.0200 M/s
3
Give the characteristic of a second-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
The rate of the reaction is proportional to the square of the concentration of the reactant.
4
Give the characteristic of a first-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
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5
Give the characteristic of a zero-order reaction having only one reactant.

A) The rate of the reaction is not proportional to the concentration of the reactant.
B) The rate of the reaction is proportional to the square of the concentration of the reactant.
C) The rate of the reaction is proportional to the square root of the concentration of the reactant.
D) The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant.
E) The rate of the reaction is directly proportional to the concentration of the reactant.
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6
A gas chromatograph can be used to determine the relative amounts of reactants and products by

A) measuring the changes in pressure as the reaction proceeds.
B) analyzing the intensity of the transmitted light.
C) separating the components of the mixture, which results in an individual peak for each component and the peaks are quantified.
D) measuring the degree of the polarization of light.
E) measuring the change in temperature of the reaction.
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7
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]1,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
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8
What is the overall order of the following reaction,given the rate law? NO(g)+ O3(g)→ NO2(g)+ O2(g)Rate = k[NO][O3]

A) 1st order
B) 2nd order
C) 3rd order
D) 1 <strong>What is the overall order of the following reaction,given the rate law? NO(g)+ O<sub>3</sub>(g)→ NO<sub>2</sub>(g)+ O<sub>2</sub>(g)Rate = k[NO][O<sub>3</sub>]</strong> A) 1st order B) 2nd order C) 3rd order D) 1   order E) 0th order order
E) 0th order
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9
Identify the CFC with the longest atmospheric lifetime.

A) CFC-113
B) CFC-12
C) CFC-114
D) CFC-11
E) CFC-115
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10
Write a balanced reaction for which the following rate relationships are true. Rate = <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O = <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O = - <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O

A) <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O N2 + O2

<strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O N2O
B) 2 N2O → 2 N2 + O2
C) N2O → N2 + 2 O2
D) <strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O N2O →
<strong>Write a balanced reaction for which the following rate relationships are true. Rate =     =   = -    </strong> A)   N<sub>2</sub> + O<sub>2 </sub>→<sub> </sub> <sub> </sub>   N<sub>2</sub>O B) 2 N<sub>2</sub>O → 2 N<sub>2</sub> + O<sub>2</sub> C) N<sub>2</sub>O → N<sub>2</sub> + 2 O<sub>2</sub> D)   N<sub>2</sub>O →   N<sub>2</sub> + O<sub>2</sub> E) 2 N<sub>2</sub> + O<sub>2 </sub>→ 2 N<sub>2</sub>O N2 + O2
E) 2 N2 + O2 → 2 N2O
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11
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]0,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
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12
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
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13
Determine the rate law and the value of k for the following reaction using the data provided. NO2(g)+ O3(g)→ NO3(g)+ O2(g)[NO2]i (M)[O3]i (M)Initial Rate (M-1s-1)
0)10 0.33 1.42
0)10 0.66 2.84
0)25 0.66 7.10

A) Rate = 1360 M-2.5s-1[NO2]2.5[O3]
B) Rate = 227 M-2.5s-1[NO2][O3]2.5
C) Rate = 43 M-1s-1[NO2][O3]
D) Rate = 430 M-2s-1[NO2]2[O3]
E) Rate = 130 M-2s-1[NO2][O3]2
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14
Determine the rate law and the value of k for the following reaction using the data provided. 2 NO(g)+ O2(g)→ 2 NO2(g)[NO]i (M)[O2]i (M)Initial Rate (M-1s-1)
0)030 0.0055 8.55 × 10-3
0)030 0.0110 1.71 × 10-2
0)060 0.0055 3.42 × 10-2

A) Rate = 57 M-1s-1[NO][O2]
B) Rate = 3.8 M-1/2s-1[NO][O2]1/2
C) Rate = 3.1 × 105 M-3s-1[NO]2[O2]2
D) Rate = 1.7 × 103 M-2s-1[NO]2[O2]
E) Rate = 9.4 × 103 M-2s-1[NO][O2]2
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15
Identify the CFC with the shortest atmospheric lifetime.

A) CFC-113
B) CFC-12
C) CFC-114
D) CFC-11
E) CFC-115
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16
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A][B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
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17
Write a balanced reaction for which the following rate relationships are true. Rate = - <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> = <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> = <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub>

A) 2 N2O5 → 4 NO2 + O2
B) 4 NO2 + O2 2 N2O5
C) 2 N2O5 → NO2 + 4 O2
D) <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> NO2 + O2

<strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> N2O5
E) <strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> N2O5

<strong>Write a balanced reaction for which the following rate relationships are true. Rate = -     =     =  </strong> A) 2 N<sub>2</sub>O<sub>5</sub> → 4 NO<sub>2</sub> + O<sub>2</sub> B) 4 NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub>2 N<sub>2</sub>O<sub>5</sub> C) 2 N<sub>2</sub>O<sub>5</sub> → NO<sub>2</sub> + 4 O<sub>2</sub> D)   NO<sub>2</sub> + O<sub>2 </sub> →<sub> </sub> <sub> </sub>   N<sub>2</sub>O<sub>5</sub> E)   N<sub>2</sub>O<sub>5 </sub>→<sub> </sub> <sub> </sub>   NO<sub>2</sub> + O<sub>2</sub> NO2 + O2
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18
Identify the methods used to monitor a reaction as it occurs in the reaction flask.

A) polarimeter
B) spectrometer
C) pressure measurement
D) none of the above
E) all of the above
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19
A rate is equal to 0.0200 M/s.If [A] = 0.100 M and rate = k[A]2[B]2,what is the new rate if the concentration of [A] is increased to 0.200 M?

A) 0.0200 M/s
B) 0.0400 M/s
C) 0.0600 M/s
D) 0.0800 M/s
E) 0.100 M/s
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20
Determine the rate law and the value of k for the following reaction using the data provided. S2O82⁻(aq)+ 3 I⁻(aq)→ 2 SO42⁻(g)+ I3⁻(aq)[S2O82⁻]i (M)[I⁻]i (M)Initial Rate (M-1s-1)
0)30 0.42 4.54
0)44 0.42 6.65
0)44 0.21 3.33

A) Rate = 120 M-2s-1 [S2O82]2[I⁻]
B) Rate = 36 M-1s-1 [S2O82⁻][I⁻]
C) Rate = 86 M-2s-1 [S2O82⁻][I⁻]2
D) Rate = 195 M-3s-1 [S2O82⁻]2[I⁻]2
E) Rate = 23 M-1/2s-1 [S2O82⁻][I⁻]1/2
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21
The second-order decomposition of HI has a rate constant of 1.80 × 10-3 M-1s-1.How much HI remains after 27.3 s if the initial concentration of HI is 4.78 M?

A) 4.55 M
B) 0.258 M
C) 3.87 M
D) 2.20 M
E) 2.39 M
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22
The first-order decomposition of N2O5 at 328 K has a rate constant of 1.70 × 10-3 s-1.If the initial concentration of N2O5 is 2.88 M,what is the concentration of N2O5 after 12.5 minutes?

A) 0.124 M
B) 0.805 M
C) 2.82 M
D) 0.355 M
E) 0.174 M
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23
The first-order decomposition of N2O at 1000 K has a rate constant of 0.76 s-1.If the initial concentration of N2O is 10.9 M,what is the concentration of N2O after 9.6 s?

A) 7.4 × 10-3 M
B) 1.0 × 10-3 M
C) 1.4 × 10-3 M
D) 3.6 × 10-3 M
E) 8.7 × 10-3 M
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24
What data should be plotted to show that experimental concentration data fits a second-order reaction?

A) ln[reactant] vs. time
B) [reactant] vs. time
C) ln(k) vs. 1/T
D) 1/[reactant] vs. time
E) ln(k) vs. Ea
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25
The second-order decomposition of NO2 has a rate constant of 0.255 M-1s-1.How much NO2 decomposes in 4.00 s if the initial concentration of NO2 (1.00 L volume)is 1.33 M?

A) 1.8 mol
B) 0.85 mol
C) 0.48 mol
D) 0.77 mol
E) 0.56 mol
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26
The rate constant for the first-order decomposition of N2O is 3.40 s-1.What is the half-life of the decomposition?

A) 0.491 s
B) 0.204 s
C) 0.236 s
D) 0.424 s
E) 0.294 s
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27
Which of the following statements is FALSE?

A) The average rate of a reaction decreases during a reaction.
B) It is not possible to determine the rate of a reaction from its balanced equation.
C) The rate of zero-order reactions is not dependent on concentration.
D) The half-life of a first-order reaction is dependent on the initial concentration of reactant.
E) None of the statements is FALSE.
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28
What data should be plotted to show that experimental concentration data fits a first-order reaction?

A) 1/[reactant] vs. time
B) [reactant] vs. time
C) ln[reactant] vs. time
D) ln(k) vs. 1/T
E) ln(k) vs. Ea
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29
The first-order decomposition of cyclopropane has a rate constant of 6.7 × 10-4 s-1.If the initial concentration of cyclopropane is 1.33 M,what is the concentration of cyclopropane after 644 s?

A) 0.43 M
B) 0.15 M
C) 0.94 M
D) 0.86 M
E) 0.67 M
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30
Identify the rate-determining step.

A) the slowest step
B) the faster step
C) the fast step
D) always the last step
E) always the second step
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31
The half-life for the second-order decomposition of HI is 15.4 s when the initial concentration of HI is 0.67 M.What is the rate constant for this reaction?

A) 1.0 × 10-2 M-1s-1
B) 4.5 × 10-2 M-1s-1
C) 9.7 × 10-2 M-1s-1
D) 2.2 × 10-2 M-1s-1
E) 3.8 × 10-2 M-1s-1
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32
The first-order decay of radon has a half-life of 3.823 days.How many grams of radon decompose after 5.55 days if the sample initially weighs 100.0 grams?

A) 83.4 g
B) 16.6 g
C) 50.0 g
D) 36.6 g
E) 63.4 g
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33
Which of the following statements is FALSE?

A) The half-life of a zero-order reaction is dependent on concentration.
B) The half-life of a second-order reaction is not dependent on concentration.
C) The rate of second-order reactions is dependent on concentration.
D) The rate of a first-order reaction is dependent on concentration.
E) None of the statements is FALSE.
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34
The first-order rearrangement of CH3NC is measured to have a rate constant of 3.61 × 10-15 s-1 at 298 K and a rate constant of 8.66 × 10-7 s-1 at 425 K.Determine the activation energy for this reaction.

A) 160. kJ/mol
B) 240. kJ/mol
C) 417 kJ/mol
D) 127 kJ/mol
E) 338 kJ/mol
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35
The first-order decay of radon has a half-life of 3.823 days.How many grams of radon remain after 7.22 days if the sample initially weighs 250.0 grams?

A) 4.21 g
B) 183 g
C) 54.8 g
D) 76.3 g
E) 67.5 g
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36
Carbon-14 has a half-life of 5720 years and this is a first-order reaction.If a piece of wood has converted 75% of the carbon-14,then how old is it?

A) 11440 years
B) 2375 years
C) 4750 years
D) 4290 years
E) 1430 years
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37
What data should be plotted to show that experimental concentration data fits a zeroth-order reaction?

A) ln[reactant] vs. time
B) 1/[reactant] vs. time
C) ln(k) vs. 1/T
D) ln(k) vs. Ea
E) [reactant] vs. time
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38
Carbon-14 has a half-life of 5720 years and this is a first-order reaction.If a piece of wood has converted 25% of the carbon-14,then how old is it?

A) 11440 years
B) 2375 years
C) 4750 years
D) 4290 years
E) 1430 years
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39
The half-life for the decay of radium is 1620 years.What is the rate constant for this first-order process?

A) 4.28 × 10-4 yr-1
B) 1.12 × 10-4 yr-1
C) 2.33 × 10-4 yr-1
D) 8.91 × 10-4 yr-1
E) 6.17 × 10-4 yr-1
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40
For a reaction,what generally happens if the temperature is increased?

A) A decrease in k occurs, which results in a faster rate.
B) A decrease in k occurs, which results in a slower rate.
C) An increase in k occurs, which results in a faster rate.
D) An increase in k occurs, which results in a slower rate.
E) There is no change with k or the rate.
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41
Given the following balanced equation,determine the rate of reaction with respect to [O2]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -   D) Rate = -   E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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42
Identify an heterogeneous catalyst.

A) CFCs with ozone
B) Pd in H2 gas
C) KI dissolved in H2O2
D) H2SO4 with concentrated HCl
E) H3PO4 with an alcohol
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43
If the activation energy for a given compound is found to be 42.0 kJ/mol,with a frequency factor of 8.0 × 1010 s-1,what is the rate constant for this reaction at 298 K?

A) 2.9 × 10-4 s-1
B) 7.4 × 10-4 s-1
C) 1.4 × 109 s-1
D) 4.6 × 105 s-1
E) 3.5 × 103 s-1
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44
Which rate law has a molecularity of three?

A) Rate = k[A]0
B) Rate = k[A][B]2
C) Rate = k[A][B]
D) Rate = k[A]
E) Rate = k[A]2
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45
Biological catalysts that increase the rates of biochemical reactions are known as

A) substrates.
B) inhibitors.
C) enzymes.
D) binders.
E) trumanettes.
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46
If the activation energy for a given compound is found to be 103 kJ/mol,with a frequency factor of 4.0 × 1013 s-1,what is the rate constant for this reaction at 398 K?

A) 1.2 s-1
B) 8.2 s-1
C) 3.9 × 1010 s-1
D) 1.7 × 1010 s-1
E) 2.5 × 107 s-1
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47
In the hydrogenation of double bonds,a catalyst is needed.In the third step,the reactants react to form the product.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
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48
A reaction is followed and found to have a rate constant of 3.36 × 104 M-1s-1 at 344 K and a rate constant of 7.69 M-1s-1 at 219 K.Determine the activation energy for this reaction.

A) 23.8 kJ/mol
B) 42.0 kJ/mol
C) 11.5 kJ/mol
D) 12.5 kJ/mol
E) 58.2 kJ/mol
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49
In the hydrogenation of double bonds,a catalyst is needed.In the first step,the reactants must come into contact with a metal surface.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
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50
Which rate law has a molecularity of one?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]2
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51
In the hydrogenation of double bonds,a catalyst is needed.In the second step,the reactants diffuse on the surface until they approach each other.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
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52
In the hydrogenation of double bonds,a catalyst is needed.In the last step,the reactants must escape from the surface into the gas phase.This step is known as

A) adsorption.
B) diffusion.
C) reaction.
D) desorption.
E) none of the above
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53
Given the following balanced equation,determine the rate of reaction with respect to [SO2]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
B) Rate = <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>2</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate =     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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54
A reaction is found to have an activation energy of 108 kJ/mol.If the rate constant for this reaction is 4.60 × 10-6 s-1 at 275 K,what is the rate constant at 366 K?

A) 12 s-1
B) 1.7 s-1
C) 0.58 s-1
D) 5.4 × 10-5 s-1
E) 1.9 × 10-4 s-1
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55
Given the following balanced equation,determine the rate of reaction with respect to [SO3]. 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [SO<sub>3</sub>]. 2 SO<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2 SO<sub>3</sub>(g)</strong> A) Rate = -     B) Rate = +     C) Rate = +   D) Rate = -   E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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56
Which of the following statements is TRUE?

A) The rate constant does not depend on the activation energy for a reaction where the products are lower in energy than the reactants.
B) A catalyst raises the activation energy of a reaction.
C) Rate constants are temperature dependent.
D) The addition of a homogeneous catalyst does not change the activation energy of a given reaction.
E) None of the above is true.
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57
Which rate law has a molecularity of three?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]2
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58
Which rate law is unimolecular?

A) Rate = k[A]2
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]3
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59
Which rate law has a molecularity of two?

A) Rate = k[A]0
B) Rate = k[A][B]
C) Rate = k[A][B][C]
D) Rate = k[A]
E) Rate = k[A]3
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60
A reaction is found to have an activation energy of 38.0 kJ/mol.If the rate constant for this reaction is 1.60 × 102 M-1s-1 at 249 K,what is the rate constant at 436 K?

A) 2.38 × 105 M-1s-1
B) 1.26 × 103 M-1s-1
C) 7.94 × 104 M-1s-1
D) 4.20 × 105 M-1s-1
E) 3.80 × 104 M-1s-1
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61
What are the units of k in the following rate law? Rate = k[X] [Y]3

A) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)
B) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)
C) M s2
D) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)
E) <strong>What are the units of k in the following rate law? Rate = k[X]<sup> </sup>[Y]<sup>3</sup></strong> A)   B)   C) M<sup> </sup>s<sup>2</sup> D)   E)
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62
What are the units of k in a zero-order reaction?

A) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)
B) M
C) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)
D) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)
E) <strong>What are the units of k in a zero-order reaction?</strong> A)   B) M C)   D)   E)
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63
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of appearance of O2 is equal to 3.00 mol/min at a particular moment,what is the rate of disappearance of N2O5 at that moment?

A) 0.750 mol/min
B) 1.50 mol/min
C) 6.00 mol/min
D) 12.0 mol/min
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64
What are the units of k in a second-order reaction?

A) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)
B) M2s2
C) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)
D) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)
E) <strong>What are the units of k in a second-order reaction?</strong> A)   B) M<sup>2</sup>s<sup>2</sup> C)   D)   E)
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65
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of disappearance of N2O5 is equal to 1.80 mol/min at a particular moment,what is the rate of appearance of NO2 at that moment?

A) 0.900 mol/min
B) 1.80 mol/min
C) 3.60 mol/min
D) 7.20 mol/min
E) 1.50 mol/min
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66
Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NOCl]. 2 NO(g)+ Cl<sub>2</sub>(g)→ 2 NOCl(g)</strong> A) Rate = -     B) Rate = +     C) Rate = -     D) Rate = -   E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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67
Given the following balanced equation,determine the rate of reaction with respect to [O2]. 2 O3(g)→ 3 O2(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
D) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [O<sub>2</sub>]. 2 O<sub>3</sub>(g)→ 3 O<sub>2</sub>(g)</strong> A) Rate = +   B) Rate = -     C) Rate = +     D) Rate = +   E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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68
Given the following balanced equation,determine the rate of reaction with respect to [Cl2].If the rate of Cl2 loss is 4.24 × 10-2 M/s,what is the rate of formation of NOCl? 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) 4.24 × 10-2 M/s
B) 2.12 × 10-2 M/s
C) 1.06 × 10-1 M/s
D) 8.48 × 10-2 M/s
E) 1.61 × 10-2 M/s
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69
What are the units of k in the following rate law? Rate = k[X]2[Y]

A) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)
B) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)
C) M2s2
D) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)
E) <strong>What are the units of k in the following rate law? Rate = k[X]<sup>2</sup>[Y]<sup> </sup></strong> A)   B)   C) M<sup>2</sup>s<sup>2</sup> D)   E)
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70
Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H2(g)+ Cl2(g)→ 2 HCl(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
C) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
D) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [HCl]. H<sub>2</sub>(g)+ Cl<sub>2</sub>(g)→ 2 HCl(g)</strong> A) Rate = +   B) Rate = -   C) Rate = -     D) Rate = +     E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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71
Given the following balanced equation,determine the rate of reaction with respect to [O2].If the rate of formation of O2 is 7.78 × 10-1 M/s,what is the rate of the loss of O3? 2 O3(g)→ 3 O2(g)

A) 0.519 M/s
B) 1.56 M/s
C) 2.34 M/s
D) 1.17 M/s
E) 7.78 M/s
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72
What are the units of k in the following rate law? Rate = k[X][Y]

A) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)
B) M s2
C) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)
D) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)
E) <strong>What are the units of k in the following rate law? Rate = k[X][Y]</strong> A)   B) M<sup> </sup>s<sup>2</sup> C)   D)   E)
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73
Determine the rate law and the value of k for the following reaction using the data provided. 2 N2O5(g)→ 4 NO2(g)+ O2(g)[N2O5]i (M)Initial Rate (M-1s-1)
0)093 4.84 × 10-4
0)084 4.37 × 10-4
0)224 1.16 × 10-3

A) Rate = 5.6 × 10-2 M-1s-1[N2O5]2
B) Rate = 6.0 × 10-1 M-2s-1[N2O5]3
C) Rate = 1.6 × 10-3 M1/2s-1[N2O5]1/2
D) Rate = 1.7 × 10-2 M-1/2s-1[N2O5]3/2
E) Rate = 5.2 × 10⁻3 s-1[N2O5]
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74
Given the following balanced equation,determine the rate of reaction with respect to [H2]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
B) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [H<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = +     C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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75
The decomposition of dinitrogen pentoxide is described by the following chemical equation 2 N2O5(g)→ 4 NO2(g)+ O2(g)
If the rate of appearance of NO2 is equal to 0.560 mol/min at a particular moment,what is the rate of appearance of O2 at that moment?

A) 0.140 mol/min
B) 0.280 mol/min
C) 1.12 mol/min
D) 2.24 mol/min
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76
Given the following balanced equation,determine the rate of reaction with respect to [NH3]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [NH<sub>3</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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77
Given the following balanced equation,determine the rate of reaction with respect to [O2].If the rate of O2 loss is 2.64 × 10-3 M/s,what is the rate of formation of SO3? 2 SO2(g)+ O2(g)→ 2 SO3(g)

A) 2.64 × 10-3 M/s
B) 1.19 × 10-3 M/s
C) 1.32 × 10-3 M/s
D) 6.60 × 10-2 M/s
E) 5.28 × 10-3 M/s
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78
Given the following balanced equation,determine the rate of reaction with respect to [Cl2].If the rate of disappearance of Cl2 is 4.24 × 10-2 M/s,what is the rate of formation of NO? 2 NO(g)+ Cl2(g)→ 2 NOCl(g)

A) 4.24 × 10-2 M/s
B) 2.12 × 10-2 M/s
C) 1.06 × 10-1 M/s
D) 8.48 × 10-2 M/s
E) 1.61 × 10-2 M/s
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79
Given the following balanced equation,determine the rate of reaction with respect to [N2]. N2(g)+ 3 H2(g)→ 2 NH3(g)

A) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
B) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
C) Rate = + <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
D) Rate = - <strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
<strong>Given the following balanced equation,determine the rate of reaction with respect to [N<sub>2</sub>]. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)</strong> A) Rate = +   B) Rate = -   C) Rate = +     D) Rate = -     E) It is not possible to determine without more information.
E) It is not possible to determine without more information.
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80
What are the units of k in a first-order reaction?

A) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)
B) M2s
C) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)
D) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)
E) <strong>What are the units of k in a first-order reaction?</strong> A)   B) M<sup>2</sup>s<sup> </sup> C)   D)   E)
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