Deck 19: Electrochemistry

ملء الشاشة (f)
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سؤال
What element is being oxidized in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2-(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
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سؤال
What element is being reduced in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
سؤال
What element is being reduced in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
سؤال
Identify the location of oxidation in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
سؤال
What element is being oxidized in the following redox reaction? Cr(OH)4-(aq)+ ClO-(aq)→ CrO42-(aq)+ Cl-(aq)

A) Cr
B) O
C) H
D) Cl
سؤال
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
سؤال
What element is being oxidized in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
سؤال
Identify the location of reduction in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
سؤال
What element is being oxidized in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
سؤال
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)

A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
سؤال
In a hydrogen-oxygen fuel cell,

A) neither oxygen or hydrogen atoms are oxidized or reduced.
B) both oxygen and hydrogen atoms are oxidized.
C) both oxygen and hydrogen atoms are reduced.
D) oxygen atoms are reduced and hydrogen atoms are oxidized.
E) oxygen atoms are oxidized and hydrogen atoms are reduced.
سؤال
What element is being reduced in the following redox reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr
B) O
C) H
D) Cl
سؤال
In a hydrogen-oxygen fuel cell,

A) no transfer of electrons occurs.
B) both oxygen and hydrogen atoms lose electrons.
C) both oxygen and hydrogen atoms gain electrons.
D) oxygen atoms lose electrons and hydrogen atoms gain electrons.
E) oxygen atoms gain electrons and hydrogen atoms lose electrons.
سؤال
What element is being reduced in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
سؤال
In a voltaic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
سؤال
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
سؤال
Define a salt bridge.

A) A pathway composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counterions can flow between the half-cells without the solutions in the half-cell totally mixing.
سؤال
A voltaic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
سؤال
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Br2 and OH⁻ in the balanced reaction? Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)

A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
سؤال
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4 and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
سؤال
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
سؤال
Determine the cell notation for the redox reaction given below. 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)

A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe(s) ∣ Fe3+(aq)
B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe3+(aq) Fe(s)
C) Fe3+(aq) ∣ Fe(s) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Cl⁻(aq) ∣ Cl2(g) ∣ Pt
D) Fe(s) ∣ Cl2(g) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe3+(aq) ∣ Cl⁻(aq) ∣ Pt
E) Fe(s) ∣ Fe3+(aq) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Cl2(g) ∣ Cl⁻(aq) ∣ Pt
سؤال
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
سؤال
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V

A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,1.8 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,1.8 M)   Ag<sup>+</sup>(aq,0.055 M)∣ Ag(s)</strong> A) -0.94 V B) -0.85 V C) +1.02 V D) +0.98 V E) +0.86 V <div style=padding-top: 35px> Ag+(aq,0.055 M)∣ Ag(s)

A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M)   Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)</strong> A) +1.01 V B) -0.83 V C) +1.31 V D) +0.01 V E) -0.66 V <div style=padding-top: 35px> Ag+(aq,2.7 M)∣ Ag(s)

A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
سؤال
What statement is NOT true about standard electrode potentials?

A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
سؤال
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
سؤال
Identify the characteristics of a spontaneous reaction.

A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
سؤال
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V

A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
سؤال
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2 K(s)+ I2(s)→ 2 K⁺(aq)+ 2 I⁻(aq)
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V

A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
سؤال
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq)
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e- → 2 Br-(aq)E° = +1.07 V

A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
سؤال
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V

A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
سؤال
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.3 × 10-16
E) 1.1 × 10-8
سؤال
Which of the following reactions would have the smallest value of K at 298 K?

A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
سؤال
Identify a characteristic that does not describe a standard hydrogen electrode.

A) 1 M HCl solution with hydrogen gas
B) 1 atmosphere
C) zinc electrode
D) inert platinum electrode
E) potential of zero
سؤال
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) 3.5 × 10-59
B) 1.1 × 1017
C) 2.4 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
سؤال
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe<sup>3+</sup>(aq,0.0011 M)   Fe<sup>3+</sup>(aq,2.33 M)∣ Fe(s)</strong> A) +0.066 V B) -0.036 V C) 0.00 V D) -0.099 V E) +0.20 V <div style=padding-top: 35px> Fe3+(aq,2.33 M)∣ Fe(s)

A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg2+(aq,2.74 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg<sup>2+</sup>(aq,2.74 M)   Cu<sup>2+</sup>(aq,0.0033 M)∣ Cu(s)</strong> A) -2.80 V B) +2.62 V C) +2.71 V D) +2.12 V E) -1.94 V <div style=padding-top: 35px> Cu2+(aq,0.0033 M)∣ Cu(s)

A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
سؤال
In an electrolytic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
سؤال
Identify the battery that is in most automobiles.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
سؤال
What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current? Ag⁺(aq)+ e⁻ → Ag(s)

A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
سؤال
What is the reaction at the cathode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
سؤال
What is the reaction at the anode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
سؤال
In a nickel-cadmium battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
سؤال
An electrolytic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu<sup>2+</sup>(aq,0.0032 M)   Cu<sup>2+</sup>(aq,4.48 M)∣ Cu(s)</strong> A) 0.00 V B) +0.093 V C) +0.34 V D) +0.186 V E) +0.052 V <div style=padding-top: 35px> Cu2+(aq,4.48 M)∣ Cu(s)

A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
سؤال
Identify the battery that is used as a common flashlight battery.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
سؤال
What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
سؤال
Describe how water can be a good conductor of current.

A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
سؤال
In an alkaline battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
سؤال
Identify the battery type that has a high overcharge tolerance.

A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
سؤال
In a lead-acid storage battery,PbO2 is reduced to

A) Pb.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
سؤال
In a dry-cell battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
سؤال
Identify the components of a fuel cell.

A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
سؤال
Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
سؤال
In a lead-acid storage battery,Pb is oxidized to

A) PbO2.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
سؤال
In a nickel-metal hydride battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
سؤال
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al<sup>3+</sup>(aq,0.115 M)   Al<sup>3+</sup>(aq,3.89 M)∣ Al(s)</strong> A) +1.66 V B) +0.060 V C) 0.00 V D) +0.090 V E) +0.030 V <div style=padding-top: 35px> Al3+(aq,3.89 M)∣ Al(s)

A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
سؤال
Balance the following reaction in KOH.What are the coefficients in front of C9H20O2 and KMnO4 in the balanced reaction? C9H20O2(aq)+ KMnO4(aq)→ C9H14O4K2(aq)+ MnO2(aq)

A) C9H20O2 = 3, KMnO4 = 8
B) C9H20O2 = 3, KMnO4 = 4
C) C9H20O2 = 8, KMnO4 = 4
D) C9H20O2 = 2, KMnO4 = 8
E) C9H20O2 = 3, KMnO4 = 2
سؤال
What element is being oxidized in the following redox reaction? C10H22O2(aq)+ KMnO4(aq)→ C10H16O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
سؤال
What element is being oxidized in the following redox reaction? Mg2+(aq)+ NH4+(aq)→ Mg(s)+ NO3⁻(aq)

A) Mg
B) N
C) H
D) O
سؤال
What element is being reduced in the following redox reaction? C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
سؤال
A sacrificial electrode is composed of a metal that

A) does not serve as a protective coating.
B) reduces more easily than iron.
C) has an oxide that is crumbly when formed.
D) oxidizes more easily than iron.
E) oxidizes the same as iron.
سؤال
Aluminum is quickly oxidized in the air to form

A) Al2O3.
B) Al(OH)2.
C) Al(OH)3.
D) Al3O2.
E) AlO.
سؤال
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+,Ca2+,Cl⁻,Br⁻,F⁻

A) Na+
B) Cl-
C) Ca2+
D) Br-
E) F-
سؤال
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+,Fe3+,Mg2+,Br-,I-

A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
سؤال
Identify a component in the formation of rust.

A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
سؤال
Define extraction.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
سؤال
Identify oxidation.

A) increase in oxidation number
B) loss of electrons
C) gain of protons
D) loss of neutrons
E) both A and B
سؤال
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr and Cl2 in the balanced reaction? Cr(s)+ Cl2(g)→ Cr3+(aq)+ Cl-(aq)

A) Cr = 2, Cl2 = 3
B) Cr = 2, Cl2 = 4
C) Cr = 1, Cl2 = 2
D) Cr = 2, Cl2 = 1
E) Cr = 3, Cl2 = 2
سؤال
Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻

A) Cl-
B) F-
C) Cu2+
D) Mg2+
E) Br-
سؤال
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of C10H22O2 and H2SO4 in the balanced reaction? C10H22O2(aq)+ Na2Cr2O7(aq)→ C10H18O4(aq)+ Cr2(SO4)3(aq)

A) C10H22O2 = 3, H2SO4 = 4
B) C10H22O2 = 2, H2SO4 = 8
C) C10H22O2 = 1, H2SO4 = 16
D) C10H22O2 = 3, H2SO4 = 16
E) C10H22O2 = 2, H2SO4 = 4
سؤال
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Fe and Ag+ in the balanced reaction? Fe(s)+ Ag+(aq)→ Ag(s)+ Fe2+(aq)

A) Fe = 1, Ag⁺ = 2
B) Fe = 1, Ag⁺ = 3
C) Fe = 2, Ag⁺ = 1
D) Fe = 2, Ag⁺ = 3
E) Fe = 3, Ag⁺ = 3
سؤال
Define corrosion.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
سؤال
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Pb and H+ in the balanced reaction?
Pb2+(aq)+ NH4+(aq)? Pb(s)+ NO3?(aq)

A) Pb = 1, H? = 8
B) Pb = 1, H? = 2
C) Pb = 4, H? = 10
D) Pb = 2, H? = 3
E) Pb = 3, H? = 5
سؤال
To prevent rust,nails are coated with

A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
سؤال
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction? C7H16O2(aq)+ Na2Cr2O7(aq)→ C7H12O4(aq)+ Cr2(SO4)3(aq)

A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 4
سؤال
Describe the reactions during the electrolysis of water.

A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen nor hydrogen are oxidized or reduced.
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Deck 19: Electrochemistry
1
What element is being oxidized in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2-(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
O
2
What element is being reduced in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
Cr
3
What element is being reduced in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
Cl
4
Identify the location of oxidation in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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5
What element is being oxidized in the following redox reaction? Cr(OH)4-(aq)+ ClO-(aq)→ CrO42-(aq)+ Cl-(aq)

A) Cr
B) O
C) H
D) Cl
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6
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
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7
What element is being oxidized in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
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8
Identify the location of reduction in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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9
What element is being oxidized in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
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10
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)

A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
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11
In a hydrogen-oxygen fuel cell,

A) neither oxygen or hydrogen atoms are oxidized or reduced.
B) both oxygen and hydrogen atoms are oxidized.
C) both oxygen and hydrogen atoms are reduced.
D) oxygen atoms are reduced and hydrogen atoms are oxidized.
E) oxygen atoms are oxidized and hydrogen atoms are reduced.
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12
What element is being reduced in the following redox reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr
B) O
C) H
D) Cl
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13
In a hydrogen-oxygen fuel cell,

A) no transfer of electrons occurs.
B) both oxygen and hydrogen atoms lose electrons.
C) both oxygen and hydrogen atoms gain electrons.
D) oxygen atoms lose electrons and hydrogen atoms gain electrons.
E) oxygen atoms gain electrons and hydrogen atoms lose electrons.
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14
What element is being reduced in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
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15
In a voltaic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
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16
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
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17
Define a salt bridge.

A) A pathway composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counterions can flow between the half-cells without the solutions in the half-cell totally mixing.
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18
A voltaic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
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19
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Br2 and OH⁻ in the balanced reaction? Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)

A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
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20
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4 and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
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21
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
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22
Determine the cell notation for the redox reaction given below. 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)

A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe(s) ∣ Fe3+(aq)
B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe3+(aq) Fe(s)
C) Fe3+(aq) ∣ Fe(s) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Cl⁻(aq) ∣ Cl2(g) ∣ Pt
D) Fe(s) ∣ Cl2(g) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe3+(aq) ∣ Cl⁻(aq) ∣ Pt
E) Fe(s) ∣ Fe3+(aq) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Cl2(g) ∣ Cl⁻(aq) ∣ Pt
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23
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
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24
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V

A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
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25
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,1.8 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,1.8 M)   Ag<sup>+</sup>(aq,0.055 M)∣ Ag(s)</strong> A) -0.94 V B) -0.85 V C) +1.02 V D) +0.98 V E) +0.86 V Ag+(aq,0.055 M)∣ Ag(s)

A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
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26
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M)   Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)</strong> A) +1.01 V B) -0.83 V C) +1.31 V D) +0.01 V E) -0.66 V Ag+(aq,2.7 M)∣ Ag(s)

A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
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27
What statement is NOT true about standard electrode potentials?

A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
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28
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
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29
Identify the characteristics of a spontaneous reaction.

A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
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30
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V

A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
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31
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2 K(s)+ I2(s)→ 2 K⁺(aq)+ 2 I⁻(aq)
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V

A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
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32
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq)
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e- → 2 Br-(aq)E° = +1.07 V

A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
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33
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V

A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
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34
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.3 × 10-16
E) 1.1 × 10-8
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35
Which of the following reactions would have the smallest value of K at 298 K?

A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
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36
Identify a characteristic that does not describe a standard hydrogen electrode.

A) 1 M HCl solution with hydrogen gas
B) 1 atmosphere
C) zinc electrode
D) inert platinum electrode
E) potential of zero
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37
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) 3.5 × 10-59
B) 1.1 × 1017
C) 2.4 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
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38
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
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39
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe<sup>3+</sup>(aq,0.0011 M)   Fe<sup>3+</sup>(aq,2.33 M)∣ Fe(s)</strong> A) +0.066 V B) -0.036 V C) 0.00 V D) -0.099 V E) +0.20 V Fe3+(aq,2.33 M)∣ Fe(s)

A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
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40
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg2+(aq,2.74 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg<sup>2+</sup>(aq,2.74 M)   Cu<sup>2+</sup>(aq,0.0033 M)∣ Cu(s)</strong> A) -2.80 V B) +2.62 V C) +2.71 V D) +2.12 V E) -1.94 V Cu2+(aq,0.0033 M)∣ Cu(s)

A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
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41
In an electrolytic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
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42
Identify the battery that is in most automobiles.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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43
What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current? Ag⁺(aq)+ e⁻ → Ag(s)

A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
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44
What is the reaction at the cathode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
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45
What is the reaction at the anode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
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46
In a nickel-cadmium battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
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47
An electrolytic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
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48
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu<sup>2+</sup>(aq,0.0032 M)   Cu<sup>2+</sup>(aq,4.48 M)∣ Cu(s)</strong> A) 0.00 V B) +0.093 V C) +0.34 V D) +0.186 V E) +0.052 V Cu2+(aq,4.48 M)∣ Cu(s)

A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
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49
Identify the battery that is used as a common flashlight battery.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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50
What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
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51
Describe how water can be a good conductor of current.

A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
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52
In an alkaline battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
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53
Identify the battery type that has a high overcharge tolerance.

A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
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54
In a lead-acid storage battery,PbO2 is reduced to

A) Pb.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
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55
In a dry-cell battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
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56
Identify the components of a fuel cell.

A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
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57
Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
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58
In a lead-acid storage battery,Pb is oxidized to

A) PbO2.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
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59
In a nickel-metal hydride battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
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60
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al<sup>3+</sup>(aq,0.115 M)   Al<sup>3+</sup>(aq,3.89 M)∣ Al(s)</strong> A) +1.66 V B) +0.060 V C) 0.00 V D) +0.090 V E) +0.030 V Al3+(aq,3.89 M)∣ Al(s)

A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
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61
Balance the following reaction in KOH.What are the coefficients in front of C9H20O2 and KMnO4 in the balanced reaction? C9H20O2(aq)+ KMnO4(aq)→ C9H14O4K2(aq)+ MnO2(aq)

A) C9H20O2 = 3, KMnO4 = 8
B) C9H20O2 = 3, KMnO4 = 4
C) C9H20O2 = 8, KMnO4 = 4
D) C9H20O2 = 2, KMnO4 = 8
E) C9H20O2 = 3, KMnO4 = 2
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62
What element is being oxidized in the following redox reaction? C10H22O2(aq)+ KMnO4(aq)→ C10H16O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
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63
What element is being oxidized in the following redox reaction? Mg2+(aq)+ NH4+(aq)→ Mg(s)+ NO3⁻(aq)

A) Mg
B) N
C) H
D) O
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64
What element is being reduced in the following redox reaction? C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
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65
A sacrificial electrode is composed of a metal that

A) does not serve as a protective coating.
B) reduces more easily than iron.
C) has an oxide that is crumbly when formed.
D) oxidizes more easily than iron.
E) oxidizes the same as iron.
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66
Aluminum is quickly oxidized in the air to form

A) Al2O3.
B) Al(OH)2.
C) Al(OH)3.
D) Al3O2.
E) AlO.
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67
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+,Ca2+,Cl⁻,Br⁻,F⁻

A) Na+
B) Cl-
C) Ca2+
D) Br-
E) F-
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68
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+,Fe3+,Mg2+,Br-,I-

A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
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69
Identify a component in the formation of rust.

A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
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70
Define extraction.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
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71
Identify oxidation.

A) increase in oxidation number
B) loss of electrons
C) gain of protons
D) loss of neutrons
E) both A and B
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72
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr and Cl2 in the balanced reaction? Cr(s)+ Cl2(g)→ Cr3+(aq)+ Cl-(aq)

A) Cr = 2, Cl2 = 3
B) Cr = 2, Cl2 = 4
C) Cr = 1, Cl2 = 2
D) Cr = 2, Cl2 = 1
E) Cr = 3, Cl2 = 2
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73
Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻

A) Cl-
B) F-
C) Cu2+
D) Mg2+
E) Br-
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74
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of C10H22O2 and H2SO4 in the balanced reaction? C10H22O2(aq)+ Na2Cr2O7(aq)→ C10H18O4(aq)+ Cr2(SO4)3(aq)

A) C10H22O2 = 3, H2SO4 = 4
B) C10H22O2 = 2, H2SO4 = 8
C) C10H22O2 = 1, H2SO4 = 16
D) C10H22O2 = 3, H2SO4 = 16
E) C10H22O2 = 2, H2SO4 = 4
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75
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Fe and Ag+ in the balanced reaction? Fe(s)+ Ag+(aq)→ Ag(s)+ Fe2+(aq)

A) Fe = 1, Ag⁺ = 2
B) Fe = 1, Ag⁺ = 3
C) Fe = 2, Ag⁺ = 1
D) Fe = 2, Ag⁺ = 3
E) Fe = 3, Ag⁺ = 3
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76
Define corrosion.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
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77
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Pb and H+ in the balanced reaction?
Pb2+(aq)+ NH4+(aq)? Pb(s)+ NO3?(aq)

A) Pb = 1, H? = 8
B) Pb = 1, H? = 2
C) Pb = 4, H? = 10
D) Pb = 2, H? = 3
E) Pb = 3, H? = 5
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78
To prevent rust,nails are coated with

A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
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79
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction? C7H16O2(aq)+ Na2Cr2O7(aq)→ C7H12O4(aq)+ Cr2(SO4)3(aq)

A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 4
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80
Describe the reactions during the electrolysis of water.

A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen nor hydrogen are oxidized or reduced.
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