The experimental rate law for the photochemical decomposition of NO2 to NO and O2 is Rate = k[NO2].Which of the following mechanisms is plausible? Justify your choice.
A)
Step 1: NO2(g) N(g)+ O2(g)(slow)
Step 2: N(g)+ NO2(g) N2O2(g) (fast)
Step 3: N2O2(g) 2 NO(g)(fast)
B)
Step 1: NO2(g)+ NO2(g) NO3(g)+ NO(g)(fast)
Step 2: NO3(g) NO(g)+ O2(g)(fast)
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