Deck 5: Chemical Bonding
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Deck 5: Chemical Bonding
1
Which of these substances are ionic compounds?
I. NCl3
II. MgF2
III. AlBr3
IV. CH4
A) I and II
B) II and III
C) II and IV
D) II, III, and IV
E) I and IV
I. NCl3
II. MgF2
III. AlBr3
IV. CH4
A) I and II
B) II and III
C) II and IV
D) II, III, and IV
E) I and IV
II and III
2
An atom with two valence electrons will most likely _____.
A) lose two electrons to become negatively charged and combine with a cation
B) lose two electrons to become positively charged and combine with an anion
C) gain two electrons to become negatively charged and combine with a cation
D) gain two electrons to become positively charged and combine with an anion
E) gain two electrons to become positively charged and combine with a cation
A) lose two electrons to become negatively charged and combine with a cation
B) lose two electrons to become positively charged and combine with an anion
C) gain two electrons to become negatively charged and combine with a cation
D) gain two electrons to become positively charged and combine with an anion
E) gain two electrons to become positively charged and combine with a cation
lose two electrons to become positively charged and combine with an anion
3
The total number of valence electrons in NO 2 − is _____.
A) 16
B) 17
C) 18
D) 15
E) 19
A) 16
B) 17
C) 18
D) 15
E) 19
18
4
Which of these is the correct Lewis dot structure for sulfur?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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5
Which of these substances are covalent compounds?
I. CaO
II. H20
III. PF3
IV. CH4
A) I and II
B) II and III
C) II and IV
D) II, III, and IV
E) I, II, and III
I. CaO
II. H20
III. PF3
IV. CH4
A) I and II
B) II and III
C) II and IV
D) II, III, and IV
E) I, II, and III
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6
Which of these is the correct Lewis dot structure for chlorine?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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7
Which of these is the most likely identity of element A in the Lewis dot structure?

A) Ca
B) Li
C) Al
D) Cs
E) P

A) Ca
B) Li
C) Al
D) Cs
E) P
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8
How many valence electrons are present in the Lewis structure of NO 3 − ?
A) 32
B) 30
C) 20
D) 22
E) 24
A) 32
B) 30
C) 20
D) 22
E) 24
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9
Ionic bonds are formed when electrons are _____.
A) transferred from one atom to another
B) split into smaller units
C) shared between atoms
D) destroyed during bonding
E) transferred to a higher energy level
A) transferred from one atom to another
B) split into smaller units
C) shared between atoms
D) destroyed during bonding
E) transferred to a higher energy level
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10
Which of these is the correct Lewis dot structure for carbon monoxide?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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11
Which of these is the correct formula for sodium phosphide?
A) NaP
B) NaP2
C) Na3P
D) NaP3
E) Na3P2
A) NaP
B) NaP2
C) Na3P
D) NaP3
E) Na3P2
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12
What does the V in VSEPR theory stand for?
A) Very
B) Variable
C) Valence
D) Vanadium
E) Volume
A) Very
B) Variable
C) Valence
D) Vanadium
E) Volume
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13
Which of these is the most likely identity of element A in the Lewis dot structure?

A) Ca
B) K
C) N
D) Cl
E) O

A) Ca
B) K
C) N
D) Cl
E) O
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14
Which of these is the correct formula for aluminum oxide?
A) AlO
B) Al2O
C) AlO2
D) Al2O3
E) Al2O2
A) AlO
B) Al2O
C) AlO2
D) Al2O3
E) Al2O2
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15
Which of these theories is utilized in the prediction of molecular shapes?
A) Dalton's atomic theory
B) VSEPR theory
C) Bohr's atomic theory
D) Lewis theory of bonding
E) Einstein's theory of relativity
A) Dalton's atomic theory
B) VSEPR theory
C) Bohr's atomic theory
D) Lewis theory of bonding
E) Einstein's theory of relativity
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16
Which of these will not form a positive ion in an ionic compound?
A) Ba
B) Rb
C) P
D) Sn
E) Mg
A) Ba
B) Rb
C) P
D) Sn
E) Mg
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17
Which of the following is true about sodium?
A) It is most stable as an atom.
B) It is most stable as a negatively charged ion.
C) It is most stable as a positively charged ion.
D) All forms of sodium are very stable.
E) All forms of sodium are very unstable.
A) It is most stable as an atom.
B) It is most stable as a negatively charged ion.
C) It is most stable as a positively charged ion.
D) All forms of sodium are very stable.
E) All forms of sodium are very unstable.
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18
Covalent bonds are formed when electrons are _____.
A) transferred from one atom to another
B) split into smaller units
C) shared between atoms
D) destroyed during bonding
E) heated during bonding
A) transferred from one atom to another
B) split into smaller units
C) shared between atoms
D) destroyed during bonding
E) heated during bonding
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19
Which of these is not a fundamental postulate of Lewis theory?
A) Valence electrons are shared in covalent bonding.
B) The valence shell is involved in chemical bonding.
C) Atoms bond to achieve a more stable configuration.
D) Atoms bond to achieve an octet of electrons in the valence shell.
E) Valence electrons are shared between atoms to form ionic bonds.
A) Valence electrons are shared in covalent bonding.
B) The valence shell is involved in chemical bonding.
C) Atoms bond to achieve a more stable configuration.
D) Atoms bond to achieve an octet of electrons in the valence shell.
E) Valence electrons are shared between atoms to form ionic bonds.
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20
Which of these is the correct formula for strontium iodide?
A) SrI
B) SrI2
C) Sr2I
D) SrI3
E) Sr2I2
A) SrI
B) SrI2
C) Sr2I
D) SrI3
E) Sr2I2
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21
Which of these molecules contains a triple bond?
A) NH3
B) OCl2
C) C2H2
D) H2O
E) MgO
A) NH3
B) OCl2
C) C2H2
D) H2O
E) MgO
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22
Which of these is the correct Lewis dot structure for nitrogen, N2?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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23
Which of the following is true about ozone?
A) Its Lewis structure is best represented by resonance structures.
B) It increases the amount of ultraviolet radiation reaching the Earth's surface.
C) It cannot be broken down by ultraviolet radiation.
D) Its chemical formula is O2.
E) It contains triple bonds between oxygen atoms.
A) Its Lewis structure is best represented by resonance structures.
B) It increases the amount of ultraviolet radiation reaching the Earth's surface.
C) It cannot be broken down by ultraviolet radiation.
D) Its chemical formula is O2.
E) It contains triple bonds between oxygen atoms.
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24
Which of these molecules contains a triple bond?
A) PCl3
B) N2
C) SO2
D) H2O
E) CO2
A) PCl3
B) N2
C) SO2
D) H2O
E) CO2
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25
Which of the following is the molecular geometry of NH3?
A) Tetrahedral
B) Bent
C) Trigonal pyramidal
D) Trigonal planar
E) Linear
A) Tetrahedral
B) Bent
C) Trigonal pyramidal
D) Trigonal planar
E) Linear
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26
How many lone pairs of electrons are present around the central atom in CO2?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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27
Which of these is the correct Lewis dot structure for sulfur trioxide?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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28
How many lone pairs of electrons are present around the central atom in SO2?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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29
Which of these molecules contains one double bond and one single bond?
A) PCl3
B) NH3
C) SO2
D) H2O
E) CO2
A) PCl3
B) NH3
C) SO2
D) H2O
E) CO2
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30
Barium fluoride is often used in glass manufacturing. Which of these is the correct formula and bonding type for barium fluoride?
A) BaF, ionic
B) BaF, covalent
C) BaF2, ionic
D) BaF2, covalent
E) Ba2F, ionic
A) BaF, ionic
B) BaF, covalent
C) BaF2, ionic
D) BaF2, covalent
E) Ba2F, ionic
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31
How many bonding pairs of electrons are present around the central atom in CO2?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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32
How many bonding pairs of electrons are present around the central atom in HCN?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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33
Which of these molecules will have a tetrahedral molecular geometry?
A) NH3
B) N2O
C) C2H2
D) CH3Cl
E) MgO
A) NH3
B) N2O
C) C2H2
D) CH3Cl
E) MgO
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34
The molecular geometry of a two-atom molecule _____.
A) is always bent
B) is always tetrahedral
C) is always linear
D) depends on the atoms involved
E) depends on the type of bonding
A) is always bent
B) is always tetrahedral
C) is always linear
D) depends on the atoms involved
E) depends on the type of bonding
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35
Identify the element X present in the third row of the periodic table that forms the following compound:

A) S
B) Cl
C) P
D) Si
E) Al

A) S
B) Cl
C) P
D) Si
E) Al
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36
Identify the element X present in the fourth row of the periodic table that forms the following ion:

A) Ge
B) As
C) Se
D) Kr
E) Br

A) Ge
B) As
C) Se
D) Kr
E) Br
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37
How many lone pairs of electrons are present around the central atom in PCl3?
A) 0
B) 1
C) 2
D) 3
E) 20
A) 0
B) 1
C) 2
D) 3
E) 20
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38
How many lone pairs of electrons are present around the central atom in CH4?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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39
Which of these molecules contains two double bonds?
A) PCl3
B) N2
C) SO2
D) H2O
E) CO2
A) PCl3
B) N2
C) SO2
D) H2O
E) CO2
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40
How many lone pairs of electrons are present around the central atom in H2O?
A) 0
B) 1
C) 2
D) 3
E) 4
A) 0
B) 1
C) 2
D) 3
E) 4
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41
Which of these is the correct molecular geometry of PCl3?
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
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42
Which of these molecules will have a tetrahedral electron geometry and a bent molecular geometry?
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
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43
Which of these would be expected to have a trigonal planar electron geometry?

A) I and II
B) II and III
C) I, II, and III
D) I and III
E) I only

A) I and II
B) II and III
C) I, II, and III
D) I and III
E) I only
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44
Which of these molecules will have a tetrahedral electron geometry and a trigonal pyramidal molecular geometry?
A) NH 3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
A) NH 3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
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45
Which of these molecules will have a linear electron geometry and a linear molecular geometry?
A) PCl3
B) H2O
C) CO2
D) CH3Cl
E) BF3
A) PCl3
B) H2O
C) CO2
D) CH3Cl
E) BF3
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46
Which of these molecules will have a linear electron geometry and a trigonal pyramidal molecular geometry?
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) None of these
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) None of these
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47
Which of the following results in bent molecular geometry?
A) Four bonding groups and zero lone pair on the central atom
B) Two bonding groups and three lone pairs on the central atom
C) Two bonding groups and two lone pairs on the central atom
D) Two bonding groups and zero lone pair on the central atom
E) Three bonding groups and one lone pair on the central atom
A) Four bonding groups and zero lone pair on the central atom
B) Two bonding groups and three lone pairs on the central atom
C) Two bonding groups and two lone pairs on the central atom
D) Two bonding groups and zero lone pair on the central atom
E) Three bonding groups and one lone pair on the central atom
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48
Which of these is the correct molecular geometry of BF3?
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
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49
Which of these molecules will have a tetrahedral electron geometry and a tetrahedral molecular geometry?
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
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50
Which of these theories is utilized in the prediction of molecular polarity?
A) Dalton's theory
B) VSEPR theory
C) Bohr's atomic theory
D) Einstein's relativity theory
E) Lewis bonding theory
A) Dalton's theory
B) VSEPR theory
C) Bohr's atomic theory
D) Einstein's relativity theory
E) Lewis bonding theory
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51
Which of these molecules will have a trigonal planar electron geometry and a bent molecular geometry?
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
A) PCl3
B) H2O
C) C2H2
D) CH3Cl
E) SO2
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52
Electronegativity is _____.
A) the ability of an atom to form positively charged ions
B) the ability of an atom to form negatively charged ions
C) the ability of an atom to attract protons in a covalent bond
D) the ability of an atom to attract electrons in a covalent bond
E) the ability of an atom to remain neutral
A) the ability of an atom to form positively charged ions
B) the ability of an atom to form negatively charged ions
C) the ability of an atom to attract protons in a covalent bond
D) the ability of an atom to attract electrons in a covalent bond
E) the ability of an atom to remain neutral
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53
Which of the following molecular geometries can a molecule with a tetrahedral electron geometry possess?
A) Tetrahedral
B) Trigonal pyramidal
C) Bent
D) All of these
E) None of these
A) Tetrahedral
B) Trigonal pyramidal
C) Bent
D) All of these
E) None of these
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54
Which of the following is the molecular geometry of NH4+?
A) Trigonal planar
B) Tetrahedral
C) Trigonal pyramidal
D) Bent
E) Linear
A) Trigonal planar
B) Tetrahedral
C) Trigonal pyramidal
D) Bent
E) Linear
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55
The element with the highest electronegativity is _____.
A) fluorine
B) hydrogen
C) helium
D) neon
E) chlorine
A) fluorine
B) hydrogen
C) helium
D) neon
E) chlorine
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56
Which of these molecules will have a trigonal pyramidal molecular geometry?
A) PCl3
B) N2O
C) C2H2
D) CH3Cl
E) SO2
A) PCl3
B) N2O
C) C2H2
D) CH3Cl
E) SO2
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57
Which of these is the correct molecular geometry of CO2?
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
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58
Which of the following is the correct molecular geometry of CCl4?
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
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59
Which of these is the correct molecular geometry of SO2?
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal pyramidal
E) Bent
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60
Which of these would be expected to have a linear molecular geometry?

A) I and II
B) II and IV
C) I, II, and IV
D) I and III
E) IV only

A) I and II
B) II and IV
C) I, II, and IV
D) I and III
E) IV only
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61
Which of the following is true of a nonpolar bond?
A) One side of a nonpolar bond is electron deficient.
B) A nonpolar bond is formed because of varying electronegativities in atoms.
C) A nonpolar bond has an uneven electron distribution.
D) Molecules in a nonpolar bond do not have a charge separation.
E) None of these
A) One side of a nonpolar bond is electron deficient.
B) A nonpolar bond is formed because of varying electronegativities in atoms.
C) A nonpolar bond has an uneven electron distribution.
D) Molecules in a nonpolar bond do not have a charge separation.
E) None of these
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62
Which of these are polar molecules with a tetrahedral electron geometry?
I. CO2
II. H2O
III. CH3Cl
IV. SiH4
A) I and IV
B) I and III
C) I, II, and III
D) III and IV
E) II and III
I. CO2
II. H2O
III. CH3Cl
IV. SiH4
A) I and IV
B) I and III
C) I, II, and III
D) III and IV
E) II and III
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63
List the elements Na, K, Al, Cl, and Cs in order of decreasing electronegativity (from greatest to least).
A) Na > Cl > Al > K > Cs
B) Cs > Na > K > Cl > Al
C) Cl > Na > Al > K > Cs
D) Cl > Al > Na > K > Cs
E) Na > Cs > K > Al > Cl
A) Na > Cl > Al > K > Cs
B) Cs > Na > K > Cl > Al
C) Cl > Na > Al > K > Cs
D) Cl > Al > Na > K > Cs
E) Na > Cs > K > Al > Cl
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64
Which of these elements has the lowest electronegativity?
A) Ca
B) N
C) Se
D) P
E) O
A) Ca
B) N
C) Se
D) P
E) O
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65
Which of the following is true of electronegativity?
A) The elements at the bottom of the periodic table have greater electronegativity than the elements at the top of the table.
B) The elements in the same row of the periodic table have equal electronegativity.
C) The elements in the same column of the periodic table have equal electronegativity.
D) The elements to the right of the periodic table have greater electronegativity than the elements to the left of the table.
E) The elements in the periodic table are arranged in the decreasing order of their electronegativity.
A) The elements at the bottom of the periodic table have greater electronegativity than the elements at the top of the table.
B) The elements in the same row of the periodic table have equal electronegativity.
C) The elements in the same column of the periodic table have equal electronegativity.
D) The elements to the right of the periodic table have greater electronegativity than the elements to the left of the table.
E) The elements in the periodic table are arranged in the decreasing order of their electronegativity.
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66
Which of these elements has the highest electronegativity?
A) Ca
B) N
C) Se
D) P
E) O
A) Ca
B) N
C) Se
D) P
E) O
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67
Which of these contain polar bonds but are nonpolar molecules?
I. NCl3
II. H2
III. CO2
IV. BF3
A) I and II
B) I and III
C) III and IV
D) II and III
E) I, III, and IV
I. NCl3
II. H2
III. CO2
IV. BF3
A) I and II
B) I and III
C) III and IV
D) II and III
E) I, III, and IV
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68
Which of the following is true according to the octet rule ?
A) A stable electron configuration usually involves eight electrons.
B) An atom must have eight protons.
C) All elements with an atomic number of eight and above are metals.
D) Eight electrons are transferred from one atom to another during ionic bonding.
E) Elements with less than eight electrons have a linear molecular geometry.
A) A stable electron configuration usually involves eight electrons.
B) An atom must have eight protons.
C) All elements with an atomic number of eight and above are metals.
D) Eight electrons are transferred from one atom to another during ionic bonding.
E) Elements with less than eight electrons have a linear molecular geometry.
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69
Which of the following are polar molecules?
I. PCl3
II. H2O
III. CO2
IV. BF3
A) I and IV
B) I and II
C) I, II, and IV
D) II and III
E) II and IV
I. PCl3
II. H2O
III. CO2
IV. BF3
A) I and IV
B) I and II
C) I, II, and IV
D) II and III
E) II and IV
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70
The averaging of two identical Lewis structures is called _____.
A) reverberation
B) resonance
C) covalence
D) shaping
E) structuring
A) reverberation
B) resonance
C) covalence
D) shaping
E) structuring
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71
_____ is based on the idea that the negative charges of bonding electrons and lone pair electrons in a molecule repel each other.
A) VSEPR theory
B) Dalton's theory
C) Bohr's atomic theory
D) Lewis bonding theory
E) Einstein's theory of relativity
A) VSEPR theory
B) Dalton's theory
C) Bohr's atomic theory
D) Lewis bonding theory
E) Einstein's theory of relativity
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72
Of the bonds below, the most polar bond would be _____.
A) C − C
B) C − N
C) C − O
D) C − F
E) B − C
A) C − C
B) C − N
C) C − O
D) C − F
E) B − C
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73
Element A has an electronegativity of 0.8, and element B has an electronegativity of 2.0. Which statement best describes the bonding in A3B?
A) The AB bond is largely covalent with a δ− on A.
B) The AB bond is largely covalent with a δ + on A.
C) The compound is largely ionic with no polar bonds.
D) The compound is largely covalent with no polar bonds.
E) The question stem lacks sufficient information.
A) The AB bond is largely covalent with a δ− on A.
B) The AB bond is largely covalent with a δ + on A.
C) The compound is largely ionic with no polar bonds.
D) The compound is largely covalent with no polar bonds.
E) The question stem lacks sufficient information.
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74
Which of the following is true about a water molecule?
A) It is a nonpolar molecule.
B) It has a bent electron geometry.
C) It has a linear molecular geometry.
D) It has two lone pairs of electrons on the central atom.
E) It contains two double bonds.
A) It is a nonpolar molecule.
B) It has a bent electron geometry.
C) It has a linear molecular geometry.
D) It has two lone pairs of electrons on the central atom.
E) It contains two double bonds.
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75
List the elements Li, K, Al, Br, and Cs in order of increasing electronegativity (from least to greatest).
A) Li < Cs < Al < K < Br
B) Cs < Li < K < Br < Al
C) Br < Li < Al < K < Cs
D) Br < Al < Li < K < Cs
E) Cs < K < Li < Al < Br
A) Li < Cs < Al < K < Br
B) Cs < Li < K < Br < Al
C) Br < Li < Al < K < Cs
D) Br < Al < Li < K < Cs
E) Cs < K < Li < Al < Br
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76
A _____ is also called a dipole.
A) polar bond
B) nonpolar bond
C) ionic bond
D) covalent bond
E) metallic bond
A) polar bond
B) nonpolar bond
C) ionic bond
D) covalent bond
E) metallic bond
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77
Which of these is a nonpolar molecule?
A) CO
B) H2O
C) O3
D) PCl3
E) SO3
A) CO
B) H2O
C) O3
D) PCl3
E) SO3
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78
Which of the following molecules is nonpolar?
A) CO2
B) N2
C) CH4
D) CCl4
E) All of these
A) CO2
B) N2
C) CH4
D) CCl4
E) All of these
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79
NO 2 − has _____ double bond(s), _____ single bond(s), _____ lone (nonbonding) pair(s) of electrons, and _____ resonance forms.
A) 2; 0; 8; 2
B) 1; 1; 8; 3
C) 1; 1; 6; 2
D) 0; 2; 10; 0
E) 2; 0; 12; 2
A) 2; 0; 8; 2
B) 1; 1; 8; 3
C) 1; 1; 6; 2
D) 0; 2; 10; 0
E) 2; 0; 12; 2
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