Deck 6: Industrial Preparation and Properties of Alcohols

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Question
Ethanol is prepared industrially by………

A)Hydration of ethylene
B)Fermentation of sugars
C)Both the above
D)None of these
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Question
Ethyl alcohol is industrially prepared from ethylene by……..

A)Permanganate oxidation
B)Catalytic reduction
C)Absorbing in H2SO4 followed by hydrolysis
D)Fermentation
Question
Coconut oil upon alkaline hydrolysis gives…….

A)Glycol
B)Alcohol
C)Glycerol
D)Ethylene oxide
Question
Which enzyme converts glucose and fructose both into ethanol……..

A)Diastase
B)Invertase
C)Zymase
D)Maltase
Question
Primary alcohols can be obtained from the reaction of the RMgX……

A)CO2
B)HCHO
C)CH3 CHO
D)H2O
Question
Formaldehyde gives an additive product with methyl magnesium iodide which on aqueous hydrolysis gives …..

A)Isopropyl alcohol
B)Ethyl alcohol
C)Methyl alcohol
D)Propyl alcohol
Question
Benzyl alcohol is obtained from benzaldehyde by…..

A)Fittig's reaction
B)Cannizaro's reaction
C)Kolbe's reaction
D)Wurtz's reaction
Question
The product of reduction of benzaldehyde is …..

A)Benzoic acid
B)Benzyl alcohol
C)Benzene
D)Catechol
Question
Alkenes convert into alcohols by……

A)Hydrolysis by dil. Sulphuric acid
B)Hydration of alkene by alkaline KMnO4
C)Hydrolysis by water vapours and conc. Sulphuric acid
D)Hydration of alkene by aqueous KOH
Question
Acetic acid and CH3 are obtained on large scale by destructive distillation of…..

A)Wood
B)Coal
C)Turpentine
D)Crude oil
Question
Acid catalyzed hydration of alkenes except ethene leads to the formation of ……

A)Primary alcohol
B)Secondary or tertiary alcohol
C)Mixture of primary and secondary alcohols
D)Mixture of secondary and tertiary alcohols
Question
The boiling point of alcohol are …. than corresponding thiols.

A)More
B)Same
C)Either of these
D)Less
Question
Methyl alcohol can be distinguished from ethyl alcohol using ……

A)Fehling solution
B)Schiff's reagent
C)Sodium hydroxide and iodine
D)Phthalein fusion test
Question
A compound X with molecular formula C3H8O can be oxidised to a compound Y with the molecular formula C3H6O2 X is most likely to be …..

A)Primary alcohol
B)Secondary alcohol
C)Aldehyde
D)Ketone
Question
On heating glycerol with conc. H2SO4 a compound is obtained which has a bad odour. The compound is…..

A)Glycerol sulphate
B)Acrolein
C)Formic acid
D)Allyl alcohol
Question
Isopropyl alcohol on oxidation forms……

A)Acetone
B)Ether
C)Ethylene
D)Acetaldehyde
Question
The alcohol that produces turbidity immediately with ZnCl2 + conc. HCl at room temperature…..

A)1-hydroxybutane
B)2-hydroxybutane
C)2-hydroxy-2-methylpropane
D)1-hydroxy-2-methylpropane
Question
The reagent which easily reacts with ethanol and propanol is……

A)Fehling solution
B)Grignard reagent
C)Schiff's reagent
D)Tollen's reagent
Question
Propene is the product obtained by dehydrogenation of …….

A)2-propanol
B)1-propanol
C)Propanal
D)n -propyl alcohol
Question
Which of the following statements is correct…..

A)Phenol is less acidic than ethyl alcohol
B)Phenol is more acidic than ethyl alcohol
C)Phenol is more acidic than carboxylic acid
D)Phenol is more acidic than carbonic acid
Question
Boiling point of alcohol is comparatively higher than that corresponding alkane due to…….

A)Intermolecular hydrogen bonding
B)Intramolecular hydrogen bonding
C)Volatile nature
D)None of these
Question
The reaction of C2H5OH with H2SO4 does not give ……

A)Ethylene
B)Diethyl ether
C)Acetylene
D)Ethyl hydrogen sulphate
Question
In reaction of alcohols with alkali metal, acid etc. which of the following alcohol will react fastest….

A)Secondary
B)Tertiary
C)Primary
D)All equal
Question
Order of reactivity of alcohols towards sodium metal is ……

A)Pri > Sec > Ter
B)Pri > Sec C)Pri < Sec > Ter
D)Pri < Sec < Ter
Question
The -OH group of methyl alcohol cannot be replaced by chlorine by the action of……

A)Chlorine
B)Hydrogen chloride
C)Phosphorus trichloride
D)Phosphorus pentachloride
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Deck 6: Industrial Preparation and Properties of Alcohols
1
Ethanol is prepared industrially by………

A)Hydration of ethylene
B)Fermentation of sugars
C)Both the above
D)None of these
Both the above
2
Ethyl alcohol is industrially prepared from ethylene by……..

A)Permanganate oxidation
B)Catalytic reduction
C)Absorbing in H2SO4 followed by hydrolysis
D)Fermentation
Absorbing in H2SO4 followed by hydrolysis
3
Coconut oil upon alkaline hydrolysis gives…….

A)Glycol
B)Alcohol
C)Glycerol
D)Ethylene oxide
Glycerol
4
Which enzyme converts glucose and fructose both into ethanol……..

A)Diastase
B)Invertase
C)Zymase
D)Maltase
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5
Primary alcohols can be obtained from the reaction of the RMgX……

A)CO2
B)HCHO
C)CH3 CHO
D)H2O
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6
Formaldehyde gives an additive product with methyl magnesium iodide which on aqueous hydrolysis gives …..

A)Isopropyl alcohol
B)Ethyl alcohol
C)Methyl alcohol
D)Propyl alcohol
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7
Benzyl alcohol is obtained from benzaldehyde by…..

A)Fittig's reaction
B)Cannizaro's reaction
C)Kolbe's reaction
D)Wurtz's reaction
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8
The product of reduction of benzaldehyde is …..

A)Benzoic acid
B)Benzyl alcohol
C)Benzene
D)Catechol
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9
Alkenes convert into alcohols by……

A)Hydrolysis by dil. Sulphuric acid
B)Hydration of alkene by alkaline KMnO4
C)Hydrolysis by water vapours and conc. Sulphuric acid
D)Hydration of alkene by aqueous KOH
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10
Acetic acid and CH3 are obtained on large scale by destructive distillation of…..

A)Wood
B)Coal
C)Turpentine
D)Crude oil
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11
Acid catalyzed hydration of alkenes except ethene leads to the formation of ……

A)Primary alcohol
B)Secondary or tertiary alcohol
C)Mixture of primary and secondary alcohols
D)Mixture of secondary and tertiary alcohols
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12
The boiling point of alcohol are …. than corresponding thiols.

A)More
B)Same
C)Either of these
D)Less
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13
Methyl alcohol can be distinguished from ethyl alcohol using ……

A)Fehling solution
B)Schiff's reagent
C)Sodium hydroxide and iodine
D)Phthalein fusion test
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14
A compound X with molecular formula C3H8O can be oxidised to a compound Y with the molecular formula C3H6O2 X is most likely to be …..

A)Primary alcohol
B)Secondary alcohol
C)Aldehyde
D)Ketone
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15
On heating glycerol with conc. H2SO4 a compound is obtained which has a bad odour. The compound is…..

A)Glycerol sulphate
B)Acrolein
C)Formic acid
D)Allyl alcohol
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16
Isopropyl alcohol on oxidation forms……

A)Acetone
B)Ether
C)Ethylene
D)Acetaldehyde
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17
The alcohol that produces turbidity immediately with ZnCl2 + conc. HCl at room temperature…..

A)1-hydroxybutane
B)2-hydroxybutane
C)2-hydroxy-2-methylpropane
D)1-hydroxy-2-methylpropane
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18
The reagent which easily reacts with ethanol and propanol is……

A)Fehling solution
B)Grignard reagent
C)Schiff's reagent
D)Tollen's reagent
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19
Propene is the product obtained by dehydrogenation of …….

A)2-propanol
B)1-propanol
C)Propanal
D)n -propyl alcohol
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20
Which of the following statements is correct…..

A)Phenol is less acidic than ethyl alcohol
B)Phenol is more acidic than ethyl alcohol
C)Phenol is more acidic than carboxylic acid
D)Phenol is more acidic than carbonic acid
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21
Boiling point of alcohol is comparatively higher than that corresponding alkane due to…….

A)Intermolecular hydrogen bonding
B)Intramolecular hydrogen bonding
C)Volatile nature
D)None of these
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22
The reaction of C2H5OH with H2SO4 does not give ……

A)Ethylene
B)Diethyl ether
C)Acetylene
D)Ethyl hydrogen sulphate
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23
In reaction of alcohols with alkali metal, acid etc. which of the following alcohol will react fastest….

A)Secondary
B)Tertiary
C)Primary
D)All equal
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24
Order of reactivity of alcohols towards sodium metal is ……

A)Pri > Sec > Ter
B)Pri > Sec C)Pri < Sec > Ter
D)Pri < Sec < Ter
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25
The -OH group of methyl alcohol cannot be replaced by chlorine by the action of……

A)Chlorine
B)Hydrogen chloride
C)Phosphorus trichloride
D)Phosphorus pentachloride
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