Deck 20: Electrochemistry
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Deck 20: Electrochemistry
1
An electrolyte is
A)a solid that conducts electrical energy.
B)an inert electrode that conducts electrical energy.
C)a metal that conducts electrical energy through a solution.
D)a compound that conducts electricity either in solution or in the molten state.
E)a solvent that conducts electricity.
A)a solid that conducts electrical energy.
B)an inert electrode that conducts electrical energy.
C)a metal that conducts electrical energy through a solution.
D)a compound that conducts electricity either in solution or in the molten state.
E)a solvent that conducts electricity.
a compound that conducts electricity either in solution or in the molten state.
2
Anions
A)are charged ions that move toward the anode of a galvanic or electrolytic cell.
B)are charged ions that move toward the negative electrode of an electrolytic cell.
C)are charged ions that move toward the north pole of a magnetic field.
D)are positively charged ions that result from electrical discharge in a liquid solution.
E)are ions that attach themselves to any electrode to react chemically during electrolytic.
A)are charged ions that move toward the anode of a galvanic or electrolytic cell.
B)are charged ions that move toward the negative electrode of an electrolytic cell.
C)are charged ions that move toward the north pole of a magnetic field.
D)are positively charged ions that result from electrical discharge in a liquid solution.
E)are ions that attach themselves to any electrode to react chemically during electrolytic.
are charged ions that move toward the anode of a galvanic or electrolytic cell.
3
Cations
A)are negatively charged ions that result from electrical discharge in a liquid solution.
B)are charged ions that move toward the cathode of a galvanic or electrolytic cell.
C)are charged ions that move toward the positive electrode of an electrolytic cell.
D)are charged ions that move toward the south pole of a magnetic field.
E)are ions that attach themselves to any electrode to react chemically during electrolysis.
A)are negatively charged ions that result from electrical discharge in a liquid solution.
B)are charged ions that move toward the cathode of a galvanic or electrolytic cell.
C)are charged ions that move toward the positive electrode of an electrolytic cell.
D)are charged ions that move toward the south pole of a magnetic field.
E)are ions that attach themselves to any electrode to react chemically during electrolysis.
are charged ions that move toward the cathode of a galvanic or electrolytic cell.
4
A galvanic cell has two electrodes. Which statement is correct?
A)Oxidation takes place at the anode, which is positively charged.
B)Oxidation takes place at the anode, which is negatively charged.
C)Oxidation takes place at the cathode, which is positively charged.
D)Oxidation takes place at the cathode, which is negatively charged.
E)Oxidation take place at the dynode, which is uncharged.
A)Oxidation takes place at the anode, which is positively charged.
B)Oxidation takes place at the anode, which is negatively charged.
C)Oxidation takes place at the cathode, which is positively charged.
D)Oxidation takes place at the cathode, which is negatively charged.
E)Oxidation take place at the dynode, which is uncharged.
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5
A galvanic cell has two electrodes. Which statement is correct?
A)Reduction takes place at the anode, which is positively charged.
B)Reduction takes place at the anode, which is negatively charged.
C)Reduction takes place at the cathode, which is positively charged.
D)Reduction takes place at the cathode, which is negatively charged.
E)Reduction takes place at the dynode, which is uncharged.
A)Reduction takes place at the anode, which is positively charged.
B)Reduction takes place at the anode, which is negatively charged.
C)Reduction takes place at the cathode, which is positively charged.
D)Reduction takes place at the cathode, which is negatively charged.
E)Reduction takes place at the dynode, which is uncharged.
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6
A galvanic cell consists of a Cu(s)|Cu2+(aq)half-cell and a Zn(s)|Zn2+(aq)half-cell, connected by a salt bridge. Oxidation occurs in the zinc half-cell. The cell can be represented in standard notation as:
A)Cu(s)|Cu2+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Cu(s)|Cu2+(aq)
C)Cu2+(aq)|Cu(s)||Zn(s)|Zn2+(aq)
D)Zn(s)|Zn2+(aq)||Cu2+(aq)|Cu(s)
E)Zn2+(aq)|Zn(s)||Cu(s)|Cu2+(aq)
A)Cu(s)|Cu2+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Cu(s)|Cu2+(aq)
C)Cu2+(aq)|Cu(s)||Zn(s)|Zn2+(aq)
D)Zn(s)|Zn2+(aq)||Cu2+(aq)|Cu(s)
E)Zn2+(aq)|Zn(s)||Cu(s)|Cu2+(aq)
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7
A galvanic cell consists of an Ag(s)|Ag+(aq)half-cell and a Zn(s)|Zn2+(aq)half-cell connected by a salt bridge. Oxidation occurs in the zinc half-cell. The cell can be represented in standard notation as
A)Ag(s)|Ag+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Ag(s)|Ag+(aq)
C)Ag+(aq)|Ag(s)||Zn(s)|Zn2+(aq)
D)Zn2+(aq)|Zn(s)||Ag(s)|Ag+(aq)
E)Zn(s)|Zn2+(aq)||Ag+(aq)|Ag(s)
A)Ag(s)|Ag+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Ag(s)|Ag+(aq)
C)Ag+(aq)|Ag(s)||Zn(s)|Zn2+(aq)
D)Zn2+(aq)|Zn(s)||Ag(s)|Ag+(aq)
E)Zn(s)|Zn2+(aq)||Ag+(aq)|Ag(s)
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8
A galvanic cell consists of a Cd(s)|Cd2+(aq)half-cell and a Zn(s)|Zn2+(aq)half-cell connected by a salt bridge. Reduction occurs in the cadmium half-cell. The cell can be represented in standard notation as:
A)Cd(s)|Cd2+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Cd(s)|Cd2+(aq)
C)Zn(s)|Zn2+(aq)||Cd2+(aq)|Cd(s)
D)Zn2+(aq)|Zn(s)||Cd(s)|Cd2+(aq)
E)Cd2+(aq)|Cd(s)||Zn(s)|Zn2+(aq)
A)Cd(s)|Cd2+(aq)|Zn(s)|Zn2+(aq)
B)Zn(s)|Zn2+(aq)||Cd(s)|Cd2+(aq)
C)Zn(s)|Zn2+(aq)||Cd2+(aq)|Cd(s)
D)Zn2+(aq)|Zn(s)||Cd(s)|Cd2+(aq)
E)Cd2+(aq)|Cd(s)||Zn(s)|Zn2+(aq)
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9
A galvanic cell consists of a Cu(s)|Cu2+(aq)half-cell and a Cd(s)|Cd2+(aq)half-cell connected by a salt bridge. Oxidation occurs in the cadmium half-cell. The cell can be represented in standard notation as:
A)Cu(s)|Cu2+(aq)|Cd(s)|Cd2+(aq)
B)Cd(s)|Cd2+(aq)||Cu2+(aq)|Cu(s)
C)Cd2+(aq)|Cd(s)||Cu(s)|Cu2+(aq)
D)Cd(s)|Cd2+(aq)||Cu(s)|Cu2+(aq)
E)Cu2+(aq)|Cu(s)||Cd(s)|Cd2+(aq)
A)Cu(s)|Cu2+(aq)|Cd(s)|Cd2+(aq)
B)Cd(s)|Cd2+(aq)||Cu2+(aq)|Cu(s)
C)Cd2+(aq)|Cd(s)||Cu(s)|Cu2+(aq)
D)Cd(s)|Cd2+(aq)||Cu(s)|Cu2+(aq)
E)Cu2+(aq)|Cu(s)||Cd(s)|Cd2+(aq)
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10
A galvanic cell consists of an Ag(s)|Ag+(aq)half-cell and a Cu(s)|Cu2+(aq)half-cell connected by a salt bridge. The cell can be represented in standard notation as:
A)Ag(s)|Ag+(aq)|Cu(s)|Cu2+(aq)
B)Cu(s)|Cu2+(aq)||Ag(s)|Ag+(aq)
C)Ag+(aq)|Ag(s)||Cu(s)|Cu2+(aq)
D)Cu2+(aq)|Cu(s)||Ag(s)|Ag+(aq)
E)Cu(s)|Cu2+(aq)||Ag+(aq)|Ag(s)
A)Ag(s)|Ag+(aq)|Cu(s)|Cu2+(aq)
B)Cu(s)|Cu2+(aq)||Ag(s)|Ag+(aq)
C)Ag+(aq)|Ag(s)||Cu(s)|Cu2+(aq)
D)Cu2+(aq)|Cu(s)||Ag(s)|Ag+(aq)
E)Cu(s)|Cu2+(aq)||Ag+(aq)|Ag(s)
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11
A galvanic cell consists of an Ag(s)|Ag+(aq)half-cell and a Cu(s)|Cu2+(aq)half-cell connected by a salt bridge. The cell can be represented in standard notation as: Cu(s)|Cu2+(aq)||Ag+(aq)|Ag(s).Which species is being reduced?
A)Ag+(aq)
B)Cu2+(aq)
C)Ag(s)
D)Cu(s)
E)Cu+(aq)
A)Ag+(aq)
B)Cu2+(aq)
C)Ag(s)
D)Cu(s)
E)Cu+(aq)
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12
The electrode for which the standard reduction potential of 0.00 V is assigned uses the half-reaction:
A)Zn2+(aq)+ 2e-
Zn(s)
B)Cu2+(aq)+ 2e-
Cu(s)
C)Ag+(aq)+ e-
Ag(s)
D)2 H+(aq)+ 2e-
H2(g)
E)2 NH4+(aq)+ 2e-
H2(g)+ 2 NH3(g)
A)Zn2+(aq)+ 2e-
Zn(s)B)Cu2+(aq)+ 2e-
Cu(s)C)Ag+(aq)+ e-
Ag(s)D)2 H+(aq)+ 2e-
H2(g)E)2 NH4+(aq)+ 2e-
H2(g)+ 2 NH3(g) Unlock Deck
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13
Using these metal ion/metal standard reduction potentials
Calculate the standard cell potential for the cell whose reaction is:
Cu2+(aq)+ Cd(s) Cd2+(aq)+ Cu(s)
A)+0.76 V
B)+0.06 V
C)-0.06 V
D)+0.74 V
E)+0.20 V
Calculate the standard cell potential for the cell whose reaction is:Cu2+(aq)+ Cd(s) Cd2+(aq)+ Cu(s)
A)+0.76 V
B)+0.06 V
C)-0.06 V
D)+0.74 V
E)+0.20 V
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14
Using these metal ion/metal standard reduction potentials
Calculate the standard cell potential for the cell whose reaction is:
Ni2+(aq)+ Zn(s) Zn2+(aq)+ Ni(s)
A)+0.51 V
B)-1.02 V
C)-1.01 V
D)+1.01 V
E)-0.51 V
Calculate the standard cell potential for the cell whose reaction is:
Ni2+(aq)+ Zn(s) Zn2+(aq)+ Ni(s)
A)+0.51 V
B)-1.02 V
C)-1.01 V
D)+1.01 V
E)-0.51 V
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15
Using these metal ion/metal standard reduction potentials 
Calculate the standard cell potential for the cell whose reaction is:
Fe2+(aq)+ Cr(s) Fe(s)+ Cr3+(aq)
A)-0.30 V
B)-1.18 V
C)+0.30 V
D)+0.16 V
E)-0.16 V

Calculate the standard cell potential for the cell whose reaction is:
Fe2+(aq)+ Cr(s) Fe(s)+ Cr3+(aq)
A)-0.30 V
B)-1.18 V
C)+0.30 V
D)+0.16 V
E)-0.16 V
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16
Using these metal ion/metal reaction potentials:
Calculate the standard cell potential for the cell whose reaction is:
Co(s)+ Cu2+(aq) Co2+(aq)+ Cu(s)
A)-0.06 V
B)+0.06 V
C)-0.62 V
D)+0.62 V
E)+0.68 V
Calculate the standard cell potential for the cell whose reaction is:Co(s)+ Cu2+(aq) Co2+(aq)+ Cu(s)
A)-0.06 V
B)+0.06 V
C)-0.62 V
D)+0.62 V
E)+0.68 V
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17
Using the standard reduction potentials:
Calculate the value of E°cell for the reaction:
2Au(s)+ 3Ca2+(aq) 2Au3+(aq)+ 3Ca(s)
A)-1.43 V
B)+1.34 V
C)-4.18 V
D)+4.18 V
E)-1.34 V
Calculate the value of E°cell for the reaction:2Au(s)+ 3Ca2+(aq) 2Au3+(aq)+ 3Ca(s)
A)-1.43 V
B)+1.34 V
C)-4.18 V
D)+4.18 V
E)-1.34 V
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18
Using the standard reduction potentials::
Calculate the value of E°cell for the cell with the reaction:2Cr(s)+ 3Cl2(g) 2Cr3+(aq)+ 6Cl-(aq)
A)-0.96 V
B)+0.96 V
C)+2.10 V
D)-2.10 V
E)+0.98 V
Calculate the value of E°cell for the cell with the reaction:2Cr(s)+ 3Cl2(g) 2Cr3+(aq)+ 6Cl-(aq)A)-0.96 V
B)+0.96 V
C)+2.10 V
D)-2.10 V
E)+0.98 V
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19
For the reaction, 2 Cr2+(aq)+ Cl2(g)
2 Cr3+(aq)+ 2 Cl-(aq), the value of E°cell is1.78 V. What is the value of E°cell for the following reaction?
Cr3+(aq)+ Cl-(aq) Cr2+(aq)+ ½ Cl2(g)
A)-1.78 V
B)+0.89 V
C)+1.78 V
D)-0.89 V
E)-3.56 V
2 Cr3+(aq)+ 2 Cl-(aq), the value of E°cell is1.78 V. What is the value of E°cell for the following reaction?Cr3+(aq)+ Cl-(aq) Cr2+(aq)+ ½ Cl2(g)
A)-1.78 V
B)+0.89 V
C)+1.78 V
D)-0.89 V
E)-3.56 V
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20
The cell described by the net reaction:2U(s)+ 3Cl2(g)
6 Cl-(aq)+ 2U3+(aq)has a standard cell potential of 3.16 Vs. Using the standard reduction potential value shown for:Cl2(g)+ 2 e-
2 Cl-(aq)E° = +1.36 V determine the standard reduction potential of the U3+(aq)|U(s)half-cell
A)-1.80 V
B)+1.80 V
C)-1.96 V
D)-4.52 V
E)+4.52 V
6 Cl-(aq)+ 2U3+(aq)has a standard cell potential of 3.16 Vs. Using the standard reduction potential value shown for:Cl2(g)+ 2 e-
2 Cl-(aq)E° = +1.36 V determine the standard reduction potential of the U3+(aq)|U(s)half-cellA)-1.80 V
B)+1.80 V
C)-1.96 V
D)-4.52 V
E)+4.52 V
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21
Consider this electrochemical cell:Pt | Pu3+(aq), Pu4+(aq)|| Cl2(g), Cl-(aq)| Pt Given that the standard cell potential is 0.35 V, what is the standard reduction potential E°(Pu4+/Pu3+)
A)2.37 V
B)1.71 V
C)1.01 V
D)-1.71 V
E)-1.01 V
A)2.37 V
B)1.71 V
C)1.01 V
D)-1.71 V
E)-1.01 V
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22
The cell described by the reaction,2 Co3+(aq)+ 2 Cl-(aq)
2 Co2+(aq)+ Cl2(g)has a standard potential of 0.46 V. Using the standard reduction potential value shown for
determine a value for the standard reduction potential of the cathode half-cell.
A)-0.90 V
B)+0.90 V
C)+0.91 V
D)-1.82 V
E)+1.82 V
2 Co2+(aq)+ Cl2(g)has a standard potential of 0.46 V. Using the standard reduction potential value shown for
determine a value for the standard reduction potential of the cathode half-cell.A)-0.90 V
B)+0.90 V
C)+0.91 V
D)-1.82 V
E)+1.82 V
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23
Consider these metal ion/metal standard reduction potentials
Based on the data above, which one of the species below is the best reducing agent?
A)Co(s)
B)Zn(s)
C)Cu2+(aq)
D)Cu(s)
E)Ag(s)
Based on the data above, which one of the species below is the best reducing agent?A)Co(s)
B)Zn(s)
C)Cu2+(aq)
D)Cu(s)
E)Ag(s)
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24
Using the standard reduction potentials
Calculate the value of E°cell for the cell with the reaction:
3 Mg(s)+ 2 NO3-(aq)+ 8 H+(aq) 3 Mg2+(aq)+ 2 NO(g)+ 4 H2O
A)+1.41 V
B)-1.41 V
C)+3.33 V
D)+8.46 V
E)-8.46 V
Calculate the value of E°cell for the cell with the reaction:3 Mg(s)+ 2 NO3-(aq)+ 8 H+(aq) 3 Mg2+(aq)+ 2 NO(g)+ 4 H2O
A)+1.41 V
B)-1.41 V
C)+3.33 V
D)+8.46 V
E)-8.46 V
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25
Using the standard reduction potentials
Calculate the value of E°cell for the cell with the following reaction.
Ni2+(aq)+ 2 Fe2+(aq) Ni(s)+ 2 Fe3+(aq)
A)+0.52 V
B)-1.02 V
C)+2.81 V
D)+1.02 V
E)-2.81 V
Calculate the value of E°cell for the cell with the following reaction.Ni2+(aq)+ 2 Fe2+(aq) Ni(s)+ 2 Fe3+(aq)
A)+0.52 V
B)-1.02 V
C)+2.81 V
D)+1.02 V
E)-2.81 V
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26
Consider these metal ion/metal standard reduction potentials
Based on the data above, which species is the best oxidizing agent?
A)Co2+(aq)
B)Zn2+(aq)
C)Cu2+(aq)
D)Cd2+(aq)
E)Ag+(aq)
Based on the data above, which species is the best oxidizing agent?A)Co2+(aq)
B)Zn2+(aq)
C)Cu2+(aq)
D)Cd2+(aq)
E)Ag+(aq)
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27
Consider these metal ion/metal standard reduction potentials
Based on the data above, which species is the best reducing agent?
A)Cd(s)
B)Ag(s)
C)Ni(s)
D)Zn(s)
E)Cu(s)
Based on the data above, which species is the best reducing agent?A)Cd(s)
B)Ag(s)
C)Ni(s)
D)Zn(s)
E)Cu(s)
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28
Consider these metal ion/metal standard reduction potentials
Based on the data above, which species is the best oxidizing agent?
A)Cd2+(aq)
B)Zn2+(aq)
C)Co2+(aq)
D)Cu2+(aq)
E)Ni2+(aq)
Based on the data above, which species is the best oxidizing agent?A)Cd2+(aq)
B)Zn2+(aq)
C)Co2+(aq)
D)Cu2+(aq)
E)Ni2+(aq)
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29
Consider these metal ion/metal standard reduction potentials
Based on the data above, which species is the best reducing agent?
A)Co(s)
B)Cu(s)
C)Cd2+(aq)
D)Zn2+(aq)
E)Zn(s)
Based on the data above, which species is the best reducing agent?A)Co(s)
B)Cu(s)
C)Cd2+(aq)
D)Zn2+(aq)
E)Zn(s)
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30
Consider these metal ion/metal standard reduction potentials
Based on the data above, which species is the best reducing agent?
A)Ni(s)
B)Na(s)
C)Au(s)
D)Cu(s)
E)Al(s)
Based on the data above, which species is the best reducing agent?A)Ni(s)
B)Na(s)
C)Au(s)
D)Cu(s)
E)Al(s)
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31
Which statement is true concerning a galvanic cell?
A)E° for the cell is always positive.
B)E° for the cell is always negative.
C)The standard reduction potential for the anode reaction is always positive.
D)The standard reduction potential for the anode reaction is always negative.
E)The standard reduction potential for the cathode reaction is always positive.
A)E° for the cell is always positive.
B)E° for the cell is always negative.
C)The standard reduction potential for the anode reaction is always positive.
D)The standard reduction potential for the anode reaction is always negative.
E)The standard reduction potential for the cathode reaction is always positive.
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32
A certain electrochemical cell has a cell potential of +0.34 V. Which of the following is a true statement about the electrochemical reaction?
A)The reaction favors the formation of reactants and would be considered an electrolytic cell.
B)The reaction favors the formation of reactants and would be considered a galvanic cell.
C)The reaction favors the formation of products and would be considered an electrolytic cell.
D)The reaction is at equilibrium and is a galvanic cell.
E)The reaction favors the formation of products and would be considered a galvanic cell.
A)The reaction favors the formation of reactants and would be considered an electrolytic cell.
B)The reaction favors the formation of reactants and would be considered a galvanic cell.
C)The reaction favors the formation of products and would be considered an electrolytic cell.
D)The reaction is at equilibrium and is a galvanic cell.
E)The reaction favors the formation of products and would be considered a galvanic cell.
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33
A unit of electrical energy is the
A)ampere.
B)coulomb.
C)joule.
D)volt.
E)watt.
A)ampere.
B)coulomb.
C)joule.
D)volt.
E)watt.
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34
Consider the following reaction: 2Fe2+(aq)+ Cu2+ 2Fe3+(aq)+ Cu.When the ion concentrations change to the point where the reaction comes to equilibrium, what would be the cell voltage?
A)1.11 V
B)-0.43 V
C)0.0 V
D)0.43 V
E)0.78 V
A)1.11 V
B)-0.43 V
C)0.0 V
D)0.43 V
E)0.78 V
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35
A unit of electrical charge used is the
A)ampere.
B)coulomb.
C)V.
D)joule.
E)watt.
A)ampere.
B)coulomb.
C)V.
D)joule.
E)watt.
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36
The Faraday constant is equal to the ________ on 1 mole of electrons.
A)capacitance
B)current
C)power
D)pressure
E)electrical charge
A)capacitance
B)current
C)power
D)pressure
E)electrical charge
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37
One mole of electrical charge contains
A)4.184 joules.
B)3,600 coulombs.
C)23,060 joules.
D)96,485 coulombs.
E)3.47 × 108 coulombs.
A)4.184 joules.
B)3,600 coulombs.
C)23,060 joules.
D)96,485 coulombs.
E)3.47 × 108 coulombs.
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38
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy change for the cell reaction of this galvanic cell?
A)-12 kJ
B)+12 kJ
C)-23 kJ
D)+23 kJ
E)-46 kJ
What is the standard free energy change for the cell reaction of this galvanic cell?A)-12 kJ
B)+12 kJ
C)-23 kJ
D)+23 kJ
E)-46 kJ
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39
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?
A)+12 kJ
B)-12 kJ
C)+143 kJ
D)-143 kJ
E)-71 kJ
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?A)+12 kJ
B)-12 kJ
C)+143 kJ
D)-143 kJ
E)-71 kJ
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40
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy change ( G°)for the cell reaction of this galvanic cell?
A)69 kJ
B)+69 kJ
C)-224 kJ
D)+224 kJ
E)-35 kJ
What is the standard free energy change ( G°)for the cell reaction of this galvanic cell?A)69 kJ
B)+69 kJ
C)-224 kJ
D)+224 kJ
E)-35 kJ
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41
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?
A)-88.8 kJ
B)-178 kJ
C)-266 kJ
D)-295 kJ
E)-590 kJ
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?A)-88.8 kJ
B)-178 kJ
C)-266 kJ
D)-295 kJ
E)-590 kJ
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42
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?
A)-806 kJ
B)-1.22 × 103 kJ
C)-706 kJ
D)-540 kJ
E)-600 kJ
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?A)-806 kJ
B)-1.22 × 103 kJ
C)-706 kJ
D)-540 kJ
E)-600 kJ
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43
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?
A)-2.22 × 102 kJ
B)-3.14 × 102 kJ
C)-1.74 × 102 kJ
D)-6.02 × 102 kJ
E)-1.20 × 102 kJ
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?A)-2.22 × 102 kJ
B)-3.14 × 102 kJ
C)-1.74 × 102 kJ
D)-6.02 × 102 kJ
E)-1.20 × 102 kJ
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44
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?
A)-2.49 × 102 kJ
B)-3.21 × 102 kJ
C)-6.43 × 102 kJ
D)-5.32 × 102 kJ
E)-4.31 × 102 kJ
What is the standard free energy ( G°)change for the cell reaction of this galvanic cell?A)-2.49 × 102 kJ
B)-3.21 × 102 kJ
C)-6.43 × 102 kJ
D)-5.32 × 102 kJ
E)-4.31 × 102 kJ
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45
Using the standard reduction potentials
Calculate the standard free energy ( G°)change for the cell reaction:
2 Au(s)+ 3 Ca2+(aq) 2 Au3+(aq)+ 3 Ca(s)
A)2420 kJ
B)388 kJ
C)-766 kJ
D)766 kJ
E)-1210 kJ
Calculate the standard free energy ( G°)change for the cell reaction:2 Au(s)+ 3 Ca2+(aq) 2 Au3+(aq)+ 3 Ca(s)
A)2420 kJ
B)388 kJ
C)-766 kJ
D)766 kJ
E)-1210 kJ
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46
Using these metal ion/metal standard reduction potentials
Calculate the standard free energy ( G°)change for the cell reaction:Fe2+(aq)+ Cr(s) Fe(s)+ Cr3+(aq)
A)-92.6 kJ
B)-86.8 kJ
C)683.1 kJ
D)-57.9 kJ
E)-173.7 kJ
Calculate the standard free energy ( G°)change for the cell reaction:Fe2+(aq)+ Cr(s) Fe(s)+ Cr3+(aq)A)-92.6 kJ
B)-86.8 kJ
C)683.1 kJ
D)-57.9 kJ
E)-173.7 kJ
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47
Using the reduction potentials given, calculate the equilibrium constant, K, at 25°C for the reaction, 
A)1.66
B)6.4
C)3.2
D)6.1 × 10-4
E)1.6 × 104

A)1.66
B)6.4
C)3.2
D)6.1 × 10-4
E)1.6 × 104
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48
The equilibrium constant, Kc, was found to be 1.2 × 103 at 25°C for the reaction,2X(s)+ Cu2+(aq)
2X+(aq)+ Cu(s)Using the following reduction potential for copper, what is the reduction potential for the other half reaction involving the substance X? 
A)-0.16 V
B)0.091 V
C)0.52 V
D)0.18 V
E)-0.25 V
2X+(aq)+ Cu(s)Using the following reduction potential for copper, what is the reduction potential for the other half reaction involving the substance X? 
A)-0.16 V
B)0.091 V
C)0.52 V
D)0.18 V
E)-0.25 V
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49
Using the reduction potentials given, calculate the equilibrium constant, K, at 25°C for the reaction, 
A)8.5 × 1017
B)6.8
C)2.4 × 104
D)1.02
E)1.2 × 10-18

A)8.5 × 1017
B)6.8
C)2.4 × 104
D)1.02
E)1.2 × 10-18
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50
The equilibrium constant, Kc, was found to be 2.4 × 108 at 25°C for the following reaction,2X(s)+ 3Y2+(aq)
2X3+(aq)+ 3Y(s)Using this information, what is the standard reduction potential for this reaction?
A)0.25 V
B)0.083 V
C)0.17 V
D)0.50 V
E)0.21 V
2X3+(aq)+ 3Y(s)Using this information, what is the standard reduction potential for this reaction?A)0.25 V
B)0.083 V
C)0.17 V
D)0.50 V
E)0.21 V
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51
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
The actual concentrations are: [Co2+(aq)] = 0.00100 M, [Cd2+] = 0.100 M. What is the potential of this galvanic cell? Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.18 V
B)+0.12 V
C)+0.24 V
D)+0.060 V
E)+0.68 V
The actual concentrations are: [Co2+(aq)] = 0.00100 M, [Cd2+] = 0.100 M. What is the potential of this galvanic cell? Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.A)+0.18 V
B)+0.12 V
C)+0.24 V
D)+0.060 V
E)+0.68 V
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52
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
The actual concentrations in the cell are: [Co2+](aq)= 0.100 M, [Cd2+] = 0.0100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.06 V
B)+0.09 V
C)+0.15 V
D)+0.18 V
E)+0.24 V
The actual concentrations in the cell are: [Co2+](aq)= 0.100 M, [Cd2+] = 0.0100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.A)+0.06 V
B)+0.09 V
C)+0.15 V
D)+0.18 V
E)+0.24 V
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53
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
The actual concentrations in the cell are: [Co2+](aq)= 0.0100 M, [Cr3+] = 0.00100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.40 V
B)+0.46 V
C)+0.52 V
D)+0.54 V
E)+1.02 V
The actual concentrations in the cell are: [Co2+](aq)= 0.0100 M, [Cr3+] = 0.00100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.A)+0.40 V
B)+0.46 V
C)+0.52 V
D)+0.54 V
E)+1.02 V
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54
A galvanic cell is composed of these two half-cells, with the standard reduction potentials shown:
The actual concentrations in the cell are: [Co2+] = 0.00100 M, [Cr3+]= 0.100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.33 V
B)+0.39 V
C)+0.45 V
D)+0.94 V
E)+1.61 V
The actual concentrations in the cell are: [Co2+] = 0.00100 M, [Cr3+]= 0.100 M. What is the potential of this galvanic cell?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.A)+0.33 V
B)+0.39 V
C)+0.45 V
D)+0.94 V
E)+1.61 V
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55
A galvanic cell is composed of these two half-cells:
The actual concentrations in the cell are: [Cu2+] = 0.00350 M, [Cr3+] = 0.360 M. What is the potential of this galvanic cell at 25°C?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+1.06 V
B)-0.16 V
C)+1.02 V
D)+1.14 V
E)+1.98 V
The actual concentrations in the cell are: [Cu2+] = 0.00350 M, [Cr3+] = 0.360 M. What is the potential of this galvanic cell at 25°C?Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.A)+1.06 V
B)-0.16 V
C)+1.02 V
D)+1.14 V
E)+1.98 V
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56
The standard reduction potentials of Cu2+(aq)|Cu(s)and Ag+(aq)|Ag(s)are +0.34 and+0.80 V, respectively. Determine the value of the actual cell potential, Ecell, (in V)for the following cell at 25.0 °C.
Cu(s)|Cu2+(0.250 M)||Ag+(0.0010 M)|Ag(s)Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.30 V
B)+0.14 V
C)+0.62 V
D)+0.78 V
E)+0.39 V
Cu(s)|Cu2+(0.250 M)||Ag+(0.0010 M)|Ag(s)Hint: First calculate E°, then apply the solution concentrations of the galvanic cell using the Nernst equation.
A)+0.30 V
B)+0.14 V
C)+0.62 V
D)+0.78 V
E)+0.39 V
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57
Fuel cells are different from other traditional batteries because
A)they require a constant supply of reactants to produce voltage.
B)they are only used in space.
C)they have a solid medium.
D)they require voltage to work.
E)they utilize heat from combustion of gases.
A)they require a constant supply of reactants to produce voltage.
B)they are only used in space.
C)they have a solid medium.
D)they require voltage to work.
E)they utilize heat from combustion of gases.
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58
When fused (molten)sodium chloride is electrolyzed what occurs?
A)Gaseous chlorine is formed at the cathode.
B)Hydrogen gas is formed at the cathode.
C)Liquid sodium is formed at the cathode.
D)Liquid chlorine is formed at the anode.
E)Solid sodium is formed at the anode.
A)Gaseous chlorine is formed at the cathode.
B)Hydrogen gas is formed at the cathode.
C)Liquid sodium is formed at the cathode.
D)Liquid chlorine is formed at the anode.
E)Solid sodium is formed at the anode.
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59
In doping semiconductor materials,
A)the energy gap between the valence band and the conduction band is completely removed and a covalent bond is formed.
B)impurities are added that either provide extra electrons, or 'holes' for electrons to move through.
C)a large flow of electricity is added to the material kicking electrons out of the material and creating 'holes'.
D)the material is destroyed using an acid.
E)the material is dissolved in an organic solvent.
A)the energy gap between the valence band and the conduction band is completely removed and a covalent bond is formed.
B)impurities are added that either provide extra electrons, or 'holes' for electrons to move through.
C)a large flow of electricity is added to the material kicking electrons out of the material and creating 'holes'.
D)the material is destroyed using an acid.
E)the material is dissolved in an organic solvent.
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60
When an aqueous solution of AgNO3 is electrolyzed, a gas is formed at the anode. The gas is
A)dinitrogen tetroxide.
B)hydrogen.
C)mononitrogen monoxide.
D)nitrogen dioxide.
E)oxygen.
A)dinitrogen tetroxide.
B)hydrogen.
C)mononitrogen monoxide.
D)nitrogen dioxide.
E)oxygen.
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61
Electrolysis is
A)the splitting of atomic nuclei by electrical energy.
B)the splitting of atoms by electrical energy.
C)the passage of electrical energy through a split-field armature.
D)the chemical reaction which results when electrical energy is passed through a liquid electrolyte.
E)the chemical reaction which results when electrical energy is passed through a metallic liquid.
A)the splitting of atomic nuclei by electrical energy.
B)the splitting of atoms by electrical energy.
C)the passage of electrical energy through a split-field armature.
D)the chemical reaction which results when electrical energy is passed through a liquid electrolyte.
E)the chemical reaction which results when electrical energy is passed through a metallic liquid.
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62
Which statement below is true?
A)Electrolysis cells generate alternating current when their terminals are reversed.
B)Electrolysis was discovered by Lewis Latimer.
C)Galvanic cells generate electrical energy rather than consuming it.
D)Galvanic cells were invented by Thomas Edison.
E)The Laws of Electrolysis were discovered by Alberta Nernst.
A)Electrolysis cells generate alternating current when their terminals are reversed.
B)Electrolysis was discovered by Lewis Latimer.
C)Galvanic cells generate electrical energy rather than consuming it.
D)Galvanic cells were invented by Thomas Edison.
E)The Laws of Electrolysis were discovered by Alberta Nernst.
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63
When an aqueous solution of sodium chloride is electrolyzed, hydrogen gas is evolved at the cathode. The solution near the cathode becomes
A)acidic.
B)basic.
C)bubbly.
D)colored.
E)viscous.
A)acidic.
B)basic.
C)bubbly.
D)colored.
E)viscous.
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64
When an aqueous solution of sodium sulfate is electrolyzed, a gas is evolved at the anode. The solution near the anode becomes
A)acidic.
B)basic.
C)bubbly.
D)colored.
E)viscous.
A)acidic.
B)basic.
C)bubbly.
D)colored.
E)viscous.
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65
An electrolytic cell has two electrodes. Which statement is correct?
A)Oxidation takes place at the anode, which is positively charged.
B)Oxidation takes place at the anode, which is negatively charged.
C)Oxidation takes place at the cathode, which is positively charged.
D)Oxidation takes place at the cathode, which is negatively charged.
E)Oxidation take place at the dynode, which is uncharged.
A)Oxidation takes place at the anode, which is positively charged.
B)Oxidation takes place at the anode, which is negatively charged.
C)Oxidation takes place at the cathode, which is positively charged.
D)Oxidation takes place at the cathode, which is negatively charged.
E)Oxidation take place at the dynode, which is uncharged.
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66
An electrolysis cell has two electrodes. Which statement is correct?
A)Reduction takes place at the anode, which is positively charged.
B)Reduction takes place at the anode, which is negatively charged.
C)Reduction takes place at the cathode, which is positively charged.
D)Reduction takes place at the cathode, which is negatively charged.
E)Reduction takes place at the dynode, which is uncharged.
A)Reduction takes place at the anode, which is positively charged.
B)Reduction takes place at the anode, which is negatively charged.
C)Reduction takes place at the cathode, which is positively charged.
D)Reduction takes place at the cathode, which is negatively charged.
E)Reduction takes place at the dynode, which is uncharged.
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67
Which metal can be prepared by electrolysis of an aqueous solution of one of its salts?
A)aluminum
B)copper
C)magnesium
D)potassium
E)sodium
A)aluminum
B)copper
C)magnesium
D)potassium
E)sodium
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68
The products of the electrolysis of molten magnesium chloride using platinum electrodes are
A)hydrogen gas and chlorine gas.
B)magnesium metal and chlorine gas.
C)magnesium metal and oxygen gas.
D)magnesium metal and hydroxide ions.
E)chlorine gas and platinum-magnesium alloy.
A)hydrogen gas and chlorine gas.
B)magnesium metal and chlorine gas.
C)magnesium metal and oxygen gas.
D)magnesium metal and hydroxide ions.
E)chlorine gas and platinum-magnesium alloy.
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69
The products of the electrolysis of aqueous magnesium chloride using platinum electrodes are
A)magnesium metal and chlorine gas.
B)magnesium metal and oxygen gas.
C)magnesium metal and hydroxide ions.
D)hydrogen gas and chlorine gas.
E)chlorine gas and platinum-magnesium alloy.
A)magnesium metal and chlorine gas.
B)magnesium metal and oxygen gas.
C)magnesium metal and hydroxide ions.
D)hydrogen gas and chlorine gas.
E)chlorine gas and platinum-magnesium alloy.
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70
When molten sodium chloride is electrolyzed, a gas is observed to form at the anode. The gas is
A)chlorine.
B)hydrogen.
C)hydrogen peroxide.
D)oxygen.
E)sodium.
A)chlorine.
B)hydrogen.
C)hydrogen peroxide.
D)oxygen.
E)sodium.
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71
When an aqueous solution of copper sulfate is electrolyzed, a gas is observed to form at the anode. The gas is
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
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72
When an aqueous solution of sodium sulfate is electrolyzed, a gas is observed to form at the anode. The gas is
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
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73
When an aqueous solution of sodium sulfate is electrolyzed, a gas is observed to form at the cathode. The gas is
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
A)hydrogen.
B)hydrogen sulfide.
C)hydrogen peroxide.
D)oxygen.
E)sulfur dioxide.
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74
When an aqueous solution of magnesium sulfate is electrolyzed, what product is formed at the cathode?
A)hydrogen
B)hydrogen sulfide
C)magnesium
D)oxygen
E)sulfur dioxide
A)hydrogen
B)hydrogen sulfide
C)magnesium
D)oxygen
E)sulfur dioxide
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75
When an aqueous solution of nickel sulfate is electrolyzed, what product is formed at the anode?
A)hydrogen
B)hydrogen sulfide
C)nickel
D)oxygen
E)sulfur dioxide
A)hydrogen
B)hydrogen sulfide
C)nickel
D)oxygen
E)sulfur dioxide
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76
The half-reaction that occurs at the cathode during electrolysis of aqueous sodium iodide solution is:
A)2 H2O(l)+ 2 e- H2(g)+ 2 OH-(aq)
B)I2(aq)+ 2 e- 2 I-(aq)
C)2 I-(aq) I2(aq)+ 2 e-
D)Na+(aq)+ e- Na(s)
E)Na(s) Na+(aq)+ e-
A)2 H2O(l)+ 2 e- H2(g)+ 2 OH-(aq)
B)I2(aq)+ 2 e- 2 I-(aq)
C)2 I-(aq) I2(aq)+ 2 e-
D)Na+(aq)+ e- Na(s)
E)Na(s) Na+(aq)+ e-
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77
The half-reaction that occurs at the cathode during electrolysis of aqueous CuCl2 solution is:
A)Cl2(g)+ 2 e- 2 Cl-(aq)
B)2 Cl(aq) Cl2(g)+ 2 e-
C)Cu2+(aq)+ 2 e- Cu(s)
D)Cu+(aq)+ e- Cu(s)
E)2 H2O + 2 e- H2(g)+ 2 OH-(aq)
A)Cl2(g)+ 2 e- 2 Cl-(aq)
B)2 Cl(aq) Cl2(g)+ 2 e-
C)Cu2+(aq)+ 2 e- Cu(s)
D)Cu+(aq)+ e- Cu(s)
E)2 H2O + 2 e- H2(g)+ 2 OH-(aq)
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78
The half-reaction that should occur at the anode during electrolysis of aqueous potassium bromide solution is:
A)Br2(g)+ 2 e- 2 Br-(aq)
B)2 Br-(aq) Br2(l)+ 2 e-
C)2 H2O O2(g)+ 4 H+(aq)+ 4 e-
D)2 H+(aq)+ e- H2(g)
E)Na+(aq)+ e- Na(s)
A)Br2(g)+ 2 e- 2 Br-(aq)
B)2 Br-(aq) Br2(l)+ 2 e-
C)2 H2O O2(g)+ 4 H+(aq)+ 4 e-
D)2 H+(aq)+ e- H2(g)
E)Na+(aq)+ e- Na(s)
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79
The SI unit for electric current is the
A)ampere.
B)coulomb.
C)volt.
D)joule.
E)watt.
A)ampere.
B)coulomb.
C)volt.
D)joule.
E)watt.
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80
Using the same current and similar conditions, which will require the shorter length of time?
A)Depositing 0.10 mol Ag from a Ag+ solution
B)Depositing 0.10 mol Cr from a Cr3+ solution
C)Depositing 0.10 mol Cu from a Cu2+ solution
D)Depositing 0.20 mol Cu from a Cu2+ solution
E)They should all take the same time.
A)Depositing 0.10 mol Ag from a Ag+ solution
B)Depositing 0.10 mol Cr from a Cr3+ solution
C)Depositing 0.10 mol Cu from a Cu2+ solution
D)Depositing 0.20 mol Cu from a Cu2+ solution
E)They should all take the same time.
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