Deck 12: Oxidation-Reduction Reactions

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Question
<strong>‪   Determining Oxidation Numbers  -What is the oxidation number of the carbon in bold print in the following structure?   </strong> A) -1 B) +2 C) -3 D) +4 E) none of these <div style=padding-top: 35px>
Determining Oxidation Numbers

-What is the oxidation number of the carbon in bold print in the following structure?
<strong>‪   Determining Oxidation Numbers  -What is the oxidation number of the carbon in bold print in the following structure?   </strong> A) -1 B) +2 C) -3 D) +4 E) none of these <div style=padding-top: 35px>

A) -1
B) +2
C) -3
D) +4
E) none of these
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Question
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation number of the bold face carbon atom in pyruvic acid:   </strong> A)-2 B) +2 C) +3 D) +4 E) none of these <div style=padding-top: 35px>
Determining Oxidation Numbers

-Determine the oxidation number of the bold face carbon atom in pyruvic acid:
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation number of the bold face carbon atom in pyruvic acid:   </strong> A)-2 B) +2 C) +3 D) +4 E) none of these <div style=padding-top: 35px>

A)-2
B) +2
C) +3
D) +4
E) none of these
Question
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation number for bromine in HBrO<sub>4</sub>.</strong> A) +6 B) +7 C) +8 D) -6 E) -7 <div style=padding-top: 35px>
Determining Oxidation Numbers

-Determine the oxidation number for bromine in HBrO4.

A) +6
B) +7
C) +8
D) -6
E) -7
Question
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom in bold print: CH<sub>3</sub>CH<sub>2</sub>F</strong> A) 0 B) +1 C) +2 D) +3 E)-1 <div style=padding-top: 35px>
Determining Oxidation Numbers

-Determine the oxidation state of the carbon atom in bold print:
CH3CH2F

A) 0
B) +1
C) +2
D) +3
E)-1
Question
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation number of arsenic in the anion, HAsO<sub>4</sub><sup>2</sup> <sup>-</sup> .</strong> A) +5 B) +6 C) +7 D) +8 E) none of these <div style=padding-top: 35px>
Determining Oxidation Numbers

-Determine the oxidation number of arsenic in the anion, HAsO42 - .

A) +5
B) +6
C) +7
D) +8
E) none of these
Question
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom shown in bold in the following compound:   </strong> A) -1 B) 0 C) +1 D) +4 E) none of these <div style=padding-top: 35px>
Determining Oxidation Numbers

-Determine the oxidation state of the carbon atom shown in bold in the following compound:
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom shown in bold in the following compound:   </strong> A) -1 B) 0 C) +1 D) +4 E) none of these <div style=padding-top: 35px>

A) -1
B) 0
C) +1
D) +4
E) none of these
Question
The carbon in bold in the ethanol has an oxidation number of __ while the carbon in bold in acetic acid has an oxidation number of ___.

A) -1, +3
B) +1, +2
C) -2, +3
D) +2, -3
E) none of the above
Question
Which of the following statements about this reaction is correct?

A) H+ is the oxidizing agent and dichromate is the reducing agent.
B) Dichromate is oxidized and ethanol is reduced.
C) Ethanol is the reducing agent and dichromate is the oxidizing agent.
D) This is not an oxidation-reduction reaction.
E) None of the above statements is correct.
Question
How many electrons are transferred in the following oxidation-reduction reaction?
3 Sn2+(aq) + Cr2O72-(aq) + 14 H+ <strong>How many electrons are transferred in the following oxidation-reduction reaction? 3 Sn<sup>2+</sup>(aq) + Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + 14 H<sup>+</sup>   3 Sn<sup>4+</sup>(aq) + 2 Cr<sup>3+</sup>(aq) + 7 H<sub>2</sub>O(l)</strong> A) 2 B) 6 C) 12 D) 14 E) none of these <div style=padding-top: 35px> 3 Sn4+(aq) + 2 Cr3+(aq) + 7 H2O(l)

A) 2
B) 6
C) 12
D) 14
E) none of these
Question
Which of the following isn't an example of an oxidation-reduction reaction?

A) Ca3P2(s) + 6 H2O(l) \rightarrow 3 Ca2+(aq) + 6 OH-(aq) + 2 PH3(g)
B) 2 PH3(g) + 4 O2(g) \rightarrow H3PO4(s)
C) P4(s) + 5 O2(g) \rightarrow P4O10(s)
D) 6 Ca(s) + P4(s) \rightarrow 2 Ca3P2(s)
E) All of the above are oxidation-reduction reactions.
Question
Which of the following isn't an example of an oxidation-reduction reaction?

A) H2(g) + Cl2(g) \rightarrow 2 HCl(g)
B) Ag+(aq) + 2 NH3(g)  <strong>Which of the following isn't an example of an oxidation-reduction reaction?</strong> A) H<sub>2</sub>(g) + Cl<sub>2</sub>(g)   \rightarrow  2 HCl(g) B) Ag<sup>+</sup>(aq) + 2 NH<sub>3</sub>(g)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq) C) Hg<sub>2</sub>Cl<sub>2</sub>(s) + NH<sub>3</sub>(g)   \rightarrow   Hg(s) + HgNH<sub>2</sub>Cl(s) D) 2 Mg(s) + O<sub>2</sub>(g)<sub> </sub>  \rightarrow   2MgO(s) E) Cl<sub>2</sub>(g) + 2 Br<sup>-</sup>(aq)   \rightarrow   2 Cl<sup>-</sup>(aq) + Br<sub>2</sub>(l) <div style=padding-top: 35px>  Ag(NH3)2+(aq)
C) Hg2Cl2(s) + NH3(g) \rightarrow Hg(s) + HgNH2Cl(s)
D) 2 Mg(s) + O2(g) \rightarrow 2MgO(s)
E) Cl2(g) + 2 Br-(aq) \rightarrow 2 Cl-(aq) + Br2(l)
Question
A voltaic cell is constructed with a Pt wire in an aqueous solution of Br2/Br - (1M) serving as the cathode and a silver wire in a 1M solution of Ag+ serving as the anode. The potential of the cell was measured to be +0.287 V. The standard reduction potential for Br2/Br - is 1.087 V.
(I) Write the half-reaction for the reduction taking place in the cell.
(II) Write the half-reaction for the oxidation taking place in the cell.
(III) Write the overall reaction for the oxidation-reduction reaction taking place in the cell.
(IV) Calculate the potential for the Ag/Ag+ half-reaction taking place in the cell.
(V) Determine the standard reduction potential, E°, for the half-reaction below.
Ag+(aq) + e- \rightarrow Ag(s)
Question
What will be the coefficients of Ce4+ and Cl - , respectively when the following reaction is balanced?
Ce4+(aq) + Cl - (aq) \rightarrow Cl2(aq) + Ce3+(aq)

A) 1,1
B) 1,2
C) 2.1
D) 2.2
E) 3,1
Question
Use a table of standard reduction potentials to determine which of the following statements is true for the electrochemical cell diagrammed below. <strong>Use a table of standard reduction potentials to determine which of the following statements is true for the electrochemical cell diagrammed below.    </strong> A) The Al is the cathode. B) Electrons move from the Al electrode to the Fe electrode. C) The mass of the Al electrode decreases. D) Both (b) and (c) are true. . E) Both (a) and (c) are true <div style=padding-top: 35px>

A) The Al is the cathode.
B) Electrons move from the Al electrode to the Fe electrode.
C) The mass of the Al electrode decreases.
D) Both (b) and (c) are true. .
E) Both (a) and (c) are true
Question
Use the table of electrode potentials to determine which of the following reactions isn't spontaneous under standard conditions.

A) Zn(s) + 2 H+(aq) \rightarrow Zn2+(aq) + H2(g)
B) 2 Ag(s) + Zn2+(aq) \rightarrow 2 Ag+(aq) + Zn(s)
C) Cl2(aq) + 2 Fe2+(aq) \rightarrow 2 Cl-(aq) + 2 Fe3+(aq)
D) 2 Al(s) + 3/2 O2(g) + 6 H+(aq) \rightarrow 2 Al3+(aq) + 3 H2O(l)
E) Mg(s) + Cl2(g) \rightarrow MgCl2(s)
Question
Consider the following generalized half-reactions.
Aox + e- <strong>Consider the following generalized half-reactions. A<sub>ox</sub> + e<sup>-</sup>   A<sub>red</sub> B<sub>ox</sub> + e<sup>-</sup>   B<sub>red</sub> If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:</strong> A) A<sub>ox</sub> will reduce B<sub>ox</sub> B) A<sub>red</sub> will reduce B<sub>ox</sub> C) B<sub>red </sub>will reduce A<sub>ox</sub> D) B<sub>red</sub> will reduce A<sub>red</sub> E) no reaction will occur <div style=padding-top: 35px> Ared
Box + e- <strong>Consider the following generalized half-reactions. A<sub>ox</sub> + e<sup>-</sup>   A<sub>red</sub> B<sub>ox</sub> + e<sup>-</sup>   B<sub>red</sub> If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:</strong> A) A<sub>ox</sub> will reduce B<sub>ox</sub> B) A<sub>red</sub> will reduce B<sub>ox</sub> C) B<sub>red </sub>will reduce A<sub>ox</sub> D) B<sub>red</sub> will reduce A<sub>red</sub> E) no reaction will occur <div style=padding-top: 35px> Bred
If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:

A) Aox will reduce Box
B) Ared will reduce Box
C) Bred will reduce Aox
D) Bred will reduce Ared
E) no reaction will occur
Question
The potential of a cell at standard state conditions can be best be described as:

A) Eo
B) 0 volts
C) negative
D) more than one volt
E) None of the above
Question
What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations?
Oxidation: Al <strong>What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations? Oxidation: Al   Al<sup>3+</sup> + 3 e<sup>-</sup> Reduction: Zn<sup>2+</sup> + 2 e<sup>-</sup>   Zn</strong> A) -3.59 V B) -0.943 V C) 0.943 V D) 1.12 V E) 3.59 V <div style=padding-top: 35px> Al3+ + 3 e-
Reduction: Zn2+ + 2 e- <strong>What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations? Oxidation: Al   Al<sup>3+</sup> + 3 e<sup>-</sup> Reduction: Zn<sup>2+</sup> + 2 e<sup>-</sup>   Zn</strong> A) -3.59 V B) -0.943 V C) 0.943 V D) 1.12 V E) 3.59 V <div style=padding-top: 35px> Zn

A) -3.59 V
B) -0.943 V
C) 0.943 V
D) 1.12 V
E) 3.59 V
Question
What is the standard cell potential for the following redox reaction?
2 Fe3+(aq) + 2 I-(aq) \rightarrow 2 Fe2+(aq) + I2(aq)

A) -1.30 V
B) -0.24 V
C) 0.24 V
D) 1.30 V
E) none of the above
Question
What is the magnitude of the standard-state cell potential for the following redox reaction?
2 Al(s) + 3 Pb2+(aq) \rightarrow 2 Al3+(aq) + 3 Pb(s)

A) 1.58 V
B) 1.83 V
C) 3.03 V
D) 3.790 V
E) 4.866 V
Question
Oxidation-reduction reactions are often written with double arrows indicating that the reaction can go in either direction depending on the experimental conditions. For the following reaction identify the oxidizing agent on both sides of the chemical equation.
S2O82-(aq) + Zn(s) <strong>Oxidation-reduction reactions are often written with double arrows indicating that the reaction can go in either direction depending on the experimental conditions. For the following reaction identify the oxidizing agent on both sides of the chemical equation. S<sub>2</sub>O<sub>8</sub><sup>2-</sup>(aq) + Zn(s)   Zn<sup>2+</sup>(aq) + 2 SO<sub>4</sub><sup>2-</sup>(aq)</strong> A) S<sub>2</sub>O<sub>8</sub><sup>2-</sup> and SO<sub>4</sub><sup>2-</sup> B) Zn and SO<sub>4</sub><sup>2-</sup> C) Zn and Zn<sup>2+</sup> D) S<sub>2</sub>O<sub>8</sub><sup>2-</sup> and Zn<sup>2+</sup> E) none of these <div style=padding-top: 35px> Zn2+(aq) + 2 SO42-(aq)

A) S2O82- and SO42-
B) Zn and SO42-
C) Zn and Zn2+
D) S2O82- and Zn2+
E) none of these
Question
Which statement correctly describes the following oxidation-reduction reaction?
5Cr3+(aq) + 3 MnO4 - (aq) + 8 H2O (l) \rightarrow 5 CrO42 - (aq) + 3 Mn2+(aq) + 16 H+(aq)

A) MnO4 - and H2O are both reduced.
B) Cr3+ is the reducing agent.
C) Cr3+ and H2O are both reducing agents.
D) MnO4 - is oxidized.
E) None of these are correct.
Question
Which of the following is true about the reaction below?
2VO2+ (aq) + Br2(s) + 2 H2O(l) \rightarrow 2VO2+(aq) + 2 Br - (aq) + 4H+

A) Br2 is acting as a reducing agent.
B) VO2+ is acting as a weak reducing agent.
C) VO2+ is oxidized.
D) H2O is reduced.
E) H+ is acting as a weak reducing agent.
Question
Identify each of the requested compounds for the following redox reaction.
2 MnO4 - (aq) + 16 H+(aq) + 10 Cl - (aq) \rightarrow 2 Mn2+(aq) + 8 H2O + 5 Cl2(g)
(I) oxidizing agent
(II) reducing agent
(III) conjugate oxidizing agent
(IV) conjugate reducing agent
Question
Which statement correctly describes the following reaction?
O2(g) + 4 H+(aq) + 4 Cl - (aq) \rightarrow 2 H2O(l) + 2 Cl2(g)

A) O2 is a reducing agent.
B) H+ and Cl - are oxidized.
C) H+ is reduced.
D) H+ is a reducing agent.
E) Cl - is a reducing agent.
Question
For the following reaction, identify the oxidizing agents in the forward and reverse directions, respectively..
P4(s) + HNO3(aq) \rightarrow H3PO4(aq) + NO(g)

A) P4 and H3PO4
B) P4 and NO
C) P4 and HNO3
D) HNO3 and H3PO4
E) HNO3 and NO
Question
For the reaction:
3 Sn2+(aq) + Cr2O72-(aq) + 14 H+(aq) \rightarrow 3 Sn4+(aq) + 2 Cr3+(aq) + 7 H2O(l)
Which of the following statements is true?

A) Both Sn2+ and H+ are oxidizing agents.
B) Cr2O72- is the oxidizing agent.
C) Sn2+ is reduced.
D) The acid isn't important to the reaction.
E) None of the above are true.
Question
Use a table of standard reduction potentials to determine which of the following is the strongest reducing agent.

A) Co
B) Ca2+
C) Co3+
D) Cr
E) Au
Question
Given the following half-cell reduction potentials, determine which of the following is the strongest reducing agent.
<strong>Given the following half-cell reduction potentials, determine which of the following is the strongest reducing agent.   </strong> A) In<sup>3+</sup> B) In C) Pd<sup>2+</sup> D) Pd E) Cannot be determined from cell potentials alone <div style=padding-top: 35px>

A) In3+
B) In
C) Pd2+
D) Pd
E) Cannot be determined from cell potentials alone
Question
Use the following half reactions and accompanying standard reduction potentials to determine the best reducing agent. <strong>Use the following half reactions and accompanying standard reduction potentials to determine the best reducing agent.	  </strong> A) Ga<sup>3+</sup> B) Be<sup>2+</sup> C) Be D) Pd<sup>2+</sup> E) Pd <div style=padding-top: 35px>

A) Ga3+
B) Be2+
C) Be
D) Pd2+
E) Pd
Question
Given the following half-cell reduction potentials, determine which metal is the best reducing agent.
Co2+ + 2e - \rightarrow Co E  <strong>Given the following half-cell reduction potentials, determine which metal is the best reducing agent. Co<sup>2+</sup> + 2e <sup>-</sup>    \rightarrow   Co E    = -0.28 V Pd<sup>2+</sup> + 2e <sup>-</sup> <sup> </sup>  \rightarrow   Pd E   = +0.987 V Cd<sup>2+</sup> + 2e <sup>-</sup> <sup> </sup>  \rightarrow   Cd E    = -0.403 V</strong> A) Co B) Pd C) Cd D) None would be a good reducing agent. <div style=padding-top: 35px>  = -0.28 V
Pd2+ + 2e - \rightarrow Pd E 11ee9f07_2055_deec_9fac_e13ec1386541_TB9692_11 = +0.987 V
Cd2+ + 2e - \rightarrow Cd E 11ee9f07_2055_deec_9fac_e13ec1386541_TB9692_11 = -0.403 V

A) Co
B) Pd
C) Cd
D) None would be a good reducing agent.
Question
Given the following redox reactions and cell potentials, rank from weakest to strongest the relative strengths of Al, Fe, and Cr as reducing agents. Al(s) + Cr3+(aq) \rightarrow Al3+(aq) + Cr(s)     Eo = +0.966 V
Fe(s) + Cr3+(aq) \rightarrow Fe3+(aq) + Cr(s)     Eo = -0.70 V

A) Cr < Fe < Al
B) Al < Fe < Cr
C) Al < Cr < Fe
D) Fe < Cr < Al
E) Fe < Al < Cr
Question
Use a table of standard reduction potentials to determine which of the following is the strongest oxidizing agent.

A) H2O2 in base
B) H2O2 in acid
C) O2 in acid
D) CrO42- in acid
E) Br2
Question
Use a table of standard reduction potentials to determine which is the strongest oxidizing agent among the following.

A) Cl2 gas at 1 atm pressure
B) O2 gas at 1 atm pressure in contact with 1 M acid
C) F2 gas at 1 atm pressure
D) Ag metal
E) H2O2 in acid solution
Question
Which of the following pairs of ions can't coexist in aqueous solution under standard-state conditions because a spontaneous redox reaction occurs?

A) Sn4+ and Fe3+
B) Sn4+ and Fe2+
C) Sn2+ and Fe3+
D) Sn2+ and Fe2+
E) None of these pairs of ions can coexist.
Question
Which is the strongest oxidizing agent?

A) Ce4+
B) Ce3+
C) H+
D) Cr2+
E) Mg
Question
Which of the following reagents should react with H+ to produce H2?

A) either Mg2+ and Cr2+
B) either Pd and Cr2+
C) either Pd2+
D) either Mg and Cr
E) Mg, Cr, and Pd
Question
Which of the following pairs of ions cannot coexist in solution because a spontaneous redox reaction occurs?

A) Cu2+ and Zn2+
B) Fe3+ and Hg22+
C) Cu2+ and I-
D) Al3+ and S2-
E) All of these pairs of ions can coexist.
Question
Cobalt(III) oxide reacts with hydrogen gas to form cobalt metal and water.
Co2O3(s) + 3 H2(g) \rightarrow 2 Co(s) + 3 H2O(g)
What does this tell you about the relative strength of the oxidizing and reducing agents in this reaction?

A) The Co3+ ion is a stronger reducing agent than cobalt metal.
B) Cobalt metal is a better reducing agent than water.
C) Cobalt metal is a weaker reducing agent than hydrogen.
D) The Co3+ ion is a weaker oxidizing agent than water.
E) Statements (a) through (d) above are all false.
Question
The equilibrium constant at 298 K for the following reaction is 1.2 x 105.
H2(g) + Sn4+(aq) \rightarrow 2 H+(aq) + Sn2+(aq)
What is the value of E° for the reaction?

A) -0.15 V
B) 0.15 V
C) 0.30 V
D) 0.35 V
E) 0.45 V
Question
The equilibrium constant at 25 oC for the following reaction is 2 x 10-3.
H2(g) + 2Ru3+(aq) \rightarrow 2 H+(aq) + 2Ru2+(aq)
What is the value of E° for the reaction?

A) -0.16 V
B) 0.16 V
C) 1.00 V
D) 0.00 V
E) -0.08 V
Question
Calculate the value of the Ksp for CdS at 25 °C from the following data.
CdS + 2 e- <strong>Calculate the value of the K<sub>sp</sub> for CdS at 25 °C from the following data. CdS + 2 e<sup>-</sup>   Cd + S<sup>2-</sup>     E° = -1.21 V Cd<sup>2+</sup> + 2 e<sup>-</sup>   Cd     E° = -0.40 V</strong> A) 3 x 10<sup>-55</sup> B) 4 x 10<sup>-28</sup> C) 2 x 10<sup>-14</sup> D) 3 x 10<sup>27</sup> E) 6 x 10 <div style=padding-top: 35px> Cd + S2-     E° = -1.21 V
Cd2+ + 2 e- <strong>Calculate the value of the K<sub>sp</sub> for CdS at 25 °C from the following data. CdS + 2 e<sup>-</sup>   Cd + S<sup>2-</sup>     E° = -1.21 V Cd<sup>2+</sup> + 2 e<sup>-</sup>   Cd     E° = -0.40 V</strong> A) 3 x 10<sup>-55</sup> B) 4 x 10<sup>-28</sup> C) 2 x 10<sup>-14</sup> D) 3 x 10<sup>27</sup> E) 6 x 10 <div style=padding-top: 35px> Cd     E° = -0.40 V

A) 3 x 10-55
B) 4 x 10-28
C) 2 x 10-14
D) 3 x 1027
E) 6 x 10
Question
There are two half-reactions for the reduction of O2 to H2O.
There are two half-reactions for the reduction of O<sub>2</sub> to H<sub>2</sub>O.   Use these half-reactions to calculate the ionization constant for water, K<sub>w</sub>, at 25 °C. H<sub>2</sub>O(l)   H<sup>+</sup>(aq) + OH<sup>-</sup>(aq) K<sub>w</sub> = ?<div style=padding-top: 35px>
Use these half-reactions to calculate the ionization constant for water, Kw,
at 25 °C.
H2O(l) There are two half-reactions for the reduction of O<sub>2</sub> to H<sub>2</sub>O.   Use these half-reactions to calculate the ionization constant for water, K<sub>w</sub>, at 25 °C. H<sub>2</sub>O(l)   H<sup>+</sup>(aq) + OH<sup>-</sup>(aq) K<sub>w</sub> = ?<div style=padding-top: 35px> H+(aq) + OH-(aq) Kw = ?
Question
The half-reaction reduction potentials for the mercury(I) and silver(I) ions are given below.
The half-reaction reduction potentials for the mercury(I) and silver(I) ions are given below.  <div style=padding-top: 35px>
Question
Calculate the complex dissociation equilibrium constant (Kd) for the Cd(NH3)42+ complex from the following data at 298K. <strong>Calculate the complex dissociation equilibrium constant (K<sub>d</sub>) for the Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> complex from the following data at 298K.  </strong> A) 2.7 x 10<sup>-7</sup> B) 0.19 C) 6.6 D) 3.6 x 10<sup>6</sup> E) none of the above <div style=padding-top: 35px>

A) 2.7 x 10-7
B) 0.19
C) 6.6
D) 3.6 x 106
E) none of the above
Question
Calculate the weight of sodium metal that would be produced by the electrolysis of molten sodium chloride for 1.00 hour with a 10.0-amp current.
Question
What is the ratio of the weight of Cl2 produced at the anode to the weight of Al produced at the cathode when 5 moles of electrons are passed through a molten sample of AlCl3?

A) about 2 g Cl2 per 1 g Al
B) about 4 g Cl2 per 1 g Al
C) about 8 g Cl2 per 1 g Al
D) about 16 g Cl2 per 1 g Al
E) none of the above
Question
Calculate the amount of aluminum produced in 1.00 hour by the electrolysis of molten AlCl3 if the current is 10.0 A.
Question
Suppose a beer can weighs 40.0 g. Determine the amount of time in hours that a current of 100.0 amp need to be passed through a molten AlF3 electrolysis cell to produce enough Al to replace a discarded beer can. Sketch the electrolysis cell, labeling the electrodes and showing the direction of electron flow in the external circuit as part of your answer.
Question
Which of the following electrolysis processes will produce the largest volume of Cl2 gas at STP?

A) passing 35 amps for 20 hours through an aqueous Na2SO4 solution
B) passing 10 amps for 2.69 hours through a 1 M NaCl solution
C) passing 2 moles electrons through a 1 M CaCl2 solution
D) passing 1.5 moles electrons through a 5 M CaCl2 solution
E) passing 1.4 moles electrons through a 5 M AlCl3 solution
Question
A current of 1.5 amps is applied to a 1.00 L solution of 0.100 M hydrochloric acid for 1.0 hr. What is the pH of the solution after electrolysis is complete?
Question
A molten sample of TiCl4 was electrolyzed for 10.0 hours at 12 amps. What is the ratio of the weight of Cl2 produced compared to that of Ti?

A) 0.34 g Cl2/1.00 g Ti
B) 0.68 g Cl2/1.00 g Ti
C) 0.74 g Cl2/1.00 g Ti
D) 1.48 g Cl2/1.00 g Ti
E) 2.96 g Cl2/1.00 g Ti
Question
An electric current is passed through a solution of CuSO4(aq) producing Cu(s) at the cathode and O2(g) at the anode. If 3.48 L of O2(g) measured at STP is produced at the anode, how many grams of Cu(s) must have been deposited on the cathode?

A) 3.48 g
B) 4.93 g
C) 9.87 g
D) 19.7 g
E) none of these
Question
What is the ratio by weight of Br2 to Cr if a molten sample of CrBr2 is electrolyzed for 4.00 hr. at 10.0 amps?

A) 1.05 g Br2/1 g Cr
B) 1.54 g Br2/1 g Cr
C) 2.05 g Br2/1 g Cr
D) 3.07 g Br2/1 g Cr
E) 4.61 g Br2/1 g Cr
Question
How much Cl2 gas would be collected when a 2.00 M NaCl(aq) solution is electrolyzed for 2.00 hours with a current of 15.0 amps?

A) 0.0220 g
B) 39.7 g
C) 79.4 g
D) 159 g
E) none of the above
Question
A current of 10.0 amps over a period of 3.00 hr is passed through a solution of molten KCl. What weight of K metal is produced?

A) 0.365 g
B) 0.729 g
C) 21.9 g
D) 43.8 g
E) 87.5 g
Question
A current of 2.0 amps passed through a molten solution of the salt MCl2 for a period of 30 minutes produces 1.32 g of Cl2 gas and 0.453 g of M. Which of the following metals is present in this compound?

A) Mg
B) Ca
C) Zn
D) Sr
E) Hg
Question
What is the oxidation state of the osmium atom in an unknown salt if 26.7 grams of osmium plate out when a current of 15.0 amps is passed through a solution of this salt for 1.00 hour?

A) Os+
B) Os2+
C) Os3+
D) Os4+
E) Os5+
Question
What is the oxidation state of the cerium atom in CexZy if a current of 1.2 amps for 3.0 hours deposits 4.70 g of Ce at the cathode?

A) 0
B) +1
C) +2
D) +3
E) +4
Question
What is the oxidation state of the tin atom in an unknown salt if 14.8 grams of tin are plated out when a current of 40 amps is passed through a molten solution of this salt for 10 minutes?

A) +1
B) +2
C) +3
D) +4
E) +6
Question
Which of the following is the correct half-cell reaction for the anode process in the electrolysis of an aqueous solution of potassium sulfate?

A) SO42-(aq) \rightarrow SO2(g) + O2(g) + 2 e-
B) H2O(l) \rightarrow 1/2 O2(g) + 2 H+(aq) + 2 e-
C) H2O(l) + 1/2 O2(g) + 2 e- \rightarrow 2 OH-(aq)
D) SO42-(aq) + 4 H+(aq) + 2 e- \rightarrow SO2(g) + 2 H2O(l)
E) 3 H2O(l) + e- \rightarrow 1/2 H2(g) + 3 OH-(aq) + 2 H+(aq)
Question
Which of the following statements about the electrolysis of an aqueous solution of NaCl is true?

A) O2 is liberated at the cathode.
B) H2 is liberated at the cathode.
C) Na is liberated at the cathode.
D) Cl2 is liberated at the cathode.
E) The decomposition potential must not be exceeded.
Question
In the electrolysis of NaBr(aq), which of the following products is least likely to be found?

A) H2(g)
B) O2(g)
C) Br2(l)
D) Na(s)
E) NaOH(aq)
Question
What is the correct coefficient for Na2MnO4 in the balanced equation for the air oxidation of manganese dioxide to sodium manganate in the presence of sodium carbonate?
MnO2(s) + Na2CO3(aq) + O2(g) \rightarrow CO2(g) + Na2MnO4(aq)

A) 1
B) 3/2
C) 2
D) 5/2
E) 3
Question
What is the coefficient for sulfur in the following redox reaction?
S(s) + KClO3(s) \rightarrow SO2(g) + KCl(s) + bang!

A) 1
B) 2
C) 3
D) 4
E) 5
Question
The following equation, when balanced, involves a total of ___ electrons.
ClO3-(aq) + I2(aq) + H2O(l) \rightarrow IO3-(aq) + Cl-(aq) + H+(aq)

A) 5
B) 6
C) 12
D) 24
E) 30
Question
Complete and balance the following equation:
PbO2(s) + Cl-(aq) + H+(aq) \rightarrow Pb2+(aq) + Cl2(aq)
Question
refer to the following reaction in acid solution.
CuS(s) + NO3-(aq) <strong> refer to the following reaction in acid solution. CuS(s) + NO<sub>3</sub><sup>-</sup>(aq)   Cu<sup>2+</sup>(aq) + SO<sub>4</sub><sup>2-</sup>(aq) + NO(g)  -In the balanced half-reaction for the NO<sub>3</sub><sup>-</sup> ion, how many electrons are involved?</strong> A) 1 B) 2 C) 3 D) 4 E) none of these <div style=padding-top: 35px> Cu2+(aq) + SO42-(aq) + NO(g)

-In the balanced half-reaction for the NO3- ion, how many electrons are involved?

A) 1
B) 2
C) 3
D) 4
E) none of these
Question
Which of the following isn't true?

A) The reducing agent is CuS.
B) The CuS is oxidized.
C) The NO3- ion is the oxidizing agent.
D) The NO3- ion is reduced.
E) The oxidation number of the copper changes from 0 to +2.
Question
Write a balanced chemical equation for the following reaction.
MnO2(s) + PbO2(s) + H+(aq) \rightarrow MnO4-(aq) + Pb2+(aq)
Question
refer to the following incomplete, unbalanced equation
Cr2O72-(aq) + NO(g)
<strong>refer to the following incomplete, unbalanced equation Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + NO(g)   Cr<sup>3+</sup>(aq) + NO<sub>3</sub><sup>-</sup>(aq)  -How many electrons are in the half-reaction involving Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>?</strong> A) 2 B) 3 C) 4 D) 5 E) 6 <div style=padding-top: 35px> Cr3+(aq) + NO3-(aq)

-How many electrons are in the half-reaction involving Cr2O72-?

A) 2
B) 3
C) 4
D) 5
E) 6
Question
refer to the following incomplete, unbalanced equation
Cr2O72-(aq) + NO(g)
<strong>refer to the following incomplete, unbalanced equation Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + NO(g)   Cr<sup>3+</sup>(aq) + NO<sub>3</sub><sup>-</sup>(aq)  -What is the coefficient of the NO in the balanced equation?</strong> A) 1 B) 2 C) 3 D) 4 E) 6 <div style=padding-top: 35px> Cr3+(aq) + NO3-(aq)

-What is the coefficient of the NO in the balanced equation?

A) 1
B) 2
C) 3
D) 4
E) 6
Question
Write a balanced chemical equation for the following reaction, which can be used to standardize aqueous permanganate ion solutions.
H2C2O4(aq) + MnO4-(aq) + H+(aq) \rightarrow CO2(g) + Mn2+(aq)
Question
Balance the following redox reaction. Clearly show the two balanced half-reactions and indicate which represents oxidation and which reduction.
H2O2(aq) + NO(g) + H+(aq) \rightarrow NO3-(aq)
Question
Balance the following oxidation-reduction equation.
HI(aq) + HNO3(aq) \rightarrow NO(g) + I2(aq)
Question
Balance the following oxidation-reduction equation.
CrO42-(aq) + HSnO2-(aq)
Balance the following oxidation-reduction equation. CrO<sub>4</sub><sup>2-</sup>(aq) + HSnO<sub>2</sub><sup>-</sup>(aq)   HSnO<sub>3</sub><sup>-</sup>(aq) + CrO<sub>2</sub><sup>-</sup>(aq)<div style=padding-top: 35px>
HSnO3-(aq) + CrO2-(aq)
Question
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-How many OCl- ions are consumed in the balanced equation for this reaction?

A) 2
B) 3
C) 4
D) 5
E) 6
Question
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-How many OH- ions are involved in the simplest balanced equation for this reaction?

A) 0
B) 1
C) 2
D) 3
E) 4
Question
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-What is the net effect on the OH- ion concentration in this reaction?

A) The OH- ion concentration increases.
B) The OH- ion concentration decreases.
C) The OH- ion concentration remains the same.
D) There is no way to predict what happens to the OH- ion concentration in this reaction.
Question
refer to the following reaction which occurs in basic solution.
CrO42- + PH3 \rightarrow Cr(OH)4- + P4

-Which of the following are oxidizing agents in the forward and reverse directions, respectively?

A) CrO42- and PH3
B) CrO42- and P4
C) Cr(OH)4- and PH3
D) Cr(OH)4- and P4
E) CrO42- and OH-
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Deck 12: Oxidation-Reduction Reactions
1
<strong>‪   Determining Oxidation Numbers  -What is the oxidation number of the carbon in bold print in the following structure?   </strong> A) -1 B) +2 C) -3 D) +4 E) none of these
Determining Oxidation Numbers

-What is the oxidation number of the carbon in bold print in the following structure?
<strong>‪   Determining Oxidation Numbers  -What is the oxidation number of the carbon in bold print in the following structure?   </strong> A) -1 B) +2 C) -3 D) +4 E) none of these

A) -1
B) +2
C) -3
D) +4
E) none of these
+2
2
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation number of the bold face carbon atom in pyruvic acid:   </strong> A)-2 B) +2 C) +3 D) +4 E) none of these
Determining Oxidation Numbers

-Determine the oxidation number of the bold face carbon atom in pyruvic acid:
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation number of the bold face carbon atom in pyruvic acid:   </strong> A)-2 B) +2 C) +3 D) +4 E) none of these

A)-2
B) +2
C) +3
D) +4
E) none of these
+2
3
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation number for bromine in HBrO<sub>4</sub>.</strong> A) +6 B) +7 C) +8 D) -6 E) -7
Determining Oxidation Numbers

-Determine the oxidation number for bromine in HBrO4.

A) +6
B) +7
C) +8
D) -6
E) -7
+7
4
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom in bold print: CH<sub>3</sub>CH<sub>2</sub>F</strong> A) 0 B) +1 C) +2 D) +3 E)-1
Determining Oxidation Numbers

-Determine the oxidation state of the carbon atom in bold print:
CH3CH2F

A) 0
B) +1
C) +2
D) +3
E)-1
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5
? <strong>?   Determining Oxidation Numbers  -Determine the oxidation number of arsenic in the anion, HAsO<sub>4</sub><sup>2</sup> <sup>-</sup> .</strong> A) +5 B) +6 C) +7 D) +8 E) none of these
Determining Oxidation Numbers

-Determine the oxidation number of arsenic in the anion, HAsO42 - .

A) +5
B) +6
C) +7
D) +8
E) none of these
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6
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom shown in bold in the following compound:   </strong> A) -1 B) 0 C) +1 D) +4 E) none of these
Determining Oxidation Numbers

-Determine the oxidation state of the carbon atom shown in bold in the following compound:
<strong>‪   Determining Oxidation Numbers  -Determine the oxidation state of the carbon atom shown in bold in the following compound:   </strong> A) -1 B) 0 C) +1 D) +4 E) none of these

A) -1
B) 0
C) +1
D) +4
E) none of these
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7
The carbon in bold in the ethanol has an oxidation number of __ while the carbon in bold in acetic acid has an oxidation number of ___.

A) -1, +3
B) +1, +2
C) -2, +3
D) +2, -3
E) none of the above
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8
Which of the following statements about this reaction is correct?

A) H+ is the oxidizing agent and dichromate is the reducing agent.
B) Dichromate is oxidized and ethanol is reduced.
C) Ethanol is the reducing agent and dichromate is the oxidizing agent.
D) This is not an oxidation-reduction reaction.
E) None of the above statements is correct.
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9
How many electrons are transferred in the following oxidation-reduction reaction?
3 Sn2+(aq) + Cr2O72-(aq) + 14 H+ <strong>How many electrons are transferred in the following oxidation-reduction reaction? 3 Sn<sup>2+</sup>(aq) + Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + 14 H<sup>+</sup>   3 Sn<sup>4+</sup>(aq) + 2 Cr<sup>3+</sup>(aq) + 7 H<sub>2</sub>O(l)</strong> A) 2 B) 6 C) 12 D) 14 E) none of these 3 Sn4+(aq) + 2 Cr3+(aq) + 7 H2O(l)

A) 2
B) 6
C) 12
D) 14
E) none of these
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10
Which of the following isn't an example of an oxidation-reduction reaction?

A) Ca3P2(s) + 6 H2O(l) \rightarrow 3 Ca2+(aq) + 6 OH-(aq) + 2 PH3(g)
B) 2 PH3(g) + 4 O2(g) \rightarrow H3PO4(s)
C) P4(s) + 5 O2(g) \rightarrow P4O10(s)
D) 6 Ca(s) + P4(s) \rightarrow 2 Ca3P2(s)
E) All of the above are oxidation-reduction reactions.
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11
Which of the following isn't an example of an oxidation-reduction reaction?

A) H2(g) + Cl2(g) \rightarrow 2 HCl(g)
B) Ag+(aq) + 2 NH3(g)  <strong>Which of the following isn't an example of an oxidation-reduction reaction?</strong> A) H<sub>2</sub>(g) + Cl<sub>2</sub>(g)   \rightarrow  2 HCl(g) B) Ag<sup>+</sup>(aq) + 2 NH<sub>3</sub>(g)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq) C) Hg<sub>2</sub>Cl<sub>2</sub>(s) + NH<sub>3</sub>(g)   \rightarrow   Hg(s) + HgNH<sub>2</sub>Cl(s) D) 2 Mg(s) + O<sub>2</sub>(g)<sub> </sub>  \rightarrow   2MgO(s) E) Cl<sub>2</sub>(g) + 2 Br<sup>-</sup>(aq)   \rightarrow   2 Cl<sup>-</sup>(aq) + Br<sub>2</sub>(l)  Ag(NH3)2+(aq)
C) Hg2Cl2(s) + NH3(g) \rightarrow Hg(s) + HgNH2Cl(s)
D) 2 Mg(s) + O2(g) \rightarrow 2MgO(s)
E) Cl2(g) + 2 Br-(aq) \rightarrow 2 Cl-(aq) + Br2(l)
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12
A voltaic cell is constructed with a Pt wire in an aqueous solution of Br2/Br - (1M) serving as the cathode and a silver wire in a 1M solution of Ag+ serving as the anode. The potential of the cell was measured to be +0.287 V. The standard reduction potential for Br2/Br - is 1.087 V.
(I) Write the half-reaction for the reduction taking place in the cell.
(II) Write the half-reaction for the oxidation taking place in the cell.
(III) Write the overall reaction for the oxidation-reduction reaction taking place in the cell.
(IV) Calculate the potential for the Ag/Ag+ half-reaction taking place in the cell.
(V) Determine the standard reduction potential, E°, for the half-reaction below.
Ag+(aq) + e- \rightarrow Ag(s)
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13
What will be the coefficients of Ce4+ and Cl - , respectively when the following reaction is balanced?
Ce4+(aq) + Cl - (aq) \rightarrow Cl2(aq) + Ce3+(aq)

A) 1,1
B) 1,2
C) 2.1
D) 2.2
E) 3,1
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14
Use a table of standard reduction potentials to determine which of the following statements is true for the electrochemical cell diagrammed below. <strong>Use a table of standard reduction potentials to determine which of the following statements is true for the electrochemical cell diagrammed below.    </strong> A) The Al is the cathode. B) Electrons move from the Al electrode to the Fe electrode. C) The mass of the Al electrode decreases. D) Both (b) and (c) are true. . E) Both (a) and (c) are true

A) The Al is the cathode.
B) Electrons move from the Al electrode to the Fe electrode.
C) The mass of the Al electrode decreases.
D) Both (b) and (c) are true. .
E) Both (a) and (c) are true
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15
Use the table of electrode potentials to determine which of the following reactions isn't spontaneous under standard conditions.

A) Zn(s) + 2 H+(aq) \rightarrow Zn2+(aq) + H2(g)
B) 2 Ag(s) + Zn2+(aq) \rightarrow 2 Ag+(aq) + Zn(s)
C) Cl2(aq) + 2 Fe2+(aq) \rightarrow 2 Cl-(aq) + 2 Fe3+(aq)
D) 2 Al(s) + 3/2 O2(g) + 6 H+(aq) \rightarrow 2 Al3+(aq) + 3 H2O(l)
E) Mg(s) + Cl2(g) \rightarrow MgCl2(s)
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16
Consider the following generalized half-reactions.
Aox + e- <strong>Consider the following generalized half-reactions. A<sub>ox</sub> + e<sup>-</sup>   A<sub>red</sub> B<sub>ox</sub> + e<sup>-</sup>   B<sub>red</sub> If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:</strong> A) A<sub>ox</sub> will reduce B<sub>ox</sub> B) A<sub>red</sub> will reduce B<sub>ox</sub> C) B<sub>red </sub>will reduce A<sub>ox</sub> D) B<sub>red</sub> will reduce A<sub>red</sub> E) no reaction will occur Ared
Box + e- <strong>Consider the following generalized half-reactions. A<sub>ox</sub> + e<sup>-</sup>   A<sub>red</sub> B<sub>ox</sub> + e<sup>-</sup>   B<sub>red</sub> If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:</strong> A) A<sub>ox</sub> will reduce B<sub>ox</sub> B) A<sub>red</sub> will reduce B<sub>ox</sub> C) B<sub>red </sub>will reduce A<sub>ox</sub> D) B<sub>red</sub> will reduce A<sub>red</sub> E) no reaction will occur Bred
If E° for the half-reaction involving A is positive and if E° for the half-reaction involving B is negative, then at standard conditions:

A) Aox will reduce Box
B) Ared will reduce Box
C) Bred will reduce Aox
D) Bred will reduce Ared
E) no reaction will occur
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17
The potential of a cell at standard state conditions can be best be described as:

A) Eo
B) 0 volts
C) negative
D) more than one volt
E) None of the above
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18
What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations?
Oxidation: Al <strong>What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations? Oxidation: Al   Al<sup>3+</sup> + 3 e<sup>-</sup> Reduction: Zn<sup>2+</sup> + 2 e<sup>-</sup>   Zn</strong> A) -3.59 V B) -0.943 V C) 0.943 V D) 1.12 V E) 3.59 V Al3+ + 3 e-
Reduction: Zn2+ + 2 e- <strong>What is the potential for a voltaic cell produced from the following half-reactions, if all ions are present at 1.0 M concentrations? Oxidation: Al   Al<sup>3+</sup> + 3 e<sup>-</sup> Reduction: Zn<sup>2+</sup> + 2 e<sup>-</sup>   Zn</strong> A) -3.59 V B) -0.943 V C) 0.943 V D) 1.12 V E) 3.59 V Zn

A) -3.59 V
B) -0.943 V
C) 0.943 V
D) 1.12 V
E) 3.59 V
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19
What is the standard cell potential for the following redox reaction?
2 Fe3+(aq) + 2 I-(aq) \rightarrow 2 Fe2+(aq) + I2(aq)

A) -1.30 V
B) -0.24 V
C) 0.24 V
D) 1.30 V
E) none of the above
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20
What is the magnitude of the standard-state cell potential for the following redox reaction?
2 Al(s) + 3 Pb2+(aq) \rightarrow 2 Al3+(aq) + 3 Pb(s)

A) 1.58 V
B) 1.83 V
C) 3.03 V
D) 3.790 V
E) 4.866 V
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21
Oxidation-reduction reactions are often written with double arrows indicating that the reaction can go in either direction depending on the experimental conditions. For the following reaction identify the oxidizing agent on both sides of the chemical equation.
S2O82-(aq) + Zn(s) <strong>Oxidation-reduction reactions are often written with double arrows indicating that the reaction can go in either direction depending on the experimental conditions. For the following reaction identify the oxidizing agent on both sides of the chemical equation. S<sub>2</sub>O<sub>8</sub><sup>2-</sup>(aq) + Zn(s)   Zn<sup>2+</sup>(aq) + 2 SO<sub>4</sub><sup>2-</sup>(aq)</strong> A) S<sub>2</sub>O<sub>8</sub><sup>2-</sup> and SO<sub>4</sub><sup>2-</sup> B) Zn and SO<sub>4</sub><sup>2-</sup> C) Zn and Zn<sup>2+</sup> D) S<sub>2</sub>O<sub>8</sub><sup>2-</sup> and Zn<sup>2+</sup> E) none of these Zn2+(aq) + 2 SO42-(aq)

A) S2O82- and SO42-
B) Zn and SO42-
C) Zn and Zn2+
D) S2O82- and Zn2+
E) none of these
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22
Which statement correctly describes the following oxidation-reduction reaction?
5Cr3+(aq) + 3 MnO4 - (aq) + 8 H2O (l) \rightarrow 5 CrO42 - (aq) + 3 Mn2+(aq) + 16 H+(aq)

A) MnO4 - and H2O are both reduced.
B) Cr3+ is the reducing agent.
C) Cr3+ and H2O are both reducing agents.
D) MnO4 - is oxidized.
E) None of these are correct.
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23
Which of the following is true about the reaction below?
2VO2+ (aq) + Br2(s) + 2 H2O(l) \rightarrow 2VO2+(aq) + 2 Br - (aq) + 4H+

A) Br2 is acting as a reducing agent.
B) VO2+ is acting as a weak reducing agent.
C) VO2+ is oxidized.
D) H2O is reduced.
E) H+ is acting as a weak reducing agent.
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24
Identify each of the requested compounds for the following redox reaction.
2 MnO4 - (aq) + 16 H+(aq) + 10 Cl - (aq) \rightarrow 2 Mn2+(aq) + 8 H2O + 5 Cl2(g)
(I) oxidizing agent
(II) reducing agent
(III) conjugate oxidizing agent
(IV) conjugate reducing agent
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25
Which statement correctly describes the following reaction?
O2(g) + 4 H+(aq) + 4 Cl - (aq) \rightarrow 2 H2O(l) + 2 Cl2(g)

A) O2 is a reducing agent.
B) H+ and Cl - are oxidized.
C) H+ is reduced.
D) H+ is a reducing agent.
E) Cl - is a reducing agent.
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26
For the following reaction, identify the oxidizing agents in the forward and reverse directions, respectively..
P4(s) + HNO3(aq) \rightarrow H3PO4(aq) + NO(g)

A) P4 and H3PO4
B) P4 and NO
C) P4 and HNO3
D) HNO3 and H3PO4
E) HNO3 and NO
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27
For the reaction:
3 Sn2+(aq) + Cr2O72-(aq) + 14 H+(aq) \rightarrow 3 Sn4+(aq) + 2 Cr3+(aq) + 7 H2O(l)
Which of the following statements is true?

A) Both Sn2+ and H+ are oxidizing agents.
B) Cr2O72- is the oxidizing agent.
C) Sn2+ is reduced.
D) The acid isn't important to the reaction.
E) None of the above are true.
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28
Use a table of standard reduction potentials to determine which of the following is the strongest reducing agent.

A) Co
B) Ca2+
C) Co3+
D) Cr
E) Au
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29
Given the following half-cell reduction potentials, determine which of the following is the strongest reducing agent.
<strong>Given the following half-cell reduction potentials, determine which of the following is the strongest reducing agent.   </strong> A) In<sup>3+</sup> B) In C) Pd<sup>2+</sup> D) Pd E) Cannot be determined from cell potentials alone

A) In3+
B) In
C) Pd2+
D) Pd
E) Cannot be determined from cell potentials alone
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30
Use the following half reactions and accompanying standard reduction potentials to determine the best reducing agent. <strong>Use the following half reactions and accompanying standard reduction potentials to determine the best reducing agent.	  </strong> A) Ga<sup>3+</sup> B) Be<sup>2+</sup> C) Be D) Pd<sup>2+</sup> E) Pd

A) Ga3+
B) Be2+
C) Be
D) Pd2+
E) Pd
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31
Given the following half-cell reduction potentials, determine which metal is the best reducing agent.
Co2+ + 2e - \rightarrow Co E  <strong>Given the following half-cell reduction potentials, determine which metal is the best reducing agent. Co<sup>2+</sup> + 2e <sup>-</sup>    \rightarrow   Co E    = -0.28 V Pd<sup>2+</sup> + 2e <sup>-</sup> <sup> </sup>  \rightarrow   Pd E   = +0.987 V Cd<sup>2+</sup> + 2e <sup>-</sup> <sup> </sup>  \rightarrow   Cd E    = -0.403 V</strong> A) Co B) Pd C) Cd D) None would be a good reducing agent.  = -0.28 V
Pd2+ + 2e - \rightarrow Pd E 11ee9f07_2055_deec_9fac_e13ec1386541_TB9692_11 = +0.987 V
Cd2+ + 2e - \rightarrow Cd E 11ee9f07_2055_deec_9fac_e13ec1386541_TB9692_11 = -0.403 V

A) Co
B) Pd
C) Cd
D) None would be a good reducing agent.
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32
Given the following redox reactions and cell potentials, rank from weakest to strongest the relative strengths of Al, Fe, and Cr as reducing agents. Al(s) + Cr3+(aq) \rightarrow Al3+(aq) + Cr(s)     Eo = +0.966 V
Fe(s) + Cr3+(aq) \rightarrow Fe3+(aq) + Cr(s)     Eo = -0.70 V

A) Cr < Fe < Al
B) Al < Fe < Cr
C) Al < Cr < Fe
D) Fe < Cr < Al
E) Fe < Al < Cr
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33
Use a table of standard reduction potentials to determine which of the following is the strongest oxidizing agent.

A) H2O2 in base
B) H2O2 in acid
C) O2 in acid
D) CrO42- in acid
E) Br2
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34
Use a table of standard reduction potentials to determine which is the strongest oxidizing agent among the following.

A) Cl2 gas at 1 atm pressure
B) O2 gas at 1 atm pressure in contact with 1 M acid
C) F2 gas at 1 atm pressure
D) Ag metal
E) H2O2 in acid solution
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35
Which of the following pairs of ions can't coexist in aqueous solution under standard-state conditions because a spontaneous redox reaction occurs?

A) Sn4+ and Fe3+
B) Sn4+ and Fe2+
C) Sn2+ and Fe3+
D) Sn2+ and Fe2+
E) None of these pairs of ions can coexist.
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36
Which is the strongest oxidizing agent?

A) Ce4+
B) Ce3+
C) H+
D) Cr2+
E) Mg
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37
Which of the following reagents should react with H+ to produce H2?

A) either Mg2+ and Cr2+
B) either Pd and Cr2+
C) either Pd2+
D) either Mg and Cr
E) Mg, Cr, and Pd
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38
Which of the following pairs of ions cannot coexist in solution because a spontaneous redox reaction occurs?

A) Cu2+ and Zn2+
B) Fe3+ and Hg22+
C) Cu2+ and I-
D) Al3+ and S2-
E) All of these pairs of ions can coexist.
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39
Cobalt(III) oxide reacts with hydrogen gas to form cobalt metal and water.
Co2O3(s) + 3 H2(g) \rightarrow 2 Co(s) + 3 H2O(g)
What does this tell you about the relative strength of the oxidizing and reducing agents in this reaction?

A) The Co3+ ion is a stronger reducing agent than cobalt metal.
B) Cobalt metal is a better reducing agent than water.
C) Cobalt metal is a weaker reducing agent than hydrogen.
D) The Co3+ ion is a weaker oxidizing agent than water.
E) Statements (a) through (d) above are all false.
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40
The equilibrium constant at 298 K for the following reaction is 1.2 x 105.
H2(g) + Sn4+(aq) \rightarrow 2 H+(aq) + Sn2+(aq)
What is the value of E° for the reaction?

A) -0.15 V
B) 0.15 V
C) 0.30 V
D) 0.35 V
E) 0.45 V
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41
The equilibrium constant at 25 oC for the following reaction is 2 x 10-3.
H2(g) + 2Ru3+(aq) \rightarrow 2 H+(aq) + 2Ru2+(aq)
What is the value of E° for the reaction?

A) -0.16 V
B) 0.16 V
C) 1.00 V
D) 0.00 V
E) -0.08 V
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42
Calculate the value of the Ksp for CdS at 25 °C from the following data.
CdS + 2 e- <strong>Calculate the value of the K<sub>sp</sub> for CdS at 25 °C from the following data. CdS + 2 e<sup>-</sup>   Cd + S<sup>2-</sup>     E° = -1.21 V Cd<sup>2+</sup> + 2 e<sup>-</sup>   Cd     E° = -0.40 V</strong> A) 3 x 10<sup>-55</sup> B) 4 x 10<sup>-28</sup> C) 2 x 10<sup>-14</sup> D) 3 x 10<sup>27</sup> E) 6 x 10 Cd + S2-     E° = -1.21 V
Cd2+ + 2 e- <strong>Calculate the value of the K<sub>sp</sub> for CdS at 25 °C from the following data. CdS + 2 e<sup>-</sup>   Cd + S<sup>2-</sup>     E° = -1.21 V Cd<sup>2+</sup> + 2 e<sup>-</sup>   Cd     E° = -0.40 V</strong> A) 3 x 10<sup>-55</sup> B) 4 x 10<sup>-28</sup> C) 2 x 10<sup>-14</sup> D) 3 x 10<sup>27</sup> E) 6 x 10 Cd     E° = -0.40 V

A) 3 x 10-55
B) 4 x 10-28
C) 2 x 10-14
D) 3 x 1027
E) 6 x 10
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43
There are two half-reactions for the reduction of O2 to H2O.
There are two half-reactions for the reduction of O<sub>2</sub> to H<sub>2</sub>O.   Use these half-reactions to calculate the ionization constant for water, K<sub>w</sub>, at 25 °C. H<sub>2</sub>O(l)   H<sup>+</sup>(aq) + OH<sup>-</sup>(aq) K<sub>w</sub> = ?
Use these half-reactions to calculate the ionization constant for water, Kw,
at 25 °C.
H2O(l) There are two half-reactions for the reduction of O<sub>2</sub> to H<sub>2</sub>O.   Use these half-reactions to calculate the ionization constant for water, K<sub>w</sub>, at 25 °C. H<sub>2</sub>O(l)   H<sup>+</sup>(aq) + OH<sup>-</sup>(aq) K<sub>w</sub> = ? H+(aq) + OH-(aq) Kw = ?
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44
The half-reaction reduction potentials for the mercury(I) and silver(I) ions are given below.
The half-reaction reduction potentials for the mercury(I) and silver(I) ions are given below.
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45
Calculate the complex dissociation equilibrium constant (Kd) for the Cd(NH3)42+ complex from the following data at 298K. <strong>Calculate the complex dissociation equilibrium constant (K<sub>d</sub>) for the Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> complex from the following data at 298K.  </strong> A) 2.7 x 10<sup>-7</sup> B) 0.19 C) 6.6 D) 3.6 x 10<sup>6</sup> E) none of the above

A) 2.7 x 10-7
B) 0.19
C) 6.6
D) 3.6 x 106
E) none of the above
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46
Calculate the weight of sodium metal that would be produced by the electrolysis of molten sodium chloride for 1.00 hour with a 10.0-amp current.
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47
What is the ratio of the weight of Cl2 produced at the anode to the weight of Al produced at the cathode when 5 moles of electrons are passed through a molten sample of AlCl3?

A) about 2 g Cl2 per 1 g Al
B) about 4 g Cl2 per 1 g Al
C) about 8 g Cl2 per 1 g Al
D) about 16 g Cl2 per 1 g Al
E) none of the above
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48
Calculate the amount of aluminum produced in 1.00 hour by the electrolysis of molten AlCl3 if the current is 10.0 A.
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49
Suppose a beer can weighs 40.0 g. Determine the amount of time in hours that a current of 100.0 amp need to be passed through a molten AlF3 electrolysis cell to produce enough Al to replace a discarded beer can. Sketch the electrolysis cell, labeling the electrodes and showing the direction of electron flow in the external circuit as part of your answer.
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50
Which of the following electrolysis processes will produce the largest volume of Cl2 gas at STP?

A) passing 35 amps for 20 hours through an aqueous Na2SO4 solution
B) passing 10 amps for 2.69 hours through a 1 M NaCl solution
C) passing 2 moles electrons through a 1 M CaCl2 solution
D) passing 1.5 moles electrons through a 5 M CaCl2 solution
E) passing 1.4 moles electrons through a 5 M AlCl3 solution
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51
A current of 1.5 amps is applied to a 1.00 L solution of 0.100 M hydrochloric acid for 1.0 hr. What is the pH of the solution after electrolysis is complete?
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52
A molten sample of TiCl4 was electrolyzed for 10.0 hours at 12 amps. What is the ratio of the weight of Cl2 produced compared to that of Ti?

A) 0.34 g Cl2/1.00 g Ti
B) 0.68 g Cl2/1.00 g Ti
C) 0.74 g Cl2/1.00 g Ti
D) 1.48 g Cl2/1.00 g Ti
E) 2.96 g Cl2/1.00 g Ti
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53
An electric current is passed through a solution of CuSO4(aq) producing Cu(s) at the cathode and O2(g) at the anode. If 3.48 L of O2(g) measured at STP is produced at the anode, how many grams of Cu(s) must have been deposited on the cathode?

A) 3.48 g
B) 4.93 g
C) 9.87 g
D) 19.7 g
E) none of these
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54
What is the ratio by weight of Br2 to Cr if a molten sample of CrBr2 is electrolyzed for 4.00 hr. at 10.0 amps?

A) 1.05 g Br2/1 g Cr
B) 1.54 g Br2/1 g Cr
C) 2.05 g Br2/1 g Cr
D) 3.07 g Br2/1 g Cr
E) 4.61 g Br2/1 g Cr
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55
How much Cl2 gas would be collected when a 2.00 M NaCl(aq) solution is electrolyzed for 2.00 hours with a current of 15.0 amps?

A) 0.0220 g
B) 39.7 g
C) 79.4 g
D) 159 g
E) none of the above
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56
A current of 10.0 amps over a period of 3.00 hr is passed through a solution of molten KCl. What weight of K metal is produced?

A) 0.365 g
B) 0.729 g
C) 21.9 g
D) 43.8 g
E) 87.5 g
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57
A current of 2.0 amps passed through a molten solution of the salt MCl2 for a period of 30 minutes produces 1.32 g of Cl2 gas and 0.453 g of M. Which of the following metals is present in this compound?

A) Mg
B) Ca
C) Zn
D) Sr
E) Hg
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58
What is the oxidation state of the osmium atom in an unknown salt if 26.7 grams of osmium plate out when a current of 15.0 amps is passed through a solution of this salt for 1.00 hour?

A) Os+
B) Os2+
C) Os3+
D) Os4+
E) Os5+
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59
What is the oxidation state of the cerium atom in CexZy if a current of 1.2 amps for 3.0 hours deposits 4.70 g of Ce at the cathode?

A) 0
B) +1
C) +2
D) +3
E) +4
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60
What is the oxidation state of the tin atom in an unknown salt if 14.8 grams of tin are plated out when a current of 40 amps is passed through a molten solution of this salt for 10 minutes?

A) +1
B) +2
C) +3
D) +4
E) +6
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61
Which of the following is the correct half-cell reaction for the anode process in the electrolysis of an aqueous solution of potassium sulfate?

A) SO42-(aq) \rightarrow SO2(g) + O2(g) + 2 e-
B) H2O(l) \rightarrow 1/2 O2(g) + 2 H+(aq) + 2 e-
C) H2O(l) + 1/2 O2(g) + 2 e- \rightarrow 2 OH-(aq)
D) SO42-(aq) + 4 H+(aq) + 2 e- \rightarrow SO2(g) + 2 H2O(l)
E) 3 H2O(l) + e- \rightarrow 1/2 H2(g) + 3 OH-(aq) + 2 H+(aq)
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62
Which of the following statements about the electrolysis of an aqueous solution of NaCl is true?

A) O2 is liberated at the cathode.
B) H2 is liberated at the cathode.
C) Na is liberated at the cathode.
D) Cl2 is liberated at the cathode.
E) The decomposition potential must not be exceeded.
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63
In the electrolysis of NaBr(aq), which of the following products is least likely to be found?

A) H2(g)
B) O2(g)
C) Br2(l)
D) Na(s)
E) NaOH(aq)
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64
What is the correct coefficient for Na2MnO4 in the balanced equation for the air oxidation of manganese dioxide to sodium manganate in the presence of sodium carbonate?
MnO2(s) + Na2CO3(aq) + O2(g) \rightarrow CO2(g) + Na2MnO4(aq)

A) 1
B) 3/2
C) 2
D) 5/2
E) 3
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65
What is the coefficient for sulfur in the following redox reaction?
S(s) + KClO3(s) \rightarrow SO2(g) + KCl(s) + bang!

A) 1
B) 2
C) 3
D) 4
E) 5
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66
The following equation, when balanced, involves a total of ___ electrons.
ClO3-(aq) + I2(aq) + H2O(l) \rightarrow IO3-(aq) + Cl-(aq) + H+(aq)

A) 5
B) 6
C) 12
D) 24
E) 30
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67
Complete and balance the following equation:
PbO2(s) + Cl-(aq) + H+(aq) \rightarrow Pb2+(aq) + Cl2(aq)
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68
refer to the following reaction in acid solution.
CuS(s) + NO3-(aq) <strong> refer to the following reaction in acid solution. CuS(s) + NO<sub>3</sub><sup>-</sup>(aq)   Cu<sup>2+</sup>(aq) + SO<sub>4</sub><sup>2-</sup>(aq) + NO(g)  -In the balanced half-reaction for the NO<sub>3</sub><sup>-</sup> ion, how many electrons are involved?</strong> A) 1 B) 2 C) 3 D) 4 E) none of these Cu2+(aq) + SO42-(aq) + NO(g)

-In the balanced half-reaction for the NO3- ion, how many electrons are involved?

A) 1
B) 2
C) 3
D) 4
E) none of these
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69
Which of the following isn't true?

A) The reducing agent is CuS.
B) The CuS is oxidized.
C) The NO3- ion is the oxidizing agent.
D) The NO3- ion is reduced.
E) The oxidation number of the copper changes from 0 to +2.
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70
Write a balanced chemical equation for the following reaction.
MnO2(s) + PbO2(s) + H+(aq) \rightarrow MnO4-(aq) + Pb2+(aq)
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71
refer to the following incomplete, unbalanced equation
Cr2O72-(aq) + NO(g)
<strong>refer to the following incomplete, unbalanced equation Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + NO(g)   Cr<sup>3+</sup>(aq) + NO<sub>3</sub><sup>-</sup>(aq)  -How many electrons are in the half-reaction involving Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>?</strong> A) 2 B) 3 C) 4 D) 5 E) 6 Cr3+(aq) + NO3-(aq)

-How many electrons are in the half-reaction involving Cr2O72-?

A) 2
B) 3
C) 4
D) 5
E) 6
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72
refer to the following incomplete, unbalanced equation
Cr2O72-(aq) + NO(g)
<strong>refer to the following incomplete, unbalanced equation Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq) + NO(g)   Cr<sup>3+</sup>(aq) + NO<sub>3</sub><sup>-</sup>(aq)  -What is the coefficient of the NO in the balanced equation?</strong> A) 1 B) 2 C) 3 D) 4 E) 6 Cr3+(aq) + NO3-(aq)

-What is the coefficient of the NO in the balanced equation?

A) 1
B) 2
C) 3
D) 4
E) 6
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73
Write a balanced chemical equation for the following reaction, which can be used to standardize aqueous permanganate ion solutions.
H2C2O4(aq) + MnO4-(aq) + H+(aq) \rightarrow CO2(g) + Mn2+(aq)
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74
Balance the following redox reaction. Clearly show the two balanced half-reactions and indicate which represents oxidation and which reduction.
H2O2(aq) + NO(g) + H+(aq) \rightarrow NO3-(aq)
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75
Balance the following oxidation-reduction equation.
HI(aq) + HNO3(aq) \rightarrow NO(g) + I2(aq)
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76
Balance the following oxidation-reduction equation.
CrO42-(aq) + HSnO2-(aq)
Balance the following oxidation-reduction equation. CrO<sub>4</sub><sup>2-</sup>(aq) + HSnO<sub>2</sub><sup>-</sup>(aq)   HSnO<sub>3</sub><sup>-</sup>(aq) + CrO<sub>2</sub><sup>-</sup>(aq)
HSnO3-(aq) + CrO2-(aq)
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77
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-How many OCl- ions are consumed in the balanced equation for this reaction?

A) 2
B) 3
C) 4
D) 5
E) 6
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78
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-How many OH- ions are involved in the simplest balanced equation for this reaction?

A) 0
B) 1
C) 2
D) 3
E) 4
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79
Redox Reactions in Basic Solutions
refer to the following reaction which occurs in basic solution:
OCl-(aq) \rightarrow ClO2-(aq) + Cl2(aq)

-What is the net effect on the OH- ion concentration in this reaction?

A) The OH- ion concentration increases.
B) The OH- ion concentration decreases.
C) The OH- ion concentration remains the same.
D) There is no way to predict what happens to the OH- ion concentration in this reaction.
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80
refer to the following reaction which occurs in basic solution.
CrO42- + PH3 \rightarrow Cr(OH)4- + P4

-Which of the following are oxidizing agents in the forward and reverse directions, respectively?

A) CrO42- and PH3
B) CrO42- and P4
C) Cr(OH)4- and PH3
D) Cr(OH)4- and P4
E) CrO42- and OH-
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