Deck 20: Electrochemistry
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Deck 20: Electrochemistry
1
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction?
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr2(SO4)3(aq)
A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 2
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr2(SO4)3(aq)
A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 2
H2O = 22, Cr2(SO4)3 = 4
2
Balance the following reaction in KOH.What are the coefficients in front of C3H8O2 and KMnO4 in the balanced reaction?
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C3H8O2 = 3, KMnO4 = 8
B) C3H8O2 = 3, KMnO4 = 4
C) C3H8O2 = 8, KMnO4 = 3
D) C3H8O2 = 2, KMnO4 = 4
E) C3H8O2 = 3, KMnO4 = 2
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C3H8O2 = 3, KMnO4 = 8
B) C3H8O2 = 3, KMnO4 = 4
C) C3H8O2 = 8, KMnO4 = 3
D) C3H8O2 = 2, KMnO4 = 4
E) C3H8O2 = 3, KMnO4 = 2
C3H8O2 = 3, KMnO4 = 8
3
What element is being oxidized in the following redox reaction?
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C
B) H
C) O
D) K
E) Mn
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C
B) H
C) O
D) K
E) Mn
C
4
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Br2 and OH⁻ in the balanced reaction?
Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)
A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)
A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
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5
Balance the following redox reaction.What are the coefficients in front of H2O and NO in the balanced reaction?
Zn(s)+ HNO3(aq)→ Zn2+(aq)+ NO(g)
A) H2O =4, NO = 2
B) H2O =8, NO = 6
C) H2O =1, NO = 3
D) H2O =10, NO = 7
E) H2O =5, NO = 9
Zn(s)+ HNO3(aq)→ Zn2+(aq)+ NO(g)
A) H2O =4, NO = 2
B) H2O =8, NO = 6
C) H2O =1, NO = 3
D) H2O =10, NO = 7
E) H2O =5, NO = 9
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6
What element is being reduced in the following redox reaction?
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) H
B) O
C) Cl
D) N
E) C
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) H
B) O
C) Cl
D) N
E) C
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7
What element is being oxidized in the following redox reaction?
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) H
B) O
C) Cl
D) N
E) C
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) H
B) O
C) Cl
D) N
E) C
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8
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction?
Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)
A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)
A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
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9
What element is being oxidized in the following redox reaction?
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) C
B) O
C) Mn
D) H
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) C
B) O
C) Mn
D) H
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10
What element is being reduced in the following redox reaction?
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C
B) H
C) O
D) K
E) Mn
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) C
B) H
C) O
D) K
E) Mn
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11
Balance the following reaction in KOH.What are the coefficients in front of H2O and KOH in the balanced reaction and list which side of the equation that H2O and KOH appear?
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) H2O = 1, KOH = 4, right
B) H2O = 4, KOH = 1, left
C) H2O = 8, KOH = 2 right
D) H2O = 3, KOH = 2, right
E) H2O = 4, KOH = 2, left
C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)
A) H2O = 1, KOH = 4, right
B) H2O = 4, KOH = 1, left
C) H2O = 8, KOH = 2 right
D) H2O = 3, KOH = 2, right
E) H2O = 4, KOH = 2, left
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12
Balance the following reaction under basic conditions.What are the coefficients in front of H2O and Cl- in the balanced reaction?
Cl2(aq)+ Br2(l)→ BrO3-(aq)+ Cl-(aq)
A) H2O = 2, Cl- = 2
B) H2O = 2, Cl- = 5
C) H2O = 6, Cl- = 10
D) H2O = 4, Cl- = 6
E) H2O = 7, Cl- = 3
Cl2(aq)+ Br2(l)→ BrO3-(aq)+ Cl-(aq)
A) H2O = 2, Cl- = 2
B) H2O = 2, Cl- = 5
C) H2O = 6, Cl- = 10
D) H2O = 4, Cl- = 6
E) H2O = 7, Cl- = 3
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13
What element is being reduced in the following redox reaction?
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)
A) C
B) H
C) O
D) K
E) Cr
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)
A) C
B) H
C) O
D) K
E) Cr
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14
What element is being reduced in the following redox reaction?
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr
B) O
C) H
D) Cl
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr
B) O
C) H
D) Cl
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15
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction?
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
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16
What element is being reduced in the following redox reaction?
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) C
B) O
C) Mn
D) H
MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)
A) C
B) O
C) Mn
D) H
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17
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction?
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)
A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
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18
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of C3H8O2 and H2SO4 in the balanced reaction?
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr2(SO4)3(aq)
A) C3H8O2 = 3, H2SO4 = 8
B) C3H8O2 = 2, H2SO4 = 8
C) C3H8O2 = 1, H2SO4 = 16
D) C3H8O2 = 3, H2SO4 = 16
E) C3H8O2 = 2, H2SO4 = 4
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr2(SO4)3(aq)
A) C3H8O2 = 3, H2SO4 = 8
B) C3H8O2 = 2, H2SO4 = 8
C) C3H8O2 = 1, H2SO4 = 16
D) C3H8O2 = 3, H2SO4 = 16
E) C3H8O2 = 2, H2SO4 = 4
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19
What element is being oxidized in the following redox reaction?
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)
A) C
B) H
C) O
D) K
E) Cr
C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)
A) C
B) H
C) O
D) K
E) Cr
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20
What element is being oxidized in the following redox reaction?
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr
B) O
C) H
D) Cl
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr
B) O
C) H
D) Cl
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21
Identify the location of oxidation in an electrochemical cell.
A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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22
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V
A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V
A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
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23
What statement is NOT true about standard electrode potentials?
A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
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24
Define a salt bridge.
A) A pathway, composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counter ions can flow between the half-cells without the solutions in the half-cell totally mixing.
A) A pathway, composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counter ions can flow between the half-cells without the solutions in the half-cell totally mixing.
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25
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)
A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
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26
Which of the following reactions would be the most spontaneous at 298 K?
A) A + 2 B → C; E°cell = +0.98 V
B) A + B → 2 C; E°cell = -0.030 V
C) A + B → 3 C; E°cell = +0.15 V
D) A + B → C; E°cell = +1.22 V
E) More information is needed to determine.
A) A + 2 B → C; E°cell = +0.98 V
B) A + B → 2 C; E°cell = -0.030 V
C) A + B → 3 C; E°cell = +0.15 V
D) A + B → C; E°cell = +1.22 V
E) More information is needed to determine.
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27
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Ag(s)+ Pb2+(aq)→ Ag+(aq)+ Pb(s)
A) 179 kJ
B) 89.5 kJ
C) -328 kJ
D) -107 kJ
E) 212 kJ
A) 179 kJ
B) 89.5 kJ
C) -328 kJ
D) -107 kJ
E) 212 kJ
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28
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)
A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
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29
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V
A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V
A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
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30
Determine the cell notation for the redox reaction given below. 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt
Fe(s) ∣ Fe3+(aq)
B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt
Fe3+(aq) ∣ Fe(s)
C) Fe3+(aq) ∣ Fe(s)
Cl⁻(aq) ∣ Cl2(g) ∣ Pt
D) Fe(s) ∣ Cl2(g)
Fe3+(aq) ∣ Cl⁻(aq) ∣ Pt
E) Fe(s) ∣ Fe3+(aq)
Cl2(g) ∣ Cl⁻(aq) ∣ Pt
A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt
Fe(s) ∣ Fe3+(aq)B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt
Fe3+(aq) ∣ Fe(s)C) Fe3+(aq) ∣ Fe(s)
Cl⁻(aq) ∣ Cl2(g) ∣ PtD) Fe(s) ∣ Cl2(g)
Fe3+(aq) ∣ Cl⁻(aq) ∣ PtE) Fe(s) ∣ Fe3+(aq)
Cl2(g) ∣ Cl⁻(aq) ∣ Pt Unlock Deck
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31
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2 K(s)+ I2(s)→ 2 K⁺(aq)+ 2 I⁻(aq)
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V
A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V
A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
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32
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq)
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e⁻ → 2 Br⁻(aq)E° = +1.07 V
A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e⁻ → 2 Br⁻(aq)E° = +1.07 V
A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
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33
Identify the characteristics of a spontaneous reaction.
A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
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34
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2F2(g)+ Mn(s)→ 4 F⁻(aq)+ Mn2+(aq)
F2(g)+ e⁻ → 2 F⁻(aq)E° = +2.87 V
Mn2+(aq)+ 2 e⁻ → Mn(s)E° = -1.18 V
A) 1.69 V
B) 4.050 V
C) -4.050 V
D) -4.060 V
E) +2.87 V
F2(g)+ e⁻ → 2 F⁻(aq)E° = +2.87 V
Mn2+(aq)+ 2 e⁻ → Mn(s)E° = -1.18 V
A) 1.69 V
B) 4.050 V
C) -4.050 V
D) -4.060 V
E) +2.87 V
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35
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4⁻ and ClO⁻ in the balanced reaction?
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)
A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
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36
How many electrons are transferred in the following reaction? (The reaction is unbalanced.)
I2(s)+ Fe(s)→ Fe3+(aq)+ I⁻(aq)
A) 1
B) 2
C) 6
D) 3
E) 4
I2(s)+ Fe(s)→ Fe3+(aq)+ I⁻(aq)
A) 1
B) 2
C) 6
D) 3
E) 4
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37
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V
A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V
A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
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38
Identify the location of reduction in an electrochemical cell.
A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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39
Which of the following is the weakest oxidizing agent?
A) H2O2(aq)
B) Fe3+(aq)
C) ClO2(g)
D) F-(s)
E) Fe(s)
A) H2O2(aq)
B) Fe3+(aq)
C) ClO2(g)
D) F-(s)
E) Fe(s)
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40
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)
A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
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41
Identify the battery that is in most automobiles.
A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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42
Which battery uses the metal with the least dense metal?
A) nickel-metal hydride
B) lithium-ion
C) nickel-cadmium
D) lead acid
E) dry cell
A) nickel-metal hydride
B) lithium-ion
C) nickel-cadmium
D) lead acid
E) dry cell
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43
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M)
Ag+(aq,2.7 M)∣ Ag(s)
A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
Ag+(aq,2.7 M)∣ Ag(s)A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
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44
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M)
Fe3+(aq,2.33 M)∣ Fe(s)
A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
Fe3+(aq,2.33 M)∣ Fe(s)A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
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45
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M)
Al3+(aq,3.89 M)∣ Al(s)
A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
Al3+(aq,3.89 M)∣ Al(s)A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
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46
Which of the following reactions would have the smallest value of K at 298 K?
A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
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47
Identify the components of a fuel cell.
A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
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48
All of the following are examples of rechargeable batteries EXCEPT
A) NiCad batteries.
B) NiMH batteries.
C) dry cell batteries.
D) lead-acid batteries.
E) lithium ion batteries.
A) NiCad batteries.
B) NiMH batteries.
C) dry cell batteries.
D) lead-acid batteries.
E) lithium ion batteries.
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49
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)
A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
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50
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg2+(aq,2.74 M)
Cu2+(aq,0.0033 M)∣ Cu(s)
A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
Cu2+(aq,0.0033 M)∣ Cu(s)A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
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51
Describe how water can be a good conductor of current.
A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
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52
Identify the battery that is used as a common flashlight battery.
A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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53
What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current?
Ag⁺(aq)+ e⁻ → Ag(s)
A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
Ag⁺(aq)+ e⁻ → Ag(s)
A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
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54
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)
A) 3.5 × 10-59
B) 1.1 × 1017
C) 6.1 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
A) 3.5 × 10-59
B) 1.1 × 1017
C) 6.1 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
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55
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M)
Cu2+(aq,4.48 M)∣ Cu(s)
A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
Cu2+(aq,4.48 M)∣ Cu(s)A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
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56
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mn(s)∣ Mn2+(aq,1.28 M)
Ag+(aq,0.000837 M)∣ Ag(s)
A) 1.98 V
B) -1.28 V
C) 0.00 V
D) 1.79 V
E) -0.84 V
Ag+(aq,0.000837 M)∣ Ag(s)A) 1.98 V
B) -1.28 V
C) 0.00 V
D) 1.79 V
E) -0.84 V
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57
Identify the battery type that has a high overcharge tolerance.
A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
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58
What is the reaction at the anode in nickel-cadmium battery?
A) Cadmium is reduced.
B) Nickel(II) hydroxide is produced.
C) Cadmium is oxidized.
D) Nickel is oxidized.
E) Nickel is reduced.
A) Cadmium is reduced.
B) Nickel(II) hydroxide is produced.
C) Cadmium is oxidized.
D) Nickel is oxidized.
E) Nickel is reduced.
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59
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,1.8 M)
Ag+(aq,0.055 M)∣ Ag(s)
A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
Ag+(aq,0.055 M)∣ Ag(s)A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
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60
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)
A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.1 × 10-22
E) 1.1 × 10-8
A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.1 × 10-22
E) 1.1 × 10-8
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61
Identify a component in the formation of rust.
A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
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62
What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?
A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
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63
What element is being oxidized in the following redox reaction?
Ni2+(aq)+ NH4+(aq)→ Ni(s)+ NO3⁻(aq)
A) Ni
B) N
C) H
D) O
Ni2+(aq)+ NH4+(aq)→ Ni(s)+ NO3⁻(aq)
A) Ni
B) N
C) H
D) O
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64
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C. Cu(s)+ Mg2+(aq)→ Mg(s)+ Cu2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V
A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -2.72 V
E) -1.36 V
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V
A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -2.72 V
E) -1.36 V
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65
To prevent rust,nails are coated with
A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
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66
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of SO32- and MnO4⁻ in the balanced reaction?
SO32-(aq)+ MnO4⁻(aq)→ SO42-(aq)+ MnO2(s)
A) SO32- = 2, MnO4⁻ = 3
B) SO32- = 1, MnO4⁻ = 1
C) SO32- = 4, MnO4⁻ = 2
D) SO32- = 2, MnO4⁻ = 5
E) SO32- = 3, MnO4⁻ = 2
SO32-(aq)+ MnO4⁻(aq)→ SO42-(aq)+ MnO2(s)
A) SO32- = 2, MnO4⁻ = 3
B) SO32- = 1, MnO4⁻ = 1
C) SO32- = 4, MnO4⁻ = 2
D) SO32- = 2, MnO4⁻ = 5
E) SO32- = 3, MnO4⁻ = 2
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67
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of NO3-and Sn2+ in the balanced reaction?
NO3⁻(aq)+ Sn2+(aq)→ Sn4+(aq)+ NO(g)
A) NO3⁻ = 3, Sn2+ = 2
B) NO3⁻ = 2, Sn2+ = 3
C) NO3⁻ = 4, Sn2+ = 9
D) NO3⁻ = 1, Sn2+ = 1
E) NO3⁻ = 3, Sn2+ = 5
NO3⁻(aq)+ Sn2+(aq)→ Sn4+(aq)+ NO(g)
A) NO3⁻ = 3, Sn2+ = 2
B) NO3⁻ = 2, Sn2+ = 3
C) NO3⁻ = 4, Sn2+ = 9
D) NO3⁻ = 1, Sn2+ = 1
E) NO3⁻ = 3, Sn2+ = 5
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68
Describe the reactions during the electrolysis of water in an electrolytic cell.
A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen or hydrogen are oxidized or reduced.
A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen or hydrogen are oxidized or reduced.
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69
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+,Fe3+,Mg2+,Br-,I-
A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
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70
Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻
A) Cl⁻
B) F⁻
C) Cu2+
D) Mg2+
E) Br⁻
A) Cl⁻
B) F⁻
C) Cu2+
D) Mg2+
E) Br⁻
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71
Identify oxidation.
A) increase in oxidation number
B) loss of electrons
C) gain of electrons
D) loss of protons
E) both A and B
A) increase in oxidation number
B) loss of electrons
C) gain of electrons
D) loss of protons
E) both A and B
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72
How many electrons are transferred in the following reaction? (The reaction is unbalanced.)
Mg2+(aq)+ Li(s)→ Mg(s)+ Li+(aq)
A) 1
B) 2
C) 3
D) 4
E) 6
Mg2+(aq)+ Li(s)→ Mg(s)+ Li+(aq)
A) 1
B) 2
C) 3
D) 4
E) 6
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73
Determine the redox reaction represented by the following cell notation. Mn(s)∣ Mn2+(aq)
Cu2+(aq)∣ Cu(s)
A) Cu(s) + Mn2+(aq) → Mn(s) + Cu2+(aq)
B) Mn(s) + Cu2+(aq) → Cu(s) + Mn2+(aq)
C) 2 Mn(s) + Cu2+(aq) → Cu(s) + 2 Mn2+(aq)
D) 2 Cu(s) + Mn2+(aq) → Mn(s) + 2 Cu2+(aq)
E) 3 Mn(s) + 2 Cu2+(aq) → 2 Cu(s) + 3 Mn2+(aq)
Cu2+(aq)∣ Cu(s)A) Cu(s) + Mn2+(aq) → Mn(s) + Cu2+(aq)
B) Mn(s) + Cu2+(aq) → Cu(s) + Mn2+(aq)
C) 2 Mn(s) + Cu2+(aq) → Cu(s) + 2 Mn2+(aq)
D) 2 Cu(s) + Mn2+(aq) → Mn(s) + 2 Cu2+(aq)
E) 3 Mn(s) + 2 Cu2+(aq) → 2 Cu(s) + 3 Mn2+(aq)
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74
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Al and Br2 in the balanced reaction?
Al(s)+ Br2(g)→ Al3+(aq)+ Br-(aq)
A) Al = 2, Br2 = 3
B) Al = 2, Br2 = 6
C) Al = 1, Br2 = 1
D) Al = 2, Br2 = 1
E) Al = 3, Br2 = 2
Al(s)+ Br2(g)→ Al3+(aq)+ Br-(aq)
A) Al = 2, Br2 = 3
B) Al = 2, Br2 = 6
C) Al = 1, Br2 = 1
D) Al = 2, Br2 = 1
E) Al = 3, Br2 = 2
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75
Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A?
Ni2+(aq)+ 2 e⁻ → Ni(s)
A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
Ni2+(aq)+ 2 e⁻ → Ni(s)
A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
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76
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+,Ca2+,Cl⁻,Br⁻,F⁻
A) Na⁺
B) Cl⁻
C) Ca2+
D) Br⁻
E) F⁻
A) Na⁺
B) Cl⁻
C) Ca2+
D) Br⁻
E) F⁻
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77
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Ni and Ag+ in the balanced reaction?
Ni(s)+ Ag+(aq)→ Ag(s)+ Ni2+(aq)
A) Ni = 1, Ag⁺ = 2
B) Ni = 1, Ag⁺ = 1
C) Ni = 2, Ag⁺ = 1
D) Ni = 2, Ag⁺ = 2
E) Ni = 3, Ag⁺ = 1
Ni(s)+ Ag+(aq)→ Ag(s)+ Ni2+(aq)
A) Ni = 1, Ag⁺ = 2
B) Ni = 1, Ag⁺ = 1
C) Ni = 2, Ag⁺ = 1
D) Ni = 2, Ag⁺ = 2
E) Ni = 3, Ag⁺ = 1
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78
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Sn and H+ in the balanced reaction?
Sn2+(aq)+ NH4+(aq)→ Sn(s)+ NO3⁻(aq)
A) Sn = 1, H⁺ = 8
B) Sn = 1, H⁺ = 4
C) Sn = 4, H⁺ = 10
D) Sn = 2, H⁺ = 4
E) Sn = 3, H⁺ = 5
Sn2+(aq)+ NH4+(aq)→ Sn(s)+ NO3⁻(aq)
A) Sn = 1, H⁺ = 8
B) Sn = 1, H⁺ = 4
C) Sn = 4, H⁺ = 10
D) Sn = 2, H⁺ = 4
E) Sn = 3, H⁺ = 5
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79
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C. 4 F⁻(aq)+ Mn2+(aq)→ 2F2(g)+ Mn(s)
F2(g)+ 2e⁻ → 2 F⁻(aq)E° = +2.87 V
Mn2+(aq)+ 2 e⁻ → Mn(s)E° = -1.18 V
A) 1.69 V
B) 4.05 V
C) -4.05 V
D) +2.87 V
F2(g)+ 2e⁻ → 2 F⁻(aq)E° = +2.87 V
Mn2+(aq)+ 2 e⁻ → Mn(s)E° = -1.18 V
A) 1.69 V
B) 4.05 V
C) -4.05 V
D) +2.87 V
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80
How many electrons are transferred in the following reaction? (The reaction is unbalanced.)
Ba(s)+ Cr3+(aq)→ Cr(s)+ Ba2+(aq)
A) 6
B) 2
C) 3
D) 1
E) 4
Ba(s)+ Cr3+(aq)→ Cr(s)+ Ba2+(aq)
A) 6
B) 2
C) 3
D) 1
E) 4
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