Deck 16: Acid-Base Equilibria and Solubility Equilibria

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Question
Calculate the pH of a buffer solution prepared by dissolving 0.2 mole of sodium cyanate (NaCNO)and 1.0 mole of cyanic acid (HCNO)in enough water to make 1.0 liter of solution.[Ka(HCNO)= 2.0 × 10-4]

A)0
B)3.0
C)3.7
D)4.4
E)5.0
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Question
In which one of the following solutions will acetic acid have the greatest percent ionization?

A)0.1 M CH3COOH
B)0.1 M CH3COOH dissolved in 1.0 M HCl
C)0.1 M CH3COOH plus 0.1 M CH3COONa
D)0.1 M CH3COOH plus 0.2 M CH3COONa
Question
What is the net ionic equation for the reaction that occurs when small amounts of hydrochloric acid are added to a HOCl/NaOCl buffer solution?

A)H+ + H2O \rarr H3O+
B)H+ + OCl- \rarr HOCl
C)HOCl \rarr H+ + OCl-
D)H+ + HOCl \rarr H2OCl+
E)HCl + HOCl \rarr H2O + Cl2
Question
A solution is prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl.What is the pH of this solution? [Ka(HOCl)= 3.2 × 10-8]

A)4.10
B)7.00
C)7.19
D)7.49
E)7.80
Question
You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 × 10-5]

A)4.41
B)4.74
C)4.56
D)4.92
E)5.07
Question
Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 4.6-4.8?

A)CH3COO2Na / CH3COOH (Ka = 1.8 × 10-5)
B)NH3 / NH4Cl (Ka = 5.6 × 10-10)
C)NaOCl / HOCl (Ka = 3.2 × 10-8)
D)NaNO2 / HNO2 (Ka = 4.5 × 10-4)
E)NaCl / HCl
Question
Calculate the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl.[Ka(HOCl)= 3.2 × 10-8]

A)0.39
B)3.94
C)6.58
D)7.49
E)8.40
Question
Which one of the following combinations cannot function as a buffer solution?

A)HCN and KCN
B)NH3 and (NH4)2SO4
C)HNO3 and NaNO3
D)HF and NaF
E)HNO2 and NaNO2
Question
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10M HCl and 0.10 M NaCl
B)0.15 M HNO3 and 0.15 M NaNO3
C)0.10M HF and 0.10M NaF
D)0.10M HClO4 and 0.10 NaClO4
E)0.15M HBr and 0.15M NaBr
Question
Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 × 10-4]

A)0.97
B)3.10
C)4.40
D)3.70
E)4.30
Question
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10 M NH3 and 0.10 M HCl
B)0.10 M NH4+ and 0.10 M KOH
C)0.20 M NH3 0.10 M KOH
D)0.20 M NH3 and 0.10 M HCl
E)0.20 M NH4+ and 0.10M HCl
Question
What pH range is a HOCl - NaOCl buffer effective?

A)pH 2.0 - pH 4.0
B)pH 7.5 - pH 9.5
C)pH 6.5 - pH 8.5
D)pH 6.5 - pH 9.5
E)pH 1.0 - pH 14.0
Question
You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ± 0.02.What molar ratio of CH3COOH to CH3COONa should be used?

A)0.18
B)0.84
C)1.19
D)5.50
E)0.10
Question
Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 9.2-9.3?

A)CH3COONa / CH3COOH (Ka = 1.8 × 10-5)
B)NH3 / NH4Cl (Ka = 5.6 × 10-10)
C)NaOCl / HOCl (Ka = 3.2 × 10-8)
D)NaNO2 / HNO2 (Ka = 4.5 × 10-4)
E)NaCl / HCl
Question
Which one of the following is a buffer solution?

A)0.40 M HCN and 0.10 KCN
B)0.20 M CH3COOH
C)1.0 M HNO3 and 1.0 M NaNO3
D)0.10 M KCN
E)0.50 M HCl and 0.10 NaCl
Question
Consider a buffer solution prepared from HOCl and NaOCl.Which is the net ionic equation for the reaction that occurs when NaOH is added to this buffer?

A)OH- + HOCl \rarr H2O + OCl-
B)OH- + OCl- \rarr HOCl + O2-
C)Na+ + HOCl \rarr NaCl + OH-
D)H+ + HOCl \rarr H2 + OCl-
E)NaOH + HOCl \rarr H2O + NaCl
Question
Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H)and 0.15M sodium benzoate (C6H5COONa).[Ka = 6.5 × 10-5 for benzoic acid]

A)3.97
B)4.83
C)4.19
D)3.40
E)4.41
Question
Which of the following is the most acidic solution?

A)0.10 M CH3COOH and 0.10 M CH3COONa
B)0.10 M CH3COOH
C)0.10 M HNO2
D)0.10 M HNO2 and 0.10 M NaNO2
E)0.10 M CH3COONa
Question
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10M H2CO3 and 0.050M HCl
B)0.10M H2CO3 and 0.10M KOH
C)0.10M H2CO3 and 0.10M HCl
D)0.10M H2CO3 and 0.050M KOH
E)0.10M K2CO3 and 0.050M KOH
Question
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.050 M H3PO4 and 0.050M HCl
B)0.050M H3PO4 and 0.025 M HCl
C)0.050M NaH2PO4 and 0.025M NaOH
D)0.050M Na3PO4 and 0.050M M NaOH
E)0.050M Na3PO4 and 0.025M NaOH
Question
Acid dissociation constants for phosphoric acid are given below. <strong>Acid dissociation constants for phosphoric acid are given below.   A buffer with a pH = 7.4 can best be made by using</strong> A)H<sub>3</sub>PO<sub>4</sub> and NaH<sub>2</sub>PO<sub>4</sub>. B)NaH<sub>2</sub>PO<sub>4</sub><sup> </sup>and Na<sub>2</sub>HPO<sub>4</sub>. C)Na<sub>2</sub>HPO<sub>4</sub> and Na<sub>3</sub>PO<sub>4</sub>. D)only NaH<sub>2</sub>PO<sub>4</sub>. E)only Na<sub>2</sub>HPO<sub>4</sub>. <div style=padding-top: 35px> A buffer with a pH = 7.4 can best be made by using

A)H3PO4 and NaH2PO4.
B)NaH2PO4 and Na2HPO4.
C)Na2HPO4 and Na3PO4.
D)only NaH2PO4.
E)only Na2HPO4.
Question
What mass of sodium fluoride must be added to 250.mL of a 0.100 M HF solution to give a buffer solution having a pH of 3.50? [Ka(HF)= 7.1 × 10-4]

A)0.49 g
B)1.5 g
C)3.4 g
D)2.3 g
E)0.75 g
Question
Calculate the pH of the solution resulting from the addition of 25.0 mL of 0.20 M HCl to 50.0 mL of 0.10 M aniline (C6H5NH2).Kb (C6H5NH2)= 3.8 x 10-10

A)9.42
B)9.12
C)7.00
D)2.30
E)2.88
Question
Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 × 10-5).

A)2.87
B)4.98
C)5.12
D)7.00
E)11.12
Question
In which one of the following solutions will acetic acid have the greatest percent ionization?

A)0.1 M CH3COOH
B)0.1 M CH3COOH dissolved in 0.1 M HCl
C)0.1 M CH3COOH dissolved in 0.2 M HCl
D)0.1 M CH3COOH plus 0.1 M CH3COONa
E)0.1 M CH3COOH plus 0.2 M CH3COONa
Question
What mass of ammonium nitrate must be added to 350.mL of a 0.150 M solution of ammonia to give a buffer having a pH of 9.00? (Kb(NH3)= 1.8 × 10-5)

A)7.6 g
B)2.4 g
C)5.4 g
D)11 g
E)3.3 g
Question
You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH)and 0.20 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 × 10-5]

A)4.65
B)4.71
C)4.56
D)4.84
E)5.07
Question
The pH at the equivalence point of a titration may differ from 7.0 due to

A)the initial concentration of the standard solution.
B)the indicator used.
C)the self-ionization of H2O.
D)the initial pH of the unknown.
E)hydrolysis of the salt formed.
Question
Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 × 10-10)solution.

A)5.15
B)8.71
C)5.85
D)9.91
E)13.0
Question
For which type of titration will the pH be neutral at the equivalence point?

A)Strong acid vs.strong base.
B)Strong acid vs.weak base.
C)Weak acid vs.strong base.
D)All of the above.
E)None of the above.
Question
Calculate the pH of the solution resulting from the addition of 75.0 mL of 0.15 M KOH to 35.0 mL of 0.20 M HCN (Ka (HCN)= 4.9 × 10-10).

A)9.31
B)9.18
C)9.52
D)11.63
E)12.59
Question
For which type of titration will the pH be basic at the equivalence point?

A)Strong acid vs.strong base.
B)Strong acid vs.weak base.
C)Weak acid vs.strong base.
D)All of the above.
E)None of the above.
Question
Methyl red is a common acid-base indicator.It has a Ka equal to 6.3 × 10-6.Its un-ionized form is red and its anionic form is yellow.What color would a methyl red solution have at pH = 7.8?

A)green
B)red
C)blue
D)yellow
E)violet
Question
Starting with 0.750L of a buffer solution containing 0.30 M benzoic acid (C6H5COOH)and 0.35 M sodium benzoate (C6H5COONa), what will the pH of the solution be after the addition of 340.0 mL of 0.350M HCl? (Ka (C6H5COOH)= 6.5 x 10-5)

A)4.19
B)4.25
C)3.81
D)0.45
E)6.54
Question
A titration of an acid and base to the equivalence point results in a noticeably acidic solution.It is likely this titration involves

A)a strong acid and a weak base.
B)a weak acid and a strong base.
C)a weak acid and a weak base (where Ka equals Kb).
D)a strong acid and a strong base.
Question
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCN (Ka = 4.9 × 10-10)with 0.10 M NaOH?

A)3.0
B)6.0
C)7.0
D)11.0
E)12.0
Question
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with 0.10 M NaOH?

A)1.0
B)6.0
C)7.0
D)8.0
E)13.0
Question
Starting with 0.250L of a buffer solution containing 0.250 M benzoic acid (C6H5COOH)and 0.20 M sodium benzoate (C6H5COONa), what will the pH of the solution be after the addition of 25.0 mL of 0.100M HCl? (Ka (C6H5COOH)= 6.5 x 10-5)

A)4.19
B)4.10
C)4.28
D)4.05
E)3.78
Question
Calculate the percent ionization of cyanic acid, Ka = 2.0 × 10-4, in a buffer solution that is 0.50 M HCNO and 0.10 M NaCNO.

A)0.02%
B)0.10%
C)0.20%
D)2.0%
E)20%
Question
Calculate the pH of the solution resulting from the addition of 85.0 mL of 0.35 M HCl to 30.0 mL of 0.40 M aniline (C6H5NH2).Kb (C6H5NH2)= 3.8 x 10-10

A)1.75
B)0.81
C)4.64
D)4.19
E)9.09
Question
The Ksp value for lead(II)chloride is 2.4 × 10-4.What is the molar solubility of lead(II)chloride?

A)2.4 × 10-4 mol/L
B)6.2 × 10-2 mol/L
C)7.7 × 10-3 mol/L
D)3.9 × 10-2 mol/L
E)6.0 × 10-5 mol/L
Question
The solubility of strontium carbonate is 0.0011 g/100 mL at 20ºC.Calculate the Ksp value for this compound.

A)7.5 × 10-5
B)1.5 × 10-4
C)5.6 × 10-9
D)7.5 × 10-6
E)1.5 × 10-3
Question
The molar solubility of manganese(II)carbonate is 4.2 × 10-6 M.What is Ksp for this compound?

A)4.2 × 10-6
B)8.4 × 10-6
C)3.0 × 10-16
D)1.8 × 10-11
E)2.0 × 10-3
Question
The solubility product for barium sulfate is 1.1 × 10-10.Calculate the molar solubility of barium sulfate.

A)5.5 × 10-11 mol/L
B)1.1 × 10-5 mol/L
C)2.1 × 10-5 mol/L
D)1.1 × 10-10 mol/L
E)2.2 × 10-10 mol/L
Question
The solubility product for calcium phosphate is Ksp = 1.3 × 10-26.What is the molar solubility of calcium phosphate?

A)1.3 × 10-26 M
B)1.5 × 10-7 M
C)2.6 × 10-6 M
D)4.6 × 10-6 M
E)6.6 × 10-6 M
Question
The Ksp for silver(I)phosphate is 1.8 × 10-18.Calculate the molar solubility of silver(I)phosphate.

A)1.6 × 10-5 M
B)2.1 × 10-5 M
C)3.7 × 10-5 M
D)7.2 × 10-1 M
E)1.8 × 10-1 M
Question
Calculate the silver ion concentration in a saturated solution of silver(I)sulfate (Ksp = 1.4 × 10-5).

A)1.5 × 10-2 M
B)2.4 × 10-2 M
C)3.0 × 10-2 M
D)1.4 × 10-5 M
E)None of the above.
Question
The Ksp for silver(I)phosphate is 1.8 × 10-18.Determine the silver ion concentration in a saturated solution of silver(I)phosphate.

A)1.6 × 10-5 M
B)2.1 × 10-5 M
C)3.7 × 10-5 M
D)1.1 × 10-13 M
E)4.8 × 10-5 M
Question
Calculate the concentration of chloride ions in a saturated lead(II)chloride (Ksp = 2.4 × 10-4)solution.

A)2.4 × 10-4 M
B)4.8 × 10-4 M
C)3.9 × 10-2 M
D)1.2 × 10-1 M
E)7.8 × 10-2 M
Question
Which of the following would decrease the Ksp for PbI2?

A)Lowering the pH of the solution
B)Adding a solution of Pb(NO3)2
C)Adding a solution of KI
D)None of the above-the Ksp of a compound is constant at constant temperature.
Question
For PbCl2 (Ksp = 2.4 × 10-4), will a precipitate of PbCl2 form when 0.10 L of 3.0 × 10-2 M Pb(NO3)2 is added to 400 mL of 9.0 × 10-2 M NaCl?

A)Yes, because Q > Ksp..
B)No, because Q < Ksp.
C)No, because Q = Ksp
D)Yes, because Q < Ksp.
Question
Calculate the silver ion concentration in a saturated solution of silver(I)carbonate (Ksp = 8.1 × 10-12).

A)5.0 × 10-5 M
B)2.5 × 10-4 M
C)1.3 × 10-4 M
D)2.0 × 10-4 M
E)8.1 × 10-4 M
Question
The molar solubility of magnesium carbonate is 1.8 × 10-4 mol/L.What is Ksp for this compound?

A)1.8 × 10-4
B)3.6 × 10-4
C)1.3 × 10-7
D)3.2 × 10-8
E)2.8 × 10-14
Question
The solubility product for chromium(III)fluoride is Ksp = 6.6 × 10-11.What is the molar solubility of chromium(III)fluoride?

A)1.6 × 10-3 M
B)1.2 × 10-3 M
C)6.6 × 10-11 M
D)2.2 × 10-3 M
E)1.6 × 10-6 M
Question
Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride.(For MgF2 , Ksp = 6.9 × 10-9.)

A)1.4 × 107 M
B)6.9 × 10-9 M
C)6.9 × 10-8 M
D)1.7 × 10-7 M
E)6.9 × 10-7 M
Question
Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride.(For CrF3 , Ksp = 6.6 × 10-11.)

A)0.023 M
B)0.032 M
C)7.7 × 10-8 M
D)2.9 × 10-9 M
E)6.9 × 10-10 M
Question
The solubility of lead(II)iodide is 0.064 g/100 mL at 20ºC.What is the solubility product for lead(II)iodide?

A)1.1 × 10-8
B)3.9 × 10-6
C)1.1 × 10-11
D)2.7 × 10-12
E)1.4 × 10-3
Question
The molar solubility of tin(II)iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?

A)8.4 × 10-6
B)1.28 × 10-2
C)4.2 × 10-6
D)1.6 × 10-4
E)2.1 × 10-6
Question
Calculate the concentration of fluoride ions in a saturated barium fluoride (Ksp = 1.7 × 10-6)solution.

A)7.6 × 10-3 M
B)1.5 × 10-2 M
C)3.4 × 10-5 M
D)1.7 × 10-6 M
E)3.4 × 10-6 M
Question
The molar solubility of lead(II)iodate in water is 4.0 × 10-5 mol/L.Calculate Ksp for lead(II)iodate.

A)1.6 × 10-9
B)6.4 × 10-14
C)2.6 × 10-13
D)4.0 × 10-5
E)4.0 × 10-15
Question
Which of the following compounds is more soluble in acidic solution than in pure neutral water?

A)PbI2
B)CuBr
C)KClO4
D)FeS
E)NaNO3
Question
To 1.00 L of a 0.100 M aqueous solution of benzoic acid (C6H5COOH)is added 1.00 mL of 12.0 M HCl.What is the percentage ionization of the benzoic acid in the resulting solution? [Ka(C6H5COOH)= 6.5 × 10-5]

A)3.3%
B)12%
C)1.3%
D)0.52%
E)0.065%
Question
Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na2CrO4 are added to 250 mL of 0.12 M AgNO3? [Ksp(Ag2CrO4)= 1.1 × 10-12] What is the concentration of the silver ion remaining in solution?

A)Yes, [Ag+] = 2.9 × 10-6 M.
B)Yes, [Ag+] = 0.060 M.
C)Yes, [Ag+] = 1.3 × 10-4 M.
D)No, [Ag+] = 0.060 M.
E)No, [Ag+] = 0.105 M.
Question
Which of the following compounds is more soluble in acidic solution than in pure neutral water?

A)BaCO3
B)CuI
C)PbCl2
D)AgBr
E)NH4NO3
Question
A saturated sodium carbonate solution at 100°C contains 45.5 g of dissolved sodium carbonate per 100.mL of solution.The solubility product constant for sodium carbonate at this temperature is

A)79.0
B)0.316
C)0.0790
D)36.8
E)316
Question
Find the concentration of Pb2+ ions in a solution made by adding 5.00 g of lead(II)iodide to 500.mL of 0.150 M KI.[For PbI2, Ksp = 1.39 × 10-8.]

A)3.04 × 10-4 M
B)1.54 × 10-7 M
C)6.18 × 10-7 M
D)1.52 × 10-4 M
E)9.27 × 10-8 M
Question
Calculate the molar solubility of AgCl in a 0.15 M solution of NH3(aq). (Ksp (AgCl)= 1.6 x 10-10; Kf (Ag(NH3)2+)= 1.5 x 107)

A)6.7 x 10-3 M
B)1.3 x 10-5 M
C)3.9 x 103 M
D)7.5 x 10-2 M
E)3.3 x 10-5 M
Question
Calculate the molar solubility of AgBr in a 0.25M solution of NH3(aq)(Ksp (AgBr)= 7.7 x 10-13 ; Kf (Ag(NH3)2+)= 1.5 x 107.

A)8.8 x 10-7 M
B)3.4 x 10-3 M
C)8.4 x 10-4 M
D)2.5 x 10-1 M
E)9.7 x 102 M
Question
A saturated sodium carbonate solution at 0°C contains 7.1 g of dissolved sodium carbonate per 100.mL of solution.The solubility product constant for sodium carbonate at this temperature is

A)1.2
B)0.30
C)3.0 × 10-4
D)0.90
E)1.2 × 10-3
Question
Calculate the molar solubility of BaCO3 in a 0.10 M solution of Na2CO3(aq).(Ksp (BaCO3)= 8.1 x 10-9)

A)8.1 x 10-9 M
B)9.0 x 10-5 M
C)8.1 x 10-8 M
D)2.8 x 10-4 M
E)0.10 M
Question
Will a precipitate of magnesium fluoride form when 300.mL of 1.1 × 10-3 M MgCl2 are added to 500.mL of 1.2 × 10-3 M NaF? [Ksp (MgF2)= 6.9 × 10-9]

A)Yes, Q > Ksp
B)No, Q < Ksp
C)No, Q = Ksp
D)Yes, Q < Ksp
E)Yes, Q = Ksp
Question
Calculate the molar solubility of CaF2 in a 0.25 M solution of NaF(aq).(Ksp (CaF2)= 4.0 x 10-11)

A)4.0 x 10-11 M
B)6.4 x 10-10 M
C)1.6 x 10-10 M
D)1.3 x 10-5 M
E)2.2 x 10-4 M
Question
Find the concentration of calcium ions in a solution made by adding 3.50 g of calcium fluoride to 750.mL of 0.125 M NaF.[For CaF2, Ksp = 3.95 × 10-11.]

A)3.16 × 10-10 M
B)2.53 × 10-9 M
C)4.29 × 10-4 M
D)6.32 × 10-10 M
E)2.15 × 10-4 M
Question
Calculate the molar solubility of Fe(OH)2 in a solution with pH = 13.15. (Ksp Fe(OH)2 = 1.6 x 10-14)

A)1.6 x 10-14 M
B)1.1 x 10-13 M
C)1.6 x 10-5 M
D)8.0 x 10-13 M
E)3.4 x 10-7 M
Question
Calculate the molar solubility of Mg(OH)2 in a solution with pH = 12.20. (Ksp (Mg(OH)2 = 1.2 x 10-11)

A)4.8 x 10-8 M
B)7.6 x 10-10 M
C)3.5 x 10-6 M
D)1.4 x 10-4 M
E)2.4 x 10-6 M
Question
Will a precipitate (ppt)form when 20.0 mL of 1.1 × 10-3 M Ba(NO3)2 are added to 80.0 mL of 8.4 × 10-4 M Na2CO3?

A)Yes, the ppt is Ba(NO3 )2.
B)Yes, the ppt is NaNO3.
C)Yes, the ppt is BaCO3.
D)Yes, the ppt is Na2CO3.
E)No, a precipitate will not form.
Question
Will a precipitate (ppt)form when 300.mL of 5.0 × 10-5 M AgNO3 are added to 200.mL of 2.5 × 10-7 M NaBr? Answer yes or no, and identify the precipitate if there is one.

A)Yes, the ppt is AgNO3(s).
B)Yes, the ppt is AgBr(s).
C)Yes, the ppt is NaBr(s).
D)Yes, the ppt is NaNO3(s).
E)No, a precipitate will not form.
Question
Will a precipitate form (yes or no)when 50.0 mL of 1.2 × 10-3 M Pb(NO3)2 are added to 50.0 mL of 2.0 × 10-4 M Na2S? If so, identify the precipitate.

A)Yes, the precipitate is PbS.
B)Yes, the precipitate is NaNO3.
C)Yes, the precipitate is Na2S.
D)Yes, the precipitate is Pb(NO3)2.
E)No, a precipitate will not form.
Question
Will a precipitate (ppt)form when 300.mL of 2.0 × 10-5 M AgNO3 are added to 200.mL of 2.5 × 10-9 M NaI? Answer yes or no, and identify the precipitate if there is one.

A)Yes, the ppt is AgNO3(s).
B)Yes, the ppt is NaNO3(s).
C)Yes, the ppt is NaI(s).
D)Yes, the ppt is AgI(s).
E)No, a precipitate will not form.
Question
Will a precipitate of magnesium fluoride form when 200.mL of 1.9 × 10-3 M MgCl2 are added to 300.mL of 1.4 × 10-2 M NaF? [Ksp (MgF2)= 6.9 × 10-9]

A)Yes, Q > Ksp
B)No, Q < Ksp
C)No, Q = Ksp
D)Yes, Q < Ksp
E)Yes, Q = Ksp
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Deck 16: Acid-Base Equilibria and Solubility Equilibria
1
Calculate the pH of a buffer solution prepared by dissolving 0.2 mole of sodium cyanate (NaCNO)and 1.0 mole of cyanic acid (HCNO)in enough water to make 1.0 liter of solution.[Ka(HCNO)= 2.0 × 10-4]

A)0
B)3.0
C)3.7
D)4.4
E)5.0
3.0
2
In which one of the following solutions will acetic acid have the greatest percent ionization?

A)0.1 M CH3COOH
B)0.1 M CH3COOH dissolved in 1.0 M HCl
C)0.1 M CH3COOH plus 0.1 M CH3COONa
D)0.1 M CH3COOH plus 0.2 M CH3COONa
0.1 M CH3COOH
3
What is the net ionic equation for the reaction that occurs when small amounts of hydrochloric acid are added to a HOCl/NaOCl buffer solution?

A)H+ + H2O \rarr H3O+
B)H+ + OCl- \rarr HOCl
C)HOCl \rarr H+ + OCl-
D)H+ + HOCl \rarr H2OCl+
E)HCl + HOCl \rarr H2O + Cl2
H+ + OCl- \rarr HOCl
4
A solution is prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl.What is the pH of this solution? [Ka(HOCl)= 3.2 × 10-8]

A)4.10
B)7.00
C)7.19
D)7.49
E)7.80
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5
You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 × 10-5]

A)4.41
B)4.74
C)4.56
D)4.92
E)5.07
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6
Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 4.6-4.8?

A)CH3COO2Na / CH3COOH (Ka = 1.8 × 10-5)
B)NH3 / NH4Cl (Ka = 5.6 × 10-10)
C)NaOCl / HOCl (Ka = 3.2 × 10-8)
D)NaNO2 / HNO2 (Ka = 4.5 × 10-4)
E)NaCl / HCl
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7
Calculate the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl.[Ka(HOCl)= 3.2 × 10-8]

A)0.39
B)3.94
C)6.58
D)7.49
E)8.40
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8
Which one of the following combinations cannot function as a buffer solution?

A)HCN and KCN
B)NH3 and (NH4)2SO4
C)HNO3 and NaNO3
D)HF and NaF
E)HNO2 and NaNO2
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9
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10M HCl and 0.10 M NaCl
B)0.15 M HNO3 and 0.15 M NaNO3
C)0.10M HF and 0.10M NaF
D)0.10M HClO4 and 0.10 NaClO4
E)0.15M HBr and 0.15M NaBr
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10
Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 × 10-4]

A)0.97
B)3.10
C)4.40
D)3.70
E)4.30
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11
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10 M NH3 and 0.10 M HCl
B)0.10 M NH4+ and 0.10 M KOH
C)0.20 M NH3 0.10 M KOH
D)0.20 M NH3 and 0.10 M HCl
E)0.20 M NH4+ and 0.10M HCl
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12
What pH range is a HOCl - NaOCl buffer effective?

A)pH 2.0 - pH 4.0
B)pH 7.5 - pH 9.5
C)pH 6.5 - pH 8.5
D)pH 6.5 - pH 9.5
E)pH 1.0 - pH 14.0
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13
You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ± 0.02.What molar ratio of CH3COOH to CH3COONa should be used?

A)0.18
B)0.84
C)1.19
D)5.50
E)0.10
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14
Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 9.2-9.3?

A)CH3COONa / CH3COOH (Ka = 1.8 × 10-5)
B)NH3 / NH4Cl (Ka = 5.6 × 10-10)
C)NaOCl / HOCl (Ka = 3.2 × 10-8)
D)NaNO2 / HNO2 (Ka = 4.5 × 10-4)
E)NaCl / HCl
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15
Which one of the following is a buffer solution?

A)0.40 M HCN and 0.10 KCN
B)0.20 M CH3COOH
C)1.0 M HNO3 and 1.0 M NaNO3
D)0.10 M KCN
E)0.50 M HCl and 0.10 NaCl
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16
Consider a buffer solution prepared from HOCl and NaOCl.Which is the net ionic equation for the reaction that occurs when NaOH is added to this buffer?

A)OH- + HOCl \rarr H2O + OCl-
B)OH- + OCl- \rarr HOCl + O2-
C)Na+ + HOCl \rarr NaCl + OH-
D)H+ + HOCl \rarr H2 + OCl-
E)NaOH + HOCl \rarr H2O + NaCl
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17
Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H)and 0.15M sodium benzoate (C6H5COONa).[Ka = 6.5 × 10-5 for benzoic acid]

A)3.97
B)4.83
C)4.19
D)3.40
E)4.41
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18
Which of the following is the most acidic solution?

A)0.10 M CH3COOH and 0.10 M CH3COONa
B)0.10 M CH3COOH
C)0.10 M HNO2
D)0.10 M HNO2 and 0.10 M NaNO2
E)0.10 M CH3COONa
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19
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.10M H2CO3 and 0.050M HCl
B)0.10M H2CO3 and 0.10M KOH
C)0.10M H2CO3 and 0.10M HCl
D)0.10M H2CO3 and 0.050M KOH
E)0.10M K2CO3 and 0.050M KOH
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20
Which of the following yields a buffer solution when equal volumes of the two solutions are mixed?

A)0.050 M H3PO4 and 0.050M HCl
B)0.050M H3PO4 and 0.025 M HCl
C)0.050M NaH2PO4 and 0.025M NaOH
D)0.050M Na3PO4 and 0.050M M NaOH
E)0.050M Na3PO4 and 0.025M NaOH
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21
Acid dissociation constants for phosphoric acid are given below. <strong>Acid dissociation constants for phosphoric acid are given below.   A buffer with a pH = 7.4 can best be made by using</strong> A)H<sub>3</sub>PO<sub>4</sub> and NaH<sub>2</sub>PO<sub>4</sub>. B)NaH<sub>2</sub>PO<sub>4</sub><sup> </sup>and Na<sub>2</sub>HPO<sub>4</sub>. C)Na<sub>2</sub>HPO<sub>4</sub> and Na<sub>3</sub>PO<sub>4</sub>. D)only NaH<sub>2</sub>PO<sub>4</sub>. E)only Na<sub>2</sub>HPO<sub>4</sub>. A buffer with a pH = 7.4 can best be made by using

A)H3PO4 and NaH2PO4.
B)NaH2PO4 and Na2HPO4.
C)Na2HPO4 and Na3PO4.
D)only NaH2PO4.
E)only Na2HPO4.
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22
What mass of sodium fluoride must be added to 250.mL of a 0.100 M HF solution to give a buffer solution having a pH of 3.50? [Ka(HF)= 7.1 × 10-4]

A)0.49 g
B)1.5 g
C)3.4 g
D)2.3 g
E)0.75 g
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23
Calculate the pH of the solution resulting from the addition of 25.0 mL of 0.20 M HCl to 50.0 mL of 0.10 M aniline (C6H5NH2).Kb (C6H5NH2)= 3.8 x 10-10

A)9.42
B)9.12
C)7.00
D)2.30
E)2.88
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24
Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 × 10-5).

A)2.87
B)4.98
C)5.12
D)7.00
E)11.12
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25
In which one of the following solutions will acetic acid have the greatest percent ionization?

A)0.1 M CH3COOH
B)0.1 M CH3COOH dissolved in 0.1 M HCl
C)0.1 M CH3COOH dissolved in 0.2 M HCl
D)0.1 M CH3COOH plus 0.1 M CH3COONa
E)0.1 M CH3COOH plus 0.2 M CH3COONa
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26
What mass of ammonium nitrate must be added to 350.mL of a 0.150 M solution of ammonia to give a buffer having a pH of 9.00? (Kb(NH3)= 1.8 × 10-5)

A)7.6 g
B)2.4 g
C)5.4 g
D)11 g
E)3.3 g
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27
You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH)and 0.20 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 × 10-5]

A)4.65
B)4.71
C)4.56
D)4.84
E)5.07
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28
The pH at the equivalence point of a titration may differ from 7.0 due to

A)the initial concentration of the standard solution.
B)the indicator used.
C)the self-ionization of H2O.
D)the initial pH of the unknown.
E)hydrolysis of the salt formed.
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29
Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 × 10-10)solution.

A)5.15
B)8.71
C)5.85
D)9.91
E)13.0
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30
For which type of titration will the pH be neutral at the equivalence point?

A)Strong acid vs.strong base.
B)Strong acid vs.weak base.
C)Weak acid vs.strong base.
D)All of the above.
E)None of the above.
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31
Calculate the pH of the solution resulting from the addition of 75.0 mL of 0.15 M KOH to 35.0 mL of 0.20 M HCN (Ka (HCN)= 4.9 × 10-10).

A)9.31
B)9.18
C)9.52
D)11.63
E)12.59
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32
For which type of titration will the pH be basic at the equivalence point?

A)Strong acid vs.strong base.
B)Strong acid vs.weak base.
C)Weak acid vs.strong base.
D)All of the above.
E)None of the above.
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33
Methyl red is a common acid-base indicator.It has a Ka equal to 6.3 × 10-6.Its un-ionized form is red and its anionic form is yellow.What color would a methyl red solution have at pH = 7.8?

A)green
B)red
C)blue
D)yellow
E)violet
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34
Starting with 0.750L of a buffer solution containing 0.30 M benzoic acid (C6H5COOH)and 0.35 M sodium benzoate (C6H5COONa), what will the pH of the solution be after the addition of 340.0 mL of 0.350M HCl? (Ka (C6H5COOH)= 6.5 x 10-5)

A)4.19
B)4.25
C)3.81
D)0.45
E)6.54
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35
A titration of an acid and base to the equivalence point results in a noticeably acidic solution.It is likely this titration involves

A)a strong acid and a weak base.
B)a weak acid and a strong base.
C)a weak acid and a weak base (where Ka equals Kb).
D)a strong acid and a strong base.
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36
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCN (Ka = 4.9 × 10-10)with 0.10 M NaOH?

A)3.0
B)6.0
C)7.0
D)11.0
E)12.0
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37
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with 0.10 M NaOH?

A)1.0
B)6.0
C)7.0
D)8.0
E)13.0
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38
Starting with 0.250L of a buffer solution containing 0.250 M benzoic acid (C6H5COOH)and 0.20 M sodium benzoate (C6H5COONa), what will the pH of the solution be after the addition of 25.0 mL of 0.100M HCl? (Ka (C6H5COOH)= 6.5 x 10-5)

A)4.19
B)4.10
C)4.28
D)4.05
E)3.78
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39
Calculate the percent ionization of cyanic acid, Ka = 2.0 × 10-4, in a buffer solution that is 0.50 M HCNO and 0.10 M NaCNO.

A)0.02%
B)0.10%
C)0.20%
D)2.0%
E)20%
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40
Calculate the pH of the solution resulting from the addition of 85.0 mL of 0.35 M HCl to 30.0 mL of 0.40 M aniline (C6H5NH2).Kb (C6H5NH2)= 3.8 x 10-10

A)1.75
B)0.81
C)4.64
D)4.19
E)9.09
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41
The Ksp value for lead(II)chloride is 2.4 × 10-4.What is the molar solubility of lead(II)chloride?

A)2.4 × 10-4 mol/L
B)6.2 × 10-2 mol/L
C)7.7 × 10-3 mol/L
D)3.9 × 10-2 mol/L
E)6.0 × 10-5 mol/L
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42
The solubility of strontium carbonate is 0.0011 g/100 mL at 20ºC.Calculate the Ksp value for this compound.

A)7.5 × 10-5
B)1.5 × 10-4
C)5.6 × 10-9
D)7.5 × 10-6
E)1.5 × 10-3
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43
The molar solubility of manganese(II)carbonate is 4.2 × 10-6 M.What is Ksp for this compound?

A)4.2 × 10-6
B)8.4 × 10-6
C)3.0 × 10-16
D)1.8 × 10-11
E)2.0 × 10-3
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44
The solubility product for barium sulfate is 1.1 × 10-10.Calculate the molar solubility of barium sulfate.

A)5.5 × 10-11 mol/L
B)1.1 × 10-5 mol/L
C)2.1 × 10-5 mol/L
D)1.1 × 10-10 mol/L
E)2.2 × 10-10 mol/L
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45
The solubility product for calcium phosphate is Ksp = 1.3 × 10-26.What is the molar solubility of calcium phosphate?

A)1.3 × 10-26 M
B)1.5 × 10-7 M
C)2.6 × 10-6 M
D)4.6 × 10-6 M
E)6.6 × 10-6 M
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46
The Ksp for silver(I)phosphate is 1.8 × 10-18.Calculate the molar solubility of silver(I)phosphate.

A)1.6 × 10-5 M
B)2.1 × 10-5 M
C)3.7 × 10-5 M
D)7.2 × 10-1 M
E)1.8 × 10-1 M
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47
Calculate the silver ion concentration in a saturated solution of silver(I)sulfate (Ksp = 1.4 × 10-5).

A)1.5 × 10-2 M
B)2.4 × 10-2 M
C)3.0 × 10-2 M
D)1.4 × 10-5 M
E)None of the above.
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48
The Ksp for silver(I)phosphate is 1.8 × 10-18.Determine the silver ion concentration in a saturated solution of silver(I)phosphate.

A)1.6 × 10-5 M
B)2.1 × 10-5 M
C)3.7 × 10-5 M
D)1.1 × 10-13 M
E)4.8 × 10-5 M
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49
Calculate the concentration of chloride ions in a saturated lead(II)chloride (Ksp = 2.4 × 10-4)solution.

A)2.4 × 10-4 M
B)4.8 × 10-4 M
C)3.9 × 10-2 M
D)1.2 × 10-1 M
E)7.8 × 10-2 M
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50
Which of the following would decrease the Ksp for PbI2?

A)Lowering the pH of the solution
B)Adding a solution of Pb(NO3)2
C)Adding a solution of KI
D)None of the above-the Ksp of a compound is constant at constant temperature.
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51
For PbCl2 (Ksp = 2.4 × 10-4), will a precipitate of PbCl2 form when 0.10 L of 3.0 × 10-2 M Pb(NO3)2 is added to 400 mL of 9.0 × 10-2 M NaCl?

A)Yes, because Q > Ksp..
B)No, because Q < Ksp.
C)No, because Q = Ksp
D)Yes, because Q < Ksp.
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52
Calculate the silver ion concentration in a saturated solution of silver(I)carbonate (Ksp = 8.1 × 10-12).

A)5.0 × 10-5 M
B)2.5 × 10-4 M
C)1.3 × 10-4 M
D)2.0 × 10-4 M
E)8.1 × 10-4 M
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53
The molar solubility of magnesium carbonate is 1.8 × 10-4 mol/L.What is Ksp for this compound?

A)1.8 × 10-4
B)3.6 × 10-4
C)1.3 × 10-7
D)3.2 × 10-8
E)2.8 × 10-14
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54
The solubility product for chromium(III)fluoride is Ksp = 6.6 × 10-11.What is the molar solubility of chromium(III)fluoride?

A)1.6 × 10-3 M
B)1.2 × 10-3 M
C)6.6 × 10-11 M
D)2.2 × 10-3 M
E)1.6 × 10-6 M
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55
Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride.(For MgF2 , Ksp = 6.9 × 10-9.)

A)1.4 × 107 M
B)6.9 × 10-9 M
C)6.9 × 10-8 M
D)1.7 × 10-7 M
E)6.9 × 10-7 M
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56
Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride.(For CrF3 , Ksp = 6.6 × 10-11.)

A)0.023 M
B)0.032 M
C)7.7 × 10-8 M
D)2.9 × 10-9 M
E)6.9 × 10-10 M
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57
The solubility of lead(II)iodide is 0.064 g/100 mL at 20ºC.What is the solubility product for lead(II)iodide?

A)1.1 × 10-8
B)3.9 × 10-6
C)1.1 × 10-11
D)2.7 × 10-12
E)1.4 × 10-3
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58
The molar solubility of tin(II)iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?

A)8.4 × 10-6
B)1.28 × 10-2
C)4.2 × 10-6
D)1.6 × 10-4
E)2.1 × 10-6
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59
Calculate the concentration of fluoride ions in a saturated barium fluoride (Ksp = 1.7 × 10-6)solution.

A)7.6 × 10-3 M
B)1.5 × 10-2 M
C)3.4 × 10-5 M
D)1.7 × 10-6 M
E)3.4 × 10-6 M
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60
The molar solubility of lead(II)iodate in water is 4.0 × 10-5 mol/L.Calculate Ksp for lead(II)iodate.

A)1.6 × 10-9
B)6.4 × 10-14
C)2.6 × 10-13
D)4.0 × 10-5
E)4.0 × 10-15
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61
Which of the following compounds is more soluble in acidic solution than in pure neutral water?

A)PbI2
B)CuBr
C)KClO4
D)FeS
E)NaNO3
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62
To 1.00 L of a 0.100 M aqueous solution of benzoic acid (C6H5COOH)is added 1.00 mL of 12.0 M HCl.What is the percentage ionization of the benzoic acid in the resulting solution? [Ka(C6H5COOH)= 6.5 × 10-5]

A)3.3%
B)12%
C)1.3%
D)0.52%
E)0.065%
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63
Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na2CrO4 are added to 250 mL of 0.12 M AgNO3? [Ksp(Ag2CrO4)= 1.1 × 10-12] What is the concentration of the silver ion remaining in solution?

A)Yes, [Ag+] = 2.9 × 10-6 M.
B)Yes, [Ag+] = 0.060 M.
C)Yes, [Ag+] = 1.3 × 10-4 M.
D)No, [Ag+] = 0.060 M.
E)No, [Ag+] = 0.105 M.
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64
Which of the following compounds is more soluble in acidic solution than in pure neutral water?

A)BaCO3
B)CuI
C)PbCl2
D)AgBr
E)NH4NO3
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65
A saturated sodium carbonate solution at 100°C contains 45.5 g of dissolved sodium carbonate per 100.mL of solution.The solubility product constant for sodium carbonate at this temperature is

A)79.0
B)0.316
C)0.0790
D)36.8
E)316
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66
Find the concentration of Pb2+ ions in a solution made by adding 5.00 g of lead(II)iodide to 500.mL of 0.150 M KI.[For PbI2, Ksp = 1.39 × 10-8.]

A)3.04 × 10-4 M
B)1.54 × 10-7 M
C)6.18 × 10-7 M
D)1.52 × 10-4 M
E)9.27 × 10-8 M
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67
Calculate the molar solubility of AgCl in a 0.15 M solution of NH3(aq). (Ksp (AgCl)= 1.6 x 10-10; Kf (Ag(NH3)2+)= 1.5 x 107)

A)6.7 x 10-3 M
B)1.3 x 10-5 M
C)3.9 x 103 M
D)7.5 x 10-2 M
E)3.3 x 10-5 M
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68
Calculate the molar solubility of AgBr in a 0.25M solution of NH3(aq)(Ksp (AgBr)= 7.7 x 10-13 ; Kf (Ag(NH3)2+)= 1.5 x 107.

A)8.8 x 10-7 M
B)3.4 x 10-3 M
C)8.4 x 10-4 M
D)2.5 x 10-1 M
E)9.7 x 102 M
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69
A saturated sodium carbonate solution at 0°C contains 7.1 g of dissolved sodium carbonate per 100.mL of solution.The solubility product constant for sodium carbonate at this temperature is

A)1.2
B)0.30
C)3.0 × 10-4
D)0.90
E)1.2 × 10-3
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70
Calculate the molar solubility of BaCO3 in a 0.10 M solution of Na2CO3(aq).(Ksp (BaCO3)= 8.1 x 10-9)

A)8.1 x 10-9 M
B)9.0 x 10-5 M
C)8.1 x 10-8 M
D)2.8 x 10-4 M
E)0.10 M
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71
Will a precipitate of magnesium fluoride form when 300.mL of 1.1 × 10-3 M MgCl2 are added to 500.mL of 1.2 × 10-3 M NaF? [Ksp (MgF2)= 6.9 × 10-9]

A)Yes, Q > Ksp
B)No, Q < Ksp
C)No, Q = Ksp
D)Yes, Q < Ksp
E)Yes, Q = Ksp
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72
Calculate the molar solubility of CaF2 in a 0.25 M solution of NaF(aq).(Ksp (CaF2)= 4.0 x 10-11)

A)4.0 x 10-11 M
B)6.4 x 10-10 M
C)1.6 x 10-10 M
D)1.3 x 10-5 M
E)2.2 x 10-4 M
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73
Find the concentration of calcium ions in a solution made by adding 3.50 g of calcium fluoride to 750.mL of 0.125 M NaF.[For CaF2, Ksp = 3.95 × 10-11.]

A)3.16 × 10-10 M
B)2.53 × 10-9 M
C)4.29 × 10-4 M
D)6.32 × 10-10 M
E)2.15 × 10-4 M
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74
Calculate the molar solubility of Fe(OH)2 in a solution with pH = 13.15. (Ksp Fe(OH)2 = 1.6 x 10-14)

A)1.6 x 10-14 M
B)1.1 x 10-13 M
C)1.6 x 10-5 M
D)8.0 x 10-13 M
E)3.4 x 10-7 M
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75
Calculate the molar solubility of Mg(OH)2 in a solution with pH = 12.20. (Ksp (Mg(OH)2 = 1.2 x 10-11)

A)4.8 x 10-8 M
B)7.6 x 10-10 M
C)3.5 x 10-6 M
D)1.4 x 10-4 M
E)2.4 x 10-6 M
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76
Will a precipitate (ppt)form when 20.0 mL of 1.1 × 10-3 M Ba(NO3)2 are added to 80.0 mL of 8.4 × 10-4 M Na2CO3?

A)Yes, the ppt is Ba(NO3 )2.
B)Yes, the ppt is NaNO3.
C)Yes, the ppt is BaCO3.
D)Yes, the ppt is Na2CO3.
E)No, a precipitate will not form.
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77
Will a precipitate (ppt)form when 300.mL of 5.0 × 10-5 M AgNO3 are added to 200.mL of 2.5 × 10-7 M NaBr? Answer yes or no, and identify the precipitate if there is one.

A)Yes, the ppt is AgNO3(s).
B)Yes, the ppt is AgBr(s).
C)Yes, the ppt is NaBr(s).
D)Yes, the ppt is NaNO3(s).
E)No, a precipitate will not form.
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78
Will a precipitate form (yes or no)when 50.0 mL of 1.2 × 10-3 M Pb(NO3)2 are added to 50.0 mL of 2.0 × 10-4 M Na2S? If so, identify the precipitate.

A)Yes, the precipitate is PbS.
B)Yes, the precipitate is NaNO3.
C)Yes, the precipitate is Na2S.
D)Yes, the precipitate is Pb(NO3)2.
E)No, a precipitate will not form.
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79
Will a precipitate (ppt)form when 300.mL of 2.0 × 10-5 M AgNO3 are added to 200.mL of 2.5 × 10-9 M NaI? Answer yes or no, and identify the precipitate if there is one.

A)Yes, the ppt is AgNO3(s).
B)Yes, the ppt is NaNO3(s).
C)Yes, the ppt is NaI(s).
D)Yes, the ppt is AgI(s).
E)No, a precipitate will not form.
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80
Will a precipitate of magnesium fluoride form when 200.mL of 1.9 × 10-3 M MgCl2 are added to 300.mL of 1.4 × 10-2 M NaF? [Ksp (MgF2)= 6.9 × 10-9]

A)Yes, Q > Ksp
B)No, Q < Ksp
C)No, Q = Ksp
D)Yes, Q < Ksp
E)Yes, Q = Ksp
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