Deck 14: Electrochemistry

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Question
If the standard potentials for the couples Cu2+/Cu,Ag+/Ag,and Fe2+/Fe are +0.34,+0.80,and -0.44 V,respectively,which is the strongest reducing agent?

A)Fe
B)Ag
C)Ag+
D)Cu
E)Fe2+
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Question
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Pb(s) \mid Pb2+(aq)m Cu2+(aq) \mid Cu(s)
Is +0.47 V.What is the standard potential of the Pb2+/Pb electrode?

A)(-0.26 V)
B)+0.81 V
C)(-0.81V)
D)(-0.13 V)
E)+0.13 V
Question
What is the proper cell diagram for the reaction 2AgCl(s)+ H2(g) \rightarrow 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)

A)Pt \mid Cl - (aq) \mid H+(aq)m H2(g) \mid AgCl(s) \mid Ag(s)
B)Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid AgCl(s) \mid Ag(s)
C)Ag(s) \mid AgCl(s) \mid Cl - (aq)m H+(aq) \mid H2(g) \mid Pt
D)Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid Ag(s) \mid Pt
E)Ag(s) \mid AgCl(s) \mid H+(aq)m Cl - (aq) \mid H2(g) \mid Pt
Question
When the Ag(s) \mid AgCl(s) \mid Cl - (aq)electrode acts as a cathode,the reaction is

A)Ag+(aq)+ e - \rightarrow Ag(s).
B)Ag(s)+ Cl - (aq) \rightarrow AgCl(s)+ e - .
C)Ag(s) \rightarrow Ag+(aq)+ e - .
D)2AgCl(s)+ 2e - \rightarrow 2Ag+(aq)+ Cl2(g).
E)AgCl(s)+ e - \rightarrow Ag(s)+ Cl - (aq).
Question
How many electrons appear in the balanced half reaction: NO3 - (aq) \rightarrow NO(g),in acidic solution?

A)2
B)3
C)4
D)6
E)8
Question
In the determination of iron in vitamins,Fe2+ is titrated with permanganate,MnO4 - ,in acidic solution.The products of the reaction are Fe3+ and Mn2+.In the balanced equation,the number of electrons transferred is

A)5
B)1
C)10
D)7
Question
Given: Cr(OH)3(s) \rightarrow CrO42 - (aq),basic solution. How many electrons appear in the balanced half-reaction?

A)3
B)6
C)5
D)7
E)4
Question
In a working electrochemical cell (+ cell voltage),the electrons flow from the anode through the external circuit to the cathode.True or false?
Question
Given: N2H5+(aq) \rightarrow N2(g). How many electrons appear in the balanced half-reaction?

A)6
B)2
C)1
D)4
E)5
Question
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Ag(s) \mid AgCl(s) \mid Cl - (aq)m Cu2+(aq) \mid Cu(s)
Is +0.12 V.What is the standard potential of the AgCl/Ag,Cl - electrode?

A)(-0.46 V)
B)(-0.22 V)
C)+0.24 V
D)+0.46 V
E)+0.22 V
Question
A cell that uses bromine to oxidize chloride ion under standard conditions at 298 K has a positive potential.True or false?
Question
True or false: A cell that uses bromine to oxidize hydrogen to H+ under standard conditions at 298 K has a negative potential?
Question
If the standard potentials for the couples Fe3+/Fe2+,MnO42 - ,H+/Mn2+,H2O,Zn2+/Zn,V3+/V2+,and Br2/Br - are +0.77,+1.51,-0.76,-0.26,and +1.09 V,respectively,which is the strongest oxidizing agent?

A)Zn2+
B)Fe3+
C)Mn2+
D)Br2
E)MnO4 -
Question
Given: Zn(s)+ OH - (aq)+ H2O(l)+ NO3 - (aq) \rightarrow Zn(OH)42 - (aq)+ NH3(g) If the coefficient of NO3 - in the balanced equation is 1,how many electrons are transferred in the reaction?

A)10
B)6
C)2
D)4
E)8
Question
For the cell diagram Pt \mid H2(g),H+(aq)m Cu2+(aq) \mid Cu(s)
Which reaction occurs at the anode?

A)Cu(s) \rightarrow Cu2+(aq)+ 2e -
B)2H+(aq)+ 2e - \rightarrow H2(g)
C)2H+(aq)+ Cu(s) \rightarrow H2(g)+ Cu2+(aq)
D)Cu2+(aq)+ 2e - \rightarrow Cu(s)
E)H2(g) \rightarrow 2H+(aq)+ 2e -
Question
When a sample of an unknown metal is dropped into 1 M H+(aq)under standard conditions,bubbles are observed.The unknown metal could be silver.True or false?
Question
In a working electrochemical cell (+ cell voltage),the cations in the salt bridge move toward the cathode.True or false?
Question
When equilibrium is reached in an electrochemical cell,the voltage reaches its maximum value.True or false?
Question
Given: S2O42- (aq) \rightarrow SO32- (aq),basic solution. How many electrons appear in the balanced half-reaction?

A)3
B)6
C)1
D)4
E)2
Question
Given: PH3(g) \rightarrow P4(s),basic solution. How many electrons appear in the balanced half-reaction?

A)12
B)9
C)6
D)8
E)3
Question
Consider the following cell at standard conditions: Zn(s) \mid Zn2+(aq)m Fe2+(aq) \mid Fe(s)
Calculate the value of Δ\Delta Gr °\degree for the reaction that occurs when current is drawn from this cell.

A)(-62 kJ.mol - 1 )
B)(-230 kJ.mol - 1 )
C)+62 kJ.mol - 1
D)+230 kJ.mol - 1
E)(-31 kJ.mol - 1 )
Question
If the standard potential for Tl3+(aq)/Tl+(aq)is 1.21 V and the standard potential for Tl+(aq)/Tl(s)is -0.34 V,calculate the standard potential for Tl3+(aq)+ 3e - \rightarrow Tl(s).

A)0.69 V
B)0.87 V
C)1.55 V
D)0.09 V
E)0.29 V
Question
Which of the following is the strongest oxidizing agent?

A)O3
B)MnO4 -
C)Cr2O72 -
D)Cl2
Question
The standard potential of the cell Pb(s) \mid PbSO4(s) \mid SO42 - (aq)m Pb2+(aq) \mid Pb(s)
Is +0.23 V at 25 °\degree C.Calculate the equilibrium constant for the reaction of 1 M Pb2+(aq)with 1M SO42 - (aq).

A)3.7 *1016
B)8.0 * 1017
C)6.0 * 107
D)1.7 * 10 - 8
E)7.7 *103
Question
Which species will oxidize Cr2+ but not Mn2+?

A)Pb4+
B)O3 in acidic medium
C)Zn2+
D)Fe2+
E)V3+
Question
Consider the reaction: 2Ag+(aq)+ Cu(s) \rightarrow Cu2+(aq)+ 2Ag(s)
If the standard potentials of Ag+ and Cu2+ are +0.80 V and +0.34 V,respectively,calculate the value of E °\degree for the given reaction.

A)+1.48 V
B)(-1.26 V)
C)(-0.46 V)
D)+1.26 V
E)+0.46 V
Question
Calculate E °\degree for the following cell. Zn(s) \mid Zn2+(aq)m Cl - aq \mid AgCl(s) \mid Ag(s)

A)+0.54 V
B)+1.20 V
C)(-1.20 V)
D)+0.98 V
E)(-0.54 V)
Question
If the standard potential for Cu2+(aq)/Cu+(aq)is 0.15 V and the standard potential for Cu2+(aq)/Cu(s)is 0.34 V,calculate the standard potential for Cu+(aq)+ e - \rightarrow Cu(s).

A)+0.32 V
B)+0.64 V
C)+0.53 V
D)+0.83 V
E)+0.49 V
Question
Of the following five ions or molecules,which is the strongest reducing agent?

A)Fe +2
B)Cr2+
C)F-
D)H2
E)Co2+
Question
If the standard free energy change for combustion of 1 mole of CH4(g)is-818 kJ.mol - 1,calculate the standard voltage that could be obtained from a fuel cell using this reaction.

A)(-1.06 V)
B)+0.53 V
C)+4.24 V
D)+8.48 V
E)+1.06 V
Question
Which pair of metals will dissolve in nitric acid?

A)Pt, Ag
B)Pt, Au
C)Ag, Fe
D)Ag, Au
E)Pt, Fe
Question
Which species will reduce Ag+ but not Fe2+?

A)Pt
B)Au
C)V
D)Cr
E)H2
Question
Which metal will dissolve in hydrochloric acid?

A)All the metals listed will dissolve.
B)Fe
C)Ag
D)Pt
E)Au
Question
Which species will reduce Br2 but not V3+?

A)Ce
B)Zn
C)Cu
D)Cr2+
E)Al
Question
If the standard potential for Ti3+(aq)/Ti2+(aq)is -0.37 V and the standard potential for Ti2+(aq)/Ti(s)is -1.63 V,calculate the standard potential for Ti3+(aq)+ 3e - \rightarrow Ti(s).

A)(-1.19 V)
B)(-0.40 V)
C)(-2.00 V)
D)(-1.26 V)
E)(-1.21 V)
Question
Which of the following occurs when HCl(aq),Cu(s),and Fe(s)are mixed under standard conditions?

A)O2(g)is formed.
B)Cu(s)dissolves.
C)Cl2(g)is formed.
D)No reaction takes place.
E)Fe(s)dissolves.
Question
Consider the following reaction: 2Cu+(aq) \rightarrow Cu(s)+ Cu2+(aq)
If the standard potentials of Cu2+ and Cu+ are +0.34 and +0.52 V,respectively,calculate the value of E °\degree for the given reaction.

A)+0.86 V
B)+0.70 V
C)+0.18 V
D)(-0.18 V)
E)(-0.70 V)
Question
The standard potential of the cell Ag(s) \mid AgCl(s)m Cl - (aq) \mid Cu2+(aq) \mid Cu(s)
Is +0.12 V at 25 °\degree C.If the standard potential of the Cu2+/Cu couple is +0.34 V,calculate the standard potential of the AgCl/Ag,Cl - couple.

A)(-0.12 V)
B)(-0.46 V)
C)+0.46 V
D)(-0.22 V)
E)+0.22 V
Question
Given: Ag+(aq)+ e - \rightarrow Ag(s)
E° = 0.80 V
Fe3+(aq)+ e - \rightarrow Fe2+(aq)
E °\degree = 0.77 V
Cu2+(aq)+ 2e - \rightarrow Cu(s)
E °\degree = 0.34 V
Which is the strongest reducing agent?

A)Ag
B)Cu2+
C)Cu
D)Ag+
E)Fe2+
Question
Which of the following occurs when HNO3(aq),Cu(s),and Pt(s)are mixed under standard conditions?

A)Pt(s)dissolves.
B)No reaction takes place.
C)Cu(s)dissolves.
D)Pt(s)dissolves and H2(g)is formed.
E)Cu(s)dissolves and H2(g)is formed.
Question
Consider the following cell: Zn(s \mid Zn2+(aq,0.100 M)m Cl - (aq,? M) \mid Cl2(g,0.500 atm) \mid Pt
For this cell,E °\degree = 2.12 V and E = 2.27 V at 25 °\degree C.Calculate the Cl - (aq)concentration in the cathode compartment.

A)1.2*10 - 1 M
B)4.3 *10 - 5 M
C)2.9 *10 - 3 M
D)1.5 *10 - 3 M
E)6.5 *10 - 3 M
Question
Use the following to answer questions Use the following to answer questions   The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?<div style=padding-top: 35px>
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?
Question
Use the following to answer questions Use the following to answer questions   The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?<div style=padding-top: 35px>
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?
Question
The standard voltage of the cell Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid AgCl(s) \mid Ag(s)
Is +0.22 V at 25 °\degree C.Calculate the equilibrium constant for the reaction below.
2AgCl(s)+ H2(g) \rightarrow 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)

A)3.7
B)7.4
C)5.2 * 103
D)1.7 * 103
E)2.7 *107
Question
Use the following diagram of a cell to answer questions  <strong>Use the following diagram of a cell to answer questions    -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?</strong> A)Zn<sup>2+</sup>(aq)+ H<sub>2</sub>(g) \rightarrow Zn(s)+ 2H<sup>+</sup>(aq) B)Zn(s)+ 2H<sup>+</sup>(aq) \rightarrow Zn<sup>2+</sup>(aq)+ H<sub>2</sub>(g) <div style=padding-top: 35px>

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?

A)Zn2+(aq)+ H2(g) \rightarrow Zn(s)+ 2H+(aq)
B)Zn(s)+ 2H+(aq) \rightarrow Zn2+(aq)+ H2(g)
Question
The standard voltage of the cell Ag(s) \mid AgBr(s) \mid Br - (aq)m Ag+(aq) \mid Ag(s)
Is +0.73 V at 25 °\degree C.Calculate the equilibrium constant for the cell reaction.

A)5.1 * 1014
B)2.0 *10 - 15
C)2.2 * 1012
D)4.6 *10 - 13
E)3.9 * 10 - 29
Question
Calculate E for the half-reaction below. 2H+(aq,1.00 *10 - 5 M)+ 2e - \rightarrow H2(g,1.00 atm)

A)0 V
B)+0.592 V
C)(-0.592 V)
D)(-0.296 V)
E)+0.296 V
Question
What is the value of E for the following reaction?
2H+(aq,1.00 M)+ 2e - \rightarrow H2(g,1.00 atm)
Question
If E °\degree for the following cell is 0.36 V at 25 °\degree C Pb(s) \mid PbSO4(s) \mid SO42 - (aq,0.60 M)m H+(aq,0.70 M) \mid H2(g,192.5 kPa) \mid Pt
How is the Nernst equation for the cell properly expressed at this temperature?

A)E = 0.36 -0.01285ln[1.90/{(0.70)2(0.60)}]
B)E = 0.36 -0.02569ln[192.5/{(0.70)2(0.60)}]
C)E = 0.36 + 0.01285ln[192.5/{(0.70)2(0.60)}]
D)E = 0.36 + 0.01285ln[1.90/{(0.70)2(0.60)}]
E)E = 0.36 -0.01285ln[1.90/{(0.70)(0.60)}]
Question
Consider the following cell: Pt \mid H2(g,1 atm) \mid H+(aq,? M)m Ag+(aq,1.0 M) \mid Ag(s)
If the voltage of this cell is 1.04 V at 25 °\degree C and the standard potential of the Ag+/Ag couple is +0.80 V,calculate the hydrogen ion concentration in the anode compartment.

A)4.6 *10 - 10 M
B)8.8 *10 - 5 M
C)9.4 * 10 - 3 M
D)1.0 M
E)3.7 *10 - 8 M
Question
Consider the following cell:
Zn(s) \mid Zn2+(aq,0.200 M)m H+(aq,?) \mid H2(g,1.00 atm) \mid Pt
If E = +0.66 V and E °\degree = +0.76 V at 25 °\degree C,calculate the concentration of H+ in the cathode cell compartment.

A)2.1 *10-2 M
B)4.0 *101 M
C)8.4 *10-5 M
D)9.2*10-3 M
E)4.0 *10-3 M
Question
The equilibrium constant for the reaction 2Hg(l)+ 2Cl - (aq)+ Ni2+(aq) \rightarrow Ni(s)+ Hg2Cl2(s)
Is 5.6 *10 - 20 at 25 °\degree C.Calculate the value of E °\degree for a cell utilizing this reaction.

A)+0.57 V
B)(-0.25 V)
C)+1.14 V
D)(-1.14 V)
E)(-0.57 V)
Question
Consider the following cell:
Pt \mid Fe2+(aq,0.50 M),Fe3+(aq,0.30 M)m Fe3+(aq,0.035 M),Fe2+(aq,0.010) \mid Pt
The standard potential for the Fe3+/Fe2+ couple is +0.77 V.Calculate the cell voltage at 25 °\degree C.
Question
Use the following to answer questions Use the following to answer questions    -The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?<div style=padding-top: 35px>

-The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
Question
If E °\degree for the disproportionation of Cu+(aq)to Cu2+(aq)and Cu(s)is +0.18 V at 25 °\degree C,calculate the equilibrium constant for the reaction.

A)1.2 * 106
B)3.9 * 1074
C)2.5 * 1014
D)35.7
E)3.3 * 1012
Question
Use the following diagram of a cell to answer questions  <strong>Use the following diagram of a cell to answer questions    -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?</strong> A)Zn<sup>2+</sup>(aq)+ 2e <sup>-</sup>  \rightarrow  Zn(s) B)Zn(s) \rightarrow Zn<sup>2+</sup>(aq)+ 2e <sup>-</sup> <sup> </sup> <div style=padding-top: 35px>

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?

A)Zn2+(aq)+ 2e - \rightarrow Zn(s)
B)Zn(s) \rightarrow Zn2+(aq)+ 2e -
Question
The standard potential of the cell Pb(s) \mid PbSO4(s) \mid SO42 - (aq)m Pb2+(aq) \mid Pb(s)
Is +0.23 V at 25 °\degree C.Calculate the Ksp of PbSO4.

A)1.3 *10 - 18
B)1.7*10 - 8
C)1.3 * 10 - 4
D)2.7* *10 - 17
E)6.0 * 107
Question
Consider the following cell: Ag(s) \mid Ag+(aq,0.100 M)mAg+(aq,0.100 M) \mid Ag(s)
What is the voltage of this cell?

A)0
B)+0.0592 V
C)+0.0296 V
D)+0.80 V
Question
The standard voltage of the cell Ag(s) \mid AgBr(s) \mid Br - (aq)m Ag+(aq) \mid Ag(s)
Is +0.73 V at 25 °\degree C.Calculate the Ksp for AgBr.

A)3.9 *10 - 29
B)2.2 * 1012
C)2.0*10 - 15
D)5.1 * 1014
E)4.6 *10 - 13
Question
Use the following to answer questions Use the following to answer questions    -The galvanic cell shown above uses the half-cells Mg<sup>2+</sup>/Mg and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?<div style=padding-top: 35px>

-The galvanic cell shown above uses the half-cells Mg2+/Mg and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
Question
When KI(aq)is electrolyzed at a concentration of 1 M,the product at the anode is I2.True or false?
Question
The products of the electrolysis of CuSO4(aq)are

A)H2(g)and H2SO3(aq).
B)H2SO3(aq)and O2(g).
C)Cu(s)and H2SO3(aq).
D)Cu(s)and O2(g).
E)H2(g)and O2(g).
Question
How many seconds are required to produce 4.99 mg of chromium metal from an acidic solution of potassium dichromate,using a current of 0.234 A?
Question
For the reduction of Cu2+ by Zn, Δ\Delta Go = -212 kJ/mol and Eo = +1.10 V.If the coefficients in the chemical equation for this reaction are multiplied by 2, Δ\Delta Go = -424 kJ/mol.This means Eo = +2.20 V.True or false?
Question
How many moles of Cl2(g)are produced by the electrolysis of concentrated sodium chloride if 2.00 A are passed through the solution for 4.00 hours? The equation for this process,the "chloralkali" process,is 2NaCl(aq)+ 2H2O(l) \rightarrow 2NaOH(aq)+ H2(g)+ Cl2(g)

A)0.0745 mol
B)0.149 mol
C)0.447 mol
D)0.00248 mol
E)0.298 mol
Question
What current is required to produce 91.6 g of chromium meta from chromium(VI)oxide in 12.4 hours?
Question
 <strong>   -Using the cell shown above,A is a standard Ag<sup>+</sup>/Ag electrode connected to a standard hydrogen electrode (SHE).When the voltmeter reading is -0.80 V,which half-reaction occurs in the left-hand cell compartment?</strong> A)Ag(s) \rightarrow  Ag<sup>+</sup>(aq)+ e <sup>-</sup> <sup> </sup> B)Ag<sup>+</sup>(aq)+ e <sup>-</sup>  \rightarrow Ag(s) <div style=padding-top: 35px>

-Using the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).When the voltmeter reading is -0.80 V,which half-reaction occurs in the left-hand cell compartment?

A)Ag(s) \rightarrow Ag+(aq)+ e -
B)Ag+(aq)+ e - \rightarrow Ag(s)
Question
Of the following metals,which metal would be suitable to provide an iron bridge with cathodic protection from corrosion?

A)Ni
B)Cu
C)Pb
D)Sn
E)None of the metals listed is suitable.
Question
Sodium is produced by electrolysis of molten sodium chloride.What are the products at the anode and cathode,respectively?

A)Na(l)and O2(g)
B)Cl - (aq)and Na2O(l)
C)Cl2(g)and Na2O(l)
D)O2(g)and Na(l)
E)Cl2(g)and Na(l)
Question
When a lead-acid battery discharges,sulfuric acid is produced.True or false?
Question
In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,which electrode is negative?
Question
How many moles of O2(g)are produced by electrolysis of Na2SO4(aq)if 0.120 A is passed through the solution for 65.0 min?

A)0.001 21 mol
B)0.000 080 8 mol
C)0.002 42 mol
D)0.004 85 mol
E)0.000 020 2 mol
Question
The half-reaction that occurs at cathode when 1 M AgNO3(aq)is electrolyzed is __________________.
Question
In order to convert hydrazine,N2H4,to nitric acid,

A)an oxidizing agent is required.
B)a reducing agent is required.
Question
 <strong>   -In the cell shown above,A is a standard Ag<sup>+</sup>/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?</strong> A)Ag(s)+ H<sup>+</sup>(aq) \rightarrow Ag<sup>+</sup>(aq)+ ½H<sub>2</sub>(g) B)Ag<sup>+</sup>(aq)+ ½H<sub>2</sub>(g) \rightarrow  Ag(s)+ H<sup>+</sup>(aq) <div style=padding-top: 35px>

-In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?

A)Ag(s)+ H+(aq) \rightarrow Ag+(aq)+ ½H2(g)
B)Ag+(aq)+ ½H2(g) \rightarrow Ag(s)+ H+(aq)
Question
In the Daniell cell,the anode is zinc metal and the cathode is copper metal.When the cell operates,the anode gets smaller and the cathode gets larger.True or false?
Question
Galvanized iron is protected from corrosion because zinc reduces any Fe2+ formed.True or false?
Question
How long will it take to deposit 0.00235 moles of gold by electrolysis of KAuCl4(aq)using a current of 0.214 amperes?

A)17.7 min
B)26.5 min
C)70.7 min
D)106 min
E)53.0 min
Question
   -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which electrode is negative?<div style=padding-top: 35px>

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which electrode is negative?
Question
If 8686 C of charge is passed through molten magnesium chloride,calculate the number of moles of Mg(l)produced.

A)0.0225 mol
B)0.0450 mol
C)2.00 mol
D)0.0110 mol
E)0.0900 mol
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Deck 14: Electrochemistry
1
If the standard potentials for the couples Cu2+/Cu,Ag+/Ag,and Fe2+/Fe are +0.34,+0.80,and -0.44 V,respectively,which is the strongest reducing agent?

A)Fe
B)Ag
C)Ag+
D)Cu
E)Fe2+
Fe
2
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Pb(s) \mid Pb2+(aq)m Cu2+(aq) \mid Cu(s)
Is +0.47 V.What is the standard potential of the Pb2+/Pb electrode?

A)(-0.26 V)
B)+0.81 V
C)(-0.81V)
D)(-0.13 V)
E)+0.13 V
(-0.13 V)
3
What is the proper cell diagram for the reaction 2AgCl(s)+ H2(g) \rightarrow 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)

A)Pt \mid Cl - (aq) \mid H+(aq)m H2(g) \mid AgCl(s) \mid Ag(s)
B)Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid AgCl(s) \mid Ag(s)
C)Ag(s) \mid AgCl(s) \mid Cl - (aq)m H+(aq) \mid H2(g) \mid Pt
D)Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid Ag(s) \mid Pt
E)Ag(s) \mid AgCl(s) \mid H+(aq)m Cl - (aq) \mid H2(g) \mid Pt
Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid AgCl(s) \mid Ag(s)
4
When the Ag(s) \mid AgCl(s) \mid Cl - (aq)electrode acts as a cathode,the reaction is

A)Ag+(aq)+ e - \rightarrow Ag(s).
B)Ag(s)+ Cl - (aq) \rightarrow AgCl(s)+ e - .
C)Ag(s) \rightarrow Ag+(aq)+ e - .
D)2AgCl(s)+ 2e - \rightarrow 2Ag+(aq)+ Cl2(g).
E)AgCl(s)+ e - \rightarrow Ag(s)+ Cl - (aq).
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5
How many electrons appear in the balanced half reaction: NO3 - (aq) \rightarrow NO(g),in acidic solution?

A)2
B)3
C)4
D)6
E)8
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6
In the determination of iron in vitamins,Fe2+ is titrated with permanganate,MnO4 - ,in acidic solution.The products of the reaction are Fe3+ and Mn2+.In the balanced equation,the number of electrons transferred is

A)5
B)1
C)10
D)7
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7
Given: Cr(OH)3(s) \rightarrow CrO42 - (aq),basic solution. How many electrons appear in the balanced half-reaction?

A)3
B)6
C)5
D)7
E)4
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8
In a working electrochemical cell (+ cell voltage),the electrons flow from the anode through the external circuit to the cathode.True or false?
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9
Given: N2H5+(aq) \rightarrow N2(g). How many electrons appear in the balanced half-reaction?

A)6
B)2
C)1
D)4
E)5
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10
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Ag(s) \mid AgCl(s) \mid Cl - (aq)m Cu2+(aq) \mid Cu(s)
Is +0.12 V.What is the standard potential of the AgCl/Ag,Cl - electrode?

A)(-0.46 V)
B)(-0.22 V)
C)+0.24 V
D)+0.46 V
E)+0.22 V
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11
A cell that uses bromine to oxidize chloride ion under standard conditions at 298 K has a positive potential.True or false?
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12
True or false: A cell that uses bromine to oxidize hydrogen to H+ under standard conditions at 298 K has a negative potential?
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13
If the standard potentials for the couples Fe3+/Fe2+,MnO42 - ,H+/Mn2+,H2O,Zn2+/Zn,V3+/V2+,and Br2/Br - are +0.77,+1.51,-0.76,-0.26,and +1.09 V,respectively,which is the strongest oxidizing agent?

A)Zn2+
B)Fe3+
C)Mn2+
D)Br2
E)MnO4 -
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14
Given: Zn(s)+ OH - (aq)+ H2O(l)+ NO3 - (aq) \rightarrow Zn(OH)42 - (aq)+ NH3(g) If the coefficient of NO3 - in the balanced equation is 1,how many electrons are transferred in the reaction?

A)10
B)6
C)2
D)4
E)8
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15
For the cell diagram Pt \mid H2(g),H+(aq)m Cu2+(aq) \mid Cu(s)
Which reaction occurs at the anode?

A)Cu(s) \rightarrow Cu2+(aq)+ 2e -
B)2H+(aq)+ 2e - \rightarrow H2(g)
C)2H+(aq)+ Cu(s) \rightarrow H2(g)+ Cu2+(aq)
D)Cu2+(aq)+ 2e - \rightarrow Cu(s)
E)H2(g) \rightarrow 2H+(aq)+ 2e -
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16
When a sample of an unknown metal is dropped into 1 M H+(aq)under standard conditions,bubbles are observed.The unknown metal could be silver.True or false?
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17
In a working electrochemical cell (+ cell voltage),the cations in the salt bridge move toward the cathode.True or false?
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18
When equilibrium is reached in an electrochemical cell,the voltage reaches its maximum value.True or false?
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19
Given: S2O42- (aq) \rightarrow SO32- (aq),basic solution. How many electrons appear in the balanced half-reaction?

A)3
B)6
C)1
D)4
E)2
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20
Given: PH3(g) \rightarrow P4(s),basic solution. How many electrons appear in the balanced half-reaction?

A)12
B)9
C)6
D)8
E)3
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21
Consider the following cell at standard conditions: Zn(s) \mid Zn2+(aq)m Fe2+(aq) \mid Fe(s)
Calculate the value of Δ\Delta Gr °\degree for the reaction that occurs when current is drawn from this cell.

A)(-62 kJ.mol - 1 )
B)(-230 kJ.mol - 1 )
C)+62 kJ.mol - 1
D)+230 kJ.mol - 1
E)(-31 kJ.mol - 1 )
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22
If the standard potential for Tl3+(aq)/Tl+(aq)is 1.21 V and the standard potential for Tl+(aq)/Tl(s)is -0.34 V,calculate the standard potential for Tl3+(aq)+ 3e - \rightarrow Tl(s).

A)0.69 V
B)0.87 V
C)1.55 V
D)0.09 V
E)0.29 V
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23
Which of the following is the strongest oxidizing agent?

A)O3
B)MnO4 -
C)Cr2O72 -
D)Cl2
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24
The standard potential of the cell Pb(s) \mid PbSO4(s) \mid SO42 - (aq)m Pb2+(aq) \mid Pb(s)
Is +0.23 V at 25 °\degree C.Calculate the equilibrium constant for the reaction of 1 M Pb2+(aq)with 1M SO42 - (aq).

A)3.7 *1016
B)8.0 * 1017
C)6.0 * 107
D)1.7 * 10 - 8
E)7.7 *103
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25
Which species will oxidize Cr2+ but not Mn2+?

A)Pb4+
B)O3 in acidic medium
C)Zn2+
D)Fe2+
E)V3+
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26
Consider the reaction: 2Ag+(aq)+ Cu(s) \rightarrow Cu2+(aq)+ 2Ag(s)
If the standard potentials of Ag+ and Cu2+ are +0.80 V and +0.34 V,respectively,calculate the value of E °\degree for the given reaction.

A)+1.48 V
B)(-1.26 V)
C)(-0.46 V)
D)+1.26 V
E)+0.46 V
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27
Calculate E °\degree for the following cell. Zn(s) \mid Zn2+(aq)m Cl - aq \mid AgCl(s) \mid Ag(s)

A)+0.54 V
B)+1.20 V
C)(-1.20 V)
D)+0.98 V
E)(-0.54 V)
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28
If the standard potential for Cu2+(aq)/Cu+(aq)is 0.15 V and the standard potential for Cu2+(aq)/Cu(s)is 0.34 V,calculate the standard potential for Cu+(aq)+ e - \rightarrow Cu(s).

A)+0.32 V
B)+0.64 V
C)+0.53 V
D)+0.83 V
E)+0.49 V
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29
Of the following five ions or molecules,which is the strongest reducing agent?

A)Fe +2
B)Cr2+
C)F-
D)H2
E)Co2+
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30
If the standard free energy change for combustion of 1 mole of CH4(g)is-818 kJ.mol - 1,calculate the standard voltage that could be obtained from a fuel cell using this reaction.

A)(-1.06 V)
B)+0.53 V
C)+4.24 V
D)+8.48 V
E)+1.06 V
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31
Which pair of metals will dissolve in nitric acid?

A)Pt, Ag
B)Pt, Au
C)Ag, Fe
D)Ag, Au
E)Pt, Fe
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32
Which species will reduce Ag+ but not Fe2+?

A)Pt
B)Au
C)V
D)Cr
E)H2
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33
Which metal will dissolve in hydrochloric acid?

A)All the metals listed will dissolve.
B)Fe
C)Ag
D)Pt
E)Au
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34
Which species will reduce Br2 but not V3+?

A)Ce
B)Zn
C)Cu
D)Cr2+
E)Al
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35
If the standard potential for Ti3+(aq)/Ti2+(aq)is -0.37 V and the standard potential for Ti2+(aq)/Ti(s)is -1.63 V,calculate the standard potential for Ti3+(aq)+ 3e - \rightarrow Ti(s).

A)(-1.19 V)
B)(-0.40 V)
C)(-2.00 V)
D)(-1.26 V)
E)(-1.21 V)
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36
Which of the following occurs when HCl(aq),Cu(s),and Fe(s)are mixed under standard conditions?

A)O2(g)is formed.
B)Cu(s)dissolves.
C)Cl2(g)is formed.
D)No reaction takes place.
E)Fe(s)dissolves.
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37
Consider the following reaction: 2Cu+(aq) \rightarrow Cu(s)+ Cu2+(aq)
If the standard potentials of Cu2+ and Cu+ are +0.34 and +0.52 V,respectively,calculate the value of E °\degree for the given reaction.

A)+0.86 V
B)+0.70 V
C)+0.18 V
D)(-0.18 V)
E)(-0.70 V)
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38
The standard potential of the cell Ag(s) \mid AgCl(s)m Cl - (aq) \mid Cu2+(aq) \mid Cu(s)
Is +0.12 V at 25 °\degree C.If the standard potential of the Cu2+/Cu couple is +0.34 V,calculate the standard potential of the AgCl/Ag,Cl - couple.

A)(-0.12 V)
B)(-0.46 V)
C)+0.46 V
D)(-0.22 V)
E)+0.22 V
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39
Given: Ag+(aq)+ e - \rightarrow Ag(s)
E° = 0.80 V
Fe3+(aq)+ e - \rightarrow Fe2+(aq)
E °\degree = 0.77 V
Cu2+(aq)+ 2e - \rightarrow Cu(s)
E °\degree = 0.34 V
Which is the strongest reducing agent?

A)Ag
B)Cu2+
C)Cu
D)Ag+
E)Fe2+
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40
Which of the following occurs when HNO3(aq),Cu(s),and Pt(s)are mixed under standard conditions?

A)Pt(s)dissolves.
B)No reaction takes place.
C)Cu(s)dissolves.
D)Pt(s)dissolves and H2(g)is formed.
E)Cu(s)dissolves and H2(g)is formed.
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41
Consider the following cell: Zn(s \mid Zn2+(aq,0.100 M)m Cl - (aq,? M) \mid Cl2(g,0.500 atm) \mid Pt
For this cell,E °\degree = 2.12 V and E = 2.27 V at 25 °\degree C.Calculate the Cl - (aq)concentration in the cathode compartment.

A)1.2*10 - 1 M
B)4.3 *10 - 5 M
C)2.9 *10 - 3 M
D)1.5 *10 - 3 M
E)6.5 *10 - 3 M
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42
Use the following to answer questions Use the following to answer questions   The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?
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43
Use the following to answer questions Use the following to answer questions   The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?
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44
The standard voltage of the cell Pt \mid H2(g) \mid H+(aq)m Cl - (aq) \mid AgCl(s) \mid Ag(s)
Is +0.22 V at 25 °\degree C.Calculate the equilibrium constant for the reaction below.
2AgCl(s)+ H2(g) \rightarrow 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)

A)3.7
B)7.4
C)5.2 * 103
D)1.7 * 103
E)2.7 *107
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45
Use the following diagram of a cell to answer questions  <strong>Use the following diagram of a cell to answer questions    -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?</strong> A)Zn<sup>2+</sup>(aq)+ H<sub>2</sub>(g) \rightarrow Zn(s)+ 2H<sup>+</sup>(aq) B)Zn(s)+ 2H<sup>+</sup>(aq) \rightarrow Zn<sup>2+</sup>(aq)+ H<sub>2</sub>(g)

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?

A)Zn2+(aq)+ H2(g) \rightarrow Zn(s)+ 2H+(aq)
B)Zn(s)+ 2H+(aq) \rightarrow Zn2+(aq)+ H2(g)
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46
The standard voltage of the cell Ag(s) \mid AgBr(s) \mid Br - (aq)m Ag+(aq) \mid Ag(s)
Is +0.73 V at 25 °\degree C.Calculate the equilibrium constant for the cell reaction.

A)5.1 * 1014
B)2.0 *10 - 15
C)2.2 * 1012
D)4.6 *10 - 13
E)3.9 * 10 - 29
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47
Calculate E for the half-reaction below. 2H+(aq,1.00 *10 - 5 M)+ 2e - \rightarrow H2(g,1.00 atm)

A)0 V
B)+0.592 V
C)(-0.592 V)
D)(-0.296 V)
E)+0.296 V
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48
What is the value of E for the following reaction?
2H+(aq,1.00 M)+ 2e - \rightarrow H2(g,1.00 atm)
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49
If E °\degree for the following cell is 0.36 V at 25 °\degree C Pb(s) \mid PbSO4(s) \mid SO42 - (aq,0.60 M)m H+(aq,0.70 M) \mid H2(g,192.5 kPa) \mid Pt
How is the Nernst equation for the cell properly expressed at this temperature?

A)E = 0.36 -0.01285ln[1.90/{(0.70)2(0.60)}]
B)E = 0.36 -0.02569ln[192.5/{(0.70)2(0.60)}]
C)E = 0.36 + 0.01285ln[192.5/{(0.70)2(0.60)}]
D)E = 0.36 + 0.01285ln[1.90/{(0.70)2(0.60)}]
E)E = 0.36 -0.01285ln[1.90/{(0.70)(0.60)}]
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50
Consider the following cell: Pt \mid H2(g,1 atm) \mid H+(aq,? M)m Ag+(aq,1.0 M) \mid Ag(s)
If the voltage of this cell is 1.04 V at 25 °\degree C and the standard potential of the Ag+/Ag couple is +0.80 V,calculate the hydrogen ion concentration in the anode compartment.

A)4.6 *10 - 10 M
B)8.8 *10 - 5 M
C)9.4 * 10 - 3 M
D)1.0 M
E)3.7 *10 - 8 M
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51
Consider the following cell:
Zn(s) \mid Zn2+(aq,0.200 M)m H+(aq,?) \mid H2(g,1.00 atm) \mid Pt
If E = +0.66 V and E °\degree = +0.76 V at 25 °\degree C,calculate the concentration of H+ in the cathode cell compartment.

A)2.1 *10-2 M
B)4.0 *101 M
C)8.4 *10-5 M
D)9.2*10-3 M
E)4.0 *10-3 M
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52
The equilibrium constant for the reaction 2Hg(l)+ 2Cl - (aq)+ Ni2+(aq) \rightarrow Ni(s)+ Hg2Cl2(s)
Is 5.6 *10 - 20 at 25 °\degree C.Calculate the value of E °\degree for a cell utilizing this reaction.

A)+0.57 V
B)(-0.25 V)
C)+1.14 V
D)(-1.14 V)
E)(-0.57 V)
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53
Consider the following cell:
Pt \mid Fe2+(aq,0.50 M),Fe3+(aq,0.30 M)m Fe3+(aq,0.035 M),Fe2+(aq,0.010) \mid Pt
The standard potential for the Fe3+/Fe2+ couple is +0.77 V.Calculate the cell voltage at 25 °\degree C.
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54
Use the following to answer questions Use the following to answer questions    -The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?

-The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
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55
If E °\degree for the disproportionation of Cu+(aq)to Cu2+(aq)and Cu(s)is +0.18 V at 25 °\degree C,calculate the equilibrium constant for the reaction.

A)1.2 * 106
B)3.9 * 1074
C)2.5 * 1014
D)35.7
E)3.3 * 1012
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56
Use the following diagram of a cell to answer questions  <strong>Use the following diagram of a cell to answer questions    -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?</strong> A)Zn<sup>2+</sup>(aq)+ 2e <sup>-</sup>  \rightarrow  Zn(s) B)Zn(s) \rightarrow Zn<sup>2+</sup>(aq)+ 2e <sup>-</sup> <sup> </sup>

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?

A)Zn2+(aq)+ 2e - \rightarrow Zn(s)
B)Zn(s) \rightarrow Zn2+(aq)+ 2e -
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57
The standard potential of the cell Pb(s) \mid PbSO4(s) \mid SO42 - (aq)m Pb2+(aq) \mid Pb(s)
Is +0.23 V at 25 °\degree C.Calculate the Ksp of PbSO4.

A)1.3 *10 - 18
B)1.7*10 - 8
C)1.3 * 10 - 4
D)2.7* *10 - 17
E)6.0 * 107
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58
Consider the following cell: Ag(s) \mid Ag+(aq,0.100 M)mAg+(aq,0.100 M) \mid Ag(s)
What is the voltage of this cell?

A)0
B)+0.0592 V
C)+0.0296 V
D)+0.80 V
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59
The standard voltage of the cell Ag(s) \mid AgBr(s) \mid Br - (aq)m Ag+(aq) \mid Ag(s)
Is +0.73 V at 25 °\degree C.Calculate the Ksp for AgBr.

A)3.9 *10 - 29
B)2.2 * 1012
C)2.0*10 - 15
D)5.1 * 1014
E)4.6 *10 - 13
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60
Use the following to answer questions Use the following to answer questions    -The galvanic cell shown above uses the half-cells Mg<sup>2+</sup>/Mg and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?

-The galvanic cell shown above uses the half-cells Mg2+/Mg and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
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61
When KI(aq)is electrolyzed at a concentration of 1 M,the product at the anode is I2.True or false?
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62
The products of the electrolysis of CuSO4(aq)are

A)H2(g)and H2SO3(aq).
B)H2SO3(aq)and O2(g).
C)Cu(s)and H2SO3(aq).
D)Cu(s)and O2(g).
E)H2(g)and O2(g).
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63
How many seconds are required to produce 4.99 mg of chromium metal from an acidic solution of potassium dichromate,using a current of 0.234 A?
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64
For the reduction of Cu2+ by Zn, Δ\Delta Go = -212 kJ/mol and Eo = +1.10 V.If the coefficients in the chemical equation for this reaction are multiplied by 2, Δ\Delta Go = -424 kJ/mol.This means Eo = +2.20 V.True or false?
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65
How many moles of Cl2(g)are produced by the electrolysis of concentrated sodium chloride if 2.00 A are passed through the solution for 4.00 hours? The equation for this process,the "chloralkali" process,is 2NaCl(aq)+ 2H2O(l) \rightarrow 2NaOH(aq)+ H2(g)+ Cl2(g)

A)0.0745 mol
B)0.149 mol
C)0.447 mol
D)0.00248 mol
E)0.298 mol
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66
What current is required to produce 91.6 g of chromium meta from chromium(VI)oxide in 12.4 hours?
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67
 <strong>   -Using the cell shown above,A is a standard Ag<sup>+</sup>/Ag electrode connected to a standard hydrogen electrode (SHE).When the voltmeter reading is -0.80 V,which half-reaction occurs in the left-hand cell compartment?</strong> A)Ag(s) \rightarrow  Ag<sup>+</sup>(aq)+ e <sup>-</sup> <sup> </sup> B)Ag<sup>+</sup>(aq)+ e <sup>-</sup>  \rightarrow Ag(s)

-Using the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).When the voltmeter reading is -0.80 V,which half-reaction occurs in the left-hand cell compartment?

A)Ag(s) \rightarrow Ag+(aq)+ e -
B)Ag+(aq)+ e - \rightarrow Ag(s)
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68
Of the following metals,which metal would be suitable to provide an iron bridge with cathodic protection from corrosion?

A)Ni
B)Cu
C)Pb
D)Sn
E)None of the metals listed is suitable.
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69
Sodium is produced by electrolysis of molten sodium chloride.What are the products at the anode and cathode,respectively?

A)Na(l)and O2(g)
B)Cl - (aq)and Na2O(l)
C)Cl2(g)and Na2O(l)
D)O2(g)and Na(l)
E)Cl2(g)and Na(l)
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70
When a lead-acid battery discharges,sulfuric acid is produced.True or false?
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71
In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,which electrode is negative?
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72
How many moles of O2(g)are produced by electrolysis of Na2SO4(aq)if 0.120 A is passed through the solution for 65.0 min?

A)0.001 21 mol
B)0.000 080 8 mol
C)0.002 42 mol
D)0.004 85 mol
E)0.000 020 2 mol
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73
The half-reaction that occurs at cathode when 1 M AgNO3(aq)is electrolyzed is __________________.
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74
In order to convert hydrazine,N2H4,to nitric acid,

A)an oxidizing agent is required.
B)a reducing agent is required.
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75
 <strong>   -In the cell shown above,A is a standard Ag<sup>+</sup>/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?</strong> A)Ag(s)+ H<sup>+</sup>(aq) \rightarrow Ag<sup>+</sup>(aq)+ ½H<sub>2</sub>(g) B)Ag<sup>+</sup>(aq)+ ½H<sub>2</sub>(g) \rightarrow  Ag(s)+ H<sup>+</sup>(aq)

-In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?

A)Ag(s)+ H+(aq) \rightarrow Ag+(aq)+ ½H2(g)
B)Ag+(aq)+ ½H2(g) \rightarrow Ag(s)+ H+(aq)
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76
In the Daniell cell,the anode is zinc metal and the cathode is copper metal.When the cell operates,the anode gets smaller and the cathode gets larger.True or false?
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77
Galvanized iron is protected from corrosion because zinc reduces any Fe2+ formed.True or false?
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78
How long will it take to deposit 0.00235 moles of gold by electrolysis of KAuCl4(aq)using a current of 0.214 amperes?

A)17.7 min
B)26.5 min
C)70.7 min
D)106 min
E)53.0 min
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79
   -In the cell shown above,A is a standard Zn<sup>2+</sup>/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which electrode is negative?

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which electrode is negative?
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80
If 8686 C of charge is passed through molten magnesium chloride,calculate the number of moles of Mg(l)produced.

A)0.0225 mol
B)0.0450 mol
C)2.00 mol
D)0.0110 mol
E)0.0900 mol
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