Deck 14: Electrochemistry
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Deck 14: Electrochemistry
1
If the standard potentials for the couples Cu2+/Cu,Ag+/Ag,and Fe2+/Fe are +0.34,+0.80,and -0.44 V,respectively,which is the strongest reducing agent?
A)Fe
B)Ag
C)Ag+
D)Cu
E)Fe2+
A)Fe
B)Ag
C)Ag+
D)Cu
E)Fe2+
Fe
2
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Pb(s) Pb2+(aq)m Cu2+(aq) Cu(s)
Is +0.47 V.What is the standard potential of the Pb2+/Pb electrode?
A)(-0.26 V)
B)+0.81 V
C)(-0.81V)
D)(-0.13 V)
E)+0.13 V
Is +0.47 V.What is the standard potential of the Pb2+/Pb electrode?
A)(-0.26 V)
B)+0.81 V
C)(-0.81V)
D)(-0.13 V)
E)+0.13 V
(-0.13 V)
3
What is the proper cell diagram for the reaction 2AgCl(s)+ H2(g) 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)
A)Pt Cl - (aq) H+(aq)m H2(g) AgCl(s) Ag(s)
B)Pt H2(g) H+(aq)m Cl - (aq) AgCl(s) Ag(s)
C)Ag(s) AgCl(s) Cl - (aq)m H+(aq) H2(g) Pt
D)Pt H2(g) H+(aq)m Cl - (aq) Ag(s) Pt
E)Ag(s) AgCl(s) H+(aq)m Cl - (aq) H2(g) Pt
A)Pt Cl - (aq) H+(aq)m H2(g) AgCl(s) Ag(s)
B)Pt H2(g) H+(aq)m Cl - (aq) AgCl(s) Ag(s)
C)Ag(s) AgCl(s) Cl - (aq)m H+(aq) H2(g) Pt
D)Pt H2(g) H+(aq)m Cl - (aq) Ag(s) Pt
E)Ag(s) AgCl(s) H+(aq)m Cl - (aq) H2(g) Pt
Pt H2(g) H+(aq)m Cl - (aq) AgCl(s) Ag(s)
4
When the Ag(s) AgCl(s) Cl - (aq)electrode acts as a cathode,the reaction is
A)Ag+(aq)+ e - Ag(s).
B)Ag(s)+ Cl - (aq) AgCl(s)+ e - .
C)Ag(s) Ag+(aq)+ e - .
D)2AgCl(s)+ 2e - 2Ag+(aq)+ Cl2(g).
E)AgCl(s)+ e - Ag(s)+ Cl - (aq).
A)Ag+(aq)+ e - Ag(s).
B)Ag(s)+ Cl - (aq) AgCl(s)+ e - .
C)Ag(s) Ag+(aq)+ e - .
D)2AgCl(s)+ 2e - 2Ag+(aq)+ Cl2(g).
E)AgCl(s)+ e - Ag(s)+ Cl - (aq).
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5
How many electrons appear in the balanced half reaction: NO3 - (aq) NO(g),in acidic solution?
A)2
B)3
C)4
D)6
E)8
A)2
B)3
C)4
D)6
E)8
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6
In the determination of iron in vitamins,Fe2+ is titrated with permanganate,MnO4 - ,in acidic solution.The products of the reaction are Fe3+ and Mn2+.In the balanced equation,the number of electrons transferred is
A)5
B)1
C)10
D)7
A)5
B)1
C)10
D)7
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7
Given: Cr(OH)3(s) CrO42 - (aq),basic solution. How many electrons appear in the balanced half-reaction?
A)3
B)6
C)5
D)7
E)4
A)3
B)6
C)5
D)7
E)4
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8
In a working electrochemical cell (+ cell voltage),the electrons flow from the anode through the external circuit to the cathode.True or false?
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9
Given: N2H5+(aq) N2(g). How many electrons appear in the balanced half-reaction?
A)6
B)2
C)1
D)4
E)5
A)6
B)2
C)1
D)4
E)5
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10
The standard potential of the Cu2+/Cu electrode is +0.34 V and the standard potential of the cell Ag(s) AgCl(s) Cl - (aq)m Cu2+(aq) Cu(s)
Is +0.12 V.What is the standard potential of the AgCl/Ag,Cl - electrode?
A)(-0.46 V)
B)(-0.22 V)
C)+0.24 V
D)+0.46 V
E)+0.22 V
Is +0.12 V.What is the standard potential of the AgCl/Ag,Cl - electrode?
A)(-0.46 V)
B)(-0.22 V)
C)+0.24 V
D)+0.46 V
E)+0.22 V
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11
A cell that uses bromine to oxidize chloride ion under standard conditions at 298 K has a positive potential.True or false?
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12
True or false: A cell that uses bromine to oxidize hydrogen to H+ under standard conditions at 298 K has a negative potential?
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13
If the standard potentials for the couples Fe3+/Fe2+,MnO42 - ,H+/Mn2+,H2O,Zn2+/Zn,V3+/V2+,and Br2/Br - are +0.77,+1.51,-0.76,-0.26,and +1.09 V,respectively,which is the strongest oxidizing agent?
A)Zn2+
B)Fe3+
C)Mn2+
D)Br2
E)MnO4 -
A)Zn2+
B)Fe3+
C)Mn2+
D)Br2
E)MnO4 -
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14
Given: Zn(s)+ OH - (aq)+ H2O(l)+ NO3 - (aq) Zn(OH)42 - (aq)+ NH3(g) If the coefficient of NO3 - in the balanced equation is 1,how many electrons are transferred in the reaction?
A)10
B)6
C)2
D)4
E)8
A)10
B)6
C)2
D)4
E)8
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15
For the cell diagram Pt H2(g),H+(aq)m Cu2+(aq) Cu(s)
Which reaction occurs at the anode?
A)Cu(s) Cu2+(aq)+ 2e -
B)2H+(aq)+ 2e - H2(g)
C)2H+(aq)+ Cu(s) H2(g)+ Cu2+(aq)
D)Cu2+(aq)+ 2e - Cu(s)
E)H2(g) 2H+(aq)+ 2e -
Which reaction occurs at the anode?
A)Cu(s) Cu2+(aq)+ 2e -
B)2H+(aq)+ 2e - H2(g)
C)2H+(aq)+ Cu(s) H2(g)+ Cu2+(aq)
D)Cu2+(aq)+ 2e - Cu(s)
E)H2(g) 2H+(aq)+ 2e -
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16
When a sample of an unknown metal is dropped into 1 M H+(aq)under standard conditions,bubbles are observed.The unknown metal could be silver.True or false?
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17
In a working electrochemical cell (+ cell voltage),the cations in the salt bridge move toward the cathode.True or false?
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18
When equilibrium is reached in an electrochemical cell,the voltage reaches its maximum value.True or false?
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19
Given: S2O42- (aq) SO32- (aq),basic solution. How many electrons appear in the balanced half-reaction?
A)3
B)6
C)1
D)4
E)2
A)3
B)6
C)1
D)4
E)2
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20
Given: PH3(g) P4(s),basic solution. How many electrons appear in the balanced half-reaction?
A)12
B)9
C)6
D)8
E)3
A)12
B)9
C)6
D)8
E)3
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21
Consider the following cell at standard conditions: Zn(s) Zn2+(aq)m Fe2+(aq) Fe(s)
Calculate the value of Gr for the reaction that occurs when current is drawn from this cell.
A)(-62 kJ.mol - 1 )
B)(-230 kJ.mol - 1 )
C)+62 kJ.mol - 1
D)+230 kJ.mol - 1
E)(-31 kJ.mol - 1 )
Calculate the value of Gr for the reaction that occurs when current is drawn from this cell.
A)(-62 kJ.mol - 1 )
B)(-230 kJ.mol - 1 )
C)+62 kJ.mol - 1
D)+230 kJ.mol - 1
E)(-31 kJ.mol - 1 )
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22
If the standard potential for Tl3+(aq)/Tl+(aq)is 1.21 V and the standard potential for Tl+(aq)/Tl(s)is -0.34 V,calculate the standard potential for Tl3+(aq)+ 3e - Tl(s).
A)0.69 V
B)0.87 V
C)1.55 V
D)0.09 V
E)0.29 V
A)0.69 V
B)0.87 V
C)1.55 V
D)0.09 V
E)0.29 V
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23
Which of the following is the strongest oxidizing agent?
A)O3
B)MnO4 -
C)Cr2O72 -
D)Cl2
A)O3
B)MnO4 -
C)Cr2O72 -
D)Cl2
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24
The standard potential of the cell Pb(s) PbSO4(s) SO42 - (aq)m Pb2+(aq) Pb(s)
Is +0.23 V at 25 C.Calculate the equilibrium constant for the reaction of 1 M Pb2+(aq)with 1M SO42 - (aq).
A)3.7 *1016
B)8.0 * 1017
C)6.0 * 107
D)1.7 * 10 - 8
E)7.7 *103
Is +0.23 V at 25 C.Calculate the equilibrium constant for the reaction of 1 M Pb2+(aq)with 1M SO42 - (aq).
A)3.7 *1016
B)8.0 * 1017
C)6.0 * 107
D)1.7 * 10 - 8
E)7.7 *103
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25
Which species will oxidize Cr2+ but not Mn2+?
A)Pb4+
B)O3 in acidic medium
C)Zn2+
D)Fe2+
E)V3+
A)Pb4+
B)O3 in acidic medium
C)Zn2+
D)Fe2+
E)V3+
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26
Consider the reaction: 2Ag+(aq)+ Cu(s) Cu2+(aq)+ 2Ag(s)
If the standard potentials of Ag+ and Cu2+ are +0.80 V and +0.34 V,respectively,calculate the value of E for the given reaction.
A)+1.48 V
B)(-1.26 V)
C)(-0.46 V)
D)+1.26 V
E)+0.46 V
If the standard potentials of Ag+ and Cu2+ are +0.80 V and +0.34 V,respectively,calculate the value of E for the given reaction.
A)+1.48 V
B)(-1.26 V)
C)(-0.46 V)
D)+1.26 V
E)+0.46 V
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27
Calculate E for the following cell. Zn(s) Zn2+(aq)m Cl - aq AgCl(s) Ag(s)
A)+0.54 V
B)+1.20 V
C)(-1.20 V)
D)+0.98 V
E)(-0.54 V)
A)+0.54 V
B)+1.20 V
C)(-1.20 V)
D)+0.98 V
E)(-0.54 V)
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28
If the standard potential for Cu2+(aq)/Cu+(aq)is 0.15 V and the standard potential for Cu2+(aq)/Cu(s)is 0.34 V,calculate the standard potential for Cu+(aq)+ e - Cu(s).
A)+0.32 V
B)+0.64 V
C)+0.53 V
D)+0.83 V
E)+0.49 V
A)+0.32 V
B)+0.64 V
C)+0.53 V
D)+0.83 V
E)+0.49 V
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29
Of the following five ions or molecules,which is the strongest reducing agent?
A)Fe +2
B)Cr2+
C)F-
D)H2
E)Co2+
A)Fe +2
B)Cr2+
C)F-
D)H2
E)Co2+
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30
If the standard free energy change for combustion of 1 mole of CH4(g)is-818 kJ.mol - 1,calculate the standard voltage that could be obtained from a fuel cell using this reaction.
A)(-1.06 V)
B)+0.53 V
C)+4.24 V
D)+8.48 V
E)+1.06 V
A)(-1.06 V)
B)+0.53 V
C)+4.24 V
D)+8.48 V
E)+1.06 V
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31
Which pair of metals will dissolve in nitric acid?
A)Pt, Ag
B)Pt, Au
C)Ag, Fe
D)Ag, Au
E)Pt, Fe
A)Pt, Ag
B)Pt, Au
C)Ag, Fe
D)Ag, Au
E)Pt, Fe
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32
Which species will reduce Ag+ but not Fe2+?
A)Pt
B)Au
C)V
D)Cr
E)H2
A)Pt
B)Au
C)V
D)Cr
E)H2
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33
Which metal will dissolve in hydrochloric acid?
A)All the metals listed will dissolve.
B)Fe
C)Ag
D)Pt
E)Au
A)All the metals listed will dissolve.
B)Fe
C)Ag
D)Pt
E)Au
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34
Which species will reduce Br2 but not V3+?
A)Ce
B)Zn
C)Cu
D)Cr2+
E)Al
A)Ce
B)Zn
C)Cu
D)Cr2+
E)Al
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35
If the standard potential for Ti3+(aq)/Ti2+(aq)is -0.37 V and the standard potential for Ti2+(aq)/Ti(s)is -1.63 V,calculate the standard potential for Ti3+(aq)+ 3e - Ti(s).
A)(-1.19 V)
B)(-0.40 V)
C)(-2.00 V)
D)(-1.26 V)
E)(-1.21 V)
A)(-1.19 V)
B)(-0.40 V)
C)(-2.00 V)
D)(-1.26 V)
E)(-1.21 V)
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36
Which of the following occurs when HCl(aq),Cu(s),and Fe(s)are mixed under standard conditions?
A)O2(g)is formed.
B)Cu(s)dissolves.
C)Cl2(g)is formed.
D)No reaction takes place.
E)Fe(s)dissolves.
A)O2(g)is formed.
B)Cu(s)dissolves.
C)Cl2(g)is formed.
D)No reaction takes place.
E)Fe(s)dissolves.
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37
Consider the following reaction: 2Cu+(aq) Cu(s)+ Cu2+(aq)
If the standard potentials of Cu2+ and Cu+ are +0.34 and +0.52 V,respectively,calculate the value of E for the given reaction.
A)+0.86 V
B)+0.70 V
C)+0.18 V
D)(-0.18 V)
E)(-0.70 V)
If the standard potentials of Cu2+ and Cu+ are +0.34 and +0.52 V,respectively,calculate the value of E for the given reaction.
A)+0.86 V
B)+0.70 V
C)+0.18 V
D)(-0.18 V)
E)(-0.70 V)
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38
The standard potential of the cell Ag(s) AgCl(s)m Cl - (aq) Cu2+(aq) Cu(s)
Is +0.12 V at 25 C.If the standard potential of the Cu2+/Cu couple is +0.34 V,calculate the standard potential of the AgCl/Ag,Cl - couple.
A)(-0.12 V)
B)(-0.46 V)
C)+0.46 V
D)(-0.22 V)
E)+0.22 V
Is +0.12 V at 25 C.If the standard potential of the Cu2+/Cu couple is +0.34 V,calculate the standard potential of the AgCl/Ag,Cl - couple.
A)(-0.12 V)
B)(-0.46 V)
C)+0.46 V
D)(-0.22 V)
E)+0.22 V
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39
Given: Ag+(aq)+ e - Ag(s)
E° = 0.80 V
Fe3+(aq)+ e - Fe2+(aq)
E = 0.77 V
Cu2+(aq)+ 2e - Cu(s)
E = 0.34 V
Which is the strongest reducing agent?
A)Ag
B)Cu2+
C)Cu
D)Ag+
E)Fe2+
E° = 0.80 V
Fe3+(aq)+ e - Fe2+(aq)
E = 0.77 V
Cu2+(aq)+ 2e - Cu(s)
E = 0.34 V
Which is the strongest reducing agent?
A)Ag
B)Cu2+
C)Cu
D)Ag+
E)Fe2+
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40
Which of the following occurs when HNO3(aq),Cu(s),and Pt(s)are mixed under standard conditions?
A)Pt(s)dissolves.
B)No reaction takes place.
C)Cu(s)dissolves.
D)Pt(s)dissolves and H2(g)is formed.
E)Cu(s)dissolves and H2(g)is formed.
A)Pt(s)dissolves.
B)No reaction takes place.
C)Cu(s)dissolves.
D)Pt(s)dissolves and H2(g)is formed.
E)Cu(s)dissolves and H2(g)is formed.
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41
Consider the following cell: Zn(s Zn2+(aq,0.100 M)m Cl - (aq,? M) Cl2(g,0.500 atm) Pt
For this cell,E = 2.12 V and E = 2.27 V at 25 C.Calculate the Cl - (aq)concentration in the cathode compartment.
A)1.2*10 - 1 M
B)4.3 *10 - 5 M
C)2.9 *10 - 3 M
D)1.5 *10 - 3 M
E)6.5 *10 - 3 M
For this cell,E = 2.12 V and E = 2.27 V at 25 C.Calculate the Cl - (aq)concentration in the cathode compartment.
A)1.2*10 - 1 M
B)4.3 *10 - 5 M
C)2.9 *10 - 3 M
D)1.5 *10 - 3 M
E)6.5 *10 - 3 M
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42
Use the following to answer questions 
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?

The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.True or false?
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43
Use the following to answer questions 
The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?

The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or zinc.True or false?
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44
The standard voltage of the cell Pt H2(g) H+(aq)m Cl - (aq) AgCl(s) Ag(s)
Is +0.22 V at 25 C.Calculate the equilibrium constant for the reaction below.
2AgCl(s)+ H2(g) 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)
A)3.7
B)7.4
C)5.2 * 103
D)1.7 * 103
E)2.7 *107
Is +0.22 V at 25 C.Calculate the equilibrium constant for the reaction below.
2AgCl(s)+ H2(g) 2Ag(s)+ 2H+(aq)+ 2Cl - (aq)
A)3.7
B)7.4
C)5.2 * 103
D)1.7 * 103
E)2.7 *107
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45
Use the following diagram of a cell to answer questions 
-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?
A)Zn2+(aq)+ H2(g) Zn(s)+ 2H+(aq)
B)Zn(s)+ 2H+(aq) Zn2+(aq)+ H2(g)

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is-0.76 V,what is the equation for the cell reaction?
A)Zn2+(aq)+ H2(g) Zn(s)+ 2H+(aq)
B)Zn(s)+ 2H+(aq) Zn2+(aq)+ H2(g)
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46
The standard voltage of the cell Ag(s) AgBr(s) Br - (aq)m Ag+(aq) Ag(s)
Is +0.73 V at 25 C.Calculate the equilibrium constant for the cell reaction.
A)5.1 * 1014
B)2.0 *10 - 15
C)2.2 * 1012
D)4.6 *10 - 13
E)3.9 * 10 - 29
Is +0.73 V at 25 C.Calculate the equilibrium constant for the cell reaction.
A)5.1 * 1014
B)2.0 *10 - 15
C)2.2 * 1012
D)4.6 *10 - 13
E)3.9 * 10 - 29
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47
Calculate E for the half-reaction below. 2H+(aq,1.00 *10 - 5 M)+ 2e - H2(g,1.00 atm)
A)0 V
B)+0.592 V
C)(-0.592 V)
D)(-0.296 V)
E)+0.296 V
A)0 V
B)+0.592 V
C)(-0.592 V)
D)(-0.296 V)
E)+0.296 V
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48
What is the value of E for the following reaction?
2H+(aq,1.00 M)+ 2e - H2(g,1.00 atm)
2H+(aq,1.00 M)+ 2e - H2(g,1.00 atm)
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49
If E for the following cell is 0.36 V at 25 C Pb(s) PbSO4(s) SO42 - (aq,0.60 M)m H+(aq,0.70 M) H2(g,192.5 kPa) Pt
How is the Nernst equation for the cell properly expressed at this temperature?
A)E = 0.36 -0.01285ln[1.90/{(0.70)2(0.60)}]
B)E = 0.36 -0.02569ln[192.5/{(0.70)2(0.60)}]
C)E = 0.36 + 0.01285ln[192.5/{(0.70)2(0.60)}]
D)E = 0.36 + 0.01285ln[1.90/{(0.70)2(0.60)}]
E)E = 0.36 -0.01285ln[1.90/{(0.70)(0.60)}]
How is the Nernst equation for the cell properly expressed at this temperature?
A)E = 0.36 -0.01285ln[1.90/{(0.70)2(0.60)}]
B)E = 0.36 -0.02569ln[192.5/{(0.70)2(0.60)}]
C)E = 0.36 + 0.01285ln[192.5/{(0.70)2(0.60)}]
D)E = 0.36 + 0.01285ln[1.90/{(0.70)2(0.60)}]
E)E = 0.36 -0.01285ln[1.90/{(0.70)(0.60)}]
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50
Consider the following cell: Pt H2(g,1 atm) H+(aq,? M)m Ag+(aq,1.0 M) Ag(s)
If the voltage of this cell is 1.04 V at 25 C and the standard potential of the Ag+/Ag couple is +0.80 V,calculate the hydrogen ion concentration in the anode compartment.
A)4.6 *10 - 10 M
B)8.8 *10 - 5 M
C)9.4 * 10 - 3 M
D)1.0 M
E)3.7 *10 - 8 M
If the voltage of this cell is 1.04 V at 25 C and the standard potential of the Ag+/Ag couple is +0.80 V,calculate the hydrogen ion concentration in the anode compartment.
A)4.6 *10 - 10 M
B)8.8 *10 - 5 M
C)9.4 * 10 - 3 M
D)1.0 M
E)3.7 *10 - 8 M
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51
Consider the following cell:
Zn(s) Zn2+(aq,0.200 M)m H+(aq,?) H2(g,1.00 atm) Pt
If E = +0.66 V and E = +0.76 V at 25 C,calculate the concentration of H+ in the cathode cell compartment.
A)2.1 *10-2 M
B)4.0 *101 M
C)8.4 *10-5 M
D)9.2*10-3 M
E)4.0 *10-3 M
Zn(s) Zn2+(aq,0.200 M)m H+(aq,?) H2(g,1.00 atm) Pt
If E = +0.66 V and E = +0.76 V at 25 C,calculate the concentration of H+ in the cathode cell compartment.
A)2.1 *10-2 M
B)4.0 *10
C)8.4 *10-5 M
D)9.2*10-3 M
E)4.0 *10-3 M
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52
The equilibrium constant for the reaction 2Hg(l)+ 2Cl - (aq)+ Ni2+(aq) Ni(s)+ Hg2Cl2(s)
Is 5.6 *10 - 20 at 25 C.Calculate the value of E for a cell utilizing this reaction.
A)+0.57 V
B)(-0.25 V)
C)+1.14 V
D)(-1.14 V)
E)(-0.57 V)
Is 5.6 *10 - 20 at 25 C.Calculate the value of E for a cell utilizing this reaction.
A)+0.57 V
B)(-0.25 V)
C)+1.14 V
D)(-1.14 V)
E)(-0.57 V)
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53
Consider the following cell:
Pt Fe2+(aq,0.50 M),Fe3+(aq,0.30 M)m Fe3+(aq,0.035 M),Fe2+(aq,0.010) Pt
The standard potential for the Fe3+/Fe2+ couple is +0.77 V.Calculate the cell voltage at 25 C.
Pt Fe2+(aq,0.50 M),Fe3+(aq,0.30 M)m Fe3+(aq,0.035 M),Fe2+(aq,0.010) Pt
The standard potential for the Fe3+/Fe2+ couple is +0.77 V.Calculate the cell voltage at 25 C.
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54
Use the following to answer questions 
-The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?

-The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
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55
If E for the disproportionation of Cu+(aq)to Cu2+(aq)and Cu(s)is +0.18 V at 25 C,calculate the equilibrium constant for the reaction.
A)1.2 * 106
B)3.9 * 1074
C)2.5 * 1014
D)35.7
E)3.3 * 1012
A)1.2 * 106
B)3.9 * 1074
C)2.5 * 1014
D)35.7
E)3.3 * 1012
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56
Use the following diagram of a cell to answer questions 
-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?
A)Zn2+(aq)+ 2e - Zn(s)
B)Zn(s) Zn2+(aq)+ 2e -

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which half-reaction occurs in the left-hand cell compartment?
A)Zn2+(aq)+ 2e - Zn(s)
B)Zn(s) Zn2+(aq)+ 2e -
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57
The standard potential of the cell Pb(s) PbSO4(s) SO42 - (aq)m Pb2+(aq) Pb(s)
Is +0.23 V at 25 C.Calculate the Ksp of PbSO4.
A)1.3 *10 - 18
B)1.7*10 - 8
C)1.3 * 10 - 4
D)2.7* *10 - 17
E)6.0 * 107
Is +0.23 V at 25 C.Calculate the Ksp of PbSO4.
A)1.3 *10 - 18
B)1.7*10 - 8
C)1.3 * 10 - 4
D)2.7* *10 - 17
E)6.0 * 107
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58
Consider the following cell: Ag(s) Ag+(aq,0.100 M)mAg+(aq,0.100 M) Ag(s)
What is the voltage of this cell?
A)0
B)+0.0592 V
C)+0.0296 V
D)+0.80 V
What is the voltage of this cell?
A)0
B)+0.0592 V
C)+0.0296 V
D)+0.80 V
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59
The standard voltage of the cell Ag(s) AgBr(s) Br - (aq)m Ag+(aq) Ag(s)
Is +0.73 V at 25 C.Calculate the Ksp for AgBr.
A)3.9 *10 - 29
B)2.2 * 1012
C)2.0*10 - 15
D)5.1 * 1014
E)4.6 *10 - 13
Is +0.73 V at 25 C.Calculate the Ksp for AgBr.
A)3.9 *10 - 29
B)2.2 * 1012
C)2.0*10 - 15
D)5.1 * 1014
E)4.6 *10 - 13
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60
Use the following to answer questions 
-The galvanic cell shown above uses the half-cells Mg2+/Mg and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?

-The galvanic cell shown above uses the half-cells Mg2+/Mg and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.Identify A and write the half-reaction that occurs in that compartment.Does the size of the electrode A increase or decrease during operation of the cell? What is the voltmeter reading?
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61
When KI(aq)is electrolyzed at a concentration of 1 M,the product at the anode is I2.True or false?
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62
The products of the electrolysis of CuSO4(aq)are
A)H2(g)and H2SO3(aq).
B)H2SO3(aq)and O2(g).
C)Cu(s)and H2SO3(aq).
D)Cu(s)and O2(g).
E)H2(g)and O2(g).
A)H2(g)and H2SO3(aq).
B)H2SO3(aq)and O2(g).
C)Cu(s)and H2SO3(aq).
D)Cu(s)and O2(g).
E)H2(g)and O2(g).
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63
How many seconds are required to produce 4.99 mg of chromium metal from an acidic solution of potassium dichromate,using a current of 0.234 A?
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64
For the reduction of Cu2+ by Zn, Go = -212 kJ/mol and Eo = +1.10 V.If the coefficients in the chemical equation for this reaction are multiplied by 2, Go = -424 kJ/mol.This means Eo = +2.20 V.True or false?
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65
How many moles of Cl2(g)are produced by the electrolysis of concentrated sodium chloride if 2.00 A are passed through the solution for 4.00 hours? The equation for this process,the "chloralkali" process,is 2NaCl(aq)+ 2H2O(l) 2NaOH(aq)+ H2(g)+ Cl2(g)
A)0.0745 mol
B)0.149 mol
C)0.447 mol
D)0.00248 mol
E)0.298 mol
A)0.0745 mol
B)0.149 mol
C)0.447 mol
D)0.00248 mol
E)0.298 mol
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66
What current is required to produce 91.6 g of chromium meta from chromium(VI)oxide in 12.4 hours?
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67

-Using the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).When the voltmeter reading is -0.80 V,which half-reaction occurs in the left-hand cell compartment?
A)Ag(s) Ag+(aq)+ e -
B)Ag+(aq)+ e - Ag(s)
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68
Of the following metals,which metal would be suitable to provide an iron bridge with cathodic protection from corrosion?
A)Ni
B)Cu
C)Pb
D)Sn
E)None of the metals listed is suitable.
A)Ni
B)Cu
C)Pb
D)Sn
E)None of the metals listed is suitable.
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69
Sodium is produced by electrolysis of molten sodium chloride.What are the products at the anode and cathode,respectively?
A)Na(l)and O2(g)
B)Cl - (aq)and Na2O(l)
C)Cl2(g)and Na2O(l)
D)O2(g)and Na(l)
E)Cl2(g)and Na(l)
A)Na(l)and O2(g)
B)Cl - (aq)and Na2O(l)
C)Cl2(g)and Na2O(l)
D)O2(g)and Na(l)
E)Cl2(g)and Na(l)
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70
When a lead-acid battery discharges,sulfuric acid is produced.True or false?
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71
In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,which electrode is negative?
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72
How many moles of O2(g)are produced by electrolysis of Na2SO4(aq)if 0.120 A is passed through the solution for 65.0 min?
A)0.001 21 mol
B)0.000 080 8 mol
C)0.002 42 mol
D)0.004 85 mol
E)0.000 020 2 mol
A)0.001 21 mol
B)0.000 080 8 mol
C)0.002 42 mol
D)0.004 85 mol
E)0.000 020 2 mol
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73
The half-reaction that occurs at cathode when 1 M AgNO3(aq)is electrolyzed is __________________.
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74
In order to convert hydrazine,N2H4,to nitric acid,
A)an oxidizing agent is required.
B)a reducing agent is required.
A)an oxidizing agent is required.
B)a reducing agent is required.
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75

-In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?
A)Ag(s)+ H+(aq) Ag+(aq)+ ½H2(g)
B)Ag+(aq)+ ½H2(g) Ag(s)+ H+(aq)
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76
In the Daniell cell,the anode is zinc metal and the cathode is copper metal.When the cell operates,the anode gets smaller and the cathode gets larger.True or false?
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77
Galvanized iron is protected from corrosion because zinc reduces any Fe2+ formed.True or false?
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78
How long will it take to deposit 0.00235 moles of gold by electrolysis of KAuCl4(aq)using a current of 0.214 amperes?
A)17.7 min
B)26.5 min
C)70.7 min
D)106 min
E)53.0 min
A)17.7 min
B)26.5 min
C)70.7 min
D)106 min
E)53.0 min
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79

-In the cell shown above,A is a standard Zn2+/Zn electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is -0.76 V,which electrode is negative?
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80
If 8686 C of charge is passed through molten magnesium chloride,calculate the number of moles of Mg(l)produced.
A)0.0225 mol
B)0.0450 mol
C)2.00 mol
D)0.0110 mol
E)0.0900 mol
A)0.0225 mol
B)0.0450 mol
C)2.00 mol
D)0.0110 mol
E)0.0900 mol
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