Deck 14: Chemical Equilibrium

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Question
Give the direction of the reaction if K >> 1.

A)The forward reaction is favoured.
B)The reverse reaction is favoured.
C)Neither direction is favoured.
D)If the temperature is raised,then the forward reaction is favoured.
E)If the temperature is raised,then the reverse reaction is favoured.
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Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. 2HD(g)⇌ H2(g)+ D2(g)K = 0.28
2H2(g)+ 2D2(g)⇌ 4HD(g)K = ?

A)7.8 × 10-2
B)3.6
C)0.53
D)13
E)1.9
Question
Express the equilibrium constant for the following reaction:
PCl5(g)? PCl3(g)+ Cl2(g)

A)KP = P(PCl5)P(PCl3)×P(Cl2)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(PCl3)×P2(Cl2)P2(PCl5)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 2 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 5 } \right) }
C)KP = P(PCl3)×P2(Cl)P(PCl5)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 2 } ( \mathrm { Cl } ) } { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) }
D)KP = P(PCl3)×P(Cl2)P(PCl5)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) }
E)KP = P1/2(PCl5)P1/2(PCl3)×P1/2(Cl2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 5 } \right) } { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
Question
Express the equilibrium constant for the following reaction:
CH3Cl(g)+ 1/2 Cl2(g)? CH2Cl2(g)+ 1/2 H2(g)

A)KP = P(CH2Cl2)×P1/2(H2)P(CH3Cl)×P1/2(Cl2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(CH2Cl2)×P(H2)P2(CH3Cl)×P(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P2(CH3Cl)×P(Cl2)P2(CH2Cl2)×P(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(CH3Cl)×P(Cl2)P(CH2Cl2)×P(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
E)KP = P(CH3Cl)×P1/2(Cl2)P(CH2Cl2)×P1/2(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) }
Question
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ 2B(g)⇌ AB2(g)Kc = 59
AB2(g)+ B(g)⇌ AB3(g)Kc = ?
A(g)+ 3B(g)⇌ AB3(g)Kc = 478

A)3.5 × 10-5
B)2.8 × 104
C)8.1
D)0.12
E)89
Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2HBr(g)K = 3.8 × 104
4HBr(g)⇌ 2H2(g)+ 2Br2(g)K = ?

A)1.9 × 104
B)5.1 × 10-3
C)2.6 × 10-5
D)6.9 × 10-10
E)1.6 × 103
Question
Express the equilibrium constant for the following reaction:
N2(g)+ 3H2(g)? 2NH3(g)

A)KP = P(N2)×P1/3(H2)P1/2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P }^{ 1 / 3 }\left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^{1 / 2 }\left( \mathrm { NH } _ { 3 } \right) }
B)KP = P6(NH3)P3( N2)×P9(H2)\frac { \mathrm { P } ^ { 6 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } ^ { 3 } \left( \mathrm {~N} _ { 2 } \right) \times \mathrm { P } ^ { 9 } \left( \mathrm { H } _ { 2 } \right) }
C)KP = P2(NH3)P(N2)×P3(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) }
D)KP= P(N2)×P3(H2)P2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) }
E)KP = P1/2(NH3)P(N2)×P1/3(H2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { H } _ { 2 } \right) }
Question
For the following reaction,what is Δn required in the conversion of Kc to Kp? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)4
B)-4
C)-2
D)2
E)1
Question
Give the direction of the reaction if K << 1.

A)The forward reaction is favoured.
B)The reverse reaction is favoured.
C)Neither direction is favoured.
D)If the temperature is raised,then the forward reaction is favoured.
E)If the temperature is raised,then the reverse reaction is favoured.
Question
Express the equilibrium constant for the following reaction:
H2(g)+ Br2(g)? 2HBr(g)

A)KP = P(HBr)(P1/2(H2)×P1/2(Br2)\frac {P(HBr) } { (\mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Br } _ { 2 } \right) }


B)KP = P(H2)×P(Br2)P2(HBr)\frac { \mathrm { P } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { HBr } ) }
C)KP = P2(H2)×P2(Br2)P4(HBr)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^ { 2 } \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ^ { 4 } ( \mathrm { HBr } ) }
D)KP= P1/2(H2)×P1/2(Br2)P(HBr)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ( \mathrm { HBr } ) }
E)KP = P2(HBr)P(H2)×P(Br2)\frac { \mathrm { P } ^ { 2 } ( \mathrm { HBr } ) } { \mathrm { P } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { Br } _ { 2 } \right) }
Question
Express the equilibrium constant for the following reaction:
2P(g)+ 3Cl2(g)? 2PCl3(g)

A)KP = P2(PCl3)P2(P)×P3(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P1/2(PCl3)P1/2(P)×P1/3(Cl2)\frac { \mathrm { P } ^{1 / 2} \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^{1 / 2} ( \mathrm { P } ) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P(PCl3)P(P)×P3/2(Cl2)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
D)KP = P2(P)×P3(Cl2)P2(PCl3)\frac { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) }
E)KP = P(P)×P3/2(Cl2)P(PCl3)\frac { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) }
Question
Which of the following statements is correct?

A)When K >> 1,the reverse reaction is favoured and essentially goes to completion.
B)When K << 1,the forward reaction is favoured and the reverse reaction does not proceed to a great extent.
C)When K ≈ 1,neither the forward nor reverse reaction is strongly favoured,and about the same amount of reactants and products exist at equilibrium.
D)K >> 1 implies that the reaction is very fast at producing products.
E)When K = 0 the reaction is in equilibrium.
Question
Express the equilibrium constant for the following reaction:
2NH3(g)? N2(g)+ 3H2(g)

A)KP = P(N2)×P1/3(H2)P1/2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^{1 / 3} \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^{1 / 2} \left( \mathrm { NH } _ { 3 } \right) }
B)KP = P6(NH3)[N2]3[H2]9\frac { \mathrm { P } ^ { 6 } \left( \mathrm { NH } _ { 3 } \right) } { \left[ \mathrm { N } _ { 2 } \right] ^ { 3 } \left[ \mathrm { H } _ { 2 } \right] ^ { 9 } }
C)KP = P2(NH3)P(N2)×P3(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(N2)×P3(H2)P2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) }
E)KP = P1/2(NH3)P(N2)×P1/3(H2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { H } _ { 2 } \right) }
Question
Express the equilibrium constant for the following reaction:
P(g)+ 3/2 Cl2(g)? PCl3(g)

A) KP=P2(PCl3)P2(P)×P3(Cl2)K P = \frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) }
B) KP=P1/2(PCl3)P1/2(P)×P1/3(Cl2)K P = \frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 1 / 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { Cl } _ { 2 } \right) }
C) KP=P(PCl3)P(P)×P3/2(Cl2)K P = \frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
D) KP=P2(P)×P3(Cl2)P2(PCl3)K P = \frac { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) }
E) Kp=P(P)×P3/2(Cl2)P(PCl3)K p = \frac { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2} \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) }
Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. N2O4(g)⇌ 2NO2(g)K = 1.46
2N2O4(g)⇌ 4NO2(g)K = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2HBr(g)K = 3.8 × 104
2HBr(g)⇌ H2(g)+ Br2(g)K = ?

A)1.9 × 104
B)5.3 × 10-5
C)2.6 × 10-5
D)6.4 × 10-4
E)1.6 × 103
Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. 2SO2(g)+ O2(g)⇌ 2SO3(g)K = 1.7 × 106
SO3(g)⇌ 1/2 O2(g)+ SO2(g)K = ?

A)3.4 × 102
B)8.5
C)1.3 × 103
D)1.2 × 10-6
E)7.7 × 10-4
Question
Express the equilibrium constant for the following reaction:
2 CH3Cl(g)+ Cl2(g)? 2 CH2Cl2(g)+ H2(g)

A)Kp = P(CH2Cl2)×P(H2)P(CH3Cl)×P(Cl2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(CH2Cl2)×P(H2)P2(CH3Cl)×P(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P2(CH3Cl)×P(Cl2)P2(CH2Cl2)×P(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(CH3Cl)×P(Cl2)P(CH2Cl2)×P(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
E)KP = P1/2(CH3Cl)×P(Cl2)P1/2(CH2Cl2)×P(H2)\frac { \mathrm { P } 1 / 2 \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
Question
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. N2O4(g)⇌ 2NO2(g)K = 1.46
3N2O4(g)⇌ 6NO2(g)K = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
Question
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ B(g)⇌ AB(g)K = 0.24
AB(g)+ A(g)⇌ A2B(g)K = 3.8
2A(g)+ B(g)⇌ A2B(g)K = ?

A)4.0
B)0.91
C)3.6
D)16
E)0.63
Question
The reaction below has a Kp value of 3.3 × 10-5 bar.What is the value of Kc for this reaction at 700 K? 2SO3(g)⇌ 2SO2(g)+ O2(g)

A)5.7 × 10-7 M
B)1.7 × 106 M
C)3.3 × 10-5 M
D)3.0 × 104 M
E)1.9 × 10-3 M
Question
For the following reaction,what is △n required in the conversion of Kc to Kp? P4(s)+ 5O2(g)⇌ P4O10(s)

A)3
B)4
C)-4
D)5
E)-5
Question
Express the equilibrium constant for the following reaction:
\quad\quad\quad SO2(g) + H2O(l)? H2SO3(aq)

A)K = [H2SO3]×[H2O]P(SO2)\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) }
B)K = [H2SO3]P(SO2)\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) }
C)K = P[SO2)H2SO3]\frac { \mathrm { P } _ { \left[ \mathrm { SO } _ { 2 } \right) } } { \left. \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] }
D)K = [H2SO3]P(SO2)×[H2O]\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] }
E)K = P(SO2)×[H2O][H2SO3]\frac { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] }
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 mol L-1,[O2]eq = 4.1 mol L-1,[N2O]eq = 3.3 × 10-18 mol L-1. 2N2(g)+ O2(g)⇌ 2N2O(g)

A)2.2 × 10-19
B)4.5 × 1018
C)2.0 × 10-37
D)5.0 × 1036
E)4.9 × 10-17
Question
For the following reaction,what is △n required in the conversion of Kc to Kp? 2Na(s)+ 2H2O(l)⇌ 2NaOH(aq)+ H2(g)

A)3
B)-1
C)-2
D)2
E)1
Question
For which reaction will Kp = Kc?

A)S(s)+ O2(g)⇌ SO2(g)
B)2HgO(s)⇌ Hg(l)+ O2(g)
C)CaCO3(s)⇌ CaO(s)+ CO2(g)
D)H2CO3(s)⇌ H2O(l)+ CO2(g)
E)2H2O(l)⇌ 2H2(g)+ O2(g)
Question
The reaction below has a Kp value of 41 bar-2.What is the value of Kc for this reaction at 400 K? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)2.4 × 10-2 M-2
B)4.4 × 104 M-2
C)41 M-2
D)2.3 × 10-5 M-2
E)1.9 × 104 M-2
Question
For the following reaction,what is Δn required in the conversion of Kc to Kp? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)3
B)-1
C)-2
D)2
E)1
Question
Express the equilibrium constant for the following reaction:
\quad\quad P4(s)+ 5O2(g)? P4O10(s)

A)Kc = [P4][O2]5[P4O10]\frac { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 5 } } { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] }
B)Kc = [P4O10][P4][O2]5\frac { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] } { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 5 } }
C)Kc = [O2]-5
D)Kc = [O2]5
E)Kc = [P4O10][P4][O2]1/5\frac { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] } { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 1 / 5 } }
Question
Express the equilibrium constant for the following reaction:
KClO3(s)? KClO(s)+ O2(g)

A)Kc = [KClO][O2][KClO3]\frac { [ \mathrm { KClO } ] \left[ \mathrm { O } _ { 2 } \right] } { \left[ \mathrm { KClO } _ { 3 } \right] }
B)Kc = [O2]-1
C)Kc = [KClO]2[O2]2[KClO3]2\frac { [ \mathrm { KClO } ] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 2 } } { \left[ \mathrm { KClO } _ { 3 } \right] ^ { 2 } }
D)Kc = [KClO3]\left[ \mathrm { KClO } _ { 3 } \right]
[KClO][O2][ \mathrm { KClO } ] \left[ \mathrm { O } _ { 2 } \right]

[KClO3][KClO][O2]\frac {[{ KClO } _ { 3 }] } { \mathrm [{ KClO } ] \left[ \mathrm { O } _ { 2 } \right] }








E)Kc = [O2]
Question
Express the equilibrium constant for the following reaction:
\quad\quad 2Na(s)+ 2H2O(l)? 2NaOH(aq)+ H2(g)

A)
Kc = [NaOH]2[H2][Na]2[H2O]2\frac { [ \mathrm { NaOH } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \right] } { [ \mathrm { Na } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 2 } }
B)
Kc = [H2][NaOH]-2
C)
Kc = [Na]2[H2O]2[NaOH]2[H2]\frac { [ \mathrm { Na } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 2 } } { [ \mathrm { NaOH } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \right] }
D)Kc = [H2][NaOH]2
E)
Kc = [NaOH]1/2[H2][Na]1/2[H2O]1/2\frac { [ \mathrm { NaOH } ] ^ { 1 / 2 } \left[ \mathrm { H } _ { 2 } \right] } { [ \mathrm { Na } ] ^ { 1 / 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 1 / 2 } }
Question
Express the equilibrium constant for the following reaction:
\quad\quad B(OH)3(aq) + 2H2O(l)? B(OH)3(OH)-(aq)+ H3O+(aq)

A)Kc = [H3O+]×[B(OH)3(OH)][B(OH)3]×[H2O]\frac { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] }
B)Kc = [B(OH)3]\left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right]
[H3O+]×[B(OH)3(OH)]\left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right]

B(OH)3[H3O+]×[B(OH)3(OH)]\frac {B( { OH } ) _ { 3 } } { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right]}



C)Kc = [B(OH)3]×[H2O][H3O+]×[B(OH)3(OH)]\frac { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] }
D)Kc = [H3O+]×[B(OH)3(OH)][B(OH)3]\frac { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] }
E)Kc = [B(OH)3]×[H3O+][B(OH)3(OH)]\frac { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] }
Question
For the following reaction,what is △n required in the conversion of Kc to Kp? KClO3(s)⇌ KClO(s)+ O2(g)

A)3
B)-1
C)-2
D)2
E)1
Question
The reaction below has a Kc value of 61 M-2.What is the value of Kp for this reaction at 500 K? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)15 bar-2
B)61 bar-2
C)28 bar-2
D)3.6 × 10-2 bar-2
E)1.9 × 10-2 bar-2
Question
Express the equilibrium constant for the following reaction:
Fe(H2O)63+3+(aq)+6CN(aq)=Fe(CN)633(aq)+6H2O(l)\mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \underset { ( a q ) } { 3 + } + 6 \mathrm { CN } - ( a q ) = \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \underset { ( a q ) } { 3 - } + 6 \mathrm { H } _ { 2 } \mathrm { O } ( l )

A)Kc = [Fe(CN)63][CN]6×[Fe(H2O)63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] }
B)Kc = [Fe(CN)63]×[H2O]6[CN]6×[Fe(H2O)63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] }
C)Kc = [CN]6×[Fe(H2O)63+][Fe(CN)63]\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] }
D)Kc = [CN]6×[Fe(H2O)63+][Fe(CN)63]×[H2O]6\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } }
E)Kc = [Fe(CN)63]3[CN]6×[Fe(H2O)63+]3\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] ^ { 3 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] ^ { 3 } }
Question
For the following reaction,what is Δn required in the conversion of Kc to Kp? CH4(g)+ H2O(g)⇌ CO(g)+ 3H2(g)

A)3
B)-1
C)-2
D)2
E)1
Question
For the following reaction,what is Δn required in the conversion of Kc to Kp? N2O4(g)⇌ 2NO2(g)

A)3
B)-1
C)-2
D)2
E)1
Question
The reaction below has a Kc value of 1.0 × 1012 M-1.What is the value of Kp for this reaction at 500 K? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)4.2 × 10-11 bar-1
B)1.0 × 1012 bar-1
C)2.4 × 10-12 bar-1
D)4.1 × 1013 bar-1
E)2.4 × 1010 bar-1
Question
For which of the following reactions will Kc = Kp?

A)H2(g)+ I2(g)⇌ 2HI(g)
B)CH4(g)+ H2O(g)⇌ CO(g)+ 3H2(g)
C)N2O4(g)⇌ 2NO2(g)
D)CO(g)+ 2H2(g)⇌ CH3OH(g)
E)N2(g)+ 3H2(g)⇌ 2NH3(g)
Question
For which of the following reactions will Kc = Kp?

A)4NH3(g)+ 3O2(g)⇌ 2N2(g)+ 6H2O(g)
B)SO3(g)+ NO(g)⇌ SO2(g)+ NO2(g)
C)2N2(g)+ O2(g)⇌ 2N2O(g)
D)2SO2(g)+ O2(g)⇌ 2SO3(g)
E)PCl3(g) + 1/2 O2(g) ⇌ PCl3O(g)
Question
In a reaction mixture containing reactants and products,each at a concentration of 1 mol L-1,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
Question
Which of the following statements is TRUE?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the forward reaction will proceed to form more products.
C)If Q = K,it means the reaction is at equilibrium.
D)If Q << K,it means the reaction is shifted to the left.
E)If Q >> K,it means the reaction is shifted to the right.
Question
In a reaction mixture containing only products,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 mol L-1,[PCl3]eq = 0.23 mol L-1,[Cl2]eq = 4.4 mol L-1. PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)1.8 M
B)0.93 M
C)0.55 M
D)1.1 M
E)0.76 M
Question
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl)eq = 0.22 atm,P(NO)eq = 0.10 atm,P(Cl2)eq = 0.081 atm. 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

A)3.7 × 10-2 atm
B)60 atm
C)27 atm
D)1.7 × 10-2 atm
E)1.8 × 10-3 atm
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO3(g). 2SO2(g)+ O2(g)⇌ 2SO3(g)Kc = 1.7 × 108 M-1
[SO2]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

A)1.9 mol L-1
B)1.0 × 103 mol L-1
C)0.53 mol L-1
D)9.6 × 10-4 mol L-1
E)0.73 mol L-1
Question
Calculate the value of [N2]eq if [H2]eq = 2.0 mol L-1,[NH3]eq = 0.50 mol L-1,and Kc = 2.0. N2(g)+ 3H2(g)⇌ 2NH3(g)

A)0.016 mol L-1
B)0.031 mol L-1
C)0.062 mol L-1
D)0.40 mol L-1
E)62.5 mol L-1
Question
In a reaction mixture containing only reactants,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g). C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103 M-1
[C2H4]eq = 0.015 mol L-1 [C2H5OH]eq = 1.69 mol L-1

A)9.9 × 10-7 mol L-1
B)80.mol L-1
C)1.0 mol L-1
D)1.68 mol L-1
E)0.013 mol L-1
Question
Calculate P (NO)eq,if P(NOCl)eq = 0.33 bar,P(Cl2)eq = 0.50 bar,and Kp = 1.9 × 10-2 bar . 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

A)1.7 bar
B)0.0042 bar
C)0.30 bar
D)0.064 bar
E)0.087 bar
Question
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm. 2 CO(g)+ O2(g)⇌ 2 CO2(g)

A)3.6 × 10-21 atm-1
B)2.8 × 1020 atm-1
C)4.6 × 1011 atm-1
D)2.2 × 10-12 atm-1
E)3.6 × 10-15 atm-1
Question
Consider the following reaction and its equilibrium constant: I2(g)+ Br2(g)⇌ 2IBr(g)Kc = 1.1 × 102
A reaction mixture contains 0.41 mol L-1 I2,0.27 mol L-1 Br2 and 3.5 mol L-1 IBr.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of products.
B)The reaction will shift in the direction of reactants.
C)The reaction quotient will decrease.
D)The equilibrium constant will increase.
E)The system is at equilibrium.
Question
Which of the following statements is TRUE?

A)Dynamic equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction.
B)The equilibrium constant for the forward reaction is equal to the equilibrium constant for the reverse reaction.
C)A reaction quotient (Q)larger than the equilibrium constant (K)means that the reaction will favour the production of more products.
D)Dynamic equilibrium indicates that the amount of reactants and products are equal.
E)Dynamic equilibrium is established when K = 0.
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 mol L-1,[H2]eq = 1.1 mol L-1,[NH3]eq = 0.47 mol L-1. N2(g)+ 3H2(g)⇌ 2NH3(g)

A)3.5 M-2
B)0.28 M-2
C)9.1 M-2
D)0.11 M-2
E)0.78 M-2
Question
Consider the following reaction and its equilibrium constant: 4CuO(s)+ CH4(g)⇌ CO2(g)+ 4Cu(s)+ 2H2O(g)Kc = 1.10
A reaction mixture contains 0.22 mol L-1 CH4,0.67 mol L-1 CO2 and 1.3 mol L-1 H2O.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of products.
B)The equilibrium constant will increase.
C)The reaction quotient will increase.
D)The reaction will shift in the direction of reactants.
E)The system is at equilibrium.
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 mol L-1,[I2]eq = 0.39 mol L-1,[HI]eq = 1.6 mol L-1. H2(g)+ I2(g)⇌ 2HI(g)

A)2.1 × 10-2
B)29
C)47
D)3.4 × 10-2
E)8.7 × 10-2
Question
Which of the following statements is TRUE?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the reverse reaction will proceed to form more reactants.
C)If Q = K,it means the reaction is not at equilibrium.
D)Because the equilibrium is always dynamic,Q can never be equal to K.
E)If Q < K,the reaction proceeding to the left is much faster than the reaction proceeding to the right.
Question
Consider the following reaction and its equilibrium constant: SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)Kc = 0.33
A reaction mixture contains 0.39 mol L-1 SO2,0.14 mol L-1 NO2 ,0.11 mol L-1 SO3 and 0.14 mol L-1 NO.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of reactants.
B)The equilibrium constant will decrease.
C)The reaction will shift in the direction of products.
D)The reaction quotient will decrease.
E)The system is at equilibrium.
Question
Consider the following reaction and its equilibrium constant: I2(g)⇌ 2I(g)Kp = 0.209 atm
A reaction mixture contains 0.89 atm I2 and 1.77 atm I.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of reactants.
B)The reaction quotient will increase.
C)The reaction will shift in the direction of products.
D)The equilibrium constant will decrease.
E)The system is at equilibrium.
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 mol L-1,[HI]eq = 5.6 × 10-16 mol L-1,[Cl2]eq = 0.0019 mol L-1. 2HCl(g)+ I2(s)⇌ 2HI(g)+ Cl2(g)

A)8.2 × 10-18 M
B)2.9 × 1031 M
C)1.2 × 1017 M
D)1.4 × 10-19 M
E)3.5 × 10-32 M
Question
Consider the following reaction: CO2(g)+ C(graphite)⇌ 2CO(g)
A reaction mixture initially contains 0.56 bar CO2 and 0.32 bar CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25 bar.

A)0.83 bar
B)0.31 bar
C)0.26 bar
D)0.58 bar
E)0.42 bar
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 0.039 mol L-1

A)1.22 mol L-1
B)9.0 × 10-2 mol L-1
C)7.8 × 10-2 mol L-1
D)8.2 × 10-3 mol L-1
E)11 mol L-1
Question
Consider the following reaction: Xe(g)+ 2F2(g)⇌ XeF4(g)
A reaction mixture initially contains 2.24 bar Xe and 4.27 bar F2.If the equilibrium pressure of Xe is 0.34 bar,find the equilibrium constant (Kp)for the reaction.

A)25 bar-2
B)0.12 bar-2
C)0.99 bar-2
D)8.3 bar-2
E)0.040 bar-2
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 1.82 mol L-1

A)0.38 mol L-1
B)0.71 mol L-1
C)0.62 mol L-1
D)0.40 mol L-1
E)0.095 mol L-1
Question
The following reaction is exothermic.Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)raising the temperature
B)removing SO3
C)adding O2
D)increasing the pressure
E)adding SO2
Question
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.86 bar NO and 0.86 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.78 bar
B)0.084 bar
C)0.012 bar
D)0.85 bar
E)0.048 bar
Question
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 2.0 bar NO and 1.0 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.46 bar
B)0.037 bar
C)0.19 bar
D)0.14 bar
E)0.68 bar
Question
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 2.0 bar NO2 and 1.0 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

A)0.011 bar
B)0.037 bar
C)0.10 bar
D)0.0038 bar
E)0.067 bar
Question
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 1.24 bar NO and 0.92 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.32 bar
B)1.32 bar
C)0.10 bar
D)0.74 bar
E)0.022 bar
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g). NH2COONH4(s)⇌ 2NH3(g)+ CO2(g)Kc = 1.58 × 10-8 M3
[NH3]eq = 2.9 × 10-3 mol L-1

A)0.053 mol L-1
B)4.6 × 10-11 mol L-1
C)1.9 × 10-3 mol L-1
D)5.4 × 10-6 mol L-1
E)0.022 mol L-1
Question
Consider the following reaction: CH4(g)+ 2H2S(g)⇌ CS2(g)+ 4H2(g)
A reaction mixture initially contains 0.50 mol L-1 CH4 and 0.75 mol L-1 H2S.If the equilibrium concentration of H2 is 0.44 mol L-1,find the equilibrium constant (mol L-1)for the reaction.

A)0.23 mol2 L-2
B)0.038 mol2 L-2
C)2.9 mol2 L-2
D)10.mol2 L-2
E)0.34 mol2 L-2
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 0.068 mol L-1

A)1.9 mol L-1
B)0.12 mol L-1
C)0.60 mol L-1
D)0.028 mol L-1
E)0.036 mol L-1
Question
Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)
A reaction mixture initially contains 2.9 mol L-1 O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

A)1.9 mol L-1
B)1.7 mol L-1
C)2.2 mol L-1
D)1.2 mol L-1
E)0.59 mol L-1
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 1.34 mol L-1

A)0.25 mol L-1
B)0.043 mol L-1
C)0.60 mol L-1
D)0.028 mol L-1
E)0.53 mol L-1
Question
Consider the following reaction: COCl2(g)⇌ CO(g)+ Cl2(g)
A reaction mixture initially contains 1.6 mol L-1 COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4 M.Calculate this based on the assumption that the answer is negligible compared to 1.6.

A)4.2 × 10-4 mol L-1
B)1.5 × 10-3 mol L-1
C)3.7 × 10-2 mol L-1
D)2.1 × 10-2 mol L-1
E)1.3 × 10-3 mol L-1
Question
Consider the following reaction,equilibrium pressures,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO. CO(g)+ 2H2(g)⇌ CH3OH(l)Kp = 2.25 × 104 bar-3
P(H2)eq = 0.52 bar

A)8.3 × 104 bar
B)1.2 × 10-5 bar
C)6.25 × 10-3 bar
D)8.5 × 10-5 bar
E)1.6 × 10-4 bar
Question
Consider the following reaction: 2H2O(g)+ 2SO2(g)⇌ 2H2S(g)+ 3O2(g)
A reaction mixture initially contains 2.8 mol L-1 H2O and 2.6 mol L-1 SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6 mol L-1.

A)0.045 mol L-1
B)0.058 mol L-1
C)0.028 mol L-1
D)3.1 × 10-3 mol L-1
E)0.12 mol L-1
Question
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.384 bar NO2 and 0.224 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

A)0.220 bar
B)0.037 bar
C)0.67 bar
D)0.024 bar
E)0.0035 bar
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO2(g). 2SO2(g)+ O2(g)⇌ 2SO3(g)Kc = 1.7 × 108 M-1
[SO3]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

A)2.8 × 1013 mol L-1
B)1.88 mol L-1
C)6.1 × 10-6 mol L-1
D)1.0 × 103 mol L-1
E)1.4 mol L-1
Question
Consider the following reaction,equilibrium pressures,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2. D2(g)+ H2(g)⇌ 2HD(g)Kp = 1.80
P(D2)eq = 1.1 × 10-3 bar P(HD)eq = 2.7 × 10-3 bar

A)2.7 bar
B)1.4 bar
C)0.73 bar
D)3.7 × 10-3 bar
E)8.1 × 10-4 bar
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Deck 14: Chemical Equilibrium
1
Give the direction of the reaction if K >> 1.

A)The forward reaction is favoured.
B)The reverse reaction is favoured.
C)Neither direction is favoured.
D)If the temperature is raised,then the forward reaction is favoured.
E)If the temperature is raised,then the reverse reaction is favoured.
The forward reaction is favoured.
2
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. 2HD(g)⇌ H2(g)+ D2(g)K = 0.28
2H2(g)+ 2D2(g)⇌ 4HD(g)K = ?

A)7.8 × 10-2
B)3.6
C)0.53
D)13
E)1.9
13
3
Express the equilibrium constant for the following reaction:
PCl5(g)? PCl3(g)+ Cl2(g)

A)KP = P(PCl5)P(PCl3)×P(Cl2)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(PCl3)×P2(Cl2)P2(PCl5)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 2 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 5 } \right) }
C)KP = P(PCl3)×P2(Cl)P(PCl5)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 2 } ( \mathrm { Cl } ) } { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) }
D)KP = P(PCl3)×P(Cl2)P(PCl5)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) }
E)KP = P1/2(PCl5)P1/2(PCl3)×P1/2(Cl2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 5 } \right) } { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
KP = P(PCl3)×P(Cl2)P(PCl5)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 5 } \right) }
4
Express the equilibrium constant for the following reaction:
CH3Cl(g)+ 1/2 Cl2(g)? CH2Cl2(g)+ 1/2 H2(g)

A)KP = P(CH2Cl2)×P1/2(H2)P(CH3Cl)×P1/2(Cl2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(CH2Cl2)×P(H2)P2(CH3Cl)×P(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P2(CH3Cl)×P(Cl2)P2(CH2Cl2)×P(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(CH3Cl)×P(Cl2)P(CH2Cl2)×P(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
E)KP = P(CH3Cl)×P1/2(Cl2)P(CH2Cl2)×P1/2(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) }
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5
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ 2B(g)⇌ AB2(g)Kc = 59
AB2(g)+ B(g)⇌ AB3(g)Kc = ?
A(g)+ 3B(g)⇌ AB3(g)Kc = 478

A)3.5 × 10-5
B)2.8 × 104
C)8.1
D)0.12
E)89
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6
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2HBr(g)K = 3.8 × 104
4HBr(g)⇌ 2H2(g)+ 2Br2(g)K = ?

A)1.9 × 104
B)5.1 × 10-3
C)2.6 × 10-5
D)6.9 × 10-10
E)1.6 × 103
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7
Express the equilibrium constant for the following reaction:
N2(g)+ 3H2(g)? 2NH3(g)

A)KP = P(N2)×P1/3(H2)P1/2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P }^{ 1 / 3 }\left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^{1 / 2 }\left( \mathrm { NH } _ { 3 } \right) }
B)KP = P6(NH3)P3( N2)×P9(H2)\frac { \mathrm { P } ^ { 6 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } ^ { 3 } \left( \mathrm {~N} _ { 2 } \right) \times \mathrm { P } ^ { 9 } \left( \mathrm { H } _ { 2 } \right) }
C)KP = P2(NH3)P(N2)×P3(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) }
D)KP= P(N2)×P3(H2)P2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) }
E)KP = P1/2(NH3)P(N2)×P1/3(H2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { H } _ { 2 } \right) }
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8
For the following reaction,what is Δn required in the conversion of Kc to Kp? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)4
B)-4
C)-2
D)2
E)1
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9
Give the direction of the reaction if K << 1.

A)The forward reaction is favoured.
B)The reverse reaction is favoured.
C)Neither direction is favoured.
D)If the temperature is raised,then the forward reaction is favoured.
E)If the temperature is raised,then the reverse reaction is favoured.
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10
Express the equilibrium constant for the following reaction:
H2(g)+ Br2(g)? 2HBr(g)

A)KP = P(HBr)(P1/2(H2)×P1/2(Br2)\frac {P(HBr) } { (\mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 2 } \left( \mathrm { Br } _ { 2 } \right) }


B)KP = P(H2)×P(Br2)P2(HBr)\frac { \mathrm { P } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { HBr } ) }
C)KP = P2(H2)×P2(Br2)P4(HBr)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^ { 2 } \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ^ { 4 } ( \mathrm { HBr } ) }
D)KP= P1/2(H2)×P1/2(Br2)P(HBr)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } ^{1 / 2} \left( \mathrm { Br } _ { 2 } \right) } { \mathrm { P } ( \mathrm { HBr } ) }
E)KP = P2(HBr)P(H2)×P(Br2)\frac { \mathrm { P } ^ { 2 } ( \mathrm { HBr } ) } { \mathrm { P } \left( \mathrm { H } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { Br } _ { 2 } \right) }
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11
Express the equilibrium constant for the following reaction:
2P(g)+ 3Cl2(g)? 2PCl3(g)

A)KP = P2(PCl3)P2(P)×P3(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P1/2(PCl3)P1/2(P)×P1/3(Cl2)\frac { \mathrm { P } ^{1 / 2} \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^{1 / 2} ( \mathrm { P } ) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P(PCl3)P(P)×P3/2(Cl2)\frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
D)KP = P2(P)×P3(Cl2)P2(PCl3)\frac { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) }
E)KP = P(P)×P3/2(Cl2)P(PCl3)\frac { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) }
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12
Which of the following statements is correct?

A)When K >> 1,the reverse reaction is favoured and essentially goes to completion.
B)When K << 1,the forward reaction is favoured and the reverse reaction does not proceed to a great extent.
C)When K ≈ 1,neither the forward nor reverse reaction is strongly favoured,and about the same amount of reactants and products exist at equilibrium.
D)K >> 1 implies that the reaction is very fast at producing products.
E)When K = 0 the reaction is in equilibrium.
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13
Express the equilibrium constant for the following reaction:
2NH3(g)? N2(g)+ 3H2(g)

A)KP = P(N2)×P1/3(H2)P1/2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^{1 / 3} \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^{1 / 2} \left( \mathrm { NH } _ { 3 } \right) }
B)KP = P6(NH3)[N2]3[H2]9\frac { \mathrm { P } ^ { 6 } \left( \mathrm { NH } _ { 3 } \right) } { \left[ \mathrm { N } _ { 2 } \right] ^ { 3 } \left[ \mathrm { H } _ { 2 } \right] ^ { 9 } }
C)KP = P2(NH3)P(N2)×P3(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(N2)×P3(H2)P2(NH3)\frac { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 3 } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { NH } _ { 3 } \right) }
E)KP = P1/2(NH3)P(N2)×P1/3(H2)\frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { NH } _ { 3 } \right) } { \mathrm { P } \left( \mathrm { N } _ { 2 } \right) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { H } _ { 2 } \right) }
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14
Express the equilibrium constant for the following reaction:
P(g)+ 3/2 Cl2(g)? PCl3(g)

A) KP=P2(PCl3)P2(P)×P3(Cl2)K P = \frac { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) }
B) KP=P1/2(PCl3)P1/2(P)×P1/3(Cl2)K P = \frac { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ^ { 1 / 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 1 / 3 } \left( \mathrm { Cl } _ { 2 } \right) }
C) KP=P(PCl3)P(P)×P3/2(Cl2)K P = \frac { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) } { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2 } \left( \mathrm { Cl } _ { 2 } \right) }
D) KP=P2(P)×P3(Cl2)P2(PCl3)K P = \frac { \mathrm { P } ^ { 2 } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { PCl } _ { 3 } \right) }
E) Kp=P(P)×P3/2(Cl2)P(PCl3)K p = \frac { \mathrm { P } ( \mathrm { P } ) \times \mathrm { P } ^ { 3 / 2} \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { PCl } _ { 3 } \right) }
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15
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. N2O4(g)⇌ 2NO2(g)K = 1.46
2N2O4(g)⇌ 4NO2(g)K = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
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16
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2HBr(g)K = 3.8 × 104
2HBr(g)⇌ H2(g)+ Br2(g)K = ?

A)1.9 × 104
B)5.3 × 10-5
C)2.6 × 10-5
D)6.4 × 10-4
E)1.6 × 103
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17
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. 2SO2(g)+ O2(g)⇌ 2SO3(g)K = 1.7 × 106
SO3(g)⇌ 1/2 O2(g)+ SO2(g)K = ?

A)3.4 × 102
B)8.5
C)1.3 × 103
D)1.2 × 10-6
E)7.7 × 10-4
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18
Express the equilibrium constant for the following reaction:
2 CH3Cl(g)+ Cl2(g)? 2 CH2Cl2(g)+ H2(g)

A)Kp = P(CH2Cl2)×P(H2)P(CH3Cl)×P(Cl2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
B)KP = P2(CH2Cl2)×P(H2)P2(CH3Cl)×P(Cl2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) }
C)KP = P2(CH3Cl)×P(Cl2)P2(CH2Cl2)×P(H2)\frac { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
D)KP = P(CH3Cl)×P(Cl2)P(CH2Cl2)×P(H2)\frac { \mathrm { P } \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
E)KP = P1/2(CH3Cl)×P(Cl2)P1/2(CH2Cl2)×P(H2)\frac { \mathrm { P } 1 / 2 \left( \mathrm { CH } _ { 3 } \mathrm { Cl } \right) \times \mathrm { P } \left( \mathrm { Cl } _ { 2 } \right) } { \mathrm { P } ^ { 1 / 2 } \left( \mathrm { CH } _ { 2 } \mathrm { Cl } _ { 2 } \right) \times \mathrm { P } \left( \mathrm { H } _ { 2 } \right) }
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19
The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. N2O4(g)⇌ 2NO2(g)K = 1.46
3N2O4(g)⇌ 6NO2(g)K = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
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20
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ B(g)⇌ AB(g)K = 0.24
AB(g)+ A(g)⇌ A2B(g)K = 3.8
2A(g)+ B(g)⇌ A2B(g)K = ?

A)4.0
B)0.91
C)3.6
D)16
E)0.63
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21
The reaction below has a Kp value of 3.3 × 10-5 bar.What is the value of Kc for this reaction at 700 K? 2SO3(g)⇌ 2SO2(g)+ O2(g)

A)5.7 × 10-7 M
B)1.7 × 106 M
C)3.3 × 10-5 M
D)3.0 × 104 M
E)1.9 × 10-3 M
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22
For the following reaction,what is △n required in the conversion of Kc to Kp? P4(s)+ 5O2(g)⇌ P4O10(s)

A)3
B)4
C)-4
D)5
E)-5
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23
Express the equilibrium constant for the following reaction:
\quad\quad\quad SO2(g) + H2O(l)? H2SO3(aq)

A)K = [H2SO3]×[H2O]P(SO2)\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) }
B)K = [H2SO3]P(SO2)\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) }
C)K = P[SO2)H2SO3]\frac { \mathrm { P } _ { \left[ \mathrm { SO } _ { 2 } \right) } } { \left. \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] }
D)K = [H2SO3]P(SO2)×[H2O]\frac { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] } { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] }
E)K = P(SO2)×[H2O][H2SO3]\frac { \mathrm { P } \left( \mathrm { SO } _ { 2 } \right) \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \left[ \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } \right] }
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24
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 mol L-1,[O2]eq = 4.1 mol L-1,[N2O]eq = 3.3 × 10-18 mol L-1. 2N2(g)+ O2(g)⇌ 2N2O(g)

A)2.2 × 10-19
B)4.5 × 1018
C)2.0 × 10-37
D)5.0 × 1036
E)4.9 × 10-17
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25
For the following reaction,what is △n required in the conversion of Kc to Kp? 2Na(s)+ 2H2O(l)⇌ 2NaOH(aq)+ H2(g)

A)3
B)-1
C)-2
D)2
E)1
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26
For which reaction will Kp = Kc?

A)S(s)+ O2(g)⇌ SO2(g)
B)2HgO(s)⇌ Hg(l)+ O2(g)
C)CaCO3(s)⇌ CaO(s)+ CO2(g)
D)H2CO3(s)⇌ H2O(l)+ CO2(g)
E)2H2O(l)⇌ 2H2(g)+ O2(g)
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27
The reaction below has a Kp value of 41 bar-2.What is the value of Kc for this reaction at 400 K? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)2.4 × 10-2 M-2
B)4.4 × 104 M-2
C)41 M-2
D)2.3 × 10-5 M-2
E)1.9 × 104 M-2
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28
For the following reaction,what is Δn required in the conversion of Kc to Kp? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)3
B)-1
C)-2
D)2
E)1
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29
Express the equilibrium constant for the following reaction:
\quad\quad P4(s)+ 5O2(g)? P4O10(s)

A)Kc = [P4][O2]5[P4O10]\frac { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 5 } } { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] }
B)Kc = [P4O10][P4][O2]5\frac { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] } { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 5 } }
C)Kc = [O2]-5
D)Kc = [O2]5
E)Kc = [P4O10][P4][O2]1/5\frac { \left[ \mathrm { P } _ { 4 } \mathrm { O } _ { 10 } \right] } { \left[ \mathrm { P } _ { 4 } \right] \left[ \mathrm { O } _ { 2 } \right] ^ { 1 / 5 } }
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30
Express the equilibrium constant for the following reaction:
KClO3(s)? KClO(s)+ O2(g)

A)Kc = [KClO][O2][KClO3]\frac { [ \mathrm { KClO } ] \left[ \mathrm { O } _ { 2 } \right] } { \left[ \mathrm { KClO } _ { 3 } \right] }
B)Kc = [O2]-1
C)Kc = [KClO]2[O2]2[KClO3]2\frac { [ \mathrm { KClO } ] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 2 } } { \left[ \mathrm { KClO } _ { 3 } \right] ^ { 2 } }
D)Kc = [KClO3]\left[ \mathrm { KClO } _ { 3 } \right]
[KClO][O2][ \mathrm { KClO } ] \left[ \mathrm { O } _ { 2 } \right]

[KClO3][KClO][O2]\frac {[{ KClO } _ { 3 }] } { \mathrm [{ KClO } ] \left[ \mathrm { O } _ { 2 } \right] }








E)Kc = [O2]
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31
Express the equilibrium constant for the following reaction:
\quad\quad 2Na(s)+ 2H2O(l)? 2NaOH(aq)+ H2(g)

A)
Kc = [NaOH]2[H2][Na]2[H2O]2\frac { [ \mathrm { NaOH } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \right] } { [ \mathrm { Na } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 2 } }
B)
Kc = [H2][NaOH]-2
C)
Kc = [Na]2[H2O]2[NaOH]2[H2]\frac { [ \mathrm { Na } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 2 } } { [ \mathrm { NaOH } ] ^ { 2 } \left[ \mathrm { H } _ { 2 } \right] }
D)Kc = [H2][NaOH]2
E)
Kc = [NaOH]1/2[H2][Na]1/2[H2O]1/2\frac { [ \mathrm { NaOH } ] ^ { 1 / 2 } \left[ \mathrm { H } _ { 2 } \right] } { [ \mathrm { Na } ] ^ { 1 / 2 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 1 / 2 } }
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32
Express the equilibrium constant for the following reaction:
\quad\quad B(OH)3(aq) + 2H2O(l)? B(OH)3(OH)-(aq)+ H3O+(aq)

A)Kc = [H3O+]×[B(OH)3(OH)][B(OH)3]×[H2O]\frac { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] }
B)Kc = [B(OH)3]\left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right]
[H3O+]×[B(OH)3(OH)]\left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right]

B(OH)3[H3O+]×[B(OH)3(OH)]\frac {B( { OH } ) _ { 3 } } { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right]}



C)Kc = [B(OH)3]×[H2O][H3O+]×[B(OH)3(OH)]\frac { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] } { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] }
D)Kc = [H3O+]×[B(OH)3(OH)][B(OH)3]\frac { \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] \times \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] }
E)Kc = [B(OH)3]×[H3O+][B(OH)3(OH)]\frac { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } \right] \times \left[ \mathrm { H } _ { 3 } \mathrm { O } ^ { + } \right] } { \left[ \mathrm { B } ( \mathrm { OH } ) _ { 3 } ( \mathrm { OH } ) ^ { - } \right] }
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33
For the following reaction,what is △n required in the conversion of Kc to Kp? KClO3(s)⇌ KClO(s)+ O2(g)

A)3
B)-1
C)-2
D)2
E)1
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34
The reaction below has a Kc value of 61 M-2.What is the value of Kp for this reaction at 500 K? N2(g)+ 3H2(g)⇌ 2NH3(g)

A)15 bar-2
B)61 bar-2
C)28 bar-2
D)3.6 × 10-2 bar-2
E)1.9 × 10-2 bar-2
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35
Express the equilibrium constant for the following reaction:
Fe(H2O)63+3+(aq)+6CN(aq)=Fe(CN)633(aq)+6H2O(l)\mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \underset { ( a q ) } { 3 + } + 6 \mathrm { CN } - ( a q ) = \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \underset { ( a q ) } { 3 - } + 6 \mathrm { H } _ { 2 } \mathrm { O } ( l )

A)Kc = [Fe(CN)63][CN]6×[Fe(H2O)63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] }
B)Kc = [Fe(CN)63]×[H2O]6[CN]6×[Fe(H2O)63+]\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] }
C)Kc = [CN]6×[Fe(H2O)63+][Fe(CN)63]\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] }
D)Kc = [CN]6×[Fe(H2O)63+][Fe(CN)63]×[H2O]6\frac { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) 6 ^ { 3 + } \right] } { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] \times \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 6 } }
E)Kc = [Fe(CN)63]3[CN]6×[Fe(H2O)63+]3\frac { \left[ \mathrm { Fe } ( \mathrm { CN } ) _ { 6 } ^ { 3 - } \right] ^ { 3 } } { \left[ \mathrm { CN } ^ { - } \right] ^ { 6 } \times \left[ \mathrm { Fe } \left( \mathrm { H } _ { 2 } \mathrm { O } \right) _ { 6 } ^ { 3 + } \right] ^ { 3 } }
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36
For the following reaction,what is Δn required in the conversion of Kc to Kp? CH4(g)+ H2O(g)⇌ CO(g)+ 3H2(g)

A)3
B)-1
C)-2
D)2
E)1
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37
For the following reaction,what is Δn required in the conversion of Kc to Kp? N2O4(g)⇌ 2NO2(g)

A)3
B)-1
C)-2
D)2
E)1
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38
The reaction below has a Kc value of 1.0 × 1012 M-1.What is the value of Kp for this reaction at 500 K? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)4.2 × 10-11 bar-1
B)1.0 × 1012 bar-1
C)2.4 × 10-12 bar-1
D)4.1 × 1013 bar-1
E)2.4 × 1010 bar-1
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39
For which of the following reactions will Kc = Kp?

A)H2(g)+ I2(g)⇌ 2HI(g)
B)CH4(g)+ H2O(g)⇌ CO(g)+ 3H2(g)
C)N2O4(g)⇌ 2NO2(g)
D)CO(g)+ 2H2(g)⇌ CH3OH(g)
E)N2(g)+ 3H2(g)⇌ 2NH3(g)
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40
For which of the following reactions will Kc = Kp?

A)4NH3(g)+ 3O2(g)⇌ 2N2(g)+ 6H2O(g)
B)SO3(g)+ NO(g)⇌ SO2(g)+ NO2(g)
C)2N2(g)+ O2(g)⇌ 2N2O(g)
D)2SO2(g)+ O2(g)⇌ 2SO3(g)
E)PCl3(g) + 1/2 O2(g) ⇌ PCl3O(g)
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41
In a reaction mixture containing reactants and products,each at a concentration of 1 mol L-1,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
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42
Which of the following statements is TRUE?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the forward reaction will proceed to form more products.
C)If Q = K,it means the reaction is at equilibrium.
D)If Q << K,it means the reaction is shifted to the left.
E)If Q >> K,it means the reaction is shifted to the right.
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43
In a reaction mixture containing only products,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
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44
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 mol L-1,[PCl3]eq = 0.23 mol L-1,[Cl2]eq = 4.4 mol L-1. PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)1.8 M
B)0.93 M
C)0.55 M
D)1.1 M
E)0.76 M
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45
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl)eq = 0.22 atm,P(NO)eq = 0.10 atm,P(Cl2)eq = 0.081 atm. 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

A)3.7 × 10-2 atm
B)60 atm
C)27 atm
D)1.7 × 10-2 atm
E)1.8 × 10-3 atm
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46
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO3(g). 2SO2(g)+ O2(g)⇌ 2SO3(g)Kc = 1.7 × 108 M-1
[SO2]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

A)1.9 mol L-1
B)1.0 × 103 mol L-1
C)0.53 mol L-1
D)9.6 × 10-4 mol L-1
E)0.73 mol L-1
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47
Calculate the value of [N2]eq if [H2]eq = 2.0 mol L-1,[NH3]eq = 0.50 mol L-1,and Kc = 2.0. N2(g)+ 3H2(g)⇌ 2NH3(g)

A)0.016 mol L-1
B)0.031 mol L-1
C)0.062 mol L-1
D)0.40 mol L-1
E)62.5 mol L-1
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48
In a reaction mixture containing only reactants,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)Q = K
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49
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g). C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103 M-1
[C2H4]eq = 0.015 mol L-1 [C2H5OH]eq = 1.69 mol L-1

A)9.9 × 10-7 mol L-1
B)80.mol L-1
C)1.0 mol L-1
D)1.68 mol L-1
E)0.013 mol L-1
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50
Calculate P (NO)eq,if P(NOCl)eq = 0.33 bar,P(Cl2)eq = 0.50 bar,and Kp = 1.9 × 10-2 bar . 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

A)1.7 bar
B)0.0042 bar
C)0.30 bar
D)0.064 bar
E)0.087 bar
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51
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm. 2 CO(g)+ O2(g)⇌ 2 CO2(g)

A)3.6 × 10-21 atm-1
B)2.8 × 1020 atm-1
C)4.6 × 1011 atm-1
D)2.2 × 10-12 atm-1
E)3.6 × 10-15 atm-1
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52
Consider the following reaction and its equilibrium constant: I2(g)+ Br2(g)⇌ 2IBr(g)Kc = 1.1 × 102
A reaction mixture contains 0.41 mol L-1 I2,0.27 mol L-1 Br2 and 3.5 mol L-1 IBr.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of products.
B)The reaction will shift in the direction of reactants.
C)The reaction quotient will decrease.
D)The equilibrium constant will increase.
E)The system is at equilibrium.
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53
Which of the following statements is TRUE?

A)Dynamic equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction.
B)The equilibrium constant for the forward reaction is equal to the equilibrium constant for the reverse reaction.
C)A reaction quotient (Q)larger than the equilibrium constant (K)means that the reaction will favour the production of more products.
D)Dynamic equilibrium indicates that the amount of reactants and products are equal.
E)Dynamic equilibrium is established when K = 0.
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54
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 mol L-1,[H2]eq = 1.1 mol L-1,[NH3]eq = 0.47 mol L-1. N2(g)+ 3H2(g)⇌ 2NH3(g)

A)3.5 M-2
B)0.28 M-2
C)9.1 M-2
D)0.11 M-2
E)0.78 M-2
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55
Consider the following reaction and its equilibrium constant: 4CuO(s)+ CH4(g)⇌ CO2(g)+ 4Cu(s)+ 2H2O(g)Kc = 1.10
A reaction mixture contains 0.22 mol L-1 CH4,0.67 mol L-1 CO2 and 1.3 mol L-1 H2O.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of products.
B)The equilibrium constant will increase.
C)The reaction quotient will increase.
D)The reaction will shift in the direction of reactants.
E)The system is at equilibrium.
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56
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 mol L-1,[I2]eq = 0.39 mol L-1,[HI]eq = 1.6 mol L-1. H2(g)+ I2(g)⇌ 2HI(g)

A)2.1 × 10-2
B)29
C)47
D)3.4 × 10-2
E)8.7 × 10-2
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57
Which of the following statements is TRUE?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the reverse reaction will proceed to form more reactants.
C)If Q = K,it means the reaction is not at equilibrium.
D)Because the equilibrium is always dynamic,Q can never be equal to K.
E)If Q < K,the reaction proceeding to the left is much faster than the reaction proceeding to the right.
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58
Consider the following reaction and its equilibrium constant: SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)Kc = 0.33
A reaction mixture contains 0.39 mol L-1 SO2,0.14 mol L-1 NO2 ,0.11 mol L-1 SO3 and 0.14 mol L-1 NO.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of reactants.
B)The equilibrium constant will decrease.
C)The reaction will shift in the direction of products.
D)The reaction quotient will decrease.
E)The system is at equilibrium.
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59
Consider the following reaction and its equilibrium constant: I2(g)⇌ 2I(g)Kp = 0.209 atm
A reaction mixture contains 0.89 atm I2 and 1.77 atm I.Which of the following statements is TRUE concerning this system?

A)The reaction will shift in the direction of reactants.
B)The reaction quotient will increase.
C)The reaction will shift in the direction of products.
D)The equilibrium constant will decrease.
E)The system is at equilibrium.
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60
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 mol L-1,[HI]eq = 5.6 × 10-16 mol L-1,[Cl2]eq = 0.0019 mol L-1. 2HCl(g)+ I2(s)⇌ 2HI(g)+ Cl2(g)

A)8.2 × 10-18 M
B)2.9 × 1031 M
C)1.2 × 1017 M
D)1.4 × 10-19 M
E)3.5 × 10-32 M
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61
Consider the following reaction: CO2(g)+ C(graphite)⇌ 2CO(g)
A reaction mixture initially contains 0.56 bar CO2 and 0.32 bar CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25 bar.

A)0.83 bar
B)0.31 bar
C)0.26 bar
D)0.58 bar
E)0.42 bar
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62
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 0.039 mol L-1

A)1.22 mol L-1
B)9.0 × 10-2 mol L-1
C)7.8 × 10-2 mol L-1
D)8.2 × 10-3 mol L-1
E)11 mol L-1
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63
Consider the following reaction: Xe(g)+ 2F2(g)⇌ XeF4(g)
A reaction mixture initially contains 2.24 bar Xe and 4.27 bar F2.If the equilibrium pressure of Xe is 0.34 bar,find the equilibrium constant (Kp)for the reaction.

A)25 bar-2
B)0.12 bar-2
C)0.99 bar-2
D)8.3 bar-2
E)0.040 bar-2
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64
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 1.82 mol L-1

A)0.38 mol L-1
B)0.71 mol L-1
C)0.62 mol L-1
D)0.40 mol L-1
E)0.095 mol L-1
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65
The following reaction is exothermic.Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

A)raising the temperature
B)removing SO3
C)adding O2
D)increasing the pressure
E)adding SO2
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66
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.86 bar NO and 0.86 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.78 bar
B)0.084 bar
C)0.012 bar
D)0.85 bar
E)0.048 bar
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67
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 2.0 bar NO and 1.0 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.46 bar
B)0.037 bar
C)0.19 bar
D)0.14 bar
E)0.68 bar
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68
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 2.0 bar NO2 and 1.0 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

A)0.011 bar
B)0.037 bar
C)0.10 bar
D)0.0038 bar
E)0.067 bar
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69
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 1.24 bar NO and 0.92 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.32 bar
B)1.32 bar
C)0.10 bar
D)0.74 bar
E)0.022 bar
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70
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g). NH2COONH4(s)⇌ 2NH3(g)+ CO2(g)Kc = 1.58 × 10-8 M3
[NH3]eq = 2.9 × 10-3 mol L-1

A)0.053 mol L-1
B)4.6 × 10-11 mol L-1
C)1.9 × 10-3 mol L-1
D)5.4 × 10-6 mol L-1
E)0.022 mol L-1
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71
Consider the following reaction: CH4(g)+ 2H2S(g)⇌ CS2(g)+ 4H2(g)
A reaction mixture initially contains 0.50 mol L-1 CH4 and 0.75 mol L-1 H2S.If the equilibrium concentration of H2 is 0.44 mol L-1,find the equilibrium constant (mol L-1)for the reaction.

A)0.23 mol2 L-2
B)0.038 mol2 L-2
C)2.9 mol2 L-2
D)10.mol2 L-2
E)0.34 mol2 L-2
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72
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 0.068 mol L-1

A)1.9 mol L-1
B)0.12 mol L-1
C)0.60 mol L-1
D)0.028 mol L-1
E)0.036 mol L-1
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73
Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)
A reaction mixture initially contains 2.9 mol L-1 O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

A)1.9 mol L-1
B)1.7 mol L-1
C)2.2 mol L-1
D)1.2 mol L-1
E)0.59 mol L-1
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74
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g)Kc = 0.21 M
[N2O4]eq = 1.34 mol L-1

A)0.25 mol L-1
B)0.043 mol L-1
C)0.60 mol L-1
D)0.028 mol L-1
E)0.53 mol L-1
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75
Consider the following reaction: COCl2(g)⇌ CO(g)+ Cl2(g)
A reaction mixture initially contains 1.6 mol L-1 COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4 M.Calculate this based on the assumption that the answer is negligible compared to 1.6.

A)4.2 × 10-4 mol L-1
B)1.5 × 10-3 mol L-1
C)3.7 × 10-2 mol L-1
D)2.1 × 10-2 mol L-1
E)1.3 × 10-3 mol L-1
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76
Consider the following reaction,equilibrium pressures,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO. CO(g)+ 2H2(g)⇌ CH3OH(l)Kp = 2.25 × 104 bar-3
P(H2)eq = 0.52 bar

A)8.3 × 104 bar
B)1.2 × 10-5 bar
C)6.25 × 10-3 bar
D)8.5 × 10-5 bar
E)1.6 × 10-4 bar
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77
Consider the following reaction: 2H2O(g)+ 2SO2(g)⇌ 2H2S(g)+ 3O2(g)
A reaction mixture initially contains 2.8 mol L-1 H2O and 2.6 mol L-1 SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6 mol L-1.

A)0.045 mol L-1
B)0.058 mol L-1
C)0.028 mol L-1
D)3.1 × 10-3 mol L-1
E)0.12 mol L-1
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78
Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.384 bar NO2 and 0.224 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

A)0.220 bar
B)0.037 bar
C)0.67 bar
D)0.024 bar
E)0.0035 bar
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79
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO2(g). 2SO2(g)+ O2(g)⇌ 2SO3(g)Kc = 1.7 × 108 M-1
[SO3]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

A)2.8 × 1013 mol L-1
B)1.88 mol L-1
C)6.1 × 10-6 mol L-1
D)1.0 × 103 mol L-1
E)1.4 mol L-1
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80
Consider the following reaction,equilibrium pressures,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2. D2(g)+ H2(g)⇌ 2HD(g)Kp = 1.80
P(D2)eq = 1.1 × 10-3 bar P(HD)eq = 2.7 × 10-3 bar

A)2.7 bar
B)1.4 bar
C)0.73 bar
D)3.7 × 10-3 bar
E)8.1 × 10-4 bar
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