Deck 19: Electrochemistry

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Question
What element is being oxidized in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2-(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
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Question
What element is being reduced in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
Question
What element is being reduced in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
Question
Identify the location of oxidation in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
Question
What element is being oxidized in the following redox reaction? Cr(OH)4-(aq)+ ClO-(aq)→ CrO42-(aq)+ Cl-(aq)

A) Cr
B) O
C) H
D) Cl
Question
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
Question
What element is being oxidized in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
Question
Identify the location of reduction in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
Question
What element is being oxidized in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
Question
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)

A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
Question
In a hydrogen-oxygen fuel cell,

A) neither oxygen or hydrogen atoms are oxidized or reduced.
B) both oxygen and hydrogen atoms are oxidized.
C) both oxygen and hydrogen atoms are reduced.
D) oxygen atoms are reduced and hydrogen atoms are oxidized.
E) oxygen atoms are oxidized and hydrogen atoms are reduced.
Question
What element is being reduced in the following redox reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr
B) O
C) H
D) Cl
Question
In a hydrogen-oxygen fuel cell,

A) no transfer of electrons occurs.
B) both oxygen and hydrogen atoms lose electrons.
C) both oxygen and hydrogen atoms gain electrons.
D) oxygen atoms lose electrons and hydrogen atoms gain electrons.
E) oxygen atoms gain electrons and hydrogen atoms lose electrons.
Question
What element is being reduced in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
Question
In a voltaic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
Question
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
Question
Define a salt bridge.

A) A pathway composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counterions can flow between the half-cells without the solutions in the half-cell totally mixing.
Question
A voltaic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
Question
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Br2 and OH⁻ in the balanced reaction? Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)

A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
Question
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4 and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
Question
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
Question
Determine the cell notation for the redox reaction given below. 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)

A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe(s) ∣ Fe3+(aq)
B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe3+(aq) Fe(s)
C) Fe3+(aq) ∣ Fe(s) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Cl⁻(aq) ∣ Cl2(g) ∣ Pt
D) Fe(s) ∣ Cl2(g) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Fe3+(aq) ∣ Cl⁻(aq) ∣ Pt
E) Fe(s) ∣ Fe3+(aq) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt <div style=padding-top: 35px> Cl2(g) ∣ Cl⁻(aq) ∣ Pt
Question
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
Question
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V

A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,1.8 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,1.8 M)   Ag<sup>+</sup>(aq,0.055 M)∣ Ag(s)</strong> A) -0.94 V B) -0.85 V C) +1.02 V D) +0.98 V E) +0.86 V <div style=padding-top: 35px> Ag+(aq,0.055 M)∣ Ag(s)

A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M)   Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)</strong> A) +1.01 V B) -0.83 V C) +1.31 V D) +0.01 V E) -0.66 V <div style=padding-top: 35px> Ag+(aq,2.7 M)∣ Ag(s)

A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
Question
What statement is NOT true about standard electrode potentials?

A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
Question
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
Question
Identify the characteristics of a spontaneous reaction.

A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
Question
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V

A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
Question
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2 K(s)+ I2(s)→ 2 K⁺(aq)+ 2 I⁻(aq)
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V

A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
Question
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq)
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e- → 2 Br-(aq)E° = +1.07 V

A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
Question
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V

A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
Question
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.3 × 10-16
E) 1.1 × 10-8
Question
Which of the following reactions would have the smallest value of K at 298 K?

A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
Question
Identify a characteristic that does not describe a standard hydrogen electrode.

A) 1 M HCl solution with hydrogen gas
B) 1 atmosphere
C) zinc electrode
D) inert platinum electrode
E) potential of zero
Question
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) 3.5 × 10-59
B) 1.1 × 1017
C) 2.4 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
Question
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe<sup>3+</sup>(aq,0.0011 M)   Fe<sup>3+</sup>(aq,2.33 M)∣ Fe(s)</strong> A) +0.066 V B) -0.036 V C) 0.00 V D) -0.099 V E) +0.20 V <div style=padding-top: 35px> Fe3+(aq,2.33 M)∣ Fe(s)

A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg2+(aq,2.74 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg<sup>2+</sup>(aq,2.74 M)   Cu<sup>2+</sup>(aq,0.0033 M)∣ Cu(s)</strong> A) -2.80 V B) +2.62 V C) +2.71 V D) +2.12 V E) -1.94 V <div style=padding-top: 35px> Cu2+(aq,0.0033 M)∣ Cu(s)

A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
Question
In an electrolytic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
Question
Identify the battery that is in most automobiles.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
Question
What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current? Ag⁺(aq)+ e⁻ → Ag(s)

A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
Question
What is the reaction at the cathode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
Question
What is the reaction at the anode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
Question
In a nickel-cadmium battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
Question
An electrolytic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu<sup>2+</sup>(aq,0.0032 M)   Cu<sup>2+</sup>(aq,4.48 M)∣ Cu(s)</strong> A) 0.00 V B) +0.093 V C) +0.34 V D) +0.186 V E) +0.052 V <div style=padding-top: 35px> Cu2+(aq,4.48 M)∣ Cu(s)

A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
Question
Identify the battery that is used as a common flashlight battery.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
Question
What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
Question
Describe how water can be a good conductor of current.

A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
Question
In an alkaline battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
Question
Identify the battery type that has a high overcharge tolerance.

A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
Question
In a lead-acid storage battery,PbO2 is reduced to

A) Pb.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
Question
In a dry-cell battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
Question
Identify the components of a fuel cell.

A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
Question
Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
Question
In a lead-acid storage battery,Pb is oxidized to

A) PbO2.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
Question
In a nickel-metal hydride battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
Question
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al<sup>3+</sup>(aq,0.115 M)   Al<sup>3+</sup>(aq,3.89 M)∣ Al(s)</strong> A) +1.66 V B) +0.060 V C) 0.00 V D) +0.090 V E) +0.030 V <div style=padding-top: 35px> Al3+(aq,3.89 M)∣ Al(s)

A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
Question
Balance the following reaction in KOH.What are the coefficients in front of C9H20O2 and KMnO4 in the balanced reaction? C9H20O2(aq)+ KMnO4(aq)→ C9H14O4K2(aq)+ MnO2(aq)

A) C9H20O2 = 3, KMnO4 = 8
B) C9H20O2 = 3, KMnO4 = 4
C) C9H20O2 = 8, KMnO4 = 4
D) C9H20O2 = 2, KMnO4 = 8
E) C9H20O2 = 3, KMnO4 = 2
Question
What element is being oxidized in the following redox reaction? C10H22O2(aq)+ KMnO4(aq)→ C10H16O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
Question
What element is being oxidized in the following redox reaction? Mg2+(aq)+ NH4+(aq)→ Mg(s)+ NO3⁻(aq)

A) Mg
B) N
C) H
D) O
Question
What element is being reduced in the following redox reaction? C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
Question
A sacrificial electrode is composed of a metal that

A) does not serve as a protective coating.
B) reduces more easily than iron.
C) has an oxide that is crumbly when formed.
D) oxidizes more easily than iron.
E) oxidizes the same as iron.
Question
Aluminum is quickly oxidized in the air to form

A) Al2O3.
B) Al(OH)2.
C) Al(OH)3.
D) Al3O2.
E) AlO.
Question
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+,Ca2+,Cl⁻,Br⁻,F⁻

A) Na+
B) Cl-
C) Ca2+
D) Br-
E) F-
Question
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+,Fe3+,Mg2+,Br-,I-

A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
Question
Identify a component in the formation of rust.

A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
Question
Define extraction.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
Question
Identify oxidation.

A) increase in oxidation number
B) loss of electrons
C) gain of protons
D) loss of neutrons
E) both A and B
Question
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr and Cl2 in the balanced reaction? Cr(s)+ Cl2(g)→ Cr3+(aq)+ Cl-(aq)

A) Cr = 2, Cl2 = 3
B) Cr = 2, Cl2 = 4
C) Cr = 1, Cl2 = 2
D) Cr = 2, Cl2 = 1
E) Cr = 3, Cl2 = 2
Question
Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻

A) Cl-
B) F-
C) Cu2+
D) Mg2+
E) Br-
Question
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of C10H22O2 and H2SO4 in the balanced reaction? C10H22O2(aq)+ Na2Cr2O7(aq)→ C10H18O4(aq)+ Cr2(SO4)3(aq)

A) C10H22O2 = 3, H2SO4 = 4
B) C10H22O2 = 2, H2SO4 = 8
C) C10H22O2 = 1, H2SO4 = 16
D) C10H22O2 = 3, H2SO4 = 16
E) C10H22O2 = 2, H2SO4 = 4
Question
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Fe and Ag+ in the balanced reaction? Fe(s)+ Ag+(aq)→ Ag(s)+ Fe2+(aq)

A) Fe = 1, Ag⁺ = 2
B) Fe = 1, Ag⁺ = 3
C) Fe = 2, Ag⁺ = 1
D) Fe = 2, Ag⁺ = 3
E) Fe = 3, Ag⁺ = 3
Question
Define corrosion.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
Question
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Pb and H+ in the balanced reaction?
Pb2+(aq)+ NH4+(aq)? Pb(s)+ NO3?(aq)

A) Pb = 1, H? = 8
B) Pb = 1, H? = 2
C) Pb = 4, H? = 10
D) Pb = 2, H? = 3
E) Pb = 3, H? = 5
Question
To prevent rust,nails are coated with

A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
Question
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction? C7H16O2(aq)+ Na2Cr2O7(aq)→ C7H12O4(aq)+ Cr2(SO4)3(aq)

A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 4
Question
Describe the reactions during the electrolysis of water.

A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen nor hydrogen are oxidized or reduced.
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Deck 19: Electrochemistry
1
What element is being oxidized in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2-(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
O
2
What element is being reduced in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
Cr
3
What element is being reduced in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) H
B) O
C) Cl
D) N
E) C
Cl
4
Identify the location of oxidation in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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5
What element is being oxidized in the following redox reaction? Cr(OH)4-(aq)+ ClO-(aq)→ CrO42-(aq)+ Cl-(aq)

A) Cr
B) O
C) H
D) Cl
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6
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) H2C2O4 = 5, H2O = 8
B) H2C2O4 = 1, H2O = 1
C) H2C2O4 = 5, H2O = 1
D) H2C2O4 = 1, H2O = 4
E) H2C2O4 = 3, H2O = 2
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7
What element is being oxidized in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
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8
Identify the location of reduction in an electrochemical cell.

A) the anode
B) the cathode
C) the electrode
D) the salt bridge
E) the socket
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9
What element is being oxidized in the following redox reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr+3(aq)

A) C
B) H
C) O
D) K
E) Cr
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10
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)

A) H⁺ = 2, Fe3+ = 3
B) H⁺ = 8, Fe3+ = 5
C) H⁺ = 3, Fe3+ = 2
D) H⁺ = 5, Fe3+ = 1
E) H⁺ = 8, Fe3+ = 1
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11
In a hydrogen-oxygen fuel cell,

A) neither oxygen or hydrogen atoms are oxidized or reduced.
B) both oxygen and hydrogen atoms are oxidized.
C) both oxygen and hydrogen atoms are reduced.
D) oxygen atoms are reduced and hydrogen atoms are oxidized.
E) oxygen atoms are oxidized and hydrogen atoms are reduced.
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12
What element is being reduced in the following redox reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr
B) O
C) H
D) Cl
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13
In a hydrogen-oxygen fuel cell,

A) no transfer of electrons occurs.
B) both oxygen and hydrogen atoms lose electrons.
C) both oxygen and hydrogen atoms gain electrons.
D) oxygen atoms lose electrons and hydrogen atoms gain electrons.
E) oxygen atoms gain electrons and hydrogen atoms lose electrons.
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14
What element is being reduced in the following redox reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

A) C
B) O
C) Mn
D) H
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15
In a voltaic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
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16
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

A) ClO2 = 1, H2O = 1
B) ClO2 = 1, H2O = 2
C) ClO2 = 4, H2O = 3
D) ClO2 = 4, H2O = 2
E) ClO2 = 2, H2O = 2
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17
Define a salt bridge.

A) A pathway composed of salt water, that ions pass through.
B) A pathway in which no ions flow.
C) A pathway between the cathode and anode in which ions are reduced.
D) A pathway between the cathode and anode in which ions are oxidized.
E) A pathway by which counterions can flow between the half-cells without the solutions in the half-cell totally mixing.
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18
A voltaic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
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19
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Br2 and OH⁻ in the balanced reaction? Br2(l)→ BrO3⁻(aq)+ Br⁻(aq)

A) Br2 = 1, OH⁻ = 2
B) Br2 = 2, OH⁻ = 5
C) Br2 = 3, OH⁻ = 3
D) Br2 = 3, OH⁻ = 6
E) Br2 = 1, OH⁻ = 6
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20
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4 and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

A) Cr(OH)4⁻ = 2, ClO⁻ = 3
B) Cr(OH)4⁻ = 1, ClO⁻ = 1
C) Cr(OH)4⁻ = 1, ClO⁻ = 2
D) Cr(OH)4⁻ = 2, ClO⁻ = 6
E) Cr(OH)4⁻ = 6, ClO⁻ = 5
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21
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) -41 kJ
B) -0.47 kJ
C) +46 kJ
D) +91 kJ
E) -21 kJ
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22
Determine the cell notation for the redox reaction given below. 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)

A) Cl2(g) ∣ Cl⁻(aq) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe(s) ∣ Fe3+(aq)
B) Cl⁻(aq) ∣ Cl2(g) ∣ Pt <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe3+(aq) Fe(s)
C) Fe3+(aq) ∣ Fe(s) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Cl⁻(aq) ∣ Cl2(g) ∣ Pt
D) Fe(s) ∣ Cl2(g) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Fe3+(aq) ∣ Cl⁻(aq) ∣ Pt
E) Fe(s) ∣ Fe3+(aq) <strong>Determine the cell notation for the redox reaction given below. 3 Cl<sub>2</sub>(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe<sup>3+</sup>(aq)</strong> A) Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt   Fe(s) ∣ Fe<sup>3+</sup>(aq) B) Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt   Fe<sup>3+</sup>(aq)<sup> </sup>∣<sup> </sup>Fe(s) C) Fe<sup>3+</sup>(aq) ∣ Fe(s)   Cl⁻(aq) ∣ Cl<sub>2</sub>(g) ∣ Pt D) Fe(s) ∣ Cl<sub>2</sub>(g)   Fe<sup>3+</sup>(aq) ∣ Cl⁻(aq) ∣ Pt E) Fe(s) ∣ Fe<sup>3+</sup>(aq)   Cl<sub>2</sub>(g) ∣ Cl⁻(aq) ∣ Pt Cl2(g) ∣ Cl⁻(aq) ∣ Pt
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23
Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) -1.1 × 102 kJ
B) +4.9 × 101 kJ
C) -9.7 × 101 kJ
D) +2.3 × 102 kJ
E) -3.3 × 102 kJ
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24
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 3 Cl2(g)+ 2 Fe(s)→ 6 Cl⁻(aq)+ 2 Fe3+(aq)
Cl2(g)+ 2 e⁻ → 2 Cl⁻(aq)E° = +1.36 V
Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V

A) +4.16 V
B) -1.40 V
C) -1.32 V
D) +1.32 V
E) +1.40 V
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25
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,1.8 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,1.8 M)   Ag<sup>+</sup>(aq,0.055 M)∣ Ag(s)</strong> A) -0.94 V B) -0.85 V C) +1.02 V D) +0.98 V E) +0.86 V Ag+(aq,0.055 M)∣ Ag(s)

A) -0.94 V
B) -0.85 V
C) +1.02 V
D) +0.98 V
E) +0.86 V
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26
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M)   Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)</strong> A) +1.01 V B) -0.83 V C) +1.31 V D) +0.01 V E) -0.66 V Ag+(aq,2.7 M)∣ Ag(s)

A) +1.01 V
B) -0.83 V
C) +1.31 V
D) +0.01 V
E) -0.66 V
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27
What statement is NOT true about standard electrode potentials?

A) E°cell is positive for spontaneous reactions.
B) Electrons will flow from more negative electrode to more positive electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the difference in voltage between the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E°.
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28
Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) +4.1 × 102 kJ
B) +1.4 × 102 kJ
C) -2.3 × 102 kJ
D) -7.8 × 102 kJ
E) +6.8 × 102 kJ
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29
Identify the characteristics of a spontaneous reaction.

A) ΔG° < 0
B) ΔE°cell > 0
C) K > 1
D) all of the above
E) none of the above
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30
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq)
Mg2+(aq)+ 2 e⁻ → Mg(s)E° = -2.38 V
Cu2+(aq)+ 2 e⁻ → Cu(s)E° = +0.34 V

A) +2.04 V
B) -2.04 V
C) +2.72 V
D) -1.36 V
E) +1.36 V
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31
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) 2 K(s)+ I2(s)→ 2 K⁺(aq)+ 2 I⁻(aq)
K+(aq)+ e⁻ → K(s)E° = -2.93 V
I2(s)+ 2 e⁻ → 2 I⁻(aq)E° = +0.54 V

A) +6.40 V
B) +1.85 V
C) -5.32 V
D) +3.47 V
E) +5.32 V
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32
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq)
Pb2+(aq)+ 2 e⁻ → Pb(s)E° = -0.13 V
Br2(l)+ 2 e- → 2 Br-(aq)E° = +1.07 V

A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V
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33
Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced.) Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)
Sn2+(aq)+ 2 e⁻ → Sn(s)E° = -0.14 V
Ag⁺(aq)+ e⁻ → Ag(s)E° = +0.80 V

A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V
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34
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq)

A) 7.9 × 10-8
B) 8.9 × 107
C) 7.9 × 1015
D) 1.3 × 10-16
E) 1.1 × 10-8
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35
Which of the following reactions would have the smallest value of K at 298 K?

A) A + B → C; E°cell = +1.22 V
B) A + 2 B → C; E°cell = +0.98 V
C) A + B → 2 C; E°cell = -0.030 V
D) A + B → 3 C; E°cell = +0.15 V
E) More information is needed to determine.
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36
Identify a characteristic that does not describe a standard hydrogen electrode.

A) 1 M HCl solution with hydrogen gas
B) 1 atmosphere
C) zinc electrode
D) inert platinum electrode
E) potential of zero
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37
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

A) 3.5 × 10-59
B) 1.1 × 1017
C) 2.4 × 1058
D) 8.9 × 10-18
E) 1.7 × 1029
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38
Use the tabulated half-cell potentials to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s)

A) 1.1 × 1072
B) 8.9 × 10-73
C) 1.1 × 10-72
D) 1.0 × 1024
E) 4.6 × 1031
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39
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe<sup>3+</sup>(aq,0.0011 M)   Fe<sup>3+</sup>(aq,2.33 M)∣ Fe(s)</strong> A) +0.066 V B) -0.036 V C) 0.00 V D) -0.099 V E) +0.20 V Fe3+(aq,2.33 M)∣ Fe(s)

A) +0.066 V
B) -0.036 V
C) 0.00 V
D) -0.099 V
E) +0.20 V
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40
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg2+(aq,2.74 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s)∣ Mg<sup>2+</sup>(aq,2.74 M)   Cu<sup>2+</sup>(aq,0.0033 M)∣ Cu(s)</strong> A) -2.80 V B) +2.62 V C) +2.71 V D) +2.12 V E) -1.94 V Cu2+(aq,0.0033 M)∣ Cu(s)

A) -2.80 V
B) +2.62 V
C) +2.71 V
D) +2.12 V
E) -1.94 V
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41
In an electrolytic cell,the anode is defined as

A) a metal contact.
B) the more positively charged electrode.
C) the positive terminal of the power source.
D) the more negatively charged electrode.
E) the negative terminal of the power source.
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42
Identify the battery that is in most automobiles.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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43
What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current? Ag⁺(aq)+ e⁻ → Ag(s)

A) 19.6 g
B) 0.326 g
C) 9.78 g
D) 3.07 g
E) 0.102 g
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44
What is the reaction at the cathode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
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45
What is the reaction at the anode in a breathalyzer?

A) Ethanol is oxidized to acetic acid.
B) Acetic acid is reduced to ethanol.
C) Oxygen is reduced.
D) Hydrogen is oxidized.
E) Ethanol is oxidized to acetaldehyde.
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46
In a nickel-cadmium battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
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47
An electrolytic cell

A) produces electrical current from a spontaneous chemical reaction.
B) produces electrical current from electricity.
C) consumes electrical current to drive a spontaneous chemical reaction.
D) produces electrical current from a nonspontaneous chemical reaction.
E) consumes electrical current to drive a nonspontaneous chemical reaction.
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48
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu<sup>2+</sup>(aq,0.0032 M)   Cu<sup>2+</sup>(aq,4.48 M)∣ Cu(s)</strong> A) 0.00 V B) +0.093 V C) +0.34 V D) +0.186 V E) +0.052 V Cu2+(aq,4.48 M)∣ Cu(s)

A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V
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49
Identify the battery that is used as a common flashlight battery.

A) dry-cell battery
B) lithium ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell
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50
What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

A) 73.5 g
B) 24.5 g
C) 220. g
D) 147 g
E) 8.17 g
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51
Describe how water can be a good conductor of current.

A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water
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52
In an alkaline battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
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53
Identify the battery type that has a high overcharge tolerance.

A) NiCad
B) Li ion
C) NiMH
D) lead storage
E) none of the above
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54
In a lead-acid storage battery,PbO2 is reduced to

A) Pb.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
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55
In a dry-cell battery,MnO2 is reduced to

A) MnO3.
B) Mn2O2.
C) MnO(OH).
D) MnO4-.
E) Mn2O3.
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56
Identify the components of a fuel cell.

A) nickel-metal hydride
B) lithium ion
C) hydrogen-oxygen
D) nickel-cadmium
E) zinc-manganese
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57
Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

A) 1.7 × 102 min
B) 5.9 × 102 min
C) 3.5 × 102 min
D) 4.8 × 102 min
E) 6.2 × 102 min
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58
In a lead-acid storage battery,Pb is oxidized to

A) PbO2.
B) PbSO4.
C) Pb2O.
D) PbO3.
E) PbO.
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59
In a nickel-metal hydride battery,NiO(OH)is reduced to

A) Ni(OH)4.
B) NiO2.
C) Ni.
D) Ni(OH)2.
E) NiOH.
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60
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M) <strong>Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al<sup>3+</sup>(aq,0.115 M)   Al<sup>3+</sup>(aq,3.89 M)∣ Al(s)</strong> A) +1.66 V B) +0.060 V C) 0.00 V D) +0.090 V E) +0.030 V Al3+(aq,3.89 M)∣ Al(s)

A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V
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61
Balance the following reaction in KOH.What are the coefficients in front of C9H20O2 and KMnO4 in the balanced reaction? C9H20O2(aq)+ KMnO4(aq)→ C9H14O4K2(aq)+ MnO2(aq)

A) C9H20O2 = 3, KMnO4 = 8
B) C9H20O2 = 3, KMnO4 = 4
C) C9H20O2 = 8, KMnO4 = 4
D) C9H20O2 = 2, KMnO4 = 8
E) C9H20O2 = 3, KMnO4 = 2
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62
What element is being oxidized in the following redox reaction? C10H22O2(aq)+ KMnO4(aq)→ C10H16O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
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63
What element is being oxidized in the following redox reaction? Mg2+(aq)+ NH4+(aq)→ Mg(s)+ NO3⁻(aq)

A) Mg
B) N
C) H
D) O
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64
What element is being reduced in the following redox reaction? C3H8O2(aq)+ KMnO4(aq)→ C3H2O4K2(aq)+ MnO2(aq)

A) C
B) H
C) O
D) K
E) Mn
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65
A sacrificial electrode is composed of a metal that

A) does not serve as a protective coating.
B) reduces more easily than iron.
C) has an oxide that is crumbly when formed.
D) oxidizes more easily than iron.
E) oxidizes the same as iron.
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66
Aluminum is quickly oxidized in the air to form

A) Al2O3.
B) Al(OH)2.
C) Al(OH)3.
D) Al3O2.
E) AlO.
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67
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+,Ca2+,Cl⁻,Br⁻,F⁻

A) Na+
B) Cl-
C) Ca2+
D) Br-
E) F-
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68
Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+,Fe3+,Mg2+,Br-,I-

A) Zn2+
B) Mg2+
C) Br-
D) Fe3+
E) I-
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69
Identify a component in the formation of rust.

A) salt
B) moisture
C) acid
D) all of the above
E) none of the above
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70
Define extraction.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
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71
Identify oxidation.

A) increase in oxidation number
B) loss of electrons
C) gain of protons
D) loss of neutrons
E) both A and B
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72
Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr and Cl2 in the balanced reaction? Cr(s)+ Cl2(g)→ Cr3+(aq)+ Cl-(aq)

A) Cr = 2, Cl2 = 3
B) Cr = 2, Cl2 = 4
C) Cr = 1, Cl2 = 2
D) Cr = 2, Cl2 = 1
E) Cr = 3, Cl2 = 2
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73
Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻

A) Cl-
B) F-
C) Cu2+
D) Mg2+
E) Br-
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74
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of C10H22O2 and H2SO4 in the balanced reaction? C10H22O2(aq)+ Na2Cr2O7(aq)→ C10H18O4(aq)+ Cr2(SO4)3(aq)

A) C10H22O2 = 3, H2SO4 = 4
B) C10H22O2 = 2, H2SO4 = 8
C) C10H22O2 = 1, H2SO4 = 16
D) C10H22O2 = 3, H2SO4 = 16
E) C10H22O2 = 2, H2SO4 = 4
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75
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Fe and Ag+ in the balanced reaction? Fe(s)+ Ag+(aq)→ Ag(s)+ Fe2+(aq)

A) Fe = 1, Ag⁺ = 2
B) Fe = 1, Ag⁺ = 3
C) Fe = 2, Ag⁺ = 1
D) Fe = 2, Ag⁺ = 3
E) Fe = 3, Ag⁺ = 3
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76
Define corrosion.

A) Free metal is oxidized out of its ore.
B) Undesired reduction of metals from reducing agents in the environment
C) Plating a film on a metal to protect it
D) Undesired oxidation of metals from oxidizing agents in the environment
E) Free metal is reduced out of its ore.
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77
Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Pb and H+ in the balanced reaction?
Pb2+(aq)+ NH4+(aq)? Pb(s)+ NO3?(aq)

A) Pb = 1, H? = 8
B) Pb = 1, H? = 2
C) Pb = 4, H? = 10
D) Pb = 2, H? = 3
E) Pb = 3, H? = 5
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78
To prevent rust,nails are coated with

A) zinc.
B) salt.
C) calcium.
D) sodium.
E) lithium.
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79
Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction? C7H16O2(aq)+ Na2Cr2O7(aq)→ C7H12O4(aq)+ Cr2(SO4)3(aq)

A) H2O = 1, Cr2(SO4)3 = 5
B) H2O = 5, Cr2(SO4)3 = 2
C) H2O = 11, Cr2(SO4)3 = 4
D) H2O = 22, Cr2(SO4)3 = 4
E) H2O = 8, Cr2(SO4)3 = 4
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80
Describe the reactions during the electrolysis of water.

A) Oxygen is reduced and hydrogen is oxidized.
B) Oxygen and hydrogen are both oxidized.
C) Oxygen and hydrogen are both reduced.
D) Oxygen is oxidized and hydrogen is reduced.
E) Neither oxygen nor hydrogen are oxidized or reduced.
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