Deck 20: Organic Chemistry
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Deck 20: Organic Chemistry
1
In an unsaturated hydrocarbon, the carbon-carbon bond angles are always 120o.
False
2
Carbon can form single and double bonds with other atoms, but not triple bonds.
False
3
Name the following molecule. 
A) 2,2,3,5-tetramethyl-7-propyl-7-t-butyldecane
B) 6-propyl-2,6-di-t-butylnonane
C) 2,2,5,7,8,8-hexamethyl-3,3-dipropylnonane
D) isonanane
E) none of these

A) 2,2,3,5-tetramethyl-7-propyl-7-t-butyldecane
B) 6-propyl-2,6-di-t-butylnonane
C) 2,2,5,7,8,8-hexamethyl-3,3-dipropylnonane
D) isonanane
E) none of these
2,2,3,5-tetramethyl-7-propyl-7-t-butyldecane
4
A student gave a molecule the following name: 2-ethyl-3-methyl-5-isopropylhexane
However, her TA pointed out that although the molecule could be drawn correctly from this name, the name violates the systematic rules. What is the correct (systematic) name of the molecule?
A) 3,4-dimethyl-6-isopropylheptane
B) 2-isopropyl-4,5-dimethylheptane
C) 3,4,6,7-tetramethyloctane
D) 1,2-diethyl-3,6,7-trimethylheptane
E) 2,3,5,6-tetramethyloctane
However, her TA pointed out that although the molecule could be drawn correctly from this name, the name violates the systematic rules. What is the correct (systematic) name of the molecule?
A) 3,4-dimethyl-6-isopropylheptane
B) 2-isopropyl-4,5-dimethylheptane
C) 3,4,6,7-tetramethyloctane
D) 1,2-diethyl-3,6,7-trimethylheptane
E) 2,3,5,6-tetramethyloctane
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5
What's the correct formula for the alkane that contains nine carbon atoms?
A) C9H20
B) C9H18
C) C9H16
D) C9H9
E) C9H11
A) C9H20
B) C9H18
C) C9H16
D) C9H9
E) C9H11
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6
Name the following molecule. CH3-(CH2)2-CH3
A) butane
B) ethane
C) propane
D) benzene
E) pentane
A) butane
B) ethane
C) propane
D) benzene
E) pentane
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7
Name the following molecule. 
A) n-hexane
B) isohexane
C) 1,2,3-trimethylpropane
D) methyl-diethylmethane
E) 3-methylpentane

A) n-hexane
B) isohexane
C) 1,2,3-trimethylpropane
D) methyl-diethylmethane
E) 3-methylpentane
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8
Benzene has the formula C6H6 and a planar (flat) structure in which all the bond angles are 109.5o.
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9
What's the correct formula for the saturated hydrocarbon that contains four carbon atoms?
A) C4H10
B) C4H8
C) C4H12
D) C4H4
E) C4H6
A) C4H10
B) C4H8
C) C4H12
D) C4H4
E) C4H6
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10
Name the following molecule. 

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11
In lecture, the professor named a molecule 2-ethyl-4-tertiary-butylpentane. An alert student pointed out that although the correct structure could be drawn from this name, the name did not follow systematic rules. What is the correct systematic name for the molecule?
A) 2-t-butyl-5-methylhexane
B) 2-ethyl-4,5,5-trimethylhexane
C) 3,5,6,6-tetramethylheptane
D) 2,2,3,5-tetramethylheptane
E) undecane
A) 2-t-butyl-5-methylhexane
B) 2-ethyl-4,5,5-trimethylhexane
C) 3,5,6,6-tetramethylheptane
D) 2,2,3,5-tetramethylheptane
E) undecane
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12
Name the following molecule. 

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13
When carbon has four atoms bound to it, these atoms will have a square planar arrangement about the carbon.
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14
Draw the structural formula for 2,2-dimethylpropane.
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15
Those compounds whose carbon-carbon bonds are all single bonds are said to be unsaturated.
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16
What's the correct formula for the simplest alkene that contains six carbon atoms?
A) C6H12
B) C6H10
C) C6H8
D) C6H14
E) C6H16
A) C6H12
B) C6H10
C) C6H8
D) C6H14
E) C6H16
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17
A straight-chain saturated hydrocarbon cannot contain more than 10 carbon atoms.
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18
Name the following molecule. 

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19
What's the correct formula for the simplest alkene that contains seven carbon atoms?
A) C7H14
B) C7H12
C) C7H10
D) C7H16
E) C7H18
A) C7H14
B) C7H12
C) C7H10
D) C7H16
E) C7H18
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20
Butane is an example of an alkane.
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21
Name the molecule CH3C CCH2CH3.
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22
Give the name for the following molecule. 

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23
Name the following: 
A) 1,1,1-trichloro-5-bromo-3-pentene
B) 5,5,5-trichloro-1-bromo-2-pentene
C) 1,1,1-trichloro-5-bromo-2-pentene
D) 1,1,1-trichloro-5-bromo-3-pentyne

A) 1,1,1-trichloro-5-bromo-3-pentene
B) 5,5,5-trichloro-1-bromo-2-pentene
C) 1,1,1-trichloro-5-bromo-2-pentene
D) 1,1,1-trichloro-5-bromo-3-pentyne
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24
Give the name of the molecule CH3CH=CHCH2CH3.
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25
Name the molecule below. 

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26
Carboxylic acids are characterized by the presence of the -COOH group.
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27
Name the following molecule. 
A) 1-hexyne
B) 2-ethynyl butane
C) 2-ethyl-3-butyne
D) 3-methyl-1-pentyne
E) 3-methyl-4-pentyne

A) 1-hexyne
B) 2-ethynyl butane
C) 2-ethyl-3-butyne
D) 3-methyl-1-pentyne
E) 3-methyl-4-pentyne
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28
Draw the structural formula for 3-methyl-2-hexene.
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29
Classify the following molecule. 
A) acid
B) aldehyde
C) amine
D) ketone
E) carbonyl

A) acid
B) aldehyde
C) amine
D) ketone
E) carbonyl
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30
Draw the structural formula for 3-ethyl-4-methylheptane.
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31
Which of the following has the least number of carbon-oxygen bonds?
A) ketone
B) alcohol
C) ether
D) ester
E) Two of the above are equal.
A) ketone
B) alcohol
C) ether
D) ester
E) Two of the above are equal.
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32
The general name given to hydrocarbons with triple bonds is
A) alkenes
B) alkynes
C) alkanes
D) unsaturated hydrocarbons
E) aromatic hydrocarbons
A) alkenes
B) alkynes
C) alkanes
D) unsaturated hydrocarbons
E) aromatic hydrocarbons
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33
Aldehydes are characterized by the presence of the -COH group (where carbon is double bonded to the oxygen atom and single bonded to the hydrogen).
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34
Which of the following has the greatest number of carbon-oxygen bonds?
A) ketone
B) ester
C) alcohol
D) amine
E) aldehyde
A) ketone
B) ester
C) alcohol
D) amine
E) aldehyde
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35
Give the name of the molecule. 

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36
Amines are characterized by the presence of the -OH group.
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37
Esters often have sweet, fruity odors.
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38
CH3C CCH2CH2Cl is named
A) 1-chloro-3-pentyne
B) 5-chloro-2-pentene
C) 1-acetylenyl-3-chloropropane
D) 5-chloro-2-pentyne
E) 1-chloro-3-pentene
A) 1-chloro-3-pentyne
B) 5-chloro-2-pentene
C) 1-acetylenyl-3-chloropropane
D) 5-chloro-2-pentyne
E) 1-chloro-3-pentene
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39
Draw the structural formula for 4-ethyl-2-octyne.
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40
Draw the structural formula for 2-phenylpropane.
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41
Acetic acid is the common name for ethanoic acid.
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42
Name the following compound. 

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43
Draw the structural formula for pentanal.
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44
Identify the type of organic compound shown. 
A) aldehyde
B) ester
C) amine
D) ketone
E) none of these

A) aldehyde
B) ester
C) amine
D) ketone
E) none of these
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45
Write the structural formula for 3-isopropyl-3-heptanol.
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46
Name the following compound. 

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47
Name the following compound. 

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48
Which of the following is found in beverages such as wine?
A) methanol
B) ethanol
C) propanol
D) isopropanol
E) none of these
A) methanol
B) ethanol
C) propanol
D) isopropanol
E) none of these
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49
Draw the structural formula for 3-ethylhexanoic acid.
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50
Identify the type of organic compound shown. 
A) aldehyde
B) ester
C) amine
D) ketone
E) none of these

A) aldehyde
B) ester
C) amine
D) ketone
E) none of these
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51
Nylon is an example of a
A) copolymer
B) homopolymer
C) dimer
D) two of these
E) none of these
A) copolymer
B) homopolymer
C) dimer
D) two of these
E) none of these
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52
Draw the structural formula for 3,4-dichlorooctanal.
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53
Name the following. 
A) 2-chloro-3-ethyl-1-isopropylbutanone
B) isopropyl-chloromethylbutyl ketone
C) 2-butylchloroisobutanoyl methane
D) 4-chloro-2,5-dimethyl-3-heptanone
E) 3-methyl-4-chloro-1-isopropylpentanone

A) 2-chloro-3-ethyl-1-isopropylbutanone
B) isopropyl-chloromethylbutyl ketone
C) 2-butylchloroisobutanoyl methane
D) 4-chloro-2,5-dimethyl-3-heptanone
E) 3-methyl-4-chloro-1-isopropylpentanone
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54
Formic acid is the common name for pentanoic acid.
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55
Name the following compound.
CH3COOH
CH3COOH
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56
Name the following compound. 

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57
The name methanal is the systematic name for
A) acetone
B) formaldehyde
C) rubbing alcohol
D) acetaldehyde
E) water
A) acetone
B) formaldehyde
C) rubbing alcohol
D) acetaldehyde
E) water
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58
Teflon is an example of a
A) copolymer
B) homopolymer
C) dimer
D) two of these
E) none of these
A) copolymer
B) homopolymer
C) dimer
D) two of these
E) none of these
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