Deck 11: Gases and Their Properties

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Question
A glass column is filled with mercury and inverted in a pool of mercury.The mercury column stabilizes at a height of 736 mm above the pool of mercury.What is the pressure of the atmosphere?

A) 1.03 atm
B) 0.646 atm
C) 463 atm
D) 0.968 atm
E) 0.736 atm
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Question
A flexible container is filled with 49.00 L of gas at 333 Κ.Under conditions of constant pressure and moles of gas,what is the temperature of the gas when the volume is doubled?

A) 666.000 K
B) 167 K
C) 0.00600 K
D) 333.2 K
E) 1.22 K
Question
A flexible vessel is filled to a certain pressure with 93.00 L of gas.Under conditions of constant temperature and moles of gas,how does the volume of the gas change when the pressure of the gas is tripled?

A) The volume decreases by a factor of three.
B) The volume decreases by a factor of four.
C) The volume remains the same.
D) The volume decreases by a factor of two.
E) The volume increases by a factor of three.
Question
A gas sample is held at constant pressure.The gas occupies 3.62 L of volume when the temperature is 21.6°C.Determine the temperature at which the volume of the gas is 3.47 L.

A) 295 K
B) 283 K
C) 20.7 K
D) 556 K
E) 307 K
Question
A sample of methane,CH4,occupies a volume of 230.0 mL at 25°C and exerts a pressure of 900.0 mmHg.If the volume of the gas is allowed to expand to 680.0 mL at 298 K,what will be the pressure of the gas?

A) 2660 mmHg
B) 3630 mmHg
C) 304.4 mmHg
D) 0.01113 mmHg
E) 450.0 mmHg
Question
A flexible vessel contains 53 L of gas where the pressure is 1.1 atm.What will the volume be when the gas is compressed to a pressure of 0.91 atm,the temperature remaining constant?

A) 0.016 L
B) 44 L
C) 53 L
D) 0.038 L
E) 64 L
Question
Which of the following is the largest value of pressure?

A) 72539 Pa
B) 485 mm Hg
C) 12.6 psi
D) 0.677 atm
E) 14.9 in Hg
Question
A gas sample is heated from −20.0°C to 57.0°C and the volume is increased from 2.00 L to 4.50 L.If the initial pressure is 0.150 atm,what is the final pressure?

A) 0.0511 atm
B) -0.190 atm
C) 0.440 atm
D) 0.259 atm
E) 0.0869 atm
Question
Which of the following statements is true of Charles's law, <strong>Which of the following statements is true of Charles's law,   ?</strong> A) The volume of a gas varies proportionally with pressure. B) The volume of a gas sample varies directly with the absolute temperature. C) All gas samples of the same volume at STP contain the same number of atoms. D) The pressure of a gas sample varies inversely with volume. E) All gas samples of the same volume at STP contain the same number of molecules. <div style=padding-top: 35px> ?

A) The volume of a gas varies proportionally with pressure.
B) The volume of a gas sample varies directly with the absolute temperature.
C) All gas samples of the same volume at STP contain the same number of atoms.
D) The pressure of a gas sample varies inversely with volume.
E) All gas samples of the same volume at STP contain the same number of molecules.
Question
A flexible vessel contains 49.00 L of gas at a pressure of 2.81 atm.Under the conditions of constant temperature and constant number of moles of gas,what is the pressure of the gas when the volume of the vessel is quadrupled?

A) 0.702 atm
B) 11.2 atm
C) 1.42 atm
D) 2.81 atm
E) 0.0351 atm
Question
The local weather forecaster reports that the current barometric pressure is 29.2 inches of mercury.What is the current pressure in atmospheres?

A) 1 atm
B) 9.89 atm
C) 1.00 atm
D) 3.89 atm
E) 874 atm
Question
A sample of helium gas occupies 17.9 L at 23°C and 0.956 atm.What volume will it occupy at 40°C and 1.20 atm?

A) 23.8 L
B) 24.8 L
C) 13.5 L
D) 15.1 L
E) 18.1 L
Question
A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)

A) 18.2 mmHg
B) <strong>A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.2 mmHg B)   mmHg C) 1.84 mmHg D) 104 mmHg E)   mmHg <div style=padding-top: 35px> mmHg
C) 1.84 mmHg
D) 104 mmHg
E) <strong>A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.2 mmHg B)   mmHg C) 1.84 mmHg D) 104 mmHg E)   mmHg <div style=padding-top: 35px> mmHg
Question
A particular gas exerts a pressure of 5.35 × 104 Pa.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)​

A) 0.528 ​atm
B) 5.28 × 109 atm
C) 0.542 ​atm
D) 0.535 ​atm
E) 5.42 × 109 atm
Question
It is possible to make a barometer using a liquid other than mercury.What would be the height (in meters)of a column of dichloromethane at a pressure of 0.790 atm,given that 0.790 atm is equal to a 0.600 m column of mercury and the densities of mercury and dichloromethane are 13.5 g/cm3 and 1.33 g/cm3,respectively.

A) 6.09 m
B) 0.164 m
C) 0.0592 m
D) 0.799 m
E) 1.25 m
Question
A certain person has a body temperature of 309 K.On a cold day,what volume of air at 276 K must this person with a lung capacity of 3.1 L breathe in to fill his lungs?

A) 3.47 L
B) 2.77 L
C) 2.92 L
D) 5.54 L
E) none of these
Question
A balloon has a volume of 2.52 liters at 24.0°C.The balloon is heated to 48.0°C.Calculate the new volume of the balloon.

A) 2.52 L
B) 2.72 L
C) 2.33 L
D) 5.04 L
E) 1.26 L
Question
A particular gas exerts a pressure of 2.97 bar.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 3.01 atm
B) 2.23 × 103 atm
C) 2.29 × 103 atm
D) 2.93 atm
E) 2.97 atm
Question
A particular gas exerts a pressure of 681 mm Hg.What is this pressure in units of bar? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 5.11 × 105 bar
B) 5.24 × 105 bar
C) 690 bar
D) 0.884 bar
E) 0.908 bar
Question
Absolute zero is the point at which

A) a straight-line graph of V versus T (°C)intersects the origin.
B) a straight-line graph of 1/V versus P at constant T intersects the origin.
C) gaseous helium liquefies.
D) a straight-line graph of V versus 1/P at constant T intersects the origin.
E) a straight-line graph of V versus T (K)intersects the origin.
Question
A balloon is filled with He gas to a volume of 2.10 L at 35 °C.The balloon is placed in liquid nitrogen until its temperature reaches -196 °C.Assuming the pressure remains constant,what is the volume of the cooled balloon?

A) −0.375 L
B) 0.375 L
C) 0.525 L
D) 0.00909 L
E) 8.40 L
Question
What volume of oxygen will react with 21 mL of ethanol,assuming the gases are present at the same temperature and pressure? 2 CH3CH2OH(g)+ 6 O2(g)→ 4 CO2(g)+ 6 H2O(g)

A) 7.0 mL
B) 14 mL
C) 21 mL
D) 42 mL
E) 63 mL
Question
A 2.00-L glass soda bottle filled only with air is tightly capped at 19°C and 732.0 mmHg.If the bottle is placed in water at 89°C,what is the pressure in the bottle?

A) 156 mmHg
B) 907 mmHg
C) 3430 mmHg
D) 590 mmHg
E) 474 mmHg
Question
A 26.4-L sample of nitrogen at 7.50 atm and 24°C is simultaneously expanded to 58.4 L and heated to 35°C.What is the new pressure of the gas?

A) 4.94 atm
B) 3.52 atm
C) 141 atm
D) 198 atm
E) 3.27 atm
Question
Equal volumes of propane,C3H8,and carbon monoxide,CO,at the same temperature and pressure have the same ____.

A) chemical properties.
B) number of atoms.
C) average molecular speed.
D) density.
E) number of molecules.
Question
The pressure of O2 in a 15.0 L flask is 322 mm Hg at 44 °C.What mass of O2 is in the flask? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.244 g
B) 5.80 g
C) 7.82 g
D) 15.2 g
E) 56.3 g
Question
The temperature of a specific amount of gas in a sealed container changes from 40.0°C to 80.0°C.If the volume remains constant,the pressure will change from 755 mmHg to ___.

A) 755 mmHg
B) 378 mmHg
C) 1510 mmHg
D) 669 mmHg
E) 851 mmHg
Question
What is the pressure of a 52.5-L gas sample containing 1.57 mol of gas at 93.2°C? (R = 0.0821 L • atm/(K • mol),1 atm = 760 mmHg)

A) 1.74 × 102 mmHg
B) 1.18 × 10-3 mmHg
C) 0.899 mmHg
D) 6.83 × 102 mmHg
E) 8.45 × 102 mmHg
Question
What is the final volume of nitrogen gas if the pressure of 5.8 L of the gas is decreased to one-half of its original pressure,and its absolute temperature is increased to double the original temperature?

A) 2.9 L
B) 5.8 L
C) 12 L
D) 23 L
E) 1.5 L
Question
What volume is occupied by 35.0 g of C2H2 at 471 mm Hg and 21 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 29.0 L
B) 52.3 L
C) 3.74 L
D) 20.1 L
E) 0.0689 L
Question
A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?

A) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
B) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
C) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
D) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
E) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
Question
A 45.0 L gas cylinder contains 988 g He at 23 °C.What is the pressure inside the cylinder? (R = 0.08206 L⋅atm/mol⋅K)

A) 10.4 atm
B) 41.4 atm
C) 101 atm
D) 133 atm
E) 533 atm
Question
You have a 30.0 L cylinder of helium at a pressure of 132 atm and a temperature of 19 °C.The He is used to fill balloons to a volume of 1.80 L at 745 mm Hg and 27 °C.How many balloons can be filled with He? Assume that the cylinder can provide He until its internal pressure reaches 1.00 atm (i.e.,there are 131 atmospheres of usable He in the cylinder).

A) 1.90 × 102
B) 1.06 × 102
C) 4.13 × 103
D) 7.41 × 103
E) 2.29 × 103
Question
Gaseous chlorine is held in two separate containers at identical temperatures and pressures.The volume of container 1 is 1.30 L,and it contains 6.70 mol of the gas.The volume of container 2 is 2.75 L.How many moles of the gas are in container 2?

A) 14.2 mol
B) 24.0 mol
C) 0.534 mol
D) 3.17 mol
E) None of these
Question
If 0.357 g of CH4 gas is introduced into an empty 1.75 L flask at 25 °C,what will be the pressure inside the flask? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.952 atm
B) 0.261 atm
C) 0.311 atm
D) 0.419 atm
E) 4.99 atm
Question
You have 34.5 g of O2 gas in a container with twice the volume as one with CO2 gas.The pressure and temperature of both containers are the same.Calculate the mass of carbon dioxide gas you have in the container.

A) 0.539 g
B) 47.4 g
C) 2.16 g
D) 23.7 g
E) none of these
Question
Which of the following gases has the greatest density at 35 °C and 450 mm Hg?

A) CH4
B) Ar
C) N2
D) Cl2
E) C3H8
Question
The volume of a sample of gas measured at 50.0°C and 1.00 atm pressure is 2.00 L.What must the final temperature be in order for the gas to have a final volume of 3.00 L at 1.00 atm pressure?

A) 211.5°C
B) 75.0°C
C) -198.0°C
D) 33.3°C
E) -57.7°C
Question
What volume of gaseous silane,SiH4,has the same moles of gas as 9.00 L of helium gas at the same temperature and pressure?

A) 54.0 L
B) 1.50 L
C) 9.00 L
D) 1.80 L
E) 45.0 L
Question
What volume does 49.0 g of N2 gas occupy at STP? (R = 0.08206 L⋅atm/mol⋅K)

A) 78 L
B) 2 L
C) 39 L
D) 61 L
E) None of these
Question
The density of H2 gas in a rigid container is 0.117 g/L at 55 °C.What is the pressure of hydrogen in the flask if it is heated to 125 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.142 atm
B) 0.194 atm
C) 1.56 atm
D) 1.90 atm
E) 3.55 atm
Question
An excess of sodium hydroxide is treated with 2.3 L of dry hydrogen iodide gas measured at STP to produce sodium iodide and water.What is the mass of sodium iodide formed in the process?

A) 1.15 g
B) 30.8 g
C) 15.4 g
D) 19 g
E) 345 g
Question
The following equation represents the partial combustion of methane,CH4. 2CH4(g)+ 3O2(g)→ 2CO(g)+ 4H2O(g)
At constant temperature and pressure,what is the maximum volume of carbon monoxide that can be obtained from 3.86 × 102 L of methane and 1.93 × 102 L of oxygen?

A) 5.79 × 102 L
B) 3.86 × 102 L
C) 1.35 × 103 L
D) 1.29 × 102 L
E) 7.72 × 102 L
Question
A mixture of KCl and KClO3 weighing 1.65 grams was heated; the dry O2 generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO3,which decomposes as follows: <strong>A mixture of KCl and KClO<sub>3</sub> weighing 1.65 grams was heated; the dry O<sub>2</sub> generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO<sub>3</sub>,which decomposes as follows:  </strong> A) 31.6% B) 47.4% C) 71.1% D) 8.67% E) 19.2% <div style=padding-top: 35px>

A) 31.6%
B) 47.4%
C) 71.1%
D) 8.67%
E) 19.2%
Question
Into a 2.82-liter container at 25°C are placed 1.23 moles of O2 gas and 3.20 moles of solid C (graphite).If the carbon and oxygen react completely to form CO(g),what will be the final pressure in the container at 25°C?

A) 21.3 atm
B) 11 atm
C) 1.79 atm
D) 27.7 atm
E) none of these
Question
Under conditions of constant volume and moles of gas,at what temperature will 742 mm Hg of CH4 gas have the same density as 742 mm Hg of O2 gas at 273 K?

A) 137 K
B) 146 K
C) 191 K
D) 275 K
E) 545 K
Question
The density of a gas is 1.25 g/L at STP.What is its molar mass?

A) 25.0 g/mol
B) 37.6 g/mol
C) 17.9 g/mol
D) 22.4 g/mol
E) 28.0 g/mol
Question
What volume of O2,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO3? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO3(s)→ 2 KCl(s)+ 3 O2(g)

A) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px> mL
B) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px> mL
C) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px> mL
D) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px> mL
E) none of these
Question
Which of the following samples contains the fewest moles of gas?

A) 1.00 L of CH4 at STP
B) 1.00 L of Ar at STP
C) 1.00 L of NH3 at STP
D) 1.00 L of H2 at 0.0°C and 1.28 atm
E) 1.00 L of HCl at 20°C and 1.00 atm
Question
A 3.98 gram sample of a certain diatomic gas occupies a volume of 2.73-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L⋅atm/mol⋅K)

A) H2
B) F2
C) Cl2
D) N2
E) O2
Question
Sodium azide decomposes rapidly to produce nitrogen gas. 2 NaN3(s)→ 2 Na(s)+ 3 N2(g)
What mass of sodium azide will inflate a 60.0 L airbag for a car to a pressure of 1.50 atm at 32 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 2.40 g
B) 67.2 g
C) 156 g
D) 234 g
E) 351 g
Question
A 22.4 L high pressure reaction vessel is charged with 0.5930 mol of iron powder and 1.65 atm of oxygen gas at standard temperature.On heating,the iron and oxygen react according to the balanced reaction below. 4Fe(s)+ 3O2(g)→ 2Fe2O3(s)
After the reaction vessel returns to standard temperature,and assuming the reaction goes to completion,what pressure of oxygen remains?

A) 1.20 atm
B) 1.65 atm
C) 0.858 atm
D) 0.445 atm
E) 0.00 atm
Question
One way to isolate metals from their ores is by a chemical reaction of the metal oxide with carbon as shown below (M = metal): <strong>One way to isolate metals from their ores is by a chemical reaction of the metal oxide with carbon as shown below (M = metal):   If 31.75 g of a metal oxide reacts with excess carbon to form 4.07 L of CO<sub>2</sub> at 100°C and 1.50 atm,what is the identity of the metal?</strong> A) Hg B) Mg C) Cu D) Pb E) Cd <div style=padding-top: 35px> If 31.75 g of a metal oxide reacts with excess carbon to form 4.07 L of CO2 at 100°C and 1.50 atm,what is the identity of the metal?

A) Hg
B) Mg
C) Cu
D) Pb
E) Cd
Question
The density of ethane,C2H6 (30.1 g/mol),at 27°C and 1.27 atm pressure is ___.(R = 0.08206 L⋅atm/mol⋅K)

A) 1.55 g/L
B) 18.6 g/L
C) 1.34 g/L
D) 0.644 g/L
E) 0.154 g/L
Question
What volume of <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L <div style=padding-top: 35px> measured at STP is produced by the combustion of 6.50 g of natural gas <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L <div style=padding-top: 35px> in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K) <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L <div style=padding-top: 35px>

A) 4.54 L
B) 20 L
C) 9.08 L
D) 18.2 L
E) 3.25 L
Question
When 0.5000 grams of an unknown hydrocarbon,CxHy,is completely combusted with excess oxygen,1.037 L CO2 gas and is produced at 98.3 °C and 1.000 atm.What is the empirical formula of the hydrocarbon? (R = 0.08206 L⋅atm/mol⋅K)

A) CH
B) CH2
C) C2H3
D) C3H5
E) C3H8
Question
An unknown gaseous hydrocarbon contains 85.63% C.Its density is 1.524 g/L at 0.665 atm and 373 K.What is the molecular formula of the gas? (R = 0.08206 L⋅atm/mol⋅K)

A) C2H4
B) C3H6
C) C4H8
D) C5H10
E) C6H12
Question
Ammonia gas is synthesized according to the balanced equation below. N2(g)+ 3 H2(g)→ 2 NH3(g)
If 1.55 L N2 react with 4.92 L H2,what is the theoretical yield (in liters)of NH3? Assume that the volumes of reactants and products are measured at the same temperature and pressure.

A) 1.55 L
B) 3.10 L
C) 3.28 L
D) 4.93 L
E) 6.42 L
Question
Aqueous hydrochloric acid reacts with magnesium to produce hydrogen gas according to the balanced equation below. 2 HCl(aq)+ Mg(s)→ MgCl2(aq)+ H2(g)
If 250.0 mL of 3.00 M HCl is combined with 9.92 g Mg,what volume of hydrogen gas can be produced? Assume the temperature and pressure of the gas are 25 °C and 0.988 atm,respectively.(R = 0.08206 L⋅atm/mol⋅K)

A) 4.60 L
B) 5.05 L
C) 9.28 L
D) 10.1 L
E) 18.6 L
Question
What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH4NO2(s)→ N2(g)+ 2H2O(g)

A) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px> L
B) 22.4 L
C) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px> L
D) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px> L
E) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px> L
Question
A gaseous mixture containing 1.5 mol Ar and 3.5 mol CO2 has a total pressure of 8.4 atm.What is the partial pressure of CO2?

A) 3 atm
B) 2 atm
C) 25 atm
D) 6 atm
E) 8 atm
Question
Methane gas,CH4,effuses through a barrier at a rate of 0.568 mL/minute.If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute,what is the molar mass of the gas?

A) 20.8 g/mol
B) 28.0 g/mol
C) 32.0 g/mol
D) 44.0 g/mol
E) 64.0 g/mol
Question
The molar mass of an unknown gas was measured by an effusion experiment.It was found that the unknown gas effused at a rate of 2.2 × 106 mol/hr,whereas the nitrogen gas effused at a rate of 3.1 × 106 mol/hr.The molar mass of the gas is _____.

A) 24 g/mol
B) 40 g/mol
C) 14 g/mol
D) 33 g/mol
E) 56 g/mol
Question
How long will it take 10.0 mL of Ne gas to effuse through a porous barrier if it has been observed that 125 minutes are required for 10.0 mL of Ar gas to effuse through the same barrier?

A) 1.41 min.
B) 31.9 min.
C) 63.1 min.
D) 88.8 min.
E) 176 min.
Question
The rate of effusion of an unknown gas was measured and found to be 10.7 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O2)gas is 12.6 mL/min.Based on this information,the identity of the unknown gas could be:

A) N2CH2OF2
B) CO2N2O
C) NO
D) C2H6
E) none of these
Question
A pressure of 1.00 atm has a metric equivalent of 1.01 × 105 ________.
Question
In which of the following reactions will the pressure increase upon completion of the reaction at constant temperature?

A) C(s)+ O2(g)→ CO2(g)
B) 2NO(g)+ O2(g)→ 2NO2(g)
C) C2H6O(l)+ 3O2(g)→ 2CO2(g)+ 3H2O(l)
D) 4NH3(g)+ 5O2(g)→ 4NO(g)+ 6H2O(g)
E) Cl2(g)+ 3F2(g)→ 2ClF3(g)
Question
Carbon monoxide reacts with oxygen to form carbon dioxide. 2 CO(g)+ O2(g)→ 2 CO2(g)
In a 1.00 L flask,4.30 atm of CO reacts with 2.50 atm of O2.Assuming that the temperature remains constant,what is the final pressure in the flask?

A) 1.80 atm
B) 2.50 atm
C) 4.30 atm
D) 4.65 atm
E) 6.80 atm
Question
Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L⋅atm/mol⋅K) 2 H2O( <strong>Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L⋅atm/mol⋅K) 2 H<sub>2</sub>O(   )→ 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g)</strong> A) 1.47 g B) 2.95 g C) 4.42 g D) 6.63 g E) 8.84 g <div style=padding-top: 35px> )→ 2 H2(g)+ O2(g)

A) 1.47 g
B) 2.95 g
C) 4.42 g
D) 6.63 g
E) 8.84 g
Question
What is the volume occupied by a mixture of 0.329 mol of N2 gas and 0.329 mol of O2 gases at 0.83 atm and 23.2°C?

A) 5.79 × 102 L
B) 19.3 L
C) 0.755 L
D) 1.51 L
E) 9.65 L
Question
The partial pressures of CH4,N2,and O2 in a sample of a gas mixture were found to be 191 mm Hg,451 mm Hg,and 583 mm Hg,respectively.Calculate the mole fraction of nitrogen.

A) 1
B) 0.
C) 20.8
D) 0..
E) 0
Question
At STP,as the molar mass of the molecules that make up a pure gas increases,the

A) root mean square speed of the molecules increases.
B) root mean square speed of the molecules decreases.
C) root mean square speed of the molecules remains constant.
D) root mean square speed increases to a maximum,then decreases.
E) none of the above.
Question
Calculate the root-mean-square velocity for the O2 molecules in a sample of O2 gas at 20.9°C.(R = 8.3145 J/K⋅mol)

A) 15.14 m/s
B) 127.6 m/s
C) 276.3 m/s
D) 478.6 m/s
E) 9.115 × 1026 m/s
Question
Non-ideal behavior for a gas is most likely to be observed under conditions of

A) high temperature and low pressure.
B) high temperature and high pressure.
C) low temperature and low pressure.
D) standard temperature and pressure.
E) low temperature and high pressure.
Question
Place the following gases in order of increasing average velocity at 300 K: Ar,CH4,N2,and N2O.

A) Ar < CH4 < N2 < N2O
B) N2O < Ar < N2 < CH4
C) N2O < N2 < CH4 < Ar
D) Ar < N2 < N2O < CH4
E) CH4 < N2 < N2O < Ar
Question
A vessel with a volume of 17.3 L contains 2.80 g of nitrogen gas,0.403 g of hydrogen gas,and 79.9 g of argon gas.At 25°C,what is the pressure in the vessel?

A) 117 atm
B) 0 atm
C) 4 atm
D) 3 atm
E) 56 atm
Question
Real gases are those that

A) only behave ideally at high pressures or low temperatures
B) deviate from ideal behavior
C) are only available naturally in the earth's atmosphere
D) are called real gases because their behavior can easily be modeled
E) have an even number of protons
Question
The layer of the atmosphere closest to the Earth's surface is the ________.

A) thermosphere
B) stratosphere
C) stratopause
D) troposphere
E) mesosphere
Question
A 10.0 L flask at 318 K contains a mixture of Ar and CH4 with a total pressure of 1.040 atm.If the mole fraction of Ar is 0.715,what is the mass percent of Ar?

A) 13.8%
B) 68.8%
C) 71.5%
D) 82.9%
E) 86.2%
Question
Real gases deviate from ideal behavior because of intermolecular forces and _____.

A) pressures within the chemical bonds
B) nonzero molecular volumes
C) ionization energies
D) molecular vibrations
E) a wide distribution of molecular speeds
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Deck 11: Gases and Their Properties
1
A glass column is filled with mercury and inverted in a pool of mercury.The mercury column stabilizes at a height of 736 mm above the pool of mercury.What is the pressure of the atmosphere?

A) 1.03 atm
B) 0.646 atm
C) 463 atm
D) 0.968 atm
E) 0.736 atm
0.968 atm
2
A flexible container is filled with 49.00 L of gas at 333 Κ.Under conditions of constant pressure and moles of gas,what is the temperature of the gas when the volume is doubled?

A) 666.000 K
B) 167 K
C) 0.00600 K
D) 333.2 K
E) 1.22 K
666.000 K
3
A flexible vessel is filled to a certain pressure with 93.00 L of gas.Under conditions of constant temperature and moles of gas,how does the volume of the gas change when the pressure of the gas is tripled?

A) The volume decreases by a factor of three.
B) The volume decreases by a factor of four.
C) The volume remains the same.
D) The volume decreases by a factor of two.
E) The volume increases by a factor of three.
The volume decreases by a factor of three.
4
A gas sample is held at constant pressure.The gas occupies 3.62 L of volume when the temperature is 21.6°C.Determine the temperature at which the volume of the gas is 3.47 L.

A) 295 K
B) 283 K
C) 20.7 K
D) 556 K
E) 307 K
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5
A sample of methane,CH4,occupies a volume of 230.0 mL at 25°C and exerts a pressure of 900.0 mmHg.If the volume of the gas is allowed to expand to 680.0 mL at 298 K,what will be the pressure of the gas?

A) 2660 mmHg
B) 3630 mmHg
C) 304.4 mmHg
D) 0.01113 mmHg
E) 450.0 mmHg
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6
A flexible vessel contains 53 L of gas where the pressure is 1.1 atm.What will the volume be when the gas is compressed to a pressure of 0.91 atm,the temperature remaining constant?

A) 0.016 L
B) 44 L
C) 53 L
D) 0.038 L
E) 64 L
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7
Which of the following is the largest value of pressure?

A) 72539 Pa
B) 485 mm Hg
C) 12.6 psi
D) 0.677 atm
E) 14.9 in Hg
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8
A gas sample is heated from −20.0°C to 57.0°C and the volume is increased from 2.00 L to 4.50 L.If the initial pressure is 0.150 atm,what is the final pressure?

A) 0.0511 atm
B) -0.190 atm
C) 0.440 atm
D) 0.259 atm
E) 0.0869 atm
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9
Which of the following statements is true of Charles's law, <strong>Which of the following statements is true of Charles's law,   ?</strong> A) The volume of a gas varies proportionally with pressure. B) The volume of a gas sample varies directly with the absolute temperature. C) All gas samples of the same volume at STP contain the same number of atoms. D) The pressure of a gas sample varies inversely with volume. E) All gas samples of the same volume at STP contain the same number of molecules. ?

A) The volume of a gas varies proportionally with pressure.
B) The volume of a gas sample varies directly with the absolute temperature.
C) All gas samples of the same volume at STP contain the same number of atoms.
D) The pressure of a gas sample varies inversely with volume.
E) All gas samples of the same volume at STP contain the same number of molecules.
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10
A flexible vessel contains 49.00 L of gas at a pressure of 2.81 atm.Under the conditions of constant temperature and constant number of moles of gas,what is the pressure of the gas when the volume of the vessel is quadrupled?

A) 0.702 atm
B) 11.2 atm
C) 1.42 atm
D) 2.81 atm
E) 0.0351 atm
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11
The local weather forecaster reports that the current barometric pressure is 29.2 inches of mercury.What is the current pressure in atmospheres?

A) 1 atm
B) 9.89 atm
C) 1.00 atm
D) 3.89 atm
E) 874 atm
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12
A sample of helium gas occupies 17.9 L at 23°C and 0.956 atm.What volume will it occupy at 40°C and 1.20 atm?

A) 23.8 L
B) 24.8 L
C) 13.5 L
D) 15.1 L
E) 18.1 L
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13
A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)

A) 18.2 mmHg
B) <strong>A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.2 mmHg B)   mmHg C) 1.84 mmHg D) 104 mmHg E)   mmHg mmHg
C) 1.84 mmHg
D) 104 mmHg
E) <strong>A physics experiment is conducted at a pressure of 13.8 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.2 mmHg B)   mmHg C) 1.84 mmHg D) 104 mmHg E)   mmHg mmHg
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14
A particular gas exerts a pressure of 5.35 × 104 Pa.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)​

A) 0.528 ​atm
B) 5.28 × 109 atm
C) 0.542 ​atm
D) 0.535 ​atm
E) 5.42 × 109 atm
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15
It is possible to make a barometer using a liquid other than mercury.What would be the height (in meters)of a column of dichloromethane at a pressure of 0.790 atm,given that 0.790 atm is equal to a 0.600 m column of mercury and the densities of mercury and dichloromethane are 13.5 g/cm3 and 1.33 g/cm3,respectively.

A) 6.09 m
B) 0.164 m
C) 0.0592 m
D) 0.799 m
E) 1.25 m
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16
A certain person has a body temperature of 309 K.On a cold day,what volume of air at 276 K must this person with a lung capacity of 3.1 L breathe in to fill his lungs?

A) 3.47 L
B) 2.77 L
C) 2.92 L
D) 5.54 L
E) none of these
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17
A balloon has a volume of 2.52 liters at 24.0°C.The balloon is heated to 48.0°C.Calculate the new volume of the balloon.

A) 2.52 L
B) 2.72 L
C) 2.33 L
D) 5.04 L
E) 1.26 L
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18
A particular gas exerts a pressure of 2.97 bar.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 3.01 atm
B) 2.23 × 103 atm
C) 2.29 × 103 atm
D) 2.93 atm
E) 2.97 atm
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19
A particular gas exerts a pressure of 681 mm Hg.What is this pressure in units of bar? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 5.11 × 105 bar
B) 5.24 × 105 bar
C) 690 bar
D) 0.884 bar
E) 0.908 bar
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20
Absolute zero is the point at which

A) a straight-line graph of V versus T (°C)intersects the origin.
B) a straight-line graph of 1/V versus P at constant T intersects the origin.
C) gaseous helium liquefies.
D) a straight-line graph of V versus 1/P at constant T intersects the origin.
E) a straight-line graph of V versus T (K)intersects the origin.
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21
A balloon is filled with He gas to a volume of 2.10 L at 35 °C.The balloon is placed in liquid nitrogen until its temperature reaches -196 °C.Assuming the pressure remains constant,what is the volume of the cooled balloon?

A) −0.375 L
B) 0.375 L
C) 0.525 L
D) 0.00909 L
E) 8.40 L
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22
What volume of oxygen will react with 21 mL of ethanol,assuming the gases are present at the same temperature and pressure? 2 CH3CH2OH(g)+ 6 O2(g)→ 4 CO2(g)+ 6 H2O(g)

A) 7.0 mL
B) 14 mL
C) 21 mL
D) 42 mL
E) 63 mL
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23
A 2.00-L glass soda bottle filled only with air is tightly capped at 19°C and 732.0 mmHg.If the bottle is placed in water at 89°C,what is the pressure in the bottle?

A) 156 mmHg
B) 907 mmHg
C) 3430 mmHg
D) 590 mmHg
E) 474 mmHg
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24
A 26.4-L sample of nitrogen at 7.50 atm and 24°C is simultaneously expanded to 58.4 L and heated to 35°C.What is the new pressure of the gas?

A) 4.94 atm
B) 3.52 atm
C) 141 atm
D) 198 atm
E) 3.27 atm
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25
Equal volumes of propane,C3H8,and carbon monoxide,CO,at the same temperature and pressure have the same ____.

A) chemical properties.
B) number of atoms.
C) average molecular speed.
D) density.
E) number of molecules.
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26
The pressure of O2 in a 15.0 L flask is 322 mm Hg at 44 °C.What mass of O2 is in the flask? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.244 g
B) 5.80 g
C) 7.82 g
D) 15.2 g
E) 56.3 g
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27
The temperature of a specific amount of gas in a sealed container changes from 40.0°C to 80.0°C.If the volume remains constant,the pressure will change from 755 mmHg to ___.

A) 755 mmHg
B) 378 mmHg
C) 1510 mmHg
D) 669 mmHg
E) 851 mmHg
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28
What is the pressure of a 52.5-L gas sample containing 1.57 mol of gas at 93.2°C? (R = 0.0821 L • atm/(K • mol),1 atm = 760 mmHg)

A) 1.74 × 102 mmHg
B) 1.18 × 10-3 mmHg
C) 0.899 mmHg
D) 6.83 × 102 mmHg
E) 8.45 × 102 mmHg
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29
What is the final volume of nitrogen gas if the pressure of 5.8 L of the gas is decreased to one-half of its original pressure,and its absolute temperature is increased to double the original temperature?

A) 2.9 L
B) 5.8 L
C) 12 L
D) 23 L
E) 1.5 L
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30
What volume is occupied by 35.0 g of C2H2 at 471 mm Hg and 21 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 29.0 L
B) 52.3 L
C) 3.74 L
D) 20.1 L
E) 0.0689 L
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31
A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?

A) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)
B) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)
C) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)
D) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)
E) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 9.00 L and 350°C?</strong> A)   B)   C)   D)   E)
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32
A 45.0 L gas cylinder contains 988 g He at 23 °C.What is the pressure inside the cylinder? (R = 0.08206 L⋅atm/mol⋅K)

A) 10.4 atm
B) 41.4 atm
C) 101 atm
D) 133 atm
E) 533 atm
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33
You have a 30.0 L cylinder of helium at a pressure of 132 atm and a temperature of 19 °C.The He is used to fill balloons to a volume of 1.80 L at 745 mm Hg and 27 °C.How many balloons can be filled with He? Assume that the cylinder can provide He until its internal pressure reaches 1.00 atm (i.e.,there are 131 atmospheres of usable He in the cylinder).

A) 1.90 × 102
B) 1.06 × 102
C) 4.13 × 103
D) 7.41 × 103
E) 2.29 × 103
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34
Gaseous chlorine is held in two separate containers at identical temperatures and pressures.The volume of container 1 is 1.30 L,and it contains 6.70 mol of the gas.The volume of container 2 is 2.75 L.How many moles of the gas are in container 2?

A) 14.2 mol
B) 24.0 mol
C) 0.534 mol
D) 3.17 mol
E) None of these
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35
If 0.357 g of CH4 gas is introduced into an empty 1.75 L flask at 25 °C,what will be the pressure inside the flask? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.952 atm
B) 0.261 atm
C) 0.311 atm
D) 0.419 atm
E) 4.99 atm
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36
You have 34.5 g of O2 gas in a container with twice the volume as one with CO2 gas.The pressure and temperature of both containers are the same.Calculate the mass of carbon dioxide gas you have in the container.

A) 0.539 g
B) 47.4 g
C) 2.16 g
D) 23.7 g
E) none of these
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37
Which of the following gases has the greatest density at 35 °C and 450 mm Hg?

A) CH4
B) Ar
C) N2
D) Cl2
E) C3H8
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38
The volume of a sample of gas measured at 50.0°C and 1.00 atm pressure is 2.00 L.What must the final temperature be in order for the gas to have a final volume of 3.00 L at 1.00 atm pressure?

A) 211.5°C
B) 75.0°C
C) -198.0°C
D) 33.3°C
E) -57.7°C
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39
What volume of gaseous silane,SiH4,has the same moles of gas as 9.00 L of helium gas at the same temperature and pressure?

A) 54.0 L
B) 1.50 L
C) 9.00 L
D) 1.80 L
E) 45.0 L
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40
What volume does 49.0 g of N2 gas occupy at STP? (R = 0.08206 L⋅atm/mol⋅K)

A) 78 L
B) 2 L
C) 39 L
D) 61 L
E) None of these
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41
The density of H2 gas in a rigid container is 0.117 g/L at 55 °C.What is the pressure of hydrogen in the flask if it is heated to 125 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 0.142 atm
B) 0.194 atm
C) 1.56 atm
D) 1.90 atm
E) 3.55 atm
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42
An excess of sodium hydroxide is treated with 2.3 L of dry hydrogen iodide gas measured at STP to produce sodium iodide and water.What is the mass of sodium iodide formed in the process?

A) 1.15 g
B) 30.8 g
C) 15.4 g
D) 19 g
E) 345 g
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43
The following equation represents the partial combustion of methane,CH4. 2CH4(g)+ 3O2(g)→ 2CO(g)+ 4H2O(g)
At constant temperature and pressure,what is the maximum volume of carbon monoxide that can be obtained from 3.86 × 102 L of methane and 1.93 × 102 L of oxygen?

A) 5.79 × 102 L
B) 3.86 × 102 L
C) 1.35 × 103 L
D) 1.29 × 102 L
E) 7.72 × 102 L
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44
A mixture of KCl and KClO3 weighing 1.65 grams was heated; the dry O2 generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO3,which decomposes as follows: <strong>A mixture of KCl and KClO<sub>3</sub> weighing 1.65 grams was heated; the dry O<sub>2</sub> generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO<sub>3</sub>,which decomposes as follows:  </strong> A) 31.6% B) 47.4% C) 71.1% D) 8.67% E) 19.2%

A) 31.6%
B) 47.4%
C) 71.1%
D) 8.67%
E) 19.2%
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45
Into a 2.82-liter container at 25°C are placed 1.23 moles of O2 gas and 3.20 moles of solid C (graphite).If the carbon and oxygen react completely to form CO(g),what will be the final pressure in the container at 25°C?

A) 21.3 atm
B) 11 atm
C) 1.79 atm
D) 27.7 atm
E) none of these
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46
Under conditions of constant volume and moles of gas,at what temperature will 742 mm Hg of CH4 gas have the same density as 742 mm Hg of O2 gas at 273 K?

A) 137 K
B) 146 K
C) 191 K
D) 275 K
E) 545 K
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47
The density of a gas is 1.25 g/L at STP.What is its molar mass?

A) 25.0 g/mol
B) 37.6 g/mol
C) 17.9 g/mol
D) 22.4 g/mol
E) 28.0 g/mol
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48
What volume of O2,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO3? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO3(s)→ 2 KCl(s)+ 3 O2(g)

A) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these mL
B) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these mL
C) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these mL
D) <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.882 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L⋅atm/mol⋅K) 2 KClO<sub>3</sub>(s)→ 2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these mL
E) none of these
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49
Which of the following samples contains the fewest moles of gas?

A) 1.00 L of CH4 at STP
B) 1.00 L of Ar at STP
C) 1.00 L of NH3 at STP
D) 1.00 L of H2 at 0.0°C and 1.28 atm
E) 1.00 L of HCl at 20°C and 1.00 atm
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50
A 3.98 gram sample of a certain diatomic gas occupies a volume of 2.73-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L⋅atm/mol⋅K)

A) H2
B) F2
C) Cl2
D) N2
E) O2
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51
Sodium azide decomposes rapidly to produce nitrogen gas. 2 NaN3(s)→ 2 Na(s)+ 3 N2(g)
What mass of sodium azide will inflate a 60.0 L airbag for a car to a pressure of 1.50 atm at 32 °C? (R = 0.08206 L⋅atm/mol⋅K)

A) 2.40 g
B) 67.2 g
C) 156 g
D) 234 g
E) 351 g
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52
A 22.4 L high pressure reaction vessel is charged with 0.5930 mol of iron powder and 1.65 atm of oxygen gas at standard temperature.On heating,the iron and oxygen react according to the balanced reaction below. 4Fe(s)+ 3O2(g)→ 2Fe2O3(s)
After the reaction vessel returns to standard temperature,and assuming the reaction goes to completion,what pressure of oxygen remains?

A) 1.20 atm
B) 1.65 atm
C) 0.858 atm
D) 0.445 atm
E) 0.00 atm
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53
One way to isolate metals from their ores is by a chemical reaction of the metal oxide with carbon as shown below (M = metal): <strong>One way to isolate metals from their ores is by a chemical reaction of the metal oxide with carbon as shown below (M = metal):   If 31.75 g of a metal oxide reacts with excess carbon to form 4.07 L of CO<sub>2</sub> at 100°C and 1.50 atm,what is the identity of the metal?</strong> A) Hg B) Mg C) Cu D) Pb E) Cd If 31.75 g of a metal oxide reacts with excess carbon to form 4.07 L of CO2 at 100°C and 1.50 atm,what is the identity of the metal?

A) Hg
B) Mg
C) Cu
D) Pb
E) Cd
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54
The density of ethane,C2H6 (30.1 g/mol),at 27°C and 1.27 atm pressure is ___.(R = 0.08206 L⋅atm/mol⋅K)

A) 1.55 g/L
B) 18.6 g/L
C) 1.34 g/L
D) 0.644 g/L
E) 0.154 g/L
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55
What volume of <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L measured at STP is produced by the combustion of 6.50 g of natural gas <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K) <strong>What volume of   measured at STP is produced by the combustion of 6.50 g of natural gas   in excess oxygen? (R = 0.08206 L⋅atm/mol⋅K)  </strong> A) 4.54 L B) 20 L C) 9.08 L D) 18.2 L E) 3.25 L

A) 4.54 L
B) 20 L
C) 9.08 L
D) 18.2 L
E) 3.25 L
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56
When 0.5000 grams of an unknown hydrocarbon,CxHy,is completely combusted with excess oxygen,1.037 L CO2 gas and is produced at 98.3 °C and 1.000 atm.What is the empirical formula of the hydrocarbon? (R = 0.08206 L⋅atm/mol⋅K)

A) CH
B) CH2
C) C2H3
D) C3H5
E) C3H8
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57
An unknown gaseous hydrocarbon contains 85.63% C.Its density is 1.524 g/L at 0.665 atm and 373 K.What is the molecular formula of the gas? (R = 0.08206 L⋅atm/mol⋅K)

A) C2H4
B) C3H6
C) C4H8
D) C5H10
E) C6H12
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58
Ammonia gas is synthesized according to the balanced equation below. N2(g)+ 3 H2(g)→ 2 NH3(g)
If 1.55 L N2 react with 4.92 L H2,what is the theoretical yield (in liters)of NH3? Assume that the volumes of reactants and products are measured at the same temperature and pressure.

A) 1.55 L
B) 3.10 L
C) 3.28 L
D) 4.93 L
E) 6.42 L
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59
Aqueous hydrochloric acid reacts with magnesium to produce hydrogen gas according to the balanced equation below. 2 HCl(aq)+ Mg(s)→ MgCl2(aq)+ H2(g)
If 250.0 mL of 3.00 M HCl is combined with 9.92 g Mg,what volume of hydrogen gas can be produced? Assume the temperature and pressure of the gas are 25 °C and 0.988 atm,respectively.(R = 0.08206 L⋅atm/mol⋅K)

A) 4.60 L
B) 5.05 L
C) 9.28 L
D) 10.1 L
E) 18.6 L
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60
What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH4NO2(s)→ N2(g)+ 2H2O(g)

A) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L L
B) 22.4 L
C) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L L
D) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L L
E) <strong>What is the total volume of gases produced at 819 K and 1.00 atm pressure when 256 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s)→ N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L L
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61
A gaseous mixture containing 1.5 mol Ar and 3.5 mol CO2 has a total pressure of 8.4 atm.What is the partial pressure of CO2?

A) 3 atm
B) 2 atm
C) 25 atm
D) 6 atm
E) 8 atm
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62
Methane gas,CH4,effuses through a barrier at a rate of 0.568 mL/minute.If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute,what is the molar mass of the gas?

A) 20.8 g/mol
B) 28.0 g/mol
C) 32.0 g/mol
D) 44.0 g/mol
E) 64.0 g/mol
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63
The molar mass of an unknown gas was measured by an effusion experiment.It was found that the unknown gas effused at a rate of 2.2 × 106 mol/hr,whereas the nitrogen gas effused at a rate of 3.1 × 106 mol/hr.The molar mass of the gas is _____.

A) 24 g/mol
B) 40 g/mol
C) 14 g/mol
D) 33 g/mol
E) 56 g/mol
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64
How long will it take 10.0 mL of Ne gas to effuse through a porous barrier if it has been observed that 125 minutes are required for 10.0 mL of Ar gas to effuse through the same barrier?

A) 1.41 min.
B) 31.9 min.
C) 63.1 min.
D) 88.8 min.
E) 176 min.
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65
The rate of effusion of an unknown gas was measured and found to be 10.7 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O2)gas is 12.6 mL/min.Based on this information,the identity of the unknown gas could be:

A) N2CH2OF2
B) CO2N2O
C) NO
D) C2H6
E) none of these
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66
A pressure of 1.00 atm has a metric equivalent of 1.01 × 105 ________.
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67
In which of the following reactions will the pressure increase upon completion of the reaction at constant temperature?

A) C(s)+ O2(g)→ CO2(g)
B) 2NO(g)+ O2(g)→ 2NO2(g)
C) C2H6O(l)+ 3O2(g)→ 2CO2(g)+ 3H2O(l)
D) 4NH3(g)+ 5O2(g)→ 4NO(g)+ 6H2O(g)
E) Cl2(g)+ 3F2(g)→ 2ClF3(g)
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68
Carbon monoxide reacts with oxygen to form carbon dioxide. 2 CO(g)+ O2(g)→ 2 CO2(g)
In a 1.00 L flask,4.30 atm of CO reacts with 2.50 atm of O2.Assuming that the temperature remains constant,what is the final pressure in the flask?

A) 1.80 atm
B) 2.50 atm
C) 4.30 atm
D) 4.65 atm
E) 6.80 atm
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69
Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L⋅atm/mol⋅K) 2 H2O( <strong>Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L⋅atm/mol⋅K) 2 H<sub>2</sub>O(   )→ 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g)</strong> A) 1.47 g B) 2.95 g C) 4.42 g D) 6.63 g E) 8.84 g )→ 2 H2(g)+ O2(g)

A) 1.47 g
B) 2.95 g
C) 4.42 g
D) 6.63 g
E) 8.84 g
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70
What is the volume occupied by a mixture of 0.329 mol of N2 gas and 0.329 mol of O2 gases at 0.83 atm and 23.2°C?

A) 5.79 × 102 L
B) 19.3 L
C) 0.755 L
D) 1.51 L
E) 9.65 L
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71
The partial pressures of CH4,N2,and O2 in a sample of a gas mixture were found to be 191 mm Hg,451 mm Hg,and 583 mm Hg,respectively.Calculate the mole fraction of nitrogen.

A) 1
B) 0.
C) 20.8
D) 0..
E) 0
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72
At STP,as the molar mass of the molecules that make up a pure gas increases,the

A) root mean square speed of the molecules increases.
B) root mean square speed of the molecules decreases.
C) root mean square speed of the molecules remains constant.
D) root mean square speed increases to a maximum,then decreases.
E) none of the above.
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73
Calculate the root-mean-square velocity for the O2 molecules in a sample of O2 gas at 20.9°C.(R = 8.3145 J/K⋅mol)

A) 15.14 m/s
B) 127.6 m/s
C) 276.3 m/s
D) 478.6 m/s
E) 9.115 × 1026 m/s
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74
Non-ideal behavior for a gas is most likely to be observed under conditions of

A) high temperature and low pressure.
B) high temperature and high pressure.
C) low temperature and low pressure.
D) standard temperature and pressure.
E) low temperature and high pressure.
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75
Place the following gases in order of increasing average velocity at 300 K: Ar,CH4,N2,and N2O.

A) Ar < CH4 < N2 < N2O
B) N2O < Ar < N2 < CH4
C) N2O < N2 < CH4 < Ar
D) Ar < N2 < N2O < CH4
E) CH4 < N2 < N2O < Ar
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76
A vessel with a volume of 17.3 L contains 2.80 g of nitrogen gas,0.403 g of hydrogen gas,and 79.9 g of argon gas.At 25°C,what is the pressure in the vessel?

A) 117 atm
B) 0 atm
C) 4 atm
D) 3 atm
E) 56 atm
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77
Real gases are those that

A) only behave ideally at high pressures or low temperatures
B) deviate from ideal behavior
C) are only available naturally in the earth's atmosphere
D) are called real gases because their behavior can easily be modeled
E) have an even number of protons
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78
The layer of the atmosphere closest to the Earth's surface is the ________.

A) thermosphere
B) stratosphere
C) stratopause
D) troposphere
E) mesosphere
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79
A 10.0 L flask at 318 K contains a mixture of Ar and CH4 with a total pressure of 1.040 atm.If the mole fraction of Ar is 0.715,what is the mass percent of Ar?

A) 13.8%
B) 68.8%
C) 71.5%
D) 82.9%
E) 86.2%
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80
Real gases deviate from ideal behavior because of intermolecular forces and _____.

A) pressures within the chemical bonds
B) nonzero molecular volumes
C) ionization energies
D) molecular vibrations
E) a wide distribution of molecular speeds
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