Deck 7: Gases,liquids,and Solids
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Deck 7: Gases,liquids,and Solids
1
Which gas law describes the relationship between the volume and temperature of a sample of gas at constant pressure?
A)Boyle's law
B)Charles's law
C)Gay-Lussac's law
D)Avogadro's law
E)Dalton's law
A)Boyle's law
B)Charles's law
C)Gay-Lussac's law
D)Avogadro's law
E)Dalton's law
Charles's law
2
How many moles are contained in 5.33 L of O2 at standard temperature and pressure?
A)5.33 mol of O2
B)1.00 mol of O2
C)0.238 mol of O2
D)22.4 mol of O2
E)4.20 mol of O2
A)5.33 mol of O2
B)1.00 mol of O2
C)0.238 mol of O2
D)22.4 mol of O2
E)4.20 mol of O2
0.238 mol of O2
3
A scuba diver typically begins a dive with a compressed air tank at 2,350 psi. What is this pressure expressed in units of Pa?
A)0.0232 Pa
B)3.09 Pa
C)2.38 × 108 Pa
D)1.62 × 107 Pa
E)45.5 Pa
A)0.0232 Pa
B)3.09 Pa
C)2.38 × 108 Pa
D)1.62 × 107 Pa
E)45.5 Pa
1.62 × 107 Pa
4
A birthday balloon contains helium at a pressure of 815 torr. What is this pressure expressed in units of mm Hg?
A)815 mm Hg
B)1.07 mm Hg
C)0.815 mm Hg
D)6.19 × 105 mm Hg
A)815 mm Hg
B)1.07 mm Hg
C)0.815 mm Hg
D)6.19 × 105 mm Hg
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5
A scuba diver typically begins a dive with a compressed air tank at 2,350 psi. What is this pressure expressed in units of atmospheres?
A)160. atm
B)2.35 atm
C)3.45 × 104 atm
D)3.09 atm
E)45.5 atm
A)160. atm
B)2.35 atm
C)3.45 × 104 atm
D)3.09 atm
E)45.5 atm
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6
A scuba diver typically begins a dive with a compressed air tank at 2,350 psi. What is this pressure expressed in units of mm Hg?
A)160. mm Hg
B)3.09 mm Hg
C)1.21 × 105 mm Hg
D)1.79 × 106 mm Hg
E)45.5 mm Hg
A)160. mm Hg
B)3.09 mm Hg
C)1.21 × 105 mm Hg
D)1.79 × 106 mm Hg
E)45.5 mm Hg
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7
How many moles of gas are contained in a scuba diver's 12.6-L tank filled with 3422 psi of air at 25 °C?
A)1760 moles
B)2.10 × 104 moles
C)120. moles
D)1430 moles
A)1760 moles
B)2.10 × 104 moles
C)120. moles
D)1430 moles
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8
Which cylinder at STP will contain the greatest mass of gas particles?
A)a 5.0-L cylinder of neon
B)a 5.0-L cylinder of helium
C)a 5.0-L cylinder of nitrogen
D)a 5.0-L cylinder of hydrogen
E)All of the cylinders contain the same mass of gas particles.
A)a 5.0-L cylinder of neon
B)a 5.0-L cylinder of helium
C)a 5.0-L cylinder of nitrogen
D)a 5.0-L cylinder of hydrogen
E)All of the cylinders contain the same mass of gas particles.
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9
A 54.2 L sample of gas at 115 K is heated to 345 K,at constant pressure. What volume does the gas now occupy?
A)2.15 × 106 L
B)163 L
C)18.1 L
D)732 L
A)2.15 × 106 L
B)163 L
C)18.1 L
D)732 L
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10
A weather balloon contains 233 L of helium at 22 °C and 760. mm Hg. What is the volume of the balloon when it ascends to an altitude where the temperature is -54 °C and 511 mm Hg?
A)2.24 × 107 L
B)467 L
C)116 L
D)257 L
A)2.24 × 107 L
B)467 L
C)116 L
D)257 L
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11
Which cylinder at STP will contain the greatest number of gas particles?
A)a 5.0-L cylinder of neon
B)a 5.0-L cylinder of helium
C)a 5.0-L cylinder of nitrogen
D)a 5.0-L cylinder of hydrogen
E)All of the cylinders contain the same number of gas particles.
A)a 5.0-L cylinder of neon
B)a 5.0-L cylinder of helium
C)a 5.0-L cylinder of nitrogen
D)a 5.0-L cylinder of hydrogen
E)All of the cylinders contain the same number of gas particles.
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12
A sample of gas contains four gases with the following partial pressures: He (113 mm Hg),Ne (184 mm Hg),Ar (35 mm Hg),and Xe (445 mm Hg). What is the total pressure of the sample?
A)777 mm Hg
B)760. mm Hg
C)445 mm Hg
D)332 mm Hg
A)777 mm Hg
B)760. mm Hg
C)445 mm Hg
D)332 mm Hg
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13
A sample of neon gas has a volume of 5.0 mL at a pressure of 1.50 atm. What is the pressure exerted by the gas if the volume is increased to 30.0 mL,at constant temperature?
A)0.25 atm
B)9.0 atm
C)1.5 atm
D)0.21 atm
E)7.5 atm
A)0.25 atm
B)9.0 atm
C)1.5 atm
D)0.21 atm
E)7.5 atm
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14
Which assumption is NOT part of the kinetic-molecular theory of gases?
A)A gas consists of particles that move randomly and rapidly.
B)The size of gas particles is small compared to the space between the particles.
C)Because the space between gas particles is large,gas particles exert no attractive forces on each other.
D)The kinetic energy of gas particles does not change with increasing temperature.
E)When gas particles collide with each other,they rebound and travel in new directions.
A)A gas consists of particles that move randomly and rapidly.
B)The size of gas particles is small compared to the space between the particles.
C)Because the space between gas particles is large,gas particles exert no attractive forces on each other.
D)The kinetic energy of gas particles does not change with increasing temperature.
E)When gas particles collide with each other,they rebound and travel in new directions.
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15
A balloon that contains 0.500 L of helium at 25 °C is cooled to 11 °C,at a constant pressure. What volume does the balloon now occupy?
A)0.22 L
B)1.1 L
C)0.477 L
D)0.525 L
E)0.500 L
A)0.22 L
B)1.1 L
C)0.477 L
D)0.525 L
E)0.500 L
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16
A gas cylinder containing 6.38 mol of neon has a pressure of 491 mm Hg at 295 K. If 3.22 mol of helium is added to this cylinder,at constant temperature and volume,what will be the pressure in the cylinder?
A)9.73 mm Hg
B)739 mm Hg
C)1460 mm Hg
D)248 mm Hg
A)9.73 mm Hg
B)739 mm Hg
C)1460 mm Hg
D)248 mm Hg
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17
A patient's systolic pressure is measured as 128 mm Hg. What is this pressure in units of atm?
A)128 atm
B)1.28 atm
C)0.168 atm
D)9.73 x 104 atm
E)8.71 atm
A)128 atm
B)1.28 atm
C)0.168 atm
D)9.73 x 104 atm
E)8.71 atm
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18
Consider the balanced reaction: Zn(s)+ 2 HCl(aq)→ ZnCl2(aq)+ H2(g). What volume of H2(g)at STP can be generated when 134 g of zinc reacts?
A)2.05 L
B)45.9 L
C)5.98 L
D)3.00 × 103 L
A)2.05 L
B)45.9 L
C)5.98 L
D)3.00 × 103 L
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19
The temperature of a 0.750-L gas sample at 25 °C and 2.00 atm is changed to 250 °C. What is the final pressure of the system,at constant volume?
A)20.0 atm
B)0.200 atm
C)3.51 atm
D)0.427 atm
A)20.0 atm
B)0.200 atm
C)3.51 atm
D)0.427 atm
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20
An aerosol can has a pressure of 1.86 atm. What is this pressure expressed in units of mm Hg?
A)1.86 mm Hg
B)1410 mm Hg
C)1860 mm Hg
D)0.00245 mm Hg
A)1.86 mm Hg
B)1410 mm Hg
C)1860 mm Hg
D)0.00245 mm Hg
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21
Which molecule(s)exhibit London dispersion forces?
A)Kl
B)CH4
C)NH3
D)HBr
E)All of the molecules exhibit London dispersion forces.
A)Kl
B)CH4
C)NH3
D)HBr
E)All of the molecules exhibit London dispersion forces.
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22
Surface tension measures which of the following?
A)A liquid's resistance to flow
B)A liquid's resistance to spreading out
C)A liquid's ability to boil at low temperatures
D)The molecular weight of a compound
A)A liquid's resistance to flow
B)A liquid's resistance to spreading out
C)A liquid's ability to boil at low temperatures
D)The molecular weight of a compound
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23
Three of the four phase changes below are endothermic. Which phase change is NOT endothermic?
A)Vaporization
B)Sublimation
C)Condensation
D)Melting
A)Vaporization
B)Sublimation
C)Condensation
D)Melting
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24
Which molecule(s)exhibit hydrogen bonding?
A)H2S
B)CH4
C)NH3
D)HCl
E)All of the molecules exhibit London dispersion forces.
A)H2S
B)CH4
C)NH3
D)HCl
E)All of the molecules exhibit London dispersion forces.
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25
Butane,CH3CH2CH2CH3,has the structure shown below. What is the strongest type of intermolecular force that exists between two butane molecules? 
A)London dispersion forces
B)Hydrogen bonding
C)Temporary dipole interactions
D)Dipole-dipole interactions

A)London dispersion forces
B)Hydrogen bonding
C)Temporary dipole interactions
D)Dipole-dipole interactions
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26
Which is an ionic solid?
A)KCl
B)Cu
C)SiO2
D)Rubber
E)Polyethylene
A)KCl
B)Cu
C)SiO2
D)Rubber
E)Polyethylene
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27
Which is a molecular solid?
A)MgCl2
B)Au
C)Glass
D)Graphite
E)Sucrose (C12H22O11)
A)MgCl2
B)Au
C)Glass
D)Graphite
E)Sucrose (C12H22O11)
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28
What volume does 7.50 × 1020 molecules of O2 occupy at STP?
A)22.4 L
B)1.68 × 1022 L
C)0.0279 L
D)2.79 L
A)22.4 L
B)1.68 × 1022 L
C)0.0279 L
D)2.79 L
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29
The normal boiling point of a liquid is the temperature at which its vapor pressure equals which of the following?
A)1 mm Hg
B)760 mm Hg
C)The pressure above the liquid
D)The vapor pressure of water
A)1 mm Hg
B)760 mm Hg
C)The pressure above the liquid
D)The vapor pressure of water
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30
A sample of gas contains four gases (He,Ne,Ar,and Xe)with the following partial pressures: He (43 mm Hg),Ar (835 mm Hg),and Xe (111 mm Hg). If the total pressure in the container is 1355 mm Hg,what is the partial pressure of Ne in the sample?
A)989 mm Hg
B)760. mm Hg
C)366 mm Hg
D)323 mm Hg
A)989 mm Hg
B)760. mm Hg
C)366 mm Hg
D)323 mm Hg
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31
Consider the two liquids A and B shown in closed containers. Which liquid has the higher vapor pressure? 
A)Liquid A
B)Liquid B
C)Both Liquids A and B have equal vapor pressures.
D)Not enough information is given.

A)Liquid A
B)Liquid B
C)Both Liquids A and B have equal vapor pressures.
D)Not enough information is given.
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32
Which phase change below is endothermic?
A)Deposition
B)Melting
C)Condensation
D)Freezing
A)Deposition
B)Melting
C)Condensation
D)Freezing
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33
Propanol,CH3CH2CH2OH,has the structure shown below. What is the strongest type of intermolecular force that exists between two propanol molecules? 
A)London dispersion forces
B)Hydrogen bonding
C)Temporary dipole interactions
D)Dipole-dipole interactions

A)London dispersion forces
B)Hydrogen bonding
C)Temporary dipole interactions
D)Dipole-dipole interactions
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34
Which is a network solid?
A)NaBr
B)Ag
C)SiO2
D)Na
E)Sucrose (C12H22O11)
A)NaBr
B)Ag
C)SiO2
D)Na
E)Sucrose (C12H22O11)
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35
Which of the following compounds has the highest boiling point?
A)
B)
C)
D)
A)

B)

C)

D)

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36
Which molecule has the lowest surface tension?
A)
B)
C)
D)
A)

B)

C)

D)

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37
Consider the two liquids A and B shown in closed containers. Which liquid exhibits the stronger intermolecular forces? 
A)Liquid A
B)Liquid B
C)Both Liquids A and B have equal vapor pressures.
D)Not enough information is given.

A)Liquid A
B)Liquid B
C)Both Liquids A and B have equal vapor pressures.
D)Not enough information is given.
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38
Which compound has the lowest boiling point?
A)
B)
C)
D)
A)

B)

C)

D)

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39
Which molecule(s)exhibit hydrogen bonding?
A)CH4
B)CHCl3
C)NF3
D)HF
E)All of the molecules exhibit hydrogen bonding.
A)CH4
B)CHCl3
C)NF3
D)HF
E)All of the molecules exhibit hydrogen bonding.
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40
What is the volume of 62.3 g of nitrogen gas at STP?
A)22.4 L
B)49.8 L
C)99.6 L
D)2.78 L
A)22.4 L
B)49.8 L
C)99.6 L
D)2.78 L
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41
Atmospheric pressure in interstellar space is approximately 1 × 10-17 torr at a temperature of -173 °C. How many gas molecules are present in 25,000 L of interstellar space (about the volume of a bedroom)?
A)2 × 107 molecules
B)4 × 10-17 molecules
C)2 × 1010 molecules
D)3 × 10-14 molecules
A)2 × 107 molecules
B)4 × 10-17 molecules
C)2 × 1010 molecules
D)3 × 10-14 molecules
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42
If the lungs of a child hold 0.11 mol of air in a volume of 2.8 L,then the lungs of an average female adult,with a volume is 4.6 L,can be expected to hold 0.18 mol of air.
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43
The value of the universal gas constant,R,changes as a function of temperature.
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44
When a sample of gas is compressed from 6.0 L to 2.0 L at a constant temperature,the pressure of the gas triples.
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45
London dispersion forces are the strongest type of intermolecular forces.
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46
When octane evaporates,what kind of attractive forces are overcome? 
A)Covalent bonding between carbon and hydrogen atoms
B)Hydrogen bonding between octane molecules
C)Dipole-dipole interactions between octane molecules
D)London dispersion forces between octane molecules

A)Covalent bonding between carbon and hydrogen atoms
B)Hydrogen bonding between octane molecules
C)Dipole-dipole interactions between octane molecules
D)London dispersion forces between octane molecules
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47
A gas cylinder containing 3.88 mol of helium has a pressure of 549 mm Hg at 298 K. If 1.22 mol of neon is added to this cylinder,at constant temperature and volume,the pressure will rise to 1750 mm Hg.
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48
London dispersion forces are exhibited by all covalent compounds.
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49
The stronger the intermolecular forces,the lower the vapor pressure of a substance at a given temperature.
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50
Hydrogen peroxide decomposes to give water and oxygen gas according to the equation below. If 3.0 moles of hydrogen peroxide decompose,what volume of oxygen gas is produced at a pressure of 1.0 atm and a temperature of 23 °C? 2 H2O2(l)→ 2 H2O(l)+ O2(g)
A)1.9 L of O2
B)2.8 L of O2
C)24 L of O2
D)36 L of O2
E)73 L of O2
A)1.9 L of O2
B)2.8 L of O2
C)24 L of O2
D)36 L of O2
E)73 L of O2
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51
At rest,the volume of air in the lungs is 615 mL at 760 mm Hg. When the volume of the lungs expands during inhalation,what happens to the pressure inside the lungs?
A)The pressure inside the lungs decreases,which draws air into the lungs.
B)The pressure inside the lungs increases,which forces air inside the lungs.
C)The pressure inside the lungs remains constant,and air readily flows into the lungs.
D)The pressure inside the lungs cannot be determined if the weight of the person is unknown.
A)The pressure inside the lungs decreases,which draws air into the lungs.
B)The pressure inside the lungs increases,which forces air inside the lungs.
C)The pressure inside the lungs remains constant,and air readily flows into the lungs.
D)The pressure inside the lungs cannot be determined if the weight of the person is unknown.
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52
The size of gas particles is large compared to the space between the particles.
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53
STP is defined as a pressure of exactly one atmosphere and a temperature of 25 °C.
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54
Whether a substance exists as a gas,liquid,or solid depends on the balance between the kinetic energy of its particles and the strength of the interactions between the particles.
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55
Which gas sample contains the largest number of moles?
A)4.0 L of O2 at 273 K and 530 mm Hg
B)4.5 L of N2 at 298 K and 610 mm Hg
C)3.8 L of He at 250 K and 880 mm Hg
D)5.0 L Ar at 300 K and 710 mm Hg
A)4.0 L of O2 at 273 K and 530 mm Hg
B)4.5 L of N2 at 298 K and 610 mm Hg
C)3.8 L of He at 250 K and 880 mm Hg
D)5.0 L Ar at 300 K and 710 mm Hg
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56
When the pressure and temperature are held constant,the volume of a gas is inversely proportional to the number of moles present.
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57
When a sample of gas is heated from 80 °C to 160 °C at a constant pressure,the volume of the gas doubles.
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58
Air pressure at the bottom of Death Valley,at 282 ft below sea level,is 776 mm Hg. What are the partial pressures of O2 and N2,which compose 21% and 78% of the atmosphere,respectively?
A)210 mm Hg O2 and 780 mm Hg N2
B)160 mm Hg O2 and 610 mm Hg N2
C)160 mm Hg O2 and 590 mm Hg N2
D)163 mm Hg O2 and 613 mm Hg N2
A)210 mm Hg O2 and 780 mm Hg N2
B)160 mm Hg O2 and 610 mm Hg N2
C)160 mm Hg O2 and 590 mm Hg N2
D)163 mm Hg O2 and 613 mm Hg N2
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59
If 10.0 g of Ne and 10.0 g of N2 are put into a 5.0 L container,the partial pressure of N2 will be less than the partial pressure of Ne in the container.
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60
An aerosol spray can with a volume of 350 mL registers a pressure of 4.5 atm at room temperature. What happens to the pressure of the gas inside the can if the can is stored outside during the winter months?
A)The pressure of the gas will remain at 4.5 atm.
B)The pressure of the gas will be greater than 4.5 atm.
C)The pressure of the gas will be less than 4.5 atm.
D)It is impossible to predict without knowing the amount of gas present inside the can.
A)The pressure of the gas will remain at 4.5 atm.
B)The pressure of the gas will be greater than 4.5 atm.
C)The pressure of the gas will be less than 4.5 atm.
D)It is impossible to predict without knowing the amount of gas present inside the can.
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61
Viscosity is a measure of the resistance of a liquid to flow freely.
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62
All solids are crystalline solids.
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63
When the volume of a sample of gas is doubled and the Kelvin temperature is doubled,the pressure of a sample remains constant.
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64
NaCl has a higher melting point than sucrose (C12H22O11).
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65
It requires less heat to melt a 10-g sample of water than to vaporize a 10-g sample of water.
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66
The higher the vapor pressure of a compound,the higher the boiling point of the compound.
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67
Gases expand to fill the volume and shape of their container because the rapidly moving particles experience negligible attractive forces for each other.
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68
Evaporation is an endothermic process.
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69
The numerical value of the universal gas constant,R,depends on its units.
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70
Polypropylene,a typical plastic,is an example of an amorphous solid.
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71
Freeze-drying removes water from foods by the process of sublimation.
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72
The pressure of a gas is proportional to its Kelvin temperature at constant volume and number of moles. Therefore increasing the temperature increases the pressure.
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73
Gas pressure is the result of particles of gas colliding with each other.
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74
Two molecules of dimethyl ether,whose structure is shown below,are capable of hydrogen bonding with each other. 

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75
If two compounds have the same molecular formula they will have the same boiling point.
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76
When the volume of a sample of gas is doubled and the Kelvin temperature is cut in half,the pressure of a sample remains constant.
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77
Ethylene glycol is expected to be less viscous than propane. 

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78
Energy is released when a less organized state is converted to a more organized state.
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79
The density of a sample of gas increases if the temperature is increased but the pressure is held constant.
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80
A 22.4 g sample of O2 will occupy less than 22.4 L at STP.
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