Deck 11: Gases and Their Properties

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Question
Which of the following is a correct statement of Charles's law, <strong>Which of the following is a correct statement of Charles's law,   ?</strong> A) The volume of a gas varies proportionally with the pressure. B) The volume of a gas sample varies directly with the absolute temperature. C) All gas samples of the same volume at STP contain the same number of atoms. D) The pressure of a gas sample varies inversely with the volume. E) All gas samples of the same volume at STP contain the same number of molecules. <div style=padding-top: 35px> ?

A) The volume of a gas varies proportionally with the pressure.
B) The volume of a gas sample varies directly with the absolute temperature.
C) All gas samples of the same volume at STP contain the same number of atoms.
D) The pressure of a gas sample varies inversely with the volume.
E) All gas samples of the same volume at STP contain the same number of molecules.
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Question
A flexible vessel contains 38.00 L of gas at a pressure of 2.74 atm.Under conditions of constant temperature and moles of gas,what is the volume of the gas when the pressure of the vessel is decreased by a factor of two?

A) 76.0 L
B) 19.0 L
C) 0.0132 L
D) 38 L
E) 3.80 L
Question
A flexible vessel is filled to a certain pressure with 67.00 L of gas.Under conditions of constant temperature and moles of gas,how does the pressure of the gas change when the volume of the gas is tripled?

A) The pressure decreases by a factor of three.
B) The pressure decreases by a factor of four.
C) The pressure increases by a factor of two.
D) The pressure remains the same.
E) The pressure decreases by a factor of two.
Question
A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)

A) 18.8 mmHg
B) <strong>A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.8 mmHg B)   mmHg C) 1.91 mmHg D) 107 mmHg E)   mmHg <div style=padding-top: 35px> mmHg
C) 1.91 mmHg
D) 107 mmHg
E) <strong>A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.8 mmHg B)   mmHg C) 1.91 mmHg D) 107 mmHg E)   mmHg <div style=padding-top: 35px> mmHg
Question
A sample of helium gas occupies 14.7 L at 23°C and 0.956 atm.What volume will it occupy at 40°C and 1.20 atm?

A) 19.5 L
B) 20.4 L
C) 11.1 L
D) 12.4 L
E) 14.9 L
Question
A glass column is filled with mercury and inverted in a pool of mercury.The mercury column stabilizes at a height of 736 mm above the pool of mercury.What is the pressure of the atmosphere?

A) 1.03 atm
B) 0.646 atm
C) 463 atm
D) 0.968 atm
E) 0.736 atm
Question
Absolute zero is the point at which

A) a straight-line graph of V versus T ( \circ C)intersects the origin.
B) a straight-line graph of 1/V versus P at constant T intersects the origin.
C) gaseous helium liquefies.
D) a straight-line graph of V versus 1/P at constant T intersects the origin.
E) a straight-line graph of V versus T (K)intersects the origin.
Question
A gas sample is held at constant pressure.The gas occupies 3.62 L of volume when the temperature is 21.6°C.Determine the temperature at which the volume of the gas is 3.49 L.

A) 295 K
B) 284 K
C) 20.8 K
D) 557 K
E) 306 K
Question
A sample of methane,CH4,occupies a volume of 202.0 mL at 25°C and exerts a pressure of 1155.0 mmHg.If the volume of the gas is allowed to expand to 690.0 mL at 298 K,what will be the pressure of the gas?

A) 3950 mmHg
B) 4030 mmHg
C) 338.1 mmHg
D) 0.01255 mmHg
E) 488.0 mmHg
Question
A particular gas exerts a pressure of 637 mmHg.What is this pressure in units of bar? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 4.78 ×\times 105 bar
B) 4.91 ×\times 105 bar
C) 645 bar
D) 0.827 bar
E) 0.849 bar
Question
A particular gas exerts a pressure of 7.54 ×\times 104 Pa.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 0.744 atm
B) 7.44 ×\times 109 atm
C) 0.764 atm
D) 0.754 atm
E) 7.64 ×\times 109 atm
Question
A certain person has a body temperature of 309 K.On a cold day,what volume of air at 278 K must this person with a lung capacity of 3.5 L breathe in to fill his lungs?

A) 3.89 L
B) 3.15 L
C) 3.31 L
D) 6.30 L
E) none of these
Question
Which of the following would represent the greatest pressure?

A) 58143 Pa
B) 307 mmHg
C) 11.7 psi
D) 0.624 atm
E) 17.7 in Hg
Question
A flexible container is charged with 30.00 L of gas at 313K.Under conditions of constant pressure and moles of gas,what is the volume of the gas when the temperature is decreased by a factor of two?

A) 15.0 L
B) 60.0 L
C) 0.0167 L
D) 30 L
E) 3.00 L
Question
It is possible to make a barometer using a liquid other than mercury.What would be the height (in meters)of a column of carbon tetrachloride at a pressure of 0.890 atm,given that 0.890 atm is equal to a 0.676 m column of mercury and the densities of mercury and carbon tetrachloride are 13.5 g/cm3 and 1.58 g/cm3,respectively.

A) 5.78 m
B) 0.173 m
C) 0.0792 m
D) 1.07 m
E) 0.936 m
Question
A gas sample is heated from -20.0°C to 57.0°C and the volume is increased from 2.00 L to 4.50 L.If the initial pressure is 0.140 atm,what is the final pressure?

A) 0.0477 atm
B) -0.177 atm
C) 0.411 atm
D) 0.242 atm
E) 0.0811 atm
Question
The local weather forecaster reports that the current barometric pressure is 30.4 inches of mercury.What is the current pressure in atmospheres?

A) 1.02 atm
B) 10.29 atm
C) 1.00 atm
D) 4.05 atm
E) 910 atm
Question
A flexible vessel contains 45 L of gas where the pressure is 1.4 atm.What will the volume be when the gas is compressed to a pressure of 0.82 atm,the temperature remaining constant?

A) 0.013 L
B) 26 L
C) 45 L
D) 0.049 L
E) 77 L
Question
A balloon has a volume of 2.32 liters at 24.0°C.The balloon is heated to 48.0°C.Calculate the new volume of the balloon.

A) 2.32 L
B) 2.51 L
C) 2.15 L
D) 4.64 L
E) 1.16 L
Question
A particular gas exerts a pressure of 3.43 bar.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 3.48 atm
B) 2.57 ×\times 103 atm
C) 2.64 ×\times 103 atm
D) 3.39 atm
E) 3.43 atm
Question
If 0.357 g of CH4 gas is introduced into an evacuated 1.75 L flask at 25 \circ C,what is the pressure inside the flask? (R = 0.08206 L.atm/mol.K)

A) 0.952 atm
B) 0.261 atm
C) 0.311 atm
D) 0.419 atm
E) 4.99 atm
Question
What volume of gaseous water,H2O,has the same moles \underline{\text{moles }} of gas as 10.0 L of xenon gas at the same temperature and pressure?

A) 40.0 L
B) 2.50 L
C) 10.0 L
D) 3.33 L
E) 30.0 L
Question
You have a 30.0 L cylinder of helium at a pressure of 132 atm and a temperature of 19 \circ C.The He is used to fill balloons to a volume of 1.80 L at 745 mm Hg and 27 \circ C.How many balloons can be filled with He? Assume that the cylinder can provide He until its internal pressure reaches 1.00 atm (i.e.,there are 131 atmospheres of usable He in the cylinder).

A) 1.90 ×\times 102
B) 1.06 ×\times 102
C) 4.13 ×\times 103
D) 7.41 ×\times 103
E) 2.29 ×\times 103
Question
A 25.0-L sample of nitrogen at 4.45 atm and 23°C is simultaneously expanded to 60.8 L and heated to 37°C.What is the new pressure of the gas?

A) 2.94 atm
B) 1.92 atm
C) 212 atm
D) 326 atm
E) 1.75 atm
Question
A 2.00-L glass soda bottle filled only with air is tightly capped at 19°C and 680.0 mmHg.If the bottle is placed in water at 81°C,what is the pressure in the bottle?

A) 160 mmHg
B) 824 mmHg
C) 2900 mmHg
D) 561 mmHg
E) 422 mmHg
Question
Equal volumes of propane,C3H8,and carbon monoxide,CO,at the same temperature and pressure have the same ____.

A) chemical properties.
B) number of atoms.
C) average molecular speed.
D) density.
E) number of molecules.
Question
The pressure of O2 in a 15.0 L flask is 322 mm Hg at 44 \circ C.What mass of O2 is in the flask? (R = 0.08206 L.atm/mol.K)

A) 0.244 g
B) 5.80 g
C) 7.82 g
D) 15.2 g
E) 56.3 g
Question
The temperature of a specific amount of gas in a sealed container changes from 20.0°C to 40.0°C.If the volume remains constant,the pressure will change from 735 mmHg to ___.

A) 735 mmHg
B) 368 mmHg
C) 1470 mmHg
D) 688 mmHg
E) 785 mmHg
Question
A balloon is filled with He gas to a volume of 2.10 L at 35 \circ C.The balloon is placed in liquid nitrogen until its temperature reaches -196 \circ C.Assuming the pressure remains constant,what is the volume of the cooled balloon?

A) (-0.375) L
B) 0.375 L
C) 0.525 L
D) 0.00909 L
E) 8.40 L
Question
For an ideal gas, which two variables are directly proportional to each other (if all other conditions remain constant)?
1. T and n
2. V and n
3. P and T

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 2 and 3
Question
You have 49.1 g of O2 gas in a container with twice the volume as one with CO2 gas.The pressure and temperature of both containers are the same.Calculate the mass of carbon dioxide gas you have in the container.

A) 0.767 g
B) 67.5 g
C) 3.07 g
D) 33.8 g
E) none of these
Question
The volume of a sample of gas measured at 75.0°C and 1.00 atm pressure is 5.00 L.What must the final temperature be in order for the gas to have a final volume of 4.00 L at 1.00 atm pressure?

A) 5.4°C
B) 60.0°C
C) -213.0°C
D) 93.8°C
E) 162.0°C
Question
What volume of oxygen will react with 21 mL of ethanol,assuming the gases are present at the same temperature and pressure?
2 CH3CH2OH(g)+ 6 O2(g) \to 4 CO2(g)+ 6 H2O(g)

A) 7.0 mL
B) 14 mL
C) 21 mL
D) 42 mL
E) 63 mL
Question
A 45.0 L gas cylinder contains 988 g He at 23 \circ C.What is the pressure inside the cylinder? (R = 0.08206 L.atm/mol.K)

A) 10.4 atm
B) 41.4 atm
C) 101 atm
D) 133 atm
E) 533 atm
Question
What volume is occupied by 35.0 g of C2H2 at 471 mm Hg and 21 \circ C? (R = 0.08206 L.atm/mol.K)

A) 29.0 L
B) 52.3 L
C) 3.74 L
D) 20.1 L
E) 0.0689 L
Question
A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?

A) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
B) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
C) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
D) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
E) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
Question
The pressure of 5.4 L of nitrogen gas in a flexible container is decreased to one-half its original pressure,and its absolute temperature is increased to double the original temperature.The volume is now

A) 2.7 L.
B) 5.4 L.
C) 11 L.
D) 22 L.
E) 1.4 L.
Question
Gaseous chlorine is held in two separate containers at identical temperature and pressure.The volume of container 1 is 1.30 L,and it contains 6.70 mol of the gas.The volume of container 2 is 2.33 L.How many moles of the gas are in container 2?

A) 12.0 mol
B) 20.3 mol
C) 0.452 mol
D) 3.74 mol
E) none of these
Question
Which of the following concerning the behavior of ideal gases is/are true?
1)Pressure is directly proportional to volume when temperature and moles of gas are held constant.
2)Pressure is directly proportional to moles of gas when temperature and volume are held constant.
3)Volume is inversely proportional to temperature when the pressure and moles of gas are held constant.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2 only
E) 2 and 3 only
Question
What is the pressure of a 59.6-L gas sample containing 3.01 mol of gas at 44.9°C? (R = 0.0821 L • atm/(K • mol),1 atm = 760 mmHg)

A) 1.41 ×\times 102 mmHg
B) 1.73 ×\times 10-3 mmHg
C) 1.32 mmHg
D) 1.00 ×\times 103 mmHg
E) 5.77 ×\times 102 mmHg
Question
A mixture of KCl and KClO3 weighing 1.34 grams was heated; the dry O2 generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO3,which decomposes as follows: <strong>A mixture of KCl and KClO<sub>3</sub> weighing 1.34 grams was heated; the dry O<sub>2</sub> generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO<sub>3</sub>,which decomposes as follows:  </strong> A) 38.9% B) 58.4% C) 87.6% D) 10.7% E) 23.7% <div style=padding-top: 35px>

A) 38.9%
B) 58.4%
C) 87.6%
D) 10.7%
E) 23.7%
Question
Into a 2.22-liter container at 25°C are placed 1.23 moles of O2 gas and 3.20 moles of solid C (graphite).If the carbon and oxygen react completely to form CO(g),what will be the final pressure in the container at 25°C?

A) 27.1 atm
B) 13.5 atm
C) 2.27 atm
D) 35.2 atm
E) none of these
Question
The following equation represents the partial combustion of methane,CH4.
2CH4(g)+ 3O2(g) \to 2CO(g)+ 4H2O(g)
At constant temperature and pressure,what is the maximum volume of carbon monoxide that can be obtained from 3.39 ×\times 102 L of methane and 1.70 ×\times 102 L of oxygen?

A) 5.09 ×\times 102 L
B) 3.39 ×\times 102 L
C) 1.19 ×\times 103 L
D) 1.13 ×\times 102 L
E) 6.78 ×\times 102 L
Question
The density of ethane,C2H6 (30.1 g/mol),at 32°C and 1.17 atm pressure is ___.(R = 0.08206 L.atm/mol.K)

A) 1.41 g/L
B) 17.2 g/L
C) 1.34 g/L
D) 0.711 g/L
E) 0.144 g/L
Question
An excess of sodium hydroxide is treated with 3.3 L of dry hydrogen chloride gas measured at STP,producing sodium chloride and water.What is the mass of sodium chloride is formed?

A) 1.65 g
B) 17.2 g
C) 8.6 g
D) 14 g
E) 193 g
Question
One way to isolate metals from their ores is to react the metal oxide with carbon as shown in the following reaction (M = metal): <strong>One way to isolate metals from their ores is to react the metal oxide with carbon as shown in the following reaction (M = metal):   If 34.14 g of a metal oxide reacted with excess carbon and 4.38 L of CO<sub>2</sub> formed at 100°C and 1.50 atm,what is the identity of the metal?</strong> A) Hg B) Mg C) Cu D) Zn E) Cd <div style=padding-top: 35px>
If 34.14 g of a metal oxide reacted with excess carbon and 4.38 L of CO2 formed at 100°C and 1.50 atm,what is the identity of the metal?

A) Hg
B) Mg
C) Cu
D) Zn
E) Cd
Question
What volume of <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L <div style=padding-top: 35px> measured at STP is produced by the combustion of 6.46 g of natural gas <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L <div style=padding-top: 35px>
In excess oxygen? (R = 0.08206 L.atm/mol.K) <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L <div style=padding-top: 35px>

A) 4.51 L
B) 19.7 L
C) 9.02 L
D) 18.0 L
E) 3.23 L
Question
Sodium azide decomposes rapidly to produce nitrogen gas.2 NaN3(s) \to 2 Na(s)+ 3 N2(g)
What mass of sodium azide will inflate a 60.0 L airbag for a car to a pressure of 1.50 atm at 32 \circ C? (R = 0.08206 L.atm/mol.K)

A) 2.40 g
B) 67.2 g
C) 156 g
D) 234 g
E) 351 g
Question
At what temperature does 742 mm Hg of CH4 gas have the same density as 742 mm Hg of O2 gas at 273 K?

A) 137 K
B) 146 K
C) 191 K
D) 275 K
E) 545 K
Question
When 0.5000 grams of an unknown hydrocarbon,CxHy,is completely combusted with excess oxygen,1.037 L CO2 gas and is produced at 98.3 \circ C and 1.000 atm.What is the empirical formula of the hydrocarbon? (R = 0.08206 L.atm/mol.K)

A) CH
B) CH2
C) C2H3
D) C3H5
E) C3H8
Question
The density of H2 gas in a rigid container is 0.117 g/L at 55 \circ C.What is the pressure of hydrogen in the flask if it is heated to 125 \circ C? (R = 0.08206 L.atm/mol.K)

A) 0.142 atm
B) 0.194 atm
C) 1.56 atm
D) 1.90 atm
E) 3.55 atm
Question
Which of the following gases has the greatest density at 35 \circ C and 450 mm Hg?

A) CH4
B) Ar
C) N2
D) Cl2
E) C3H8
Question
The density of a gas is 1.96 g/L at STP.What is its molar mass?

A) 65.2 g/mol
B) 58.9 g/mol
C) 11.4 g/mol
D) 22.4 g/mol
E) 43.9 g/mol
Question
Which of the following samples contains the fewest moles of gas?

A) 1.00 L of CH4 at STP
B) 1.00 L of Ar at -10.0°C and 1.00 atm
C) 1.00 L of NH3 at 10°C and 1.00 atm
D) 1.00 L of H2 at 0.0°C and 1.76 atm
E) 1.00 L of HCl at 20°C and 1.00 atm
Question
What mass of O2 is required to produce 5.00 L NO2 at 305 K and 752 mm Hg? (R = 0.08206 L.atm/mol.K)
2 NO(g)+ O2(g) \to 2 NO2(g)

A) 0.198 g
B) 1.58 g
C) 3.16 g
D) 5.00 g
E) 6.33 g
Question
What volume of O2,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO3? Assume 100% yield.(R = 0.08206 L.atm/mol.K)
2 KClO3(s) \to 2 KCl(s)+ 3 O2(g)

A)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px>  mL
B)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px>  mL
C)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px>  mL
D)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these <div style=padding-top: 35px>  mL
E) none of these
Question
Ammonia gas is synthesized according to the balanced equation below.
N2(g)+ 3 H2(g) \to 2 NH3(g)
If 1.55 L N2 react with 4.92 L H2,what is the theoretical yield (in liters)of NH3? Assume that the volumes of reactants and products are measured at the same temperature and pressure.

A) 1.55 L
B) 3.10 L
C) 3.28 L
D) 4.93 L
E) 6.42 L
Question
A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)

A) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
B) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
C) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
D) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
E) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)   <div style=padding-top: 35px>
Question
What volume does 40.5 g of N2 occupy at STP? (R = 0.08206 L.atm/mol.K)

A) 64.8 L
B) 1.81 L
C) 32.4 L
D) 50.7 L
E) none of these
Question
Aqueous hydrochloric acid reacts with magnesium to produce hydrogen gas according to the balanced equation below.
2 HCl(aq)+ Mg(s) \to MgCl2(aq)+ H2(g)
If 250.0 mL of 3.00 M HCl is combined with 9.92 g Mg,what volume of hydrogen gas can be produced? Assume the temperature and pressure of the gas are 25 \circ C and 0.988 atm,respectively.(R = 0.08206 L.atm/mol.K)

A) 4.60 L
B) 5.05 L
C) 9.28 L
D) 10.1 L
E) 18.6 L
Question
What is the volume occupied by a mixture of 0.203 mol of N2 and 0.203 mol of O2 gases at 1.16 atm and 44.7°C?

A) 2.74 ×\times 102 L
B) 9.13 L
C) 0.642 L
D) 1.28 L
E) 4.57 L
Question
Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L.atm/mol.K)
2 H2O(  <strong>Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L.atm/mol.K) 2 H<sub>2</sub>O(   ) \to  2 H<sub>2</sub>(g)+ O<sub>2</sub>(g)</strong> A) 1.47 g B) 2.95 g C) 4.42 g D) 6.63 g E) 8.84 g <div style=padding-top: 35px>  ) \to 2 H2(g)+ O2(g)

A) 1.47 g
B) 2.95 g
C) 4.42 g
D) 6.63 g
E) 8.84 g
Question
What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction?
NH4NO2(s) \to 0 N2(g)+ 2H2O(g)

A)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px>  L
B) 22.4 L
C)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px>  L
D)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px>  L
E)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L <div style=padding-top: 35px>  L
Question
At STP,as the molar mass of the molecules that make up a pure gas increases,the

A) root mean square speed of the molecules increases.
B) root mean square speed of the molecules decreases.
C) root mean square speed of the molecules remains constant.
D) root mean square speed increases to a maximum,then decreases.
E) none of the above.
Question
An unknown gaseous hydrocarbon contains 85.63% C.Its density is 1.524 g/L at 0.665 atm and 373 K.What is the molecular formula of the gas? (R = 0.08206 L.atm/mol.K)

A) C2H4
B) C3H6
C) C4H8
D) C5H10
E) C6H12
Question
A 22.4 L high pressure reaction vessel is charged with 0.3750 mol of iron powder and 1.78 atm of oxygen gas at standard temperature.On heating,the iron and oxygen react according to the balanced reaction below.
4Fe(s)+ 3O2(g) \to 2Fe2O3(s)
After the reaction vessel returns to standard temperature,and assuming the reaction goes to completion,what pressure of oxygen remains?

A) 1.50 atm
B) 1.78 atm
C) 1.28 atm
D) 0.281 atm
E) 0.00 atm
Question
The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O2)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:

A) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these <div style=padding-top: 35px>
B) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these <div style=padding-top: 35px>
C) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these <div style=padding-top: 35px>
D) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these <div style=padding-top: 35px>
E) none of these
Question
Which of the following statements are postulates of the kinetic-molecular theory of gases?
1)Gas particles are in constant,random motion.
2)The distance between gas particles is large in comparison to their size.
3)The average kinetic energy of gas particles is proportional to the kelvin temperature.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 1,2,and 3
Question
A vessel with a volume of 26.9 L contains 2.80 g of nitrogen gas,0.605 g of hydrogen gas,and 79.9 g of argon gas.At 25°C,what is the pressure in the vessel?

A) 75.5 atm
B) 0.183 atm
C) 2.55 atm
D) 2.18 atm
E) 58.7 atm
Question
The partial pressures of CH4,N2,and O2 in a sample of a gas mixture were found to be 183 mmHg,493 mmHg,and 551 mmHg,respectively.Calculate the mole fraction of nitrogen.

A) 0.725
B) 0.359
C) 19.7
D) 0.449
E) 0.402
Question
The layer of the atmosphere closest to the Earth's surface is the ________.

A) thermosphere
B) stratosphere
C) stratopause
D) troposphere
E) mesosphere
Question
How long will it take 10.0 mL of Ne gas to effuse through a porous barrier if it has been observed that 125 minutes are required for 10.0 mL of Ar gas to effuse through the same barrier?

A) 1.41 min.
B) 31.9 min.
C) 63.1 min.
D) 88.8 min.
E) 176 min.
Question
The molar mass of an unknown gas was measured by an effusion experiment.It was found that the unknown gas effused at a rate of 3.7 ×\times 10-6 mol/hr,whereas nitrogen gas effused at a rate of 4.3 ×\times 10-6mol/hr.The molar mass of the gas is

A) 26 g/mol.
B) 33 g/mol.
C) 21 g/mol.
D) 30 g/mol.
E) 38 g/mol.
Question
Methane gas,CH4,effuses through a barrier at a rate of 0.568 mL/minute.If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute,what is the molar mass of the gas?

A) 20.8 g/mol
B) 28.0 g/mol
C) 32.0 g/mol
D) 44.0 g/mol
E) 64.0 g/mol
Question
Carbon monoxide reacts with oxygen to form carbon dioxide.
2 CO(g)+ O2(g) \to 2 CO2(g)
In a 1.00 L flask,4.30 atm of CO reacts with 2.50 atm of O2.Assuming that the temperature remains constant,what is the final pressure in the flask?

A) 1.80 atm
B) 2.50 atm
C) 4.30 atm
D) 4.65 atm
E) 6.80 atm
Question
Calculate the root-mean-square velocity for the O2 molecules in a sample of O2 gas at 24.9°C.(R = 8.3145 J/K.mol)

A) 15.24 m/s
B) 139.3 m/s
C) 278.2 m/s
D) 481.9 m/s
E) 9.177 ×\times 1026 m/s
Question
In which of the following reactions will the pressure increase upon completion of the reaction at constant temperature?

A) C(s)+ O2(g) \to CO2(g)
B) 2NO(g)+ O2(g) \to 2NO2(g)
C) C2H6O(l)+ 3O2(g) \to 2CO2(g)+ 3H2O(l)
D) 4NH3(g)+ 5O2(g) \to 4NO(g)+ 6H2O(g)
E) Cl2(g)+ 3F2(g) \to 2ClF3(g)
Question
Place the following gases in order of increasing average velocity at 300 K: Ar,CH4,N2,and N2O.

A) Ar = CH4 = N2 = N2O
B) N2O < Ar < N2 < CH4
C) N2O < N2 < CH4 < Ar
D) Ar < N2 < N2O < CH4
E) CH4 < N2 < N2O < Ar
Question
A 10.0 L flask at 318 K contains a mixture of Ar and CH4 with a total pressure of 1.040 atm.If the mole fraction of Ar is 0.715,what is the mass percent of Ar?

A) 13.8%
B) 68.8%
C) 71.5%
D) 82.9%
E) 86.2%
Question
A gaseous mixture containing 1.5 mol Ar and 3.5 mol CO2 has a total pressure of 7.3 atm.What is the partial pressure of CO2?

A) 2.2 atm
B) 1.4 atm
C) 17 atm
D) 5.1 atm
E) 7.3 atm
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Deck 11: Gases and Their Properties
1
Which of the following is a correct statement of Charles's law, <strong>Which of the following is a correct statement of Charles's law,   ?</strong> A) The volume of a gas varies proportionally with the pressure. B) The volume of a gas sample varies directly with the absolute temperature. C) All gas samples of the same volume at STP contain the same number of atoms. D) The pressure of a gas sample varies inversely with the volume. E) All gas samples of the same volume at STP contain the same number of molecules. ?

A) The volume of a gas varies proportionally with the pressure.
B) The volume of a gas sample varies directly with the absolute temperature.
C) All gas samples of the same volume at STP contain the same number of atoms.
D) The pressure of a gas sample varies inversely with the volume.
E) All gas samples of the same volume at STP contain the same number of molecules.
The volume of a gas sample varies directly with the absolute temperature.
2
A flexible vessel contains 38.00 L of gas at a pressure of 2.74 atm.Under conditions of constant temperature and moles of gas,what is the volume of the gas when the pressure of the vessel is decreased by a factor of two?

A) 76.0 L
B) 19.0 L
C) 0.0132 L
D) 38 L
E) 3.80 L
76.0 L
3
A flexible vessel is filled to a certain pressure with 67.00 L of gas.Under conditions of constant temperature and moles of gas,how does the pressure of the gas change when the volume of the gas is tripled?

A) The pressure decreases by a factor of three.
B) The pressure decreases by a factor of four.
C) The pressure increases by a factor of two.
D) The pressure remains the same.
E) The pressure decreases by a factor of two.
The pressure decreases by a factor of three.
4
A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)

A) 18.8 mmHg
B) <strong>A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.8 mmHg B)   mmHg C) 1.91 mmHg D) 107 mmHg E)   mmHg mmHg
C) 1.91 mmHg
D) 107 mmHg
E) <strong>A physics experiment is conducted at a pressure of 14.3 kPa.What is this pressure in mmHg? (1 atm = 760 mm Hg = 101.3 kPa)</strong> A) 18.8 mmHg B)   mmHg C) 1.91 mmHg D) 107 mmHg E)   mmHg mmHg
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5
A sample of helium gas occupies 14.7 L at 23°C and 0.956 atm.What volume will it occupy at 40°C and 1.20 atm?

A) 19.5 L
B) 20.4 L
C) 11.1 L
D) 12.4 L
E) 14.9 L
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6
A glass column is filled with mercury and inverted in a pool of mercury.The mercury column stabilizes at a height of 736 mm above the pool of mercury.What is the pressure of the atmosphere?

A) 1.03 atm
B) 0.646 atm
C) 463 atm
D) 0.968 atm
E) 0.736 atm
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7
Absolute zero is the point at which

A) a straight-line graph of V versus T ( \circ C)intersects the origin.
B) a straight-line graph of 1/V versus P at constant T intersects the origin.
C) gaseous helium liquefies.
D) a straight-line graph of V versus 1/P at constant T intersects the origin.
E) a straight-line graph of V versus T (K)intersects the origin.
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8
A gas sample is held at constant pressure.The gas occupies 3.62 L of volume when the temperature is 21.6°C.Determine the temperature at which the volume of the gas is 3.49 L.

A) 295 K
B) 284 K
C) 20.8 K
D) 557 K
E) 306 K
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9
A sample of methane,CH4,occupies a volume of 202.0 mL at 25°C and exerts a pressure of 1155.0 mmHg.If the volume of the gas is allowed to expand to 690.0 mL at 298 K,what will be the pressure of the gas?

A) 3950 mmHg
B) 4030 mmHg
C) 338.1 mmHg
D) 0.01255 mmHg
E) 488.0 mmHg
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10
A particular gas exerts a pressure of 637 mmHg.What is this pressure in units of bar? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 4.78 ×\times 105 bar
B) 4.91 ×\times 105 bar
C) 645 bar
D) 0.827 bar
E) 0.849 bar
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11
A particular gas exerts a pressure of 7.54 ×\times 104 Pa.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 0.744 atm
B) 7.44 ×\times 109 atm
C) 0.764 atm
D) 0.754 atm
E) 7.64 ×\times 109 atm
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12
A certain person has a body temperature of 309 K.On a cold day,what volume of air at 278 K must this person with a lung capacity of 3.5 L breathe in to fill his lungs?

A) 3.89 L
B) 3.15 L
C) 3.31 L
D) 6.30 L
E) none of these
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13
Which of the following would represent the greatest pressure?

A) 58143 Pa
B) 307 mmHg
C) 11.7 psi
D) 0.624 atm
E) 17.7 in Hg
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14
A flexible container is charged with 30.00 L of gas at 313K.Under conditions of constant pressure and moles of gas,what is the volume of the gas when the temperature is decreased by a factor of two?

A) 15.0 L
B) 60.0 L
C) 0.0167 L
D) 30 L
E) 3.00 L
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15
It is possible to make a barometer using a liquid other than mercury.What would be the height (in meters)of a column of carbon tetrachloride at a pressure of 0.890 atm,given that 0.890 atm is equal to a 0.676 m column of mercury and the densities of mercury and carbon tetrachloride are 13.5 g/cm3 and 1.58 g/cm3,respectively.

A) 5.78 m
B) 0.173 m
C) 0.0792 m
D) 1.07 m
E) 0.936 m
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16
A gas sample is heated from -20.0°C to 57.0°C and the volume is increased from 2.00 L to 4.50 L.If the initial pressure is 0.140 atm,what is the final pressure?

A) 0.0477 atm
B) -0.177 atm
C) 0.411 atm
D) 0.242 atm
E) 0.0811 atm
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17
The local weather forecaster reports that the current barometric pressure is 30.4 inches of mercury.What is the current pressure in atmospheres?

A) 1.02 atm
B) 10.29 atm
C) 1.00 atm
D) 4.05 atm
E) 910 atm
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18
A flexible vessel contains 45 L of gas where the pressure is 1.4 atm.What will the volume be when the gas is compressed to a pressure of 0.82 atm,the temperature remaining constant?

A) 0.013 L
B) 26 L
C) 45 L
D) 0.049 L
E) 77 L
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19
A balloon has a volume of 2.32 liters at 24.0°C.The balloon is heated to 48.0°C.Calculate the new volume of the balloon.

A) 2.32 L
B) 2.51 L
C) 2.15 L
D) 4.64 L
E) 1.16 L
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20
A particular gas exerts a pressure of 3.43 bar.What is this pressure in units of atmospheres? (1 atm = 760 mm Hg = 101.3 kPa = 1.013 bar)

A) 3.48 atm
B) 2.57 ×\times 103 atm
C) 2.64 ×\times 103 atm
D) 3.39 atm
E) 3.43 atm
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21
If 0.357 g of CH4 gas is introduced into an evacuated 1.75 L flask at 25 \circ C,what is the pressure inside the flask? (R = 0.08206 L.atm/mol.K)

A) 0.952 atm
B) 0.261 atm
C) 0.311 atm
D) 0.419 atm
E) 4.99 atm
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22
What volume of gaseous water,H2O,has the same moles \underline{\text{moles }} of gas as 10.0 L of xenon gas at the same temperature and pressure?

A) 40.0 L
B) 2.50 L
C) 10.0 L
D) 3.33 L
E) 30.0 L
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23
You have a 30.0 L cylinder of helium at a pressure of 132 atm and a temperature of 19 \circ C.The He is used to fill balloons to a volume of 1.80 L at 745 mm Hg and 27 \circ C.How many balloons can be filled with He? Assume that the cylinder can provide He until its internal pressure reaches 1.00 atm (i.e.,there are 131 atmospheres of usable He in the cylinder).

A) 1.90 ×\times 102
B) 1.06 ×\times 102
C) 4.13 ×\times 103
D) 7.41 ×\times 103
E) 2.29 ×\times 103
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24
A 25.0-L sample of nitrogen at 4.45 atm and 23°C is simultaneously expanded to 60.8 L and heated to 37°C.What is the new pressure of the gas?

A) 2.94 atm
B) 1.92 atm
C) 212 atm
D) 326 atm
E) 1.75 atm
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25
A 2.00-L glass soda bottle filled only with air is tightly capped at 19°C and 680.0 mmHg.If the bottle is placed in water at 81°C,what is the pressure in the bottle?

A) 160 mmHg
B) 824 mmHg
C) 2900 mmHg
D) 561 mmHg
E) 422 mmHg
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26
Equal volumes of propane,C3H8,and carbon monoxide,CO,at the same temperature and pressure have the same ____.

A) chemical properties.
B) number of atoms.
C) average molecular speed.
D) density.
E) number of molecules.
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27
The pressure of O2 in a 15.0 L flask is 322 mm Hg at 44 \circ C.What mass of O2 is in the flask? (R = 0.08206 L.atm/mol.K)

A) 0.244 g
B) 5.80 g
C) 7.82 g
D) 15.2 g
E) 56.3 g
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28
The temperature of a specific amount of gas in a sealed container changes from 20.0°C to 40.0°C.If the volume remains constant,the pressure will change from 735 mmHg to ___.

A) 735 mmHg
B) 368 mmHg
C) 1470 mmHg
D) 688 mmHg
E) 785 mmHg
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29
A balloon is filled with He gas to a volume of 2.10 L at 35 \circ C.The balloon is placed in liquid nitrogen until its temperature reaches -196 \circ C.Assuming the pressure remains constant,what is the volume of the cooled balloon?

A) (-0.375) L
B) 0.375 L
C) 0.525 L
D) 0.00909 L
E) 8.40 L
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30
For an ideal gas, which two variables are directly proportional to each other (if all other conditions remain constant)?
1. T and n
2. V and n
3. P and T

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 2 and 3
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31
You have 49.1 g of O2 gas in a container with twice the volume as one with CO2 gas.The pressure and temperature of both containers are the same.Calculate the mass of carbon dioxide gas you have in the container.

A) 0.767 g
B) 67.5 g
C) 3.07 g
D) 33.8 g
E) none of these
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32
The volume of a sample of gas measured at 75.0°C and 1.00 atm pressure is 5.00 L.What must the final temperature be in order for the gas to have a final volume of 4.00 L at 1.00 atm pressure?

A) 5.4°C
B) 60.0°C
C) -213.0°C
D) 93.8°C
E) 162.0°C
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33
What volume of oxygen will react with 21 mL of ethanol,assuming the gases are present at the same temperature and pressure?
2 CH3CH2OH(g)+ 6 O2(g) \to 4 CO2(g)+ 6 H2O(g)

A) 7.0 mL
B) 14 mL
C) 21 mL
D) 42 mL
E) 63 mL
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34
A 45.0 L gas cylinder contains 988 g He at 23 \circ C.What is the pressure inside the cylinder? (R = 0.08206 L.atm/mol.K)

A) 10.4 atm
B) 41.4 atm
C) 101 atm
D) 133 atm
E) 533 atm
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35
What volume is occupied by 35.0 g of C2H2 at 471 mm Hg and 21 \circ C? (R = 0.08206 L.atm/mol.K)

A) 29.0 L
B) 52.3 L
C) 3.74 L
D) 20.1 L
E) 0.0689 L
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36
A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?

A) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)
B) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)
C) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)
D) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)
E) <strong>A gas occupying a volume of 1.50 L exerts a pressure of 700 mmHg at 200°C.Which mathematical expression gives the correct pressure at 6.00 L and 400°C?</strong> A)   B)   C)   D)   E)
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37
The pressure of 5.4 L of nitrogen gas in a flexible container is decreased to one-half its original pressure,and its absolute temperature is increased to double the original temperature.The volume is now

A) 2.7 L.
B) 5.4 L.
C) 11 L.
D) 22 L.
E) 1.4 L.
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38
Gaseous chlorine is held in two separate containers at identical temperature and pressure.The volume of container 1 is 1.30 L,and it contains 6.70 mol of the gas.The volume of container 2 is 2.33 L.How many moles of the gas are in container 2?

A) 12.0 mol
B) 20.3 mol
C) 0.452 mol
D) 3.74 mol
E) none of these
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39
Which of the following concerning the behavior of ideal gases is/are true?
1)Pressure is directly proportional to volume when temperature and moles of gas are held constant.
2)Pressure is directly proportional to moles of gas when temperature and volume are held constant.
3)Volume is inversely proportional to temperature when the pressure and moles of gas are held constant.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2 only
E) 2 and 3 only
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40
What is the pressure of a 59.6-L gas sample containing 3.01 mol of gas at 44.9°C? (R = 0.0821 L • atm/(K • mol),1 atm = 760 mmHg)

A) 1.41 ×\times 102 mmHg
B) 1.73 ×\times 10-3 mmHg
C) 1.32 mmHg
D) 1.00 ×\times 103 mmHg
E) 5.77 ×\times 102 mmHg
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41
A mixture of KCl and KClO3 weighing 1.34 grams was heated; the dry O2 generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO3,which decomposes as follows: <strong>A mixture of KCl and KClO<sub>3</sub> weighing 1.34 grams was heated; the dry O<sub>2</sub> generated occupied 143 mL at STP.What percent by mass of the original mixture was KClO<sub>3</sub>,which decomposes as follows:  </strong> A) 38.9% B) 58.4% C) 87.6% D) 10.7% E) 23.7%

A) 38.9%
B) 58.4%
C) 87.6%
D) 10.7%
E) 23.7%
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42
Into a 2.22-liter container at 25°C are placed 1.23 moles of O2 gas and 3.20 moles of solid C (graphite).If the carbon and oxygen react completely to form CO(g),what will be the final pressure in the container at 25°C?

A) 27.1 atm
B) 13.5 atm
C) 2.27 atm
D) 35.2 atm
E) none of these
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43
The following equation represents the partial combustion of methane,CH4.
2CH4(g)+ 3O2(g) \to 2CO(g)+ 4H2O(g)
At constant temperature and pressure,what is the maximum volume of carbon monoxide that can be obtained from 3.39 ×\times 102 L of methane and 1.70 ×\times 102 L of oxygen?

A) 5.09 ×\times 102 L
B) 3.39 ×\times 102 L
C) 1.19 ×\times 103 L
D) 1.13 ×\times 102 L
E) 6.78 ×\times 102 L
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44
The density of ethane,C2H6 (30.1 g/mol),at 32°C and 1.17 atm pressure is ___.(R = 0.08206 L.atm/mol.K)

A) 1.41 g/L
B) 17.2 g/L
C) 1.34 g/L
D) 0.711 g/L
E) 0.144 g/L
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45
An excess of sodium hydroxide is treated with 3.3 L of dry hydrogen chloride gas measured at STP,producing sodium chloride and water.What is the mass of sodium chloride is formed?

A) 1.65 g
B) 17.2 g
C) 8.6 g
D) 14 g
E) 193 g
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46
One way to isolate metals from their ores is to react the metal oxide with carbon as shown in the following reaction (M = metal): <strong>One way to isolate metals from their ores is to react the metal oxide with carbon as shown in the following reaction (M = metal):   If 34.14 g of a metal oxide reacted with excess carbon and 4.38 L of CO<sub>2</sub> formed at 100°C and 1.50 atm,what is the identity of the metal?</strong> A) Hg B) Mg C) Cu D) Zn E) Cd
If 34.14 g of a metal oxide reacted with excess carbon and 4.38 L of CO2 formed at 100°C and 1.50 atm,what is the identity of the metal?

A) Hg
B) Mg
C) Cu
D) Zn
E) Cd
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47
What volume of <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L measured at STP is produced by the combustion of 6.46 g of natural gas <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L
In excess oxygen? (R = 0.08206 L.atm/mol.K) <strong>What volume of   measured at STP is produced by the combustion of 6.46 g of natural gas   In excess oxygen? (R = 0.08206 L.atm/mol.K)  </strong> A) 4.51 L B) 19.7 L C) 9.02 L D) 18.0 L E) 3.23 L

A) 4.51 L
B) 19.7 L
C) 9.02 L
D) 18.0 L
E) 3.23 L
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48
Sodium azide decomposes rapidly to produce nitrogen gas.2 NaN3(s) \to 2 Na(s)+ 3 N2(g)
What mass of sodium azide will inflate a 60.0 L airbag for a car to a pressure of 1.50 atm at 32 \circ C? (R = 0.08206 L.atm/mol.K)

A) 2.40 g
B) 67.2 g
C) 156 g
D) 234 g
E) 351 g
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49
At what temperature does 742 mm Hg of CH4 gas have the same density as 742 mm Hg of O2 gas at 273 K?

A) 137 K
B) 146 K
C) 191 K
D) 275 K
E) 545 K
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50
When 0.5000 grams of an unknown hydrocarbon,CxHy,is completely combusted with excess oxygen,1.037 L CO2 gas and is produced at 98.3 \circ C and 1.000 atm.What is the empirical formula of the hydrocarbon? (R = 0.08206 L.atm/mol.K)

A) CH
B) CH2
C) C2H3
D) C3H5
E) C3H8
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51
The density of H2 gas in a rigid container is 0.117 g/L at 55 \circ C.What is the pressure of hydrogen in the flask if it is heated to 125 \circ C? (R = 0.08206 L.atm/mol.K)

A) 0.142 atm
B) 0.194 atm
C) 1.56 atm
D) 1.90 atm
E) 3.55 atm
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52
Which of the following gases has the greatest density at 35 \circ C and 450 mm Hg?

A) CH4
B) Ar
C) N2
D) Cl2
E) C3H8
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53
The density of a gas is 1.96 g/L at STP.What is its molar mass?

A) 65.2 g/mol
B) 58.9 g/mol
C) 11.4 g/mol
D) 22.4 g/mol
E) 43.9 g/mol
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54
Which of the following samples contains the fewest moles of gas?

A) 1.00 L of CH4 at STP
B) 1.00 L of Ar at -10.0°C and 1.00 atm
C) 1.00 L of NH3 at 10°C and 1.00 atm
D) 1.00 L of H2 at 0.0°C and 1.76 atm
E) 1.00 L of HCl at 20°C and 1.00 atm
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55
What mass of O2 is required to produce 5.00 L NO2 at 305 K and 752 mm Hg? (R = 0.08206 L.atm/mol.K)
2 NO(g)+ O2(g) \to 2 NO2(g)

A) 0.198 g
B) 1.58 g
C) 3.16 g
D) 5.00 g
E) 6.33 g
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56
What volume of O2,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO3? Assume 100% yield.(R = 0.08206 L.atm/mol.K)
2 KClO3(s) \to 2 KCl(s)+ 3 O2(g)

A)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these  mL
B)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these  mL
C)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these  mL
D)  <strong>What volume of O<sub>2</sub>,measured at 24.0°C and 0.630 atm atm,will be produced by the decomposition of 3.00 g KClO<sub>3</sub>? Assume 100% yield.(R = 0.08206 L.atm/mol.K) 2 KClO<sub>3</sub>(s) \to  2 KCl(s)+ 3 O<sub>2</sub>(g)</strong> A)   mL B)   mL C)   mL D)   mL E) none of these  mL
E) none of these
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57
Ammonia gas is synthesized according to the balanced equation below.
N2(g)+ 3 H2(g) \to 2 NH3(g)
If 1.55 L N2 react with 4.92 L H2,what is the theoretical yield (in liters)of NH3? Assume that the volumes of reactants and products are measured at the same temperature and pressure.

A) 1.55 L
B) 3.10 L
C) 3.28 L
D) 4.93 L
E) 6.42 L
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58
A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)

A) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)
B) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)
C) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)
D) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)
E) <strong>A 3.74 gram sample of a certain diatomic gas occupies a volume of 3.48-L at 1.00 atm and a temperature of 45°C.Identify this gas.(R = 0.08206 L.atm/mol.K)</strong> A)   B)   C)   D)   E)
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59
What volume does 40.5 g of N2 occupy at STP? (R = 0.08206 L.atm/mol.K)

A) 64.8 L
B) 1.81 L
C) 32.4 L
D) 50.7 L
E) none of these
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60
Aqueous hydrochloric acid reacts with magnesium to produce hydrogen gas according to the balanced equation below.
2 HCl(aq)+ Mg(s) \to MgCl2(aq)+ H2(g)
If 250.0 mL of 3.00 M HCl is combined with 9.92 g Mg,what volume of hydrogen gas can be produced? Assume the temperature and pressure of the gas are 25 \circ C and 0.988 atm,respectively.(R = 0.08206 L.atm/mol.K)

A) 4.60 L
B) 5.05 L
C) 9.28 L
D) 10.1 L
E) 18.6 L
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61
What is the volume occupied by a mixture of 0.203 mol of N2 and 0.203 mol of O2 gases at 1.16 atm and 44.7°C?

A) 2.74 ×\times 102 L
B) 9.13 L
C) 0.642 L
D) 1.28 L
E) 4.57 L
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62
Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L.atm/mol.K)
2 H2O(  <strong>Water can be decomposed by electrolysis into hydrogen gas and oxygen gas.What mass of water must decompose to fill a 3.00 L flask to a total pressure of 2.00 atm at 298 K with a mixture hydrogen and oxygen? (R = 0.08206 L.atm/mol.K) 2 H<sub>2</sub>O(   ) \to  2 H<sub>2</sub>(g)+ O<sub>2</sub>(g)</strong> A) 1.47 g B) 2.95 g C) 4.42 g D) 6.63 g E) 8.84 g  ) \to 2 H2(g)+ O2(g)

A) 1.47 g
B) 2.95 g
C) 4.42 g
D) 6.63 g
E) 8.84 g
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63
What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction?
NH4NO2(s) \to 0 N2(g)+ 2H2O(g)

A)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L  L
B) 22.4 L
C)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L  L
D)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L  L
E)  <strong>What is the total volume of gases produced at 1092 K and 1.00 atm pressure when 192 g of ammonium nitrite undergoes the following decomposition reaction? NH<sub>4</sub>NO<sub>2</sub>(s) \to 0 N<sub>2</sub>(g)+ 2H<sub>2</sub>O(g)</strong> A)   L B) 22.4 L C)   L D)   L E)   L  L
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64
At STP,as the molar mass of the molecules that make up a pure gas increases,the

A) root mean square speed of the molecules increases.
B) root mean square speed of the molecules decreases.
C) root mean square speed of the molecules remains constant.
D) root mean square speed increases to a maximum,then decreases.
E) none of the above.
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65
An unknown gaseous hydrocarbon contains 85.63% C.Its density is 1.524 g/L at 0.665 atm and 373 K.What is the molecular formula of the gas? (R = 0.08206 L.atm/mol.K)

A) C2H4
B) C3H6
C) C4H8
D) C5H10
E) C6H12
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66
A 22.4 L high pressure reaction vessel is charged with 0.3750 mol of iron powder and 1.78 atm of oxygen gas at standard temperature.On heating,the iron and oxygen react according to the balanced reaction below.
4Fe(s)+ 3O2(g) \to 2Fe2O3(s)
After the reaction vessel returns to standard temperature,and assuming the reaction goes to completion,what pressure of oxygen remains?

A) 1.50 atm
B) 1.78 atm
C) 1.28 atm
D) 0.281 atm
E) 0.00 atm
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67
The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O2)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:

A) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these
B) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these
C) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these
D) <strong>The rate of effusion of an unknown gas was measured and found to be 14.5 mL/min.Under identical conditions,the rate of effusion of pure oxygen (O<sub>2</sub>)gas is 17.0 mL/min.Based on this information,the identity of the unknown gas could be:</strong> A)   B)   C)   D)   E) none of these
E) none of these
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68
Which of the following statements are postulates of the kinetic-molecular theory of gases?
1)Gas particles are in constant,random motion.
2)The distance between gas particles is large in comparison to their size.
3)The average kinetic energy of gas particles is proportional to the kelvin temperature.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 1,2,and 3
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69
A vessel with a volume of 26.9 L contains 2.80 g of nitrogen gas,0.605 g of hydrogen gas,and 79.9 g of argon gas.At 25°C,what is the pressure in the vessel?

A) 75.5 atm
B) 0.183 atm
C) 2.55 atm
D) 2.18 atm
E) 58.7 atm
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70
The partial pressures of CH4,N2,and O2 in a sample of a gas mixture were found to be 183 mmHg,493 mmHg,and 551 mmHg,respectively.Calculate the mole fraction of nitrogen.

A) 0.725
B) 0.359
C) 19.7
D) 0.449
E) 0.402
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71
The layer of the atmosphere closest to the Earth's surface is the ________.

A) thermosphere
B) stratosphere
C) stratopause
D) troposphere
E) mesosphere
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72
How long will it take 10.0 mL of Ne gas to effuse through a porous barrier if it has been observed that 125 minutes are required for 10.0 mL of Ar gas to effuse through the same barrier?

A) 1.41 min.
B) 31.9 min.
C) 63.1 min.
D) 88.8 min.
E) 176 min.
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73
The molar mass of an unknown gas was measured by an effusion experiment.It was found that the unknown gas effused at a rate of 3.7 ×\times 10-6 mol/hr,whereas nitrogen gas effused at a rate of 4.3 ×\times 10-6mol/hr.The molar mass of the gas is

A) 26 g/mol.
B) 33 g/mol.
C) 21 g/mol.
D) 30 g/mol.
E) 38 g/mol.
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74
Methane gas,CH4,effuses through a barrier at a rate of 0.568 mL/minute.If an unknown gas effuses through the same barrier at a rate of 0.343 mL/minute,what is the molar mass of the gas?

A) 20.8 g/mol
B) 28.0 g/mol
C) 32.0 g/mol
D) 44.0 g/mol
E) 64.0 g/mol
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75
Carbon monoxide reacts with oxygen to form carbon dioxide.
2 CO(g)+ O2(g) \to 2 CO2(g)
In a 1.00 L flask,4.30 atm of CO reacts with 2.50 atm of O2.Assuming that the temperature remains constant,what is the final pressure in the flask?

A) 1.80 atm
B) 2.50 atm
C) 4.30 atm
D) 4.65 atm
E) 6.80 atm
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76
Calculate the root-mean-square velocity for the O2 molecules in a sample of O2 gas at 24.9°C.(R = 8.3145 J/K.mol)

A) 15.24 m/s
B) 139.3 m/s
C) 278.2 m/s
D) 481.9 m/s
E) 9.177 ×\times 1026 m/s
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77
In which of the following reactions will the pressure increase upon completion of the reaction at constant temperature?

A) C(s)+ O2(g) \to CO2(g)
B) 2NO(g)+ O2(g) \to 2NO2(g)
C) C2H6O(l)+ 3O2(g) \to 2CO2(g)+ 3H2O(l)
D) 4NH3(g)+ 5O2(g) \to 4NO(g)+ 6H2O(g)
E) Cl2(g)+ 3F2(g) \to 2ClF3(g)
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78
Place the following gases in order of increasing average velocity at 300 K: Ar,CH4,N2,and N2O.

A) Ar = CH4 = N2 = N2O
B) N2O < Ar < N2 < CH4
C) N2O < N2 < CH4 < Ar
D) Ar < N2 < N2O < CH4
E) CH4 < N2 < N2O < Ar
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79
A 10.0 L flask at 318 K contains a mixture of Ar and CH4 with a total pressure of 1.040 atm.If the mole fraction of Ar is 0.715,what is the mass percent of Ar?

A) 13.8%
B) 68.8%
C) 71.5%
D) 82.9%
E) 86.2%
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80
A gaseous mixture containing 1.5 mol Ar and 3.5 mol CO2 has a total pressure of 7.3 atm.What is the partial pressure of CO2?

A) 2.2 atm
B) 1.4 atm
C) 17 atm
D) 5.1 atm
E) 7.3 atm
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