Deck 3: Atomic Structure-Explaining the Properties of Elements
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Deck 3: Atomic Structure-Explaining the Properties of Elements
1
Which of the following types of electromagnetic radiation has the highest frequency?
A)ultraviolet
B)X-rays
C)radio waves
D)infrared
E)visible
A)ultraviolet
B)X-rays
C)radio waves
D)infrared
E)visible
X-rays
2
What is the frequency ( in Hz)of the photons emitted by a He-Ne laser with a wavelength ( )of 632.8 nm?
A)4.738 105 Hz
B)1.897 102 Hz
C)1.897 1011 Hz
D)4.738 1014 Hz
E)1.897 1014 Hz
A)4.738 105 Hz
B)1.897 102 Hz
C)1.897 1011 Hz
D)4.738 1014 Hz
E)1.897 1014 Hz
4.738 1014 Hz
3
Indicate which one of the following sources produces the highest energy photons.
A)a radio station with = 106.7 MHz
B)a dentist's X-ray source with = 100 pm
C)the laser in a CD player with = 650 nm
D)a microwave oven with = 6.0 1010 Hz
E)your cell phone with = 1.750 GHz
A)a radio station with = 106.7 MHz
B)a dentist's X-ray source with = 100 pm
C)the laser in a CD player with = 650 nm
D)a microwave oven with = 6.0 1010 Hz
E)your cell phone with = 1.750 GHz
a dentist's X-ray source with = 100 pm
4
Which of the following lasers emits photons with the highest frequency?
A)a Nd:YAG laser with = 1064 nm
B)an Ar+ laser with = 514.5 nm
C)a Kr+ laser with = 647 nm
D)an ArF laser with = 193 nm
E)a He-Ne laser with = 633 nm
A)a Nd:YAG laser with = 1064 nm
B)an Ar+ laser with = 514.5 nm
C)a Kr+ laser with = 647 nm
D)an ArF laser with = 193 nm
E)a He-Ne laser with = 633 nm
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5
Which of the following lasers emits photons with the lowest energy?
A)a Nd:YAG laser with = 1064 nm
B)an Ar+ laser with = 514.5 nm
C)a Kr+ laser with = 647 nm
D)an ArF laser with = 193 nm
E)a He-Ne laser with = 633 nm
A)a Nd:YAG laser with = 1064 nm
B)an Ar+ laser with = 514.5 nm
C)a Kr+ laser with = 647 nm
D)an ArF laser with = 193 nm
E)a He-Ne laser with = 633 nm
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6
What is the wavelength ( ,in m)of a radio station operating at a frequency of 99.6 MHz?
A)3.01 106 m
B)3.01 m
C)3.32 10-7 m
D)0.332 m
E)3.32 m
A)3.01 106 m
B)3.01 m
C)3.32 10-7 m
D)0.332 m
E)3.32 m
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7
Which of the following types of electromagnetic radiation has the shortest wavelength?
A)gamma rays
B)X-rays
C)radio waves
D)infrared
E)visible
A)gamma rays
B)X-rays
C)radio waves
D)infrared
E)visible
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8
Which of the following types of electromagnetic radiation has the longest wavelength?
A)gamma rays
B)X-rays
C)visible
D)infrared
E)radio waves
A)gamma rays
B)X-rays
C)visible
D)infrared
E)radio waves
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9
Which of the following statements is NOT true regarding blackbody radiation,the ultraviolet catastrophe,and Planck's view of electromagnetic radiation?
A)A blackbody radiator does not absorb and emit one wavelength preferentially over another.
B)The emission spectrum of a blackbody radiator depends on its temperature.
C)A blackbody radiator cannot emit an infinite amount of radiation.
D)Planck theorized that real objects can only absorb or emit discrete packets of electromagnetic radiation.
E)The ultraviolet catastrophe disappears if emission spectrum of a blackbody radiator is continuous.
A)A blackbody radiator does not absorb and emit one wavelength preferentially over another.
B)The emission spectrum of a blackbody radiator depends on its temperature.
C)A blackbody radiator cannot emit an infinite amount of radiation.
D)Planck theorized that real objects can only absorb or emit discrete packets of electromagnetic radiation.
E)The ultraviolet catastrophe disappears if emission spectrum of a blackbody radiator is continuous.
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10
Fraunhofer lines are due to __________
A)emission of radiation by atoms.
B)absorption of radiation by atoms.
C)the photoelectric effect.
D)chemical reactions in the sun.
E)nuclear reactions in the sun.
A)emission of radiation by atoms.
B)absorption of radiation by atoms.
C)the photoelectric effect.
D)chemical reactions in the sun.
E)nuclear reactions in the sun.
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11
As the frequency of electromagnetic radiation decreases,which of the following statements is true?
A)Its wavelength decreases.
B)Its energy decreases.
C)Its speed decreases.
D)Its magnetic field component remains constant.
E)Its electric field component remains constant.
A)Its wavelength decreases.
B)Its energy decreases.
C)Its speed decreases.
D)Its magnetic field component remains constant.
E)Its electric field component remains constant.
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12
Which of the following photons has the highest energy?
A)a photon with = 1.064 μm
B)a photon with = 5.83 1014 Hz
C)a photon with = 647 nm
D)a photon with = 1.55 1015 Hz
E)a photon with = 633 pm
A)a photon with = 1.064 μm
B)a photon with = 5.83 1014 Hz
C)a photon with = 647 nm
D)a photon with = 1.55 1015 Hz
E)a photon with = 633 pm
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13
Cesium atomic clocks are based on the emission of microwave radiation at 9,192,631,770 Hz by cesium-133.The wavelength corresponding to this frequency is closest in value to which of the following?
A)300 m
B)3 km
C)300 pm
D)3 cm
E)300 mm
A)300 m
B)3 km
C)300 pm
D)3 cm
E)300 mm
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14
The Fraunhofer lines are evidence that __________
A)atoms contain nuclei.
B)atoms contain charged particles.
C)mass is equivalent to energy.
D)atoms absorb light.
E)atoms emit light.
A)atoms contain nuclei.
B)atoms contain charged particles.
C)mass is equivalent to energy.
D)atoms absorb light.
E)atoms emit light.
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15
Which statement about Rutherford's model of the atom is NOT correct?
A)It detailed the arrangement of the electrons in the atom.
B)It hypothesized that most of the mass of the atom was located in a very small region at the center of the atom called the nucleus.
C)It did not explain the some experimental findings,such as the photoelectric effect and the colors of light emitted by heated objects.
D)It suggested that most of the atom was empty space.
E)It suggested that the positive charge was not spread out over the atom's entire volume but,rather,concentrated in the nucleus.
A)It detailed the arrangement of the electrons in the atom.
B)It hypothesized that most of the mass of the atom was located in a very small region at the center of the atom called the nucleus.
C)It did not explain the some experimental findings,such as the photoelectric effect and the colors of light emitted by heated objects.
D)It suggested that most of the atom was empty space.
E)It suggested that the positive charge was not spread out over the atom's entire volume but,rather,concentrated in the nucleus.
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16
Which statement about electromagnetic radiation is NOT correct?
A)Electromagnetic radiation consists of perpendicular oscillating electric and magnetic fields.
B)Electromagnetic radiation is emitted by all stars.
C)All electromagnetic radiation is visible to the eye.
D)Electromagnetic radiation spans a very wide range of wavelengths,from gamma rays to radio waves.
E)The frequency and wavelength of electromagnetic radiation are inversely proportional to each other.
A)Electromagnetic radiation consists of perpendicular oscillating electric and magnetic fields.
B)Electromagnetic radiation is emitted by all stars.
C)All electromagnetic radiation is visible to the eye.
D)Electromagnetic radiation spans a very wide range of wavelengths,from gamma rays to radio waves.
E)The frequency and wavelength of electromagnetic radiation are inversely proportional to each other.
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17
Which of the following types of electromagnetic radiation has the lowest frequency?
A)gamma rays
B)X-rays
C)radio waves
D)infrared
E)visible
A)gamma rays
B)X-rays
C)radio waves
D)infrared
E)visible
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18
The speed of light generally decreases when it passes through media other than a vacuum.The speed,v,is approximately c (2.998 108m/s)divided by a quantity called the medium's refractive index, .In which of the following would the frequency of 193 nm light be the lowest? ( = c/ ; c = )
A)hydrogen, = 1.0001
B)carbon tetrachloride, = 1.461
C)silicone oil, = 1.520
D)water, = 1.3330
E)diamond, = 2.419
A)hydrogen, = 1.0001
B)carbon tetrachloride, = 1.461
C)silicone oil, = 1.520
D)water, = 1.3330
E)diamond, = 2.419
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19
In comparing the Fraunhofer lines with light emitted by elements in a flame,Bunsen and Kirchhoff demonstrated that __________
A)atoms emit and absorb electromagnetic radiation at characteristic wavelengths.
B)the solar spectrum is continuous.
C)alkali metals absorb and emit the same wavelengths.
D)nuclear reactions are responsible for the absorption and emission of electromagnetic radiation.
E)the sun's composition is changing over time.
A)atoms emit and absorb electromagnetic radiation at characteristic wavelengths.
B)the solar spectrum is continuous.
C)alkali metals absorb and emit the same wavelengths.
D)nuclear reactions are responsible for the absorption and emission of electromagnetic radiation.
E)the sun's composition is changing over time.
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20
Suppose a bar code scanner emits light in the visible region of the spectrum at 4.62 1014 s-1.What color is the light?
A)red
B)orange
C)yellow
D)green
E)blue
A)red
B)orange
C)yellow
D)green
E)blue
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21
Indicate which metal requires the shortest wavelength photons to eject photoelectrons based on the following data and graph.Work functions are in J 10-19. 
A)Ta
B)Ti
C)W
D)Si
E)Ag

A)Ta
B)Ti
C)W
D)Si
E)Ag
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22
What is the energy (E,in J)of the 488 nm photons emitted by an argon-ion laser?
A)2.46 1018 J
B)9.69 10-23 J
C)1.36 10-36 J
D)4.07 10-19 J
E)2.46 10-18 J
A)2.46 1018 J
B)9.69 10-23 J
C)1.36 10-36 J
D)4.07 10-19 J
E)2.46 10-18 J
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23
The work function of sodium is = 2.90 10-19 J.What is the maximum wavelength that can cause ejection of photoelectrons from a sodium surface?
A)151 nm
B)222 nm
C)45.1 nm
D)451 nm
E)685 nm
A)151 nm
B)222 nm
C)45.1 nm
D)451 nm
E)685 nm
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24
Based on the following data and graph,which metal will emit the highest energy photoelectron when a 250 nm photon is incident on the metal? Work functions are in J 1019. 
A)Ta
B)Ti
C)W
D)Si
E)Ag

A)Ta
B)Ti
C)W
D)Si
E)Ag
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25
Indicate which of the following photons can cause emission of photoelectrons from a surface of gallium ( = 6.7 10-19 J).
A)350 nm
B)400 nm
C)200 nm
D)650 nm
E)500 nm
A)350 nm
B)400 nm
C)200 nm
D)650 nm
E)500 nm
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26
What is the minimum frequency of a photon that can eject a photoelectron from Ba metal? (The work function of barium is = 4.3 10-19 J.)
A)2.8 10-52 Hz
B)6.5 1014 Hz
C)6.5 104 Hz
D)6.5 1013 Hz
E)2.8 1014 Hz
A)2.8 10-52 Hz
B)6.5 1014 Hz
C)6.5 104 Hz
D)6.5 1013 Hz
E)2.8 1014 Hz
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27
The theoretical work of Max Planck on blackbody emission from and the experimental evidence provided with Albert Einstein's studies of the photoelectric effect revolutionized physics because they revealed that __________
A)energy is quantized.
B)electrons can be ejected from metals by visible light.
C)light (electromagnetic radiation)has a wave nature.
D)blackbody radiation is continuous.
E)atomic spectra are discrete.
A)energy is quantized.
B)electrons can be ejected from metals by visible light.
C)light (electromagnetic radiation)has a wave nature.
D)blackbody radiation is continuous.
E)atomic spectra are discrete.
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28
Mercury lamps emit blue light with = 436 nm.What is the energy of these photons in J?
A)4.56 10-19 J
B)4.56 10-28 J
C)1.97 1044 J
D)2.19 1018 J
E)2.19 10-18 J
A)4.56 10-19 J
B)4.56 10-28 J
C)1.97 1044 J
D)2.19 1018 J
E)2.19 10-18 J
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29
Which of the following occurs only in discrete (quantized)increments?
A)the speed a car drives on the interstate
B)the altitude that an airplane flies
C)time
D)the level of water in a sink
E)money
A)the speed a car drives on the interstate
B)the altitude that an airplane flies
C)time
D)the level of water in a sink
E)money
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30
Light intensity ( I )can be described as the power emitted by a light source (P)over a given area (in m2).Suppose a 100-watt mercury vapor lamp emits 365.4 nm photons equally in all directions.At a distance of 1.450 m,how many photons hit per square meter per second? (1 watt = 1 J/s; I = P/Area = P/4 d 2,where d is the distance)
A)5 107 photons
B)7 109 photons/m2 .s
C)9 1016 photons/m2 .s
D)7 1018 photons/m2 .s
E)6 1019 photons/m2 .s
A)5 107 photons
B)7 109 photons/m2 .s
C)9 1016 photons/m2 .s
D)7 1018 photons/m2 .s
E)6 1019 photons/m2 .s
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31
Which of the following will lead to an increase in the kinetic energies of photoelectrons emitted when light is incident on a metal surface?
A)increase in the light's wavelength
B)increase in the light's intensity
C)decrease in the light's wavelength
D)decrease in the light's frequency
E)decrease in the light's intensity
A)increase in the light's wavelength
B)increase in the light's intensity
C)decrease in the light's wavelength
D)decrease in the light's frequency
E)decrease in the light's intensity
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32
Sodium lamps emit yellow light with nominal wavelength of 589 nm.What is the energy of these photons in kJ/mol?
A)3.37 10-9 kJ/mol
B)2.35 10-7 kJ/mol
C)120 kJ/mol
D)70.5 kJ/mol
E)202 kJ/mol
A)3.37 10-9 kJ/mol
B)2.35 10-7 kJ/mol
C)120 kJ/mol
D)70.5 kJ/mol
E)202 kJ/mol
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33
How many times longer is the wavelength of electromagnetic radiation used in a microwave oven at 2.45 GHz than the copper K- 1 X-ray radiation used in X-ray diffraction studies with an energy of 1.29 10-15 J?
A)6.29 107 times longer
B)7.54 107 times longer
C)7.92 108 times longer
D)7.95 1017 times longer
E)1.90 1024 times longer
A)6.29 107 times longer
B)7.54 107 times longer
C)7.92 108 times longer
D)7.95 1017 times longer
E)1.90 1024 times longer
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34
What is the energy (E,in J)of a 6.00 1010 Hz photon from a microwave oven?
A)3.98 10-30 J
B)3.98 10-39 J
C)3.98 10-23 J
D)3.98 10-17 J
E)3.98 10-13 J
A)3.98 10-30 J
B)3.98 10-39 J
C)3.98 10-23 J
D)3.98 10-17 J
E)3.98 10-13 J
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35
Which one of the following sources produces the highest energy photons?
A)a doctor's X-ray source
B)a heat lamp in a restaurant
C)a microwave oven
D)gamma rays from a star
E)radio waves from a local station
A)a doctor's X-ray source
B)a heat lamp in a restaurant
C)a microwave oven
D)gamma rays from a star
E)radio waves from a local station
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36
Which of the following metals would be an appropriate choice for the construction of a photon detector for 550 nm light?
A)sodium ( = 4.4 10-19 J)
B)rubidium ( = 3.5 10-19J)
C)barium ( = 4.3 10-19 J)
D)gold ( = 8.2 10-19 J)
E)platinum ( = 9.1 10-19 J)
A)sodium ( = 4.4 10-19 J)
B)rubidium ( = 3.5 10-19J)
C)barium ( = 4.3 10-19 J)
D)gold ( = 8.2 10-19 J)
E)platinum ( = 9.1 10-19 J)
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37
If each of the following metals is exposed to light with a wavelength of 240 nm,which will emit photoelectrons with the greatest kinetic energy?
A)iron ( = 7.2 10-19 J)
B)platinum ( = 9.1 10-19 J)
C)nickel ( = 8.3 10-19 J)
D)palladium ( = 8.2 10-19 J)
E)sodium ( = 4.4 10-19 J)
A)iron ( = 7.2 10-19 J)
B)platinum ( = 9.1 10-19 J)
C)nickel ( = 8.3 10-19 J)
D)palladium ( = 8.2 10-19 J)
E)sodium ( = 4.4 10-19 J)
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38
Which of the following is quantized?
A)the trajectory of a baseball hit from home plate
B)the speed of a Formula 1 race car
C)the diameter of a redwood tree
D)the number of marbles in a bag
E)your age
A)the trajectory of a baseball hit from home plate
B)the speed of a Formula 1 race car
C)the diameter of a redwood tree
D)the number of marbles in a bag
E)your age
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39
Suppose a blue light emitting photons with λ = 470 nm is rated at 60W (60 J of energy are emitted per second).How many photons are emitted in 5.0 seconds?
A)4.2 1019 photons
B)7.1 1020 photons
C)1.4 1020 photons
D)2.1 1038 photons
E)1.6 109 photons
A)4.2 1019 photons
B)7.1 1020 photons
C)1.4 1020 photons
D)2.1 1038 photons
E)1.6 109 photons
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40
Which of the following statements is false?
A)As the wavelength of a photon decreases,its energy increases.
B)The speed of a photon decreases as its wavelength decreases.
C)Light can be viewed as packets of energy.
D)As the frequency of a photon decreases,its energy decreases.
E)A high-energy photon has a wavelength shorter than that of a low-energy photon.
A)As the wavelength of a photon decreases,its energy increases.
B)The speed of a photon decreases as its wavelength decreases.
C)Light can be viewed as packets of energy.
D)As the frequency of a photon decreases,its energy decreases.
E)A high-energy photon has a wavelength shorter than that of a low-energy photon.
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41
Which statement regarding atomic emission spectra and the hydrogen atom is incorrect?
A)Electronic transitions in the atom are quantized.
B)Discrete wavelengths of light can be absorbed or emitted by atoms.
C)Atoms can absorb all wavelengths of light but only emit photons of discrete energies.
D)Balmer proved that the hydrogen atom had a wavelike nature.
E)Balmer and Rydberg developed empirical equations to fit experimental data.
A)Electronic transitions in the atom are quantized.
B)Discrete wavelengths of light can be absorbed or emitted by atoms.
C)Atoms can absorb all wavelengths of light but only emit photons of discrete energies.
D)Balmer proved that the hydrogen atom had a wavelike nature.
E)Balmer and Rydberg developed empirical equations to fit experimental data.
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42
Atomic spectra are due to the changes in the energy of __________
A)protons.
B)neutrons.
C)nuclei.
D)electrons.
E)electromagnetic radiation.
A)protons.
B)neutrons.
C)nuclei.
D)electrons.
E)electromagnetic radiation.
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43
What is the change in energy of the hydrogen atom when it undergoes an electronic transition from ninitial = 5 to nfinal = 2?
A)2.09 10-18 J
B)4.57 10-19 J
C)1.55 10-19 J
D)4.90 10-20 J
E)1.55 10-20 J
A)2.09 10-18 J
B)4.57 10-19 J
C)1.55 10-19 J
D)4.90 10-20 J
E)1.55 10-20 J
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44
Which transition in a hydrogen atom involves the largest change in energy?
A)n1 = 2 to n2 = 3
B)n1 = 3 to n2 = 4
C)n1 = 1 to n2 = 3
D)n1 = 1 to n2 = 2
E)n1 = 9 to n2 = 10
A)n1 = 2 to n2 = 3
B)n1 = 3 to n2 = 4
C)n1 = 1 to n2 = 3
D)n1 = 1 to n2 = 2
E)n1 = 9 to n2 = 10
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45
Which of the following statements regarding the Bohr model of the atom is NOT correct?
A)Changes in the energy of the atom involve the electron transitioning between allowed orbits.
B)The atom has discrete energy levels described by a quantum number,n.
C)The electron does not radiate energy and spiral into the nucleus if it is in an allowed orbit.
D)The atom has zero energy when in its ground state.
E)The energy of an orbit is inversely proportional to n2.
A)Changes in the energy of the atom involve the electron transitioning between allowed orbits.
B)The atom has discrete energy levels described by a quantum number,n.
C)The electron does not radiate energy and spiral into the nucleus if it is in an allowed orbit.
D)The atom has zero energy when in its ground state.
E)The energy of an orbit is inversely proportional to n2.
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46
What is the kinetic energy of the photoelectrons emitted from a sodium surface ( = 2.9 10-19 J)when it is irradiated by photons with a wavelength of 350 nm?
A)2.9 10-19 J
B)5.7 10-19 J
C)0 J
D)2.8 10-19 J
E)3.6 10-19 J
A)2.9 10-19 J
B)5.7 10-19 J
C)0 J
D)2.8 10-19 J
E)3.6 10-19 J
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47
A hydrogen atom is excited to ninitial = 8.A 955 nm photon is emitted as the electron falls to nfinal = __________.
A)6
B)5
C)4
D)3
E)2
A)6
B)5
C)4
D)3
E)2
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48
What is the longest wavelength of light emitted by an excited hydrogen atom when nfinal = 1?
A)91.16 nm
B)121.5 nm
C)273.5 nm
D)364.6 nm
E)656.2 nm
A)91.16 nm
B)121.5 nm
C)273.5 nm
D)364.6 nm
E)656.2 nm
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49
Work function values are often given in electron volts (1 eV = 1.602 10-19J).You create an oxide material that has a work function of 6.10 eV.How many electrons would be emitted from the material per second when it is irradiated by the 172 nm light of a 55.0 watt xenon excimer lamp,and what is their kinetic energy? Assume all of the incident photons cause electron emission.
A)none; 172 nm is not energetic enough
B)8.70 1017 electrons; 8.70 10-19 J
C)4.78 1019 electrons; 1.73 10-19 J
D)5.5 1017 electrons; 5.40 10-17 J
E)1.86 1016 electrons; 5.37 10-17 J
A)none; 172 nm is not energetic enough
B)8.70 1017 electrons; 8.70 10-19 J
C)4.78 1019 electrons; 1.73 10-19 J
D)5.5 1017 electrons; 5.40 10-17 J
E)1.86 1016 electrons; 5.37 10-17 J
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50
The energy change for an electronic transition in a one-electron atom or ion (H,He+,Li2+,etc.)from ninitial to nfinal is given by
,where Z is the atomic number. Which one of the following species will have the longest wavelength emission line for the transition between the ninitial = 2 and nfinal = 1 levels?
A)H
B)He+
C)Li2+
D)Be3+
E)B4+
,where Z is the atomic number. Which one of the following species will have the longest wavelength emission line for the transition between the ninitial = 2 and nfinal = 1 levels?A)H
B)He+
C)Li2+
D)Be3+
E)B4+
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51
Which of the following transitions emits the longest wavelength photon?
A)n1 = 14 to n2 = 13
B)n1 = 6 to n2 = 4
C)n1 = 4 to n2 = 3
D)n1 = 7 to n2 = 5
E)n1 = 4 to n2 = 2
A)n1 = 14 to n2 = 13
B)n1 = 6 to n2 = 4
C)n1 = 4 to n2 = 3
D)n1 = 7 to n2 = 5
E)n1 = 4 to n2 = 2
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52
What is the shortest wavelength of light emitted by an excited hydrogen atom when nfinal = 2?
A)91.16 nm
B)121.5 nm
C)273.5 nm
D)364.6 nm
E)656.3 nm
A)91.16 nm
B)121.5 nm
C)273.5 nm
D)364.6 nm
E)656.3 nm
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53
You think you have identified a new type of atom based on its atomic emission spectrum.Based on empirical data,it appears as though the energy levels of the atom are inversely proportional to n2,like hydrogen.When an electron falls from ninitial = 5 to nfinal = 2,a 1.4 10-18 J photon is emitted.What is the value of the Rydberg constant for this atom?
A)6.7 10-18 J
B)4.7 10-18 J
C)4.2 10-18 J
D)1.5 1017 J
E)2.1 1017 J
A)6.7 10-18 J
B)4.7 10-18 J
C)4.2 10-18 J
D)1.5 1017 J
E)2.1 1017 J
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54
How much energy would be required to excited one mole of hydrogen atoms from their ground state to n2 = 10?
A)1.3 103 J/mol
B)1.3 106 J/mol
C)2.2 103 J/mol
D)2.2 106 J/mol
E)9.2 102 J
A)1.3 103 J/mol
B)1.3 106 J/mol
C)2.2 103 J/mol
D)2.2 106 J/mol
E)9.2 102 J
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55
Electromagnetic radiation with a frequency of 8.6 1014 Hz incident on an unknown metal surface causes ejection of photoelectrons with kinetic energies of 1.3 10-19 J.What is the unknown metal?
A)rubidium ( = 3.5 10-19 J)
B)gold ( = 8.2 10-19 J)
C)nickel ( = 8.3 10-19 J)
D)sodium ( = 4.4 10-19 J)
E)platinum ( = 9.1 10-19 J)
A)rubidium ( = 3.5 10-19 J)
B)gold ( = 8.2 10-19 J)
C)nickel ( = 8.3 10-19 J)
D)sodium ( = 4.4 10-19 J)
E)platinum ( = 9.1 10-19 J)
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56
Which of the transitions in the hydrogen atom energy-level diagram shown here is not possible? 
A)all are possible
B)a
C)b
D)c
E)d

A)all are possible
B)a
C)b
D)c
E)d
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57
Determine the wavelength of the line in the hydrogen atomic emission spectrum corresponding to the ninitial = 4 to nfinal = 3 transition.
A)1094 nm
B)1875 nm
C)656 nm
D)335 nm
E)109 nm
A)1094 nm
B)1875 nm
C)656 nm
D)335 nm
E)109 nm
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58
What wavelength of light is required to cause the ejection of photoelectrons with kinetic energies of 5.0 10-20 J from a calcium surface ( = 4.60 10-19 J)?
A)485 nm
B)390 nm
C)308 nm
D)632 nm
E)480 nm
A)485 nm
B)390 nm
C)308 nm
D)632 nm
E)480 nm
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59
Which transition in a hydrogen atom will cause emission of the shortest wavelength photon?
A)ninitial = 5 to nfinal = 3
B)ninitial = 4 to nfinal = 3
C)ninitial = 4 to nfinal = 2
D)ninitial = 3 to nfinal = 2
E)ninitial = 3 to nfinal = 1
A)ninitial = 5 to nfinal = 3
B)ninitial = 4 to nfinal = 3
C)ninitial = 4 to nfinal = 2
D)ninitial = 3 to nfinal = 2
E)ninitial = 3 to nfinal = 1
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60
What is the difference in energy between the two electronic levels in hydrogen that are responsible for the emission line in the observed at 1282 nm,and to which series does this line belong?
A)1.55 10-19 J,Balmer
B)1.05 10-19 J,Paschen
C)1.55 10-19 J,Paschen
D)1.82 10-19 J,Balmer
E)1.82 10-19 J,Lyman
A)1.55 10-19 J,Balmer
B)1.05 10-19 J,Paschen
C)1.55 10-19 J,Paschen
D)1.82 10-19 J,Balmer
E)1.82 10-19 J,Lyman
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61
The energy of a one-electron atom or ion is given by
,where Z is the atomic number of the element.Which of the following one-electron ions would require the most energy to remove its electron?
A)Li2+
B)Be3+
C)He+
D)B4+
E)C5+
,where Z is the atomic number of the element.Which of the following one-electron ions would require the most energy to remove its electron?A)Li2+
B)Be3+
C)He+
D)B4+
E)C5+
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62
An electron __________ will have the smallest de Broglie wavelength.
A)moving at 220 m/s
B)moving at 20 mi/hr
C)moving at 3600 km/s
D)moving at 25% the speed of light
E)moving at 2.998 108 km/hr
A)moving at 220 m/s
B)moving at 20 mi/hr
C)moving at 3600 km/s
D)moving at 25% the speed of light
E)moving at 2.998 108 km/hr
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63
What is the velocity of an oxygen molecule if its de Broglie wavelength is 26 pm? (1 amu = 1.66054 10-27 kg)
A)46 m/s
B)960 m/s
C)790 m/s
D)390 m/s
E)480 m/s
A)46 m/s
B)960 m/s
C)790 m/s
D)390 m/s
E)480 m/s
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64
The energy change for an electronic transition in a one-electron atom or ion (H,He+,Li2+,etc.)from ninitial to nfinal is given by
,where Z is the atomic number. How much energy is required to ionize a ground-state He+ ion (nfinal = )?
A)2.18 10-18 J
B)4.36 10-18 J
C)8.72 10-18 J
D)1.09 10-18 J
E)5.45 10-19 J
,where Z is the atomic number. How much energy is required to ionize a ground-state He+ ion (nfinal = )?A)2.18 10-18 J
B)4.36 10-18 J
C)8.72 10-18 J
D)1.09 10-18 J
E)5.45 10-19 J
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65
What is the de Broglie wavelength of an electron (9.11 10-31 kg)traveling at 95% of the speed of light?
A)2.6 fm
B)2.6 pm
C)240 pm
D)24 fm
E)2.4 pm
A)2.6 fm
B)2.6 pm
C)240 pm
D)24 fm
E)2.4 pm
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66
Which of the following statements regarding the energy of a particle is NOT correct?
A)The ground state of a particle is the lowest and most stable energy state.
B)The energy of a particle is zero when it is in its ground state.
C)An excited state is any energy state above the ground state.
D)When the particle undergoes a transition from a higher energy state to a lower one,energy is emitted.
E)The energy state of a particle increases when it absorbs a photon.
A)The ground state of a particle is the lowest and most stable energy state.
B)The energy of a particle is zero when it is in its ground state.
C)An excited state is any energy state above the ground state.
D)When the particle undergoes a transition from a higher energy state to a lower one,energy is emitted.
E)The energy state of a particle increases when it absorbs a photon.
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67
Calculate the de Broglie wavelength of an electron (9.11 10-31 kg)when the distance it travels in one second is equal to its wavelength.
A)22.9 mm
B)37.0 m
C)1.38 km
D)2.70 cm
E)0.727 mm
A)22.9 mm
B)37.0 m
C)1.38 km
D)2.70 cm
E)0.727 mm
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68
If the electron (9.11 10-31 kg)in the hydrogen atom is traveling at about 2.2 106 m/s ± 5%,what is the uncertainty in electron's position?
A)±58 μm
B)±220 nm
C)±130 pm
D)±260 pm
E)±5.2 fm
A)±58 μm
B)±220 nm
C)±130 pm
D)±260 pm
E)±5.2 fm
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69
What is the de Broglie wavelength of a fast neutron (1.6749 10-27 kg)traveling at 14,000 km/s?
A)53 fm
B)5.3 pm
C)28 pm
D)28 fm
E)25 m/s
A)53 fm
B)5.3 pm
C)28 pm
D)28 fm
E)25 m/s
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70
What is the approximate total uncertainty in the velocity of an electron (9.11 10-31 kg)confined within a gold atom whose diameter is about 270 pm? The uncertainty in the position of the electron is ±5.0% of the atom's diameter.
A)±1.4 103 m/s
B)±2.1 105 m/s
C)±3.7 105 m/s
D)±2.1 106 m/s
E)±4.3 106 m/s
A)±1.4 103 m/s
B)±2.1 105 m/s
C)±3.7 105 m/s
D)±2.1 106 m/s
E)±4.3 106 m/s
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71
Which of the following objects,all moving at the same speed,will have the longest de Broglie wavelength?
A)a proton
B)an electron
C)a baseball
D)a neon atom
E)a neutron
A)a proton
B)an electron
C)a baseball
D)a neon atom
E)a neutron
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72
De Broglie reasoned that for the electron in the hydrogen atom to behave as a stable circular wave,the circumference of the electron's orbit must be __________
A)equal to the wavelength of the electron.
B)an integer multiple of the electron's wavelength.
C)a half-integer multiple of the electron's wavelength.
D)twice the wavelength of the electron.
E)twice the diameter of the orbit.
A)equal to the wavelength of the electron.
B)an integer multiple of the electron's wavelength.
C)a half-integer multiple of the electron's wavelength.
D)twice the wavelength of the electron.
E)twice the diameter of the orbit.
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73
What is the speed of an average argon atom that has a de Broglie wavelength of 5.2 pm? (1 amu = 1.66054 10-27 kg)
A)0.52 m/s
B)5.2 103 m/s
C)1.9 103 m/s
D)1.9 m/s
E)25 m/s
A)0.52 m/s
B)5.2 103 m/s
C)1.9 103 m/s
D)1.9 m/s
E)25 m/s
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74
What is the approximate uncertainty in the position of a proton (1.673 10-27 kg)in a particle accelerator if its velocity is known to about ±2.5 m/s (total uncertainty is 5.0 m/s)?
A)±6.4 10-9 m
B)±3.2 10-9 m
C)±1.3 10-9 m
D)±3.2 10-8 m
E)±6.4 10-10 m
A)±6.4 10-9 m
B)±3.2 10-9 m
C)±1.3 10-9 m
D)±3.2 10-8 m
E)±6.4 10-10 m
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75
The absorption and emission spectra of an atom and its ion(s)are different.This is evidence that the spectra observed are due to energy changes associated with the __________
A)electrons.
B)protons.
C)neutrons.
D)nuclei.
E)electromagnetic interactions.
A)electrons.
B)protons.
C)neutrons.
D)nuclei.
E)electromagnetic interactions.
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76
According to de Broglie's explanation of matter waves,if the circumference of the electron's orbit in the hydrogen atom is twice the electron's wavelength,the orbit will __________
A)decay until the electron falls into the nucleus.
B)diverge,allowing the electron to escape.
C)be stable.
D)cause the electron to emit a photon.
E)not be circular.
A)decay until the electron falls into the nucleus.
B)diverge,allowing the electron to escape.
C)be stable.
D)cause the electron to emit a photon.
E)not be circular.
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77
The de Broglie wavelength of buckyballs (buckminsterfullerene,C60)has been observed experimentally.If a C60 molecule (1.20 10-24 kg)has a velocity of 220 m/s,what is its de Broglie wavelength?
A)2.52 pm
B)2.52 fm
C)2.52 m
D)1.20 pm
E)5.22 m
A)2.52 pm
B)2.52 fm
C)2.52 m
D)1.20 pm
E)5.22 m
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78
The emission spectra of Na and Na+ are different because __________
A)Na+ has fewer electrons.
B)Na has fewer electrons.
C)Na+ has more protons.
D)Na has fewer neutrons.
E)Na has more protons.
A)Na+ has fewer electrons.
B)Na has fewer electrons.
C)Na+ has more protons.
D)Na has fewer neutrons.
E)Na has more protons.
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79
How many times longer is the de Broglie wavelength of a helium atom (6.647 10-27kg)moving at 220 m/s than that of a baseball (0.145 kg)moving at 35 m/s?
A)3.5 1024
B)2.2 1025
C)9.5 1033
D)1.5 109
E)3.7 1034
A)3.5 1024
B)2.2 1025
C)9.5 1033
D)1.5 109
E)3.7 1034
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80
The de Broglie wavelength of a particle traveling at 1% of the speed of light is 33.25 fm.Identify the particle from the following.(1 amu = 1.66054 10-27 kg)
A)a proton (1.00727 amu)
B)a neutron (1.00866 amu)
C)an electron (0.0005486 amu)
D)a hydrogen atom
E)a helium atom
A)a proton (1.00727 amu)
B)a neutron (1.00866 amu)
C)an electron (0.0005486 amu)
D)a hydrogen atom
E)a helium atom
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