Deck 10: Quantity Relationships in Chemical Reactions

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Question
Consider the hypothetical reaction A + 2 B \rightarrow AB2.If 2 moles of A and 5 moles of B are placed in a container an allowed to react,how many moles of AB2 will be formed and how many moles of which reactant will remain unreacted?

A)2 moles of AB2 will form and 3 moles of B will remain unreacted.
B)2 moles of AB2 will form and 1 mole of B will remain unreacted.
C)5 moles of AB2 will form and 3 moles of B will remain unreacted.
D)4 moles of AB2 will form and 1 mole of B will remain unreacted.
E)5/2 (2.5)moles of AB2 will form and nothing will remain unreacted.
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Question
Consider the conversion diagram given below. <strong>Consider the conversion diagram given below.   At which point(s)in the diagram is a molar mass needed?</strong> A)A and B B)B and E C)A and D D)D and E E)C only <div style=padding-top: 35px> At which point(s)in the diagram is a molar mass needed?

A)A and B
B)B and E
C)A and D
D)D and E
E)C only
Question
How many moles of oxygen are consumed in the complete combustion of 1.60 moles of benzene,C6H6?

A)6.00 mol
B)12.0 mol
C)15.0 mol
D)18.0 mol
E)24.0 mol
Question
In reacting aluminum carbonate with hydrochloric acid according to the equation Al2(CO3)3 + 6 HCl \rightarrow 2 AlCl3 + 3 H2O + 3 CO2,57.6 mg of carbon dioxide was formed.What mass of aluminum carbonate reacted to form this amount of carbon dioxide?

A)10.8 mg
B)32.5 mg
C)102 mg
D)306 mg
E)919 mg
Question
In the reaction P4 + 5 O2 \rightarrow 2 P2O5,in order the convert from moles of any substance to moles of another substance as shown by the block diagram.  <strong>In the reaction P<sub>4</sub> + 5 O<sub>2</sub>  \rightarrow  2 P<sub>2</sub>O<sub>5</sub>,in order the convert from moles of any substance to moles of another substance as shown by the block diagram.   What is the conversion factor needed?</strong> A)molar mass of a reactant B)molar mass of a product C)mole ratio from the equation D)Avogadro's number <div style=padding-top: 35px>  What is the conversion factor needed?

A)molar mass of a reactant
B)molar mass of a product
C)mole ratio from the equation
D)Avogadro's number
Question
The reaction C6H6 + HNO3 \rightarrow C6H5NO2 + H2O has a 73.5 percent yield under certain conditions.If 12.75 g of C6H6 is used,how much C6H5NO2 will be produced?

A)20.1 g
B)27.4 g
C)8.09 g
D)11.0 g
E)14.8 g
Question
Which of the following defines the percent yield for a reaction?

A) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
B) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
C) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
D) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
Question
How many moles of water are produced by burning 5.77 moles of C4H10?

A)1.15 mol
B)5.77 mol
C)23.1 mol
D)28.9 mol
E)37.5 mol
Question
Which of the following best describes a limiting reactant?

A)The reactant that limits the rate (or speed)of a chemical reaction.
B)The reactant that limits the position of equilibrium in a reversible chemical change.
C)The reactant that remains at the end of the reaction.
D)The reactant that can produce the greatest amount of product.
E)The reactant that is completely used up by a reaction.
Question
How many moles of bromine will react with 0.0500 mole of C2H2 in the reaction C2H4 + Br2 \rightarrow C2H4Br2?

A)0.100 mol
B)0.186 mol
C)0.0250 mol
D)0.0500 mol
E)2.00 mol
Question
In the reaction CaCN2 + 3 H2O \rightarrow CaCO3 + 2 NH3,how many kilograms of NH3 will be produced when 25.0 kg of CaCN2 react with excess water?

A)10.6 kg
B)12.9 kg
C)2.66 kg
D)5.31 kg
E)7.56 kg
Question
Barium chloride was used to precipitate silver chloride from a solution of silver nitrate.What mass of barium chloride had to react if 0.635 g of silver chloride formed?

A)0.437 g
B)0.461 g
C)0.874 g
D)0.923 g
E)1.85 g
Question
In the reaction 2 AgI + HgI2 \rightarrow Ag2HgI4,2.00 g of AgI and 3.50 g of HgI2 were used.What is the limiting reactant?

A)AgI
B)HgI2
C)Ag2HgI4
D)There is no limiting reactant.
Question
A chemical reaction resulted in 1.376 g of product,which represented a 78.5 percent yield for the reaction.What is the theoretical yield?

A)0.785 g
B)1.08 g
C)10.8 g
D)1.75 g
E)2.16 g
Question
In the complete combustion of C3H8O3,how many moles of carbon dioxide are produced when 23.0 g of C3H8O3 burns?

A)0.250 mol
B)0.750 mol
C)0.0833 mol
D)3.00 mol
E)33.0 mol
Question
Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?

A) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
B) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
C) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
D) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)   <div style=padding-top: 35px>
Question
PCl5 can be produced by the reaction PCl3 + Cl2 \rightarrow PCl5.What mass of PCl3 must be used to produce 127 g of PCl5 if the percent yield is 84.8%?

A)71.1 g
B)83.8 g
C)98.8 g
D)108 g
E)150 g
Question
How many moles of C6H12O6 are formed when 0.250 mole of CO2 is consumed in the reaction 6 CO2 + 6 H2O \rightarrow C6H12O6 + 6 O2?

A)1.50 mol
B)1.00 mol
C)0.250 mol
D)0.167 mol
E)0.0417 mol
Question
The reaction 2 Sb + 3 Cl2 \rightarrow 2 SbCl3 has an 88.3% yield.If 4.07 g of SbCl3 is desired,what mass of chlorine should be used?

A)2.15 g
B)0.957 g
C)1.68 g
D)1.90 g
E)3.00 g
Question
In the combustion of natural gas according to the equation CH4 + 2 O2 \rightarrow CO2 + 2 H2O,how many grams of water are formed during the combustion of 0.264 mole of CH4?

A)0.528 g
B)2.00 g
C)2.38 g
D)4.75 g
E)9.50 g
Question
When one mole of gaseous hydrogen peroxide,H2O2,is made from hydrogen and oxygen gases,the enthalpy change is -136 kJ.Which of the following correctly represents the thermochemical equation?
(i)H2(g)+ O2(g) \rightarrow H2O2(g)+ 136 kJ
(ii)H2(g)+ O2(g)+ 136 kJ \rightarrow H2O2(g)
(iii)H2(g)+ O2(g) \rightarrow H2O2(g)?0?H = -136 kJ
(iv)H2(g)+ O2(g) \rightarrow H2O2(g)?0?H = +136 kJ

A)i only
B)ii only
C)iii only
D)i and iii
E)ii and iv
Question
Ammonium sulfate can be made by the reaction H2SO4 + 2 NH3 \rightarrow (NH4)2SO4.What quantity of ammonium sulfate will result from the reaction of 5.00 kg of ammonia and 20.0 kg of sulfuric acid?

A)13.5 kg
B)19.4 kg
C)25.0 kg
D)26.9 kg
E)38.8 kg
Question
Formation of two moles of hydrogen chloride gas from the gases hydrogen and chlorine is a reaction for which Δ\Delta H is -185 kJ.Which of the following statements is correct?
(i)The reaction is exothermic.
(ii)Enthalpy of the system decreases.
(iii)Heat is a "product".

A)All are correct
B)All are incorrect
C)i only
D)ii only
E)iii only
Question
How much energy is required to produce 1.00 kg of aluminum by the reaction 2 Al2O3(s)+ 3 C(s)+ 1.97 * 103 kJ \rightarrow 4 Al(s)+ 3 CO2(g)?

A)5.50 * 10-5 kJ
B)7.52 * 10-2 kJ
C)2.70 *103 kJ
D)7.30 * 104 kJ
E)1.83 * 104 kJ
Question
Δ\Delta H = +572 kJ for the decomposition of water by the reaction 2 H2O(  <strong> \Delta H = +572 kJ for the decomposition of water by the reaction 2 H<sub>2</sub>O(   ) \rightarrow 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g).How many grams of water can be decomposed by 5.00 *10<sup>3</sup> kJ of energy?</strong> A)157 g B)315 g C)0.0629 g D)2.57* 10<sup>7</sup> g E)5.15 * 10<sup>7</sup> g <div style=padding-top: 35px>  ) \rightarrow 2 H2(g)+ O2(g).How many grams of water can be decomposed by 5.00 *103 kJ of energy?

A)157 g
B)315 g
C)0.0629 g
D)2.57* 107 g
E)5.15 * 107 g
Question
The metabolism of glucose can be represented by the equation C6H12O6(s)+ 6 O2(g) \rightarrow 6 CO2(g)+ 6 H2O(g) Δ\Delta H = -2.82 *103 kJ.How many grams of glucose must be metabolized to produce 282 kJ of energy?

A)18.0 g
B)1.80 * 102 g
C)0.100 g
D)10.0 g
E)67.4 g
Question
Cu2HgI4 is prepared according to the equation 2 CuI + HgI2 \rightarrow Cu2HgI4.When 2.00 g of each reactant are used,which one is the limiting reactant?

A)Both reactants are limiting
B)This reaction has no limiting reactant
C)CuI
D)HgI2
E)Cu2HgI4
Question
A typical diet provides about 2000 food Calories per day,or 2000 kilocalories.Calculate the equivalent number of joules.

A)8 J
B)8 *103 J
C)8 * 106 J
D)0.5 J
E)5 * 105 J
Question
A typical candy bar contains 281 food Calories,which is 281 kcal.How many kilojoules are contained in one such candy bar?

A)1.18 * 103 kJ
B)1.18 *104 kJ
C)67.2 kJ
D)672 kJ
E)6.72 * 104 kJ
Question
When 1.00 g of C6H12O6(s)is formed during photosynthesis,15.67 kJ of the sun's energy is converted to chemical energy.What is the thermochemical equation for the photosynthesis of glucose?

A)6 CO2(g)+ 6 H2O(g) \rightarrow C6H12O6(s)+ 6 O2(g)+ 15.67 kJ
B)CO2(g)+ H2O(g) \rightarrow C6H12O6(s)+ O2(g)?0?H = 15.67 kJ
C)6 CO2(g)+ 6 H2O(g)+ 2.82 *103 kJ \rightarrow C6H12O6(s)+ 6 O2(g)
D)C6H12O6(s)+ 6 O2(g) \rightarrow 6 CO2(g)+ 6 H2O(g)+ 2.82*103 kJ
E)6 CO2(g)+ 6 H2O(g) \rightarrow C6H12O6(s)+ 6 O2(g)?0?H = -2.82 * 103 kJ
Question
If the reaction N2 + 3 H2 \rightarrow 2 NH3 is carried out using 1.40 g of N2 and 0.400 g of H2,what mass of excess reactant will remain?

A)0.200 g N2
B)1.00 g N2
C)0.100 g H2
D)0.300 g H2
E)Both reactants will be completely consumed
Question
The thermochemical equation describing the heat change in the decomposition of limestone,CaCO3,is given by CaCO3(s)+ 176 kJ \rightarrow CaO(s)+ CO2(g).What is the heat change that accompanies the decomposition of 25.0 g of limestone?

A)7.12 kJ
B)25.0 kJ
C)44.0 kJ
D)176 kJ
E)1.42 *10-3 kJ
Question
Consider the following thermochemical equation: CaO(s)+ H2O(  <strong>Consider the following thermochemical equation: CaO(s)+ H<sub>2</sub>O(   ) \rightarrow  Ca(OH)<sub>2</sub>(s) \Delta H = -66.5 kJ Which of the following statements is/are correct? (i)The reaction is exothermic (ii)The reaction releases 66.5 kJ per gram of Ca(OH)<sub>2</sub>(s)formed (iii)Alternatively,the \Delta H term could be added to the product side of the equation</strong> A)i only B)ii only C)i and ii D)i and iii E)i,ii,and iii <div style=padding-top: 35px>  ) \rightarrow Ca(OH)2(s) Δ\Delta H = -66.5 kJ Which of the following statements is/are correct?
(i)The reaction is exothermic
(ii)The reaction releases 66.5 kJ per gram of Ca(OH)2(s)formed
(iii)Alternatively,the Δ\Delta H term could be added to the product side of the equation

A)i only
B)ii only
C)i and ii
D)i and iii
E)i,ii,and iii
Question
Convert 357 J to kcal.

A)1.49 kcal
B)1.49 * 106 kcal
C)8.53 *104 kcal
D)85.3 kcal
E)0.0853 kcal
Question
The decomposition of potassium chlorate is written as shown below.What energy change occurs when 12.3 g of KClO3 decompose? 2 KClO3(s)+ 89.6 kJ \rightarrow 2 KCl(s)+ 3 O2(g)

A)Release of 8.99 kJ
B)Absorption of 8.99 kJ
C)Release of 4.49 kJ
D)Absorption of 4.49 kJ
E)Release of 0.00112 kJ
Question
Aqueous HCl is added to an aqueous solution of NaOH at 25 °C and the result is shown in the figure below.  <strong>Aqueous HCl is added to an aqueous solution of NaOH at 25 °C and the result is shown in the figure below.   Which of the following correctly characterizes this reaction?</strong> A)The reaction is exothermic. B)The  \Delta H for the reaction has a + sign. C)Energy could be considered to be a reactant in the equation for the reaction. D)The energy (enthalpy)of the products is greater than the reactants. E)This reaction consumes energy. <div style=padding-top: 35px>  Which of the following correctly characterizes this reaction?

A)The reaction is exothermic.
B)The Δ\Delta H for the reaction has a + sign.
C)Energy could be considered to be a reactant in the equation for the reaction.
D)The energy (enthalpy)of the products is greater than the reactants.
E)This reaction consumes energy.
Question
A chemist combines hydrochloric acid with a sodium hydroxide solution,transferring 5.75 kJ of heat.Express this in calories.

A)2.41* 10-2 cal
B)2.41* 101 cal
C)2.41 *104 cal
D)1.37 *10-3 cal
E)1.37 * 103 cal
Question
Calculate the mass of Na2O that can be produced by the reaction of 4.00 g of sodium and 2.00 g of oxygen in the reaction 4 Na + O2 \rightarrow 2 Na2O.

A)1.94 g
B)2.00 g
C)4.50 g
D)5.39 g
E)6.00 g
Question
When C2H5Cl(g)is burned in oxygen,chlorine gas is produced in addition to carbon dioxide and water vapor.5145 kJ of heat are released for every four moles of C2H5Cl(g)burned.Which of the following correctly represents the thermochemical equation?

A)4 C2H5Cl(g)+ 5145 kJ + 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
B)4 C2H5Cl(g)+ 13 O2(g)+ 5145 kJ \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
C)4 C2H5Cl(g)+ 13 O2(g) \rightarrow (5145 kJ) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
D)4 C2H5Cl(g)+ 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)?0?H = +5145 kJ
E)4 C2H5Cl(g)+ 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)?0?H = -5145 kJ
Question
What is the theoretical yield of phosphorus triiodide when 4.50 g of phosphorus is combined with 45.0 g of iodine? The compound is made by the direct combination of the elements.

A)48.7 g
B)49.5 g
C)59.8 g
D)30.0 g
E)39.9 g
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Deck 10: Quantity Relationships in Chemical Reactions
1
Consider the hypothetical reaction A + 2 B \rightarrow AB2.If 2 moles of A and 5 moles of B are placed in a container an allowed to react,how many moles of AB2 will be formed and how many moles of which reactant will remain unreacted?

A)2 moles of AB2 will form and 3 moles of B will remain unreacted.
B)2 moles of AB2 will form and 1 mole of B will remain unreacted.
C)5 moles of AB2 will form and 3 moles of B will remain unreacted.
D)4 moles of AB2 will form and 1 mole of B will remain unreacted.
E)5/2 (2.5)moles of AB2 will form and nothing will remain unreacted.
2 moles of AB2 will form and 1 mole of B will remain unreacted.
2
Consider the conversion diagram given below. <strong>Consider the conversion diagram given below.   At which point(s)in the diagram is a molar mass needed?</strong> A)A and B B)B and E C)A and D D)D and E E)C only At which point(s)in the diagram is a molar mass needed?

A)A and B
B)B and E
C)A and D
D)D and E
E)C only
A and D
3
How many moles of oxygen are consumed in the complete combustion of 1.60 moles of benzene,C6H6?

A)6.00 mol
B)12.0 mol
C)15.0 mol
D)18.0 mol
E)24.0 mol
12.0 mol
4
In reacting aluminum carbonate with hydrochloric acid according to the equation Al2(CO3)3 + 6 HCl \rightarrow 2 AlCl3 + 3 H2O + 3 CO2,57.6 mg of carbon dioxide was formed.What mass of aluminum carbonate reacted to form this amount of carbon dioxide?

A)10.8 mg
B)32.5 mg
C)102 mg
D)306 mg
E)919 mg
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5
In the reaction P4 + 5 O2 \rightarrow 2 P2O5,in order the convert from moles of any substance to moles of another substance as shown by the block diagram.  <strong>In the reaction P<sub>4</sub> + 5 O<sub>2</sub>  \rightarrow  2 P<sub>2</sub>O<sub>5</sub>,in order the convert from moles of any substance to moles of another substance as shown by the block diagram.   What is the conversion factor needed?</strong> A)molar mass of a reactant B)molar mass of a product C)mole ratio from the equation D)Avogadro's number  What is the conversion factor needed?

A)molar mass of a reactant
B)molar mass of a product
C)mole ratio from the equation
D)Avogadro's number
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6
The reaction C6H6 + HNO3 \rightarrow C6H5NO2 + H2O has a 73.5 percent yield under certain conditions.If 12.75 g of C6H6 is used,how much C6H5NO2 will be produced?

A)20.1 g
B)27.4 g
C)8.09 g
D)11.0 g
E)14.8 g
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7
Which of the following defines the percent yield for a reaction?

A) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)
B) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)
C) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)
D) <strong>Which of the following defines the percent yield for a reaction?</strong> A)   B)   C)   D)
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8
How many moles of water are produced by burning 5.77 moles of C4H10?

A)1.15 mol
B)5.77 mol
C)23.1 mol
D)28.9 mol
E)37.5 mol
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9
Which of the following best describes a limiting reactant?

A)The reactant that limits the rate (or speed)of a chemical reaction.
B)The reactant that limits the position of equilibrium in a reversible chemical change.
C)The reactant that remains at the end of the reaction.
D)The reactant that can produce the greatest amount of product.
E)The reactant that is completely used up by a reaction.
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10
How many moles of bromine will react with 0.0500 mole of C2H2 in the reaction C2H4 + Br2 \rightarrow C2H4Br2?

A)0.100 mol
B)0.186 mol
C)0.0250 mol
D)0.0500 mol
E)2.00 mol
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11
In the reaction CaCN2 + 3 H2O \rightarrow CaCO3 + 2 NH3,how many kilograms of NH3 will be produced when 25.0 kg of CaCN2 react with excess water?

A)10.6 kg
B)12.9 kg
C)2.66 kg
D)5.31 kg
E)7.56 kg
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12
Barium chloride was used to precipitate silver chloride from a solution of silver nitrate.What mass of barium chloride had to react if 0.635 g of silver chloride formed?

A)0.437 g
B)0.461 g
C)0.874 g
D)0.923 g
E)1.85 g
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13
In the reaction 2 AgI + HgI2 \rightarrow Ag2HgI4,2.00 g of AgI and 3.50 g of HgI2 were used.What is the limiting reactant?

A)AgI
B)HgI2
C)Ag2HgI4
D)There is no limiting reactant.
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14
A chemical reaction resulted in 1.376 g of product,which represented a 78.5 percent yield for the reaction.What is the theoretical yield?

A)0.785 g
B)1.08 g
C)10.8 g
D)1.75 g
E)2.16 g
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15
In the complete combustion of C3H8O3,how many moles of carbon dioxide are produced when 23.0 g of C3H8O3 burns?

A)0.250 mol
B)0.750 mol
C)0.0833 mol
D)3.00 mol
E)33.0 mol
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16
Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?

A) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)
B) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)
C) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)
D) <strong>Silver nitrate and magnesium chloride solutions are mixed.What is the Per expression that allows one to convert moles of silver nitrate to moles of magnesium chloride?</strong> A)   B)   C)   D)
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17
PCl5 can be produced by the reaction PCl3 + Cl2 \rightarrow PCl5.What mass of PCl3 must be used to produce 127 g of PCl5 if the percent yield is 84.8%?

A)71.1 g
B)83.8 g
C)98.8 g
D)108 g
E)150 g
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18
How many moles of C6H12O6 are formed when 0.250 mole of CO2 is consumed in the reaction 6 CO2 + 6 H2O \rightarrow C6H12O6 + 6 O2?

A)1.50 mol
B)1.00 mol
C)0.250 mol
D)0.167 mol
E)0.0417 mol
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19
The reaction 2 Sb + 3 Cl2 \rightarrow 2 SbCl3 has an 88.3% yield.If 4.07 g of SbCl3 is desired,what mass of chlorine should be used?

A)2.15 g
B)0.957 g
C)1.68 g
D)1.90 g
E)3.00 g
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20
In the combustion of natural gas according to the equation CH4 + 2 O2 \rightarrow CO2 + 2 H2O,how many grams of water are formed during the combustion of 0.264 mole of CH4?

A)0.528 g
B)2.00 g
C)2.38 g
D)4.75 g
E)9.50 g
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21
When one mole of gaseous hydrogen peroxide,H2O2,is made from hydrogen and oxygen gases,the enthalpy change is -136 kJ.Which of the following correctly represents the thermochemical equation?
(i)H2(g)+ O2(g) \rightarrow H2O2(g)+ 136 kJ
(ii)H2(g)+ O2(g)+ 136 kJ \rightarrow H2O2(g)
(iii)H2(g)+ O2(g) \rightarrow H2O2(g)?0?H = -136 kJ
(iv)H2(g)+ O2(g) \rightarrow H2O2(g)?0?H = +136 kJ

A)i only
B)ii only
C)iii only
D)i and iii
E)ii and iv
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22
Ammonium sulfate can be made by the reaction H2SO4 + 2 NH3 \rightarrow (NH4)2SO4.What quantity of ammonium sulfate will result from the reaction of 5.00 kg of ammonia and 20.0 kg of sulfuric acid?

A)13.5 kg
B)19.4 kg
C)25.0 kg
D)26.9 kg
E)38.8 kg
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23
Formation of two moles of hydrogen chloride gas from the gases hydrogen and chlorine is a reaction for which Δ\Delta H is -185 kJ.Which of the following statements is correct?
(i)The reaction is exothermic.
(ii)Enthalpy of the system decreases.
(iii)Heat is a "product".

A)All are correct
B)All are incorrect
C)i only
D)ii only
E)iii only
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24
How much energy is required to produce 1.00 kg of aluminum by the reaction 2 Al2O3(s)+ 3 C(s)+ 1.97 * 103 kJ \rightarrow 4 Al(s)+ 3 CO2(g)?

A)5.50 * 10-5 kJ
B)7.52 * 10-2 kJ
C)2.70 *103 kJ
D)7.30 * 104 kJ
E)1.83 * 104 kJ
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25
Δ\Delta H = +572 kJ for the decomposition of water by the reaction 2 H2O(  <strong> \Delta H = +572 kJ for the decomposition of water by the reaction 2 H<sub>2</sub>O(   ) \rightarrow 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g).How many grams of water can be decomposed by 5.00 *10<sup>3</sup> kJ of energy?</strong> A)157 g B)315 g C)0.0629 g D)2.57* 10<sup>7</sup> g E)5.15 * 10<sup>7</sup> g  ) \rightarrow 2 H2(g)+ O2(g).How many grams of water can be decomposed by 5.00 *103 kJ of energy?

A)157 g
B)315 g
C)0.0629 g
D)2.57* 107 g
E)5.15 * 107 g
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26
The metabolism of glucose can be represented by the equation C6H12O6(s)+ 6 O2(g) \rightarrow 6 CO2(g)+ 6 H2O(g) Δ\Delta H = -2.82 *103 kJ.How many grams of glucose must be metabolized to produce 282 kJ of energy?

A)18.0 g
B)1.80 * 102 g
C)0.100 g
D)10.0 g
E)67.4 g
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27
Cu2HgI4 is prepared according to the equation 2 CuI + HgI2 \rightarrow Cu2HgI4.When 2.00 g of each reactant are used,which one is the limiting reactant?

A)Both reactants are limiting
B)This reaction has no limiting reactant
C)CuI
D)HgI2
E)Cu2HgI4
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28
A typical diet provides about 2000 food Calories per day,or 2000 kilocalories.Calculate the equivalent number of joules.

A)8 J
B)8 *103 J
C)8 * 106 J
D)0.5 J
E)5 * 105 J
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29
A typical candy bar contains 281 food Calories,which is 281 kcal.How many kilojoules are contained in one such candy bar?

A)1.18 * 103 kJ
B)1.18 *104 kJ
C)67.2 kJ
D)672 kJ
E)6.72 * 104 kJ
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30
When 1.00 g of C6H12O6(s)is formed during photosynthesis,15.67 kJ of the sun's energy is converted to chemical energy.What is the thermochemical equation for the photosynthesis of glucose?

A)6 CO2(g)+ 6 H2O(g) \rightarrow C6H12O6(s)+ 6 O2(g)+ 15.67 kJ
B)CO2(g)+ H2O(g) \rightarrow C6H12O6(s)+ O2(g)?0?H = 15.67 kJ
C)6 CO2(g)+ 6 H2O(g)+ 2.82 *103 kJ \rightarrow C6H12O6(s)+ 6 O2(g)
D)C6H12O6(s)+ 6 O2(g) \rightarrow 6 CO2(g)+ 6 H2O(g)+ 2.82*103 kJ
E)6 CO2(g)+ 6 H2O(g) \rightarrow C6H12O6(s)+ 6 O2(g)?0?H = -2.82 * 103 kJ
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31
If the reaction N2 + 3 H2 \rightarrow 2 NH3 is carried out using 1.40 g of N2 and 0.400 g of H2,what mass of excess reactant will remain?

A)0.200 g N2
B)1.00 g N2
C)0.100 g H2
D)0.300 g H2
E)Both reactants will be completely consumed
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32
The thermochemical equation describing the heat change in the decomposition of limestone,CaCO3,is given by CaCO3(s)+ 176 kJ \rightarrow CaO(s)+ CO2(g).What is the heat change that accompanies the decomposition of 25.0 g of limestone?

A)7.12 kJ
B)25.0 kJ
C)44.0 kJ
D)176 kJ
E)1.42 *10-3 kJ
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33
Consider the following thermochemical equation: CaO(s)+ H2O(  <strong>Consider the following thermochemical equation: CaO(s)+ H<sub>2</sub>O(   ) \rightarrow  Ca(OH)<sub>2</sub>(s) \Delta H = -66.5 kJ Which of the following statements is/are correct? (i)The reaction is exothermic (ii)The reaction releases 66.5 kJ per gram of Ca(OH)<sub>2</sub>(s)formed (iii)Alternatively,the \Delta H term could be added to the product side of the equation</strong> A)i only B)ii only C)i and ii D)i and iii E)i,ii,and iii  ) \rightarrow Ca(OH)2(s) Δ\Delta H = -66.5 kJ Which of the following statements is/are correct?
(i)The reaction is exothermic
(ii)The reaction releases 66.5 kJ per gram of Ca(OH)2(s)formed
(iii)Alternatively,the Δ\Delta H term could be added to the product side of the equation

A)i only
B)ii only
C)i and ii
D)i and iii
E)i,ii,and iii
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34
Convert 357 J to kcal.

A)1.49 kcal
B)1.49 * 106 kcal
C)8.53 *104 kcal
D)85.3 kcal
E)0.0853 kcal
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35
The decomposition of potassium chlorate is written as shown below.What energy change occurs when 12.3 g of KClO3 decompose? 2 KClO3(s)+ 89.6 kJ \rightarrow 2 KCl(s)+ 3 O2(g)

A)Release of 8.99 kJ
B)Absorption of 8.99 kJ
C)Release of 4.49 kJ
D)Absorption of 4.49 kJ
E)Release of 0.00112 kJ
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36
Aqueous HCl is added to an aqueous solution of NaOH at 25 °C and the result is shown in the figure below.  <strong>Aqueous HCl is added to an aqueous solution of NaOH at 25 °C and the result is shown in the figure below.   Which of the following correctly characterizes this reaction?</strong> A)The reaction is exothermic. B)The  \Delta H for the reaction has a + sign. C)Energy could be considered to be a reactant in the equation for the reaction. D)The energy (enthalpy)of the products is greater than the reactants. E)This reaction consumes energy.  Which of the following correctly characterizes this reaction?

A)The reaction is exothermic.
B)The Δ\Delta H for the reaction has a + sign.
C)Energy could be considered to be a reactant in the equation for the reaction.
D)The energy (enthalpy)of the products is greater than the reactants.
E)This reaction consumes energy.
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37
A chemist combines hydrochloric acid with a sodium hydroxide solution,transferring 5.75 kJ of heat.Express this in calories.

A)2.41* 10-2 cal
B)2.41* 101 cal
C)2.41 *104 cal
D)1.37 *10-3 cal
E)1.37 * 103 cal
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38
Calculate the mass of Na2O that can be produced by the reaction of 4.00 g of sodium and 2.00 g of oxygen in the reaction 4 Na + O2 \rightarrow 2 Na2O.

A)1.94 g
B)2.00 g
C)4.50 g
D)5.39 g
E)6.00 g
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39
When C2H5Cl(g)is burned in oxygen,chlorine gas is produced in addition to carbon dioxide and water vapor.5145 kJ of heat are released for every four moles of C2H5Cl(g)burned.Which of the following correctly represents the thermochemical equation?

A)4 C2H5Cl(g)+ 5145 kJ + 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
B)4 C2H5Cl(g)+ 13 O2(g)+ 5145 kJ \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
C)4 C2H5Cl(g)+ 13 O2(g) \rightarrow (5145 kJ) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)
D)4 C2H5Cl(g)+ 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)?0?H = +5145 kJ
E)4 C2H5Cl(g)+ 13 O2(g) \rightarrow 2 Cl2(g)+ 8 CO2(g)+ 10 H2O(g)?0?H = -5145 kJ
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40
What is the theoretical yield of phosphorus triiodide when 4.50 g of phosphorus is combined with 45.0 g of iodine? The compound is made by the direct combination of the elements.

A)48.7 g
B)49.5 g
C)59.8 g
D)30.0 g
E)39.9 g
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