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The Relative Reactivity of the 1°: 2°: 3° Hydrogens of (CH3)3CCH2CH3

Question 109

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The relative reactivity of the 1°: 2°: 3° hydrogens of (CH3)3CCH2CH3 in free radical chlorination is 1: 3.8: 5.0. Provide the structure of each monochlorination product, and estimate the relative amount of each in the mixture of monochlorinated products.

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ClCH2C(CH3)2CH2CH3, 45.9%...

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