Exhibit 19-2
Consider the data below to answer the following question(s).
Cyanohydrins are important intermediates in the synthesis of α-hydroxycarboxylic acids from ketones and aldehydes.The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid.Nitriles can also be hydrolyzed to carboxylic acids using aqueous base.Unfortunately,when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated.
-Refer to Exhibit 19-2.The reaction of benzaldehyde with hydrogen cyanide is catalyzed by the addition of a small amount of KCN.Write the complete reaction mechanism for the KCN-catalyzed reaction.Show all electron flow with arrows and show all intermediate structures.

Question

Exhibit 19-2
Consider the data below to answer the following question(s).
Cyanohydrins are important intermediates in the synthesis of α-hydroxycarboxylic acids from ketones and aldehydes.The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid.Nitriles can also be hydrolyzed to carboxylic acids using aqueous base.Unfortunately,when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. 
-Refer to Exhibit 19-2.The reaction of benzaldehyde with hydrogen cyanide is catalyzed by the addition of a small amount of KCN.Write the complete reaction mechanism for the KCN-catalyzed reaction.Show all electron flow with arrows and show all intermediate structures.

Quizplus · Accepted Answer

The Answer of Exhibit 19-2
Consider the data below to answer the following question(s).
Cyanohydrins are important intermediates in the synthesis of α-hydroxycarboxylic acids from ketones and aldehydes.The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid.Nitriles can also be hydrolyzed to carboxylic acids using aqueous base.Unfortunately,when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. 
-Refer to Exhibit 19-2.The reaction of benzaldehyde with hydrogen cyanide is catalyzed by the addition of a small amount of KCN.Write the complete reaction mechanism for the KCN-catalyzed reaction.Show all electron flow with arrows and show all intermediate structures.

Exhibit 19-2 Consider the Data Below to Answer the Following Question(s)