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Given the Initial Rate Data for the Decomposition Reaction, a

Question 15

Multiple Choice

Given the initial rate data for the decomposition reaction, A ? B + C
Determine the rate expression for the reaction.
[A],MΔ[A]/ΔtM/s0.08412.4×1060.0639.3×1060.0426.2×106\begin{array} { l l } { [ \mathrm { A } ] , \mathrm { M } } & - \Delta [ \mathrm { A } ] / \Delta t \mathrm { M } / \mathrm { s } \\\hline0.084 & 12.4 \times 10 ^ { - 6 } \\0.063 & 9.3 \times 10 ^ { - 6 } \\0.042 & 6.2 \times 10 ^ { - 6 }\end{array}


A) Δ[A]Δt=1.5×104 s1[ A]\frac { - \Delta [ \mathrm { A } ] } { \Delta t } = 1.5 \times 10 ^ { - 4 } \mathrm {~s} ^ { - 1 } [ \mathrm {~A} ]
B) Δ[A]Δt=1.5×104M1 s1[ A]2\frac { - \Delta [ \mathrm { A } ] } { \Delta t } = 1.5 \times 10 ^ { - 4 } \mathrm { M } ^ { - 1 } \mathrm {~s} ^ { - 1 } [ \mathrm {~A} ] ^ { 2 }
C) Δ[A]Δt=1.8×109M1 s1[ A]2\frac { - \Delta [ \mathrm { A } ] } { \Delta t } = 1.8 \times 10 ^ { - 9 } \mathrm { M } ^ { - 1 } \mathrm {~s} ^ { - 1 } [ \mathrm {~A} ] ^ { 2 }
D) Δ[A]Δt=1.2×105Ms1\frac { - \Delta [ \mathrm { A } ] } { \Delta t } = 1.2 \times 10 ^ { - 5 } \mathrm { Ms } ^ { - 1 }
E) Δ[A]Δt=6.8×103 s1[ A]\frac { - \Delta [ \mathrm { A } ] } { \Delta t } = 6.8 \times 10 ^ { 3 } \mathrm {~s} ^ { - 1 } [ \mathrm {~A} ]

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