The bond angles in CH4, NH3, and H2O are 109.5°, 107°, and 104.5°, respectfully. Which of the statements best describes the variance in bond angles?
A) CH4 has no lone pairs of electrons on the central atom so the optimal molecular shape would be tetrahedral with bond angles of 109.5°. In NH3 and H2O there are 1 and 2 lone pairs, respectfully, so more repulsion exists between the bonds and lone pairs, as a result, the bond angles are less than 109.5°.
B) NH3 and H2O have a trigonal pyramidal and bent molecular shape, respectfully, which is the reason why the bond angles are less than 109.5°.
C) CH4 only has nonpolar bonds while NH3 and H2O have polar bonds which results in the difference in bond angels.
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