The following solvolysis reaction goes through a hydride shift to give the rearranged product.The hydrogen atom that moves is explicitly shown.
When this hydrogen atom is replaced with a deuterium atom, the rate of reaction slows
Considerably.Which of the following conclusions can be drawn correctly from this result?
A) The bromide ion leaves before the hydride shift occurs.
B) The hydride shift occurs, then the bromide ion leaves.
C) The hydride shift occurs at the same time as the bromide ion leaves.
D) These data describe the presence of a kinetic isotope effect.
E) Both c and d are reasonable conclusions.
Correct Answer:
Verified
Q1: What reagent(s) could be used to perform
Q2: Consider these two similar reactions and their
Q3: What experimental observation rules out the possibility
Q5: Anchimeric assistance
A)generally slows the rate of a
Q6: Why does the following reaction result in
Q7: Which product would be expected to form
Q8: Which of the following bicyclic amines will
Q9: Predict the product of the reaction conditions
Q10: Which of the following is an intermediate
Q11: Which of these can participate as neighboring
Unlock this Answer For Free Now!
View this answer and more for free by performing one of the following actions
Scan the QR code to install the App and get 2 free unlocks
Unlock quizzes for free by uploading documents