A branched-chain alkane will have a higher boiling point than a straight-chain alkane with the same number of carbons.

Name: A branched-chain alkane will have a higher boiling point than a straight-chain alkane with the same number of carbons.
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Branched-chain alkanes have lower boiling points than their straight-chain counterparts because the branching decreases the surface area available for van der Waals forces, thus reducing the intermolecular attractions.

A Branched-Chain Alkane Will Have a Higher Boiling Point Than