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A Galvanic Cell Consists of Two Beakers Which of the Following Is the Oxidation Half-Reaction That Occurs

Question 7

Multiple Choice

A galvanic cell consists of two beakers. One beaker contains a strip of lead immersed in aqueous sulfuric acid, and the other contains a platinum electrode immersed in aqueous nitric acid. The two solutions are connected by a salt bridge, and the electrodes are connected by a wire. Current begins to flow, and bubbles of a gas appear at the platinum electrode. The spontaneous redox reaction that occurs is described by the following balanced chemical equation: 3 Pb( s) +2NO3(aq) +8H+(aq) 3 Pb2+(aq) +2NO(g) +4H2O(l) 3 \mathrm {~Pb} ( \mathrm {~s} ) + 2 \mathrm { NO } _ { 3 } ^ { - } ( \mathrm { aq } ) + 8 \mathrm { H } ^ { + } ( \mathrm { aq } ) \rightarrow 3 \mathrm {~Pb} ^ { 2 + } ( \mathrm { aq } ) + 2 \mathrm { NO } ( \mathrm { g } ) + 4 \mathrm { H } _ { 2 } \mathrm { O } ( \mathrm { l } ) Which of the following is the oxidation half-reaction that occurs in the anode?


A) Pb(s) Pb2+(aq) +2e\mathrm { Pb } ( \mathrm { s } ) \rightarrow \mathrm { Pb } ^ { 2 + } ( \mathrm { aq } ) + 2 \mathrm { e } ^ { - }
B) NO3(aq) +3eNO(g) \mathrm { NO } _ { 3 } ^ { - } ( \mathrm { aq } ) + 3 \mathrm { e } ^ { - } \rightarrow \mathrm { NO } ( \mathrm { g } )
C) NO3(aq) +4H+(aq) +3eNO(g) +2H2O(l) \mathrm { NO } _ { 3 } ^ { - } ( \mathrm { aq } ) + 4 \mathrm { H } ^ { + } ( \mathrm { aq } ) + 3 \mathrm { e } ^ { - } \rightarrow \mathrm { NO } ( \mathrm { g } ) + 2 \mathrm { H } _ { 2 } \mathrm { O } ( \mathrm { l } )
D) Pb2+(aq) +H2O(l) PbO(s) +2H+(aq) +2e\mathrm { Pb } ^ { 2 + } ( \mathrm { aq } ) + \mathrm { H } _ { 2 } \mathrm { O } ( \mathrm { l } ) \rightarrow \mathrm { PbO } ( \mathrm { s } ) + 2 \mathrm { H } ^ { + } ( \mathrm { aq } ) + 2 \mathrm { e } ^ { - }
E) 3 Pb( s) +2NO3(aq) 3 Pb2+(aq) +2NO(g) +3e3 \mathrm {~Pb} ( \mathrm {~s} ) + 2 \mathrm { NO } _ { 3 } ^ { - } ( \mathrm { aq } ) \rightarrow 3 \mathrm {~Pb} ^ { 2 + } ( \mathrm { aq } ) + 2 \mathrm { NO } ( \mathrm { g } ) + 3 \mathrm { e } ^ { - }

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