What city was the second important center of revolutionary activity in Spanish South America?

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Buenos Aires was a significant center of revolutionary activity in Spanish South America, following the lead of Caracas. It played a crucial role in the independence movements against Spanish rule, particularly after the May Revolution of 1810, which led to the establishment of the United Provinces of the Rio de la Plata, a precursor to modern Argentina.

What City Was the Second Important Center of Revolutionary Activity