One reason given by Wittgenstein for concluding that sensations such as pains are not mental objects is that:

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Wittgenstein argued that sensations like pains do not follow conventional rules of localization, meaning they cannot be pinpointed to a specific location in the body like a physical object can. This leads him to conclude that they are not mental objects because they do not behave like other objects that we would consider to be mental or physical.

One Reason Given by Wittgenstein for Concluding That Sensations Such