A mixture contains benzoic acid, a monoprotic acid (Ka = 6.28 × 10−5, 0.250 M), and sodium benzoate (0.400 moles/liter). How many mL of a HCl(aq)solution whose pH is 0.523 should be added to 500 mL of this buffer to change its pH from what it is to pH = 4.20?Hint: Determine the pH of the original buffer, the original [base]/[acid] ratio, and then the target [base]/[acid] ratio.
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