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Pure Glacial Acetic Acid, HC2H3O2, Has a Molar Mass of 60.052

Question 127

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Pure glacial acetic acid, HC2H3O2, has a molar mass of 60.052 g mol−1 and a density of 1.0492 g mL−1, a freezing point of 16.62°C, and a boiling point of 118.3°C. Its freezing point depression and boiling point elevation constants are: Kf = 3.57 °C m−1; Kb = 3.07 °C m−1. A solution was made by taking 19.51 g of an unknown nonelectrolyte and dissolving it in 181.0 g of glacial acetic acid. The measured freezing point of the solution was 8.64°C. Calculate the molar mass of the unknown substance.Hint: Find molality, then moles, then molar mass, being sure to keep track of units.

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