In the orbital diagram for carbon in the ground state, the sixth electron cannot be placed in any one of the 2p orbitals because it must be placed in an empty orbital.

Name: In the orbital diagram for carbon in the ground state, the sixth electron cannot be placed in any one of the 2p orbitals because it must be placed in an empty orbital.
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The sixth electron must be placed in the 2p orbital, which is empty in the ground state of carbon.

In the Orbital Diagram for Carbon in the Ground State