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What Is the Correct Order of Reagents Needed for the Following

Question 7

Multiple Choice

What is the correct order of reagents needed for the following reaction? What is the correct order of reagents needed for the following reaction?   A)  1)  Hg(OAc) <sub>2</sub>, THF:H<sub>2</sub>O 2)  NaBH<sub>4</sub>, OH<sup>-</sup>3)  TBDMS-Cl, imidazole, DMF 4)  Potassium tert-butoxide 5)  HBr/H<sub>2</sub>O<sub>2</sub> 6)  TBAF/THF B)  1)  Potassium tert-butoxide 2)  1 eq. HBr/H<sub>2</sub>O<sub>2</sub> 3)  Hg(OAc) <sub>2</sub>, THF:H<sub>2</sub>O 4)  NaBH<sub>4</sub>, OH<sup>-</sup>(assume that terminalalkenes react in preference to internal alkenes)  C)  1)  Hg(OAc) <sub>2</sub>, THF:H<sub>2</sub>O 2)  NaBH<sub>4</sub>, OH<sup>-</sup> 3)  TBDMS-Cl, imidazole, DMF 4)  Potassium tert-butoxide 5)  BH<sub>3</sub>:THF 6 <sub>)  H</sub><sub>2</sub><sub>O</sub><sub>2</sub><sub>, OH</sub>- <sub>7) PBr</sub><sub>3</sub> <sub>8)  TBAF/THF</sub>  D)  all of the above


A) 1) Hg(OAc) 2, THF:H2O 2) NaBH4, OH-3) TBDMS-Cl, imidazole, DMF 4) Potassium tert-butoxide 5) HBr/H2O2 6) TBAF/THF
B) 1) Potassium tert-butoxide 2) 1 eq. HBr/H2O2 3) Hg(OAc) 2, THF:H2O 4) NaBH4, OH-(assume that terminalalkenes react in preference to internal alkenes)
C) 1) Hg(OAc) 2, THF:H2O 2) NaBH4, OH- 3) TBDMS-Cl, imidazole, DMF
4) Potassium tert-butoxide 5) BH3:THF 6 ) H2O2, OH- 7) PBr3 8) TBAF/THF
D) all of the above

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