Who cast the tie breaking vote in the Senate that killed Van Buren's appointment as ambassador to England?

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According to historical accounts, John C. Calhoun cast the tie-breaking vote in the Senate that killed Van Buren's appointment as ambassador to England. This was in retaliation against Van Buren's opposition to Calhoun's efforts to declare several states, including South Carolina, null and void.

Who Cast the Tie Breaking Vote in the Senate That