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Silver Ion Is Being Considered as a Reagent for Separating

Question 16

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Silver ion is being considered as a reagent for separating IO3 from CO32 in a solution that is 0.060 M in K2CO3 and 0.070 M in NaIO3.Which anion will precipitate first and what will its concentration be when the second anion begins to precipitate? Can the two ions be separated with 99.99% efficiency?
Ksp = 3.1 x 108 for AgIO3
Ksp = 8.1 x 1012 for Ag2CO3

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Iodate precipitates first,[IO3]...

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