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The Gas Phase Reaction of Nitrogen Dioxide and Carbon Monoxide \circ

Question 86

Multiple Choice

The gas phase reaction of nitrogen dioxide and carbon monoxide was found experimentally to be second-order with respect to NO2, and zero-order with respect to CO below 25 \circ C.
NO2 + CO \rarr NO + CO2
Which one of the following mechanisms is consistent with the observed reaction order


A) NO2 + 2CO \rarr N + 2CO2 fast
N + NO2 \rarr 2NO slow
B) NO2 + 2CO \rarr N + 2CO2 slow
N + NO2 \rarr 2NO fast
C) NO2 + NO2 \rarr NO3 + NO fast
NO3 + CO \rarr NO2 + CO2 slow
D) NO2 + NO2 \rarr NO3 + NO slow
NO3+CONO2+CO2NO_3 + CO \rarr NO_2 + CO_2 fast

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