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When the Concentration of a Is Doubled,the Rate for the Reaction

Question 94

Multiple Choice

When the concentration of A is doubled,the rate for the reaction: 2 A + B \rarr 2 C quadruples.
When the concentration of B is doubled the rate remains the same.Which mechanism below is consistent with the experimental observations?


A) Step 1: A + B ? D (fast equilibrium) Step 2: A + D ? 2 C (slow)
B) Step 1: A + B ? D (slow) Step 2: A + D ? 2 C (fast equilibrium)
C) Step 1: 2 A ? D (slow) Step 2: B + D ? E (fast)
Step 3: E ? 2 C (fast)
D) Step 1: 2 A ? D (fast equilibrium) Step 2: B + D ? E (slow)
Step 3: E ? 2 C (fast)

Correct Answer:

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