The gas phase reaction of nitrogen dioxide and carbon monoxide was found experimentally to be second-order with respect to NO2, and zero-order with respect to CO below 25°C. NO2 + CO NO + CO2
Which one of the following mechanisms is consistent with the observed reaction order?
A) NO2 + 2CO
N + 2CO2 fast N + NO2 2NO slow
B) NO2 + 2CO N + 2CO2 slow N + NO2 2NO fast
C) NO2 + NO2 NO3 + NO fast NO3 + CO NO2 + CO2 slow
D) NO2 + NO2 NO3 + NO slow NO3 + CO NO2 + CO2 fast
Correct Answer:
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