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The Gas Phase Reaction of Nitrogen Dioxide and Carbon Monoxide \rarr

Question 90

Multiple Choice

The gas phase reaction of nitrogen dioxide and carbon monoxide was found experimentally to be second-order with respect to NO2, and zero-order with respect to CO below 25°C. NO2 + CO \rarr NO + CO2
Which one of the following mechanisms is consistent with the observed reaction order?


A) NO2 + 2CO  The gas phase reaction of nitrogen dioxide and carbon monoxide was found experimentally to be second-order with respect to NO<sub>2</sub>, and zero-order with respect to CO below 25°C. NO<sub>2</sub> + CO  \rarr  NO + CO<sub>2</sub> <sub> </sub>Which one of the following mechanisms is consistent with the observed reaction order? A) NO<sub>2</sub> + 2CO   N + 2CO<sub>2 </sub>fast N + NO<sub>2</sub>  \rarr  2NO slow B) NO<sub>2</sub> + 2CO  \rarr N + 2CO<sub>2 </sub>slow N + NO<sub>2</sub>  \rarr  2NO fast C) NO<sub>2</sub> + NO<sub>2 </sub> \rarr <sub> </sub>NO<sub>3</sub> + NO fast NO<sub>3</sub> + CO  \rarr NO<sub>2</sub> + CO<sub>2 </sub>slow D) NO<sub>2</sub> + NO<sub>2 </sub> \rarr <sub> </sub>NO<sub>3</sub> + NO slow NO<sub>3</sub> + CO  \rarr NO<sub>2</sub> + CO<sub>2 </sub>fast N + 2CO2 fast N + NO2 \rarr 2NO slow
B) NO2 + 2CO \rarr N + 2CO2 slow N + NO2 \rarr 2NO fast
C) NO2 + NO2 \rarr NO3 + NO fast NO3 + CO \rarr NO2 + CO2 slow
D) NO2 + NO2 \rarr NO3 + NO slow NO3 + CO \rarr NO2 + CO2 fast

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