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Consider the Reaction
CH3(CH2)4CH2CH(Br)CH3 + NaOH \rarr CH3(CH2)4CH2CH(OH)CH3
(Optically Pure Enantiomer)
the Rate Law for This Reaction

Question 91

Multiple Choice

Consider the reaction
CH3(CH2) 4CH2CH(Br) CH3 + NaOH \rarr CH3(CH2) 4CH2CH(OH) CH3
(optically pure enantiomer)
The rate law for this reaction over a wide range of [OH-] is R = k1[RX] + k2[RX][OH-] where RX is 2-bromooctane and k2/k1 = 20.
At very low hydroxide ion concentration,


A) the product of the reaction does not rotate the plane of polarized light.
B) the product formed is CH3(CH2) 4CH=CHCH3 and not the alcohol.
C) the reaction proceeds by an SN2 mechanism.
D) the hydroxide ion attacks the face of the carbocation in a concerted mechanism on the face opposite the leaving group.
E) the product is optically active and rotates the plane of polarized light in the opposite direction with respect to 2-bromooctane.

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