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Nitric Acid, Which Is Among the Top 15 Chemicals Produced Δ\Delta

Question 58

Multiple Choice

Nitric acid, which is among the top 15 chemicals produced in the United States, was first prepared over 1200 years ago by heating naturally occurring sodium nitrate (called saltpeter) with sulfuric acid and collecting the vapors produced. Calculate Δ\Deltarxn for this reaction. Δ\Deltaf [NaNO3(s) ] = -467.8 kJ/mol; Δ\Deltaf [NaHSO4(s) ] = -1125.5 kJ/mol; Δ\Deltaf [H2SO4(l) = -814.0 kJ/mol; Δ\Deltaf [HNO3(g) ] = -135.1 kJ/mol
NaNO3(s) + H2SO4(l) \to NaHSO4(s) + HNO3(g)


A) -644.2 kJ
B) -291.4 kJ
C) -21.2 kJ
D) 21.2 kJ
E) 644.2 kJ

Correct Answer:

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