Tertiary carbocations will form the fastest because they have a transition state that is the lowest in free energy.

Name: Tertiary carbocations will form the fastest because they have a transition state that is the lowest in free energy.
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Tertiary carbocations have a greater number of alkyl groups bonded to the carbon atom carrying the positive charge which stabilizes the carbocation. This stabilization causes a lower activation energy for the reaction, leading to a faster reaction rate.

Tertiary Carbocations Will Form the Fastest Because They Have a Transition