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A Proposed Mechanism for the Reaction Cl2(g)+ CHCl3(g) \to HCl(g)+ CCl4(g)in the Atmosphere Is Step 1: Cl2(g)

Question 155

Multiple Choice

A proposed mechanism for the reaction Cl2(g) + CHCl3(g) \to HCl(g) + CCl4(g) in the atmosphere is Step 1: Cl2(g) \to 2 Cl(g)
(very fast,reversible)
Step 2: Cl(g) + CHCl3(g) \to HCl(g) + CCl3(g) (slow)
Step 3: Cl(g) + CCl3(g) \to CCl4(g) (fast)
What is the rate law for the overall reaction?


A) k[Cl2]
B) k[Cl2][CHCl3]
C) k[CHCl3][Cl2]2
D) k[CHCl3][Cl2]1/2
E) k[Cl][CCl3]

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