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Under Certain Conditions the Reaction H2O2 + 3I- + 2H+ \to

Question 94

Multiple Choice

Under certain conditions the reaction H2O2 + 3I- + 2H+ \to I3- + 2H2O occurs by the following series of steps:
k1
Step 1.
H2O2 + H+  Under certain conditions the reaction H<sub>2</sub>O<sub>2</sub> + 3I<sup>-</sup> + 2H<sup>+</sup>  \to I<sub>3</sub><sup>-</sup> + 2H<sub>2</sub>O occurs by the following series of steps: k<sub>1</sub> Step 1. H<sub>2</sub>O<sub>2 </sub>+ H<sup>+</sup>   H<sub>3</sub>O<sub>2</sub><sup>+</sup> k<sub>-</sub><sub>1</sub>   Step 2. H<sub>3</sub>O<sub>2</sub><sup>+</sup> + I<sup>-</sup>  \to  H<sub>2</sub>O + HOI (slow,rate constant k<sub>2</sub>)  Step 3. HOI + I<sup>-</sup>  \to  OH<sup>-</sup> + I<sub>2</sub> (fast,rate constant k<sub>3</sub>)  Step 4. OH<sup>-</sup> + H<sup>+</sup>  \to  H<sub>2</sub>O (fast,rate constant k<sub>4</sub>)  Step 5. I<sub>2</sub> + I<sup>-</sup>  \to  I<sub>3</sub><sup>-</sup> (fast,rate constant k<sub>5</sub>)  -Which of the steps would be called the rate-determining step? A) 1 B) 2 C) 3 D) 4 E) 5 H3O2+
k-1  Under certain conditions the reaction H<sub>2</sub>O<sub>2</sub> + 3I<sup>-</sup> + 2H<sup>+</sup>  \to I<sub>3</sub><sup>-</sup> + 2H<sub>2</sub>O occurs by the following series of steps: k<sub>1</sub> Step 1. H<sub>2</sub>O<sub>2 </sub>+ H<sup>+</sup>   H<sub>3</sub>O<sub>2</sub><sup>+</sup> k<sub>-</sub><sub>1</sub>   Step 2. H<sub>3</sub>O<sub>2</sub><sup>+</sup> + I<sup>-</sup>  \to  H<sub>2</sub>O + HOI (slow,rate constant k<sub>2</sub>)  Step 3. HOI + I<sup>-</sup>  \to  OH<sup>-</sup> + I<sub>2</sub> (fast,rate constant k<sub>3</sub>)  Step 4. OH<sup>-</sup> + H<sup>+</sup>  \to  H<sub>2</sub>O (fast,rate constant k<sub>4</sub>)  Step 5. I<sub>2</sub> + I<sup>-</sup>  \to  I<sub>3</sub><sup>-</sup> (fast,rate constant k<sub>5</sub>)  -Which of the steps would be called the rate-determining step? A) 1 B) 2 C) 3 D) 4 E) 5 Step 2.
H3O2+ + I- \to H2O + HOI
(slow,rate constant k2)
Step 3.
HOI + I- \to OH- + I2
(fast,rate constant k3)
Step 4.
OH- + H+ \to H2O
(fast,rate constant k4)
Step 5.
I2 + I- \to I3-
(fast,rate constant k5)
-Which of the steps would be called the rate-determining step?


A) 1
B) 2
C) 3
D) 4
E) 5

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