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Organic Chemistry Study Set 17
Quiz 21: Benzene and the Concept of Aromaticity
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Question 61
Essay
Why are nitrophenols more acidic than phenols?
Question 62
Short Answer
Assuming that the sulfur atom is sp
2
-hybridized, there are _____ π-electrons in the sulfathiazole ring.
Question 63
True/False
The following compound could be produced by reaction of phenol with bromobenzene.
Question 64
Multiple Choice
Identify the most acidic compound.
Question 65
Short Answer
Consider the following structure.
-If named as an annulene, the name would be [ __ ] annulene.
Question 66
True/False
Consider the following general structure.
Positions 1,4 and 2,6 and 3,5 are termed para, ortho, and meta, respectively.
Question 67
Multiple Choice
The ______ substituent is affected during the oxidation of 2-bromo-4-nitrotoulene using chromic acid.
Question 68
Multiple Choice
Which of the following compound is nonaromatic?
Question 69
Essay
List all of the requirements of a molecule for it to be considered aromatic.
Question 70
Short Answer
Consider the following structure.
-This structure contains ____ π electrons.
Question 71
Essay
Provide a brief explanation of why the cyclopentadienyl anion (below) is aromatic. Your answer should identify the hybridization of each carbon atom and account for which electrons are in the pi system.
Question 72
Multiple Choice
Identify the major product of the following reaction.
Question 73
Essay
Provide a brief explanation of why furan (below) is aromatic. Your answer should identify the hybridization of the oxygen atom and account for which electrons are in the pi system.
Question 74
Short Answer
Using the Hückel criteria, the compound would be ______________.
Question 75
Short Answer
According to Hückel criteria, sulfathiazole is predicted to be ___________.
Question 76
Multiple Choice
Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound "A" by the process of esterification, using acetic anhydride. Identify compound "A".