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Chemistry
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Chemistry Study Set 1
Quiz 13: Chemical Equilibrium
Path 4
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Question 121
Multiple Choice
At a certain temperature,nitrogen and hydrogen react to form ammonia: N
2
(g) + 3 H
2
(g) ⇌ 2 NH
3
(g) . When initial amounts of N
2
,H
2
,and NH
3
are mixed,the concentration of NH
3
increases.Which statement below is true?
Question 122
Multiple Choice
Picture (1) represents an equilibrium mixture of solid CaCO
3
,solid CaO,and gaseous CO
2
,obtained as a result of the endothermic decomposition of CaCO
3
.
-Which picture (2) -(4) represents the equilibrium mixture when more solid CaCO
3
is added?
Question 123
Multiple Choice
For the reaction: N
2
(g) + 2 O
2
(g) ⇌ 2 NO
2
(g) ,K
c
= 8.3 × 10
-10
at 25°C.What is the concentration of N
2
gas at equilibrium when the concentration of NO
2
is five times the concentration of O
2
gas?
Question 124
Multiple Choice
At a certain temperature the equilibrium constant,K
c
,equals 0.11 for the reaction: 2 ICl(g) ⇌ I
2
(g) + Cl
2
(g) . What is the equilibrium concentration of ICl if 0.75 mol of I
2
and 0.75 mol of Cl
2
are initially mixed in a 2.0-L flask?
Question 125
Multiple Choice
Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation: PCl
5
(g) ⇌ PCl
3
(g) + Cl
2
(g) At 250° 0.125 M PCl
5
is added to the flask.If K
c
= 1.80,what are the equilibrium concentrations of each gas?
Question 126
Multiple Choice
Picture (1) represents an equilibrium mixture of solid CaCO
3
,solid CaO,and gaseous CO
2
,obtained as a result of the endothermic decomposition of CaCO
3
.
-Which picture (2) -(4) represents the equilibrium mixture at a higher temperature?
Question 127
Multiple Choice
Cyclohexane,C
6
H
12
,undergoes a molecular rearrangement in the presence of AlCl
3
to form methylcyclopentane,CH
3
C
5
H
9,
according to the equation: C
6
H
12
⇌ CH
3
C
5
H
9
If K
c
= 0.143 at 25°C for this reaction,find the equilibrium concentrations of C
6
H
12
and CH
3
C
5
H
9
if the initial concentrations are 0.200 M and 0.075 M,respectively.
Question 128
Multiple Choice
Picture (1) represents the equilibrium mixture for the reaction A + B ⇌ 2 AB at 298 K.
-If this reaction is endothermic,which picture (2) -(4) represents the equilibrium mixture at 400 K?
Question 129
Multiple Choice
The decomposition of ammonia is: 2 NH
3
(g) = N
2
(g) + 3 H
2
(g) .If K
p
is 1.5 × 10
3
at 400°C,what is the partial pressure of ammonia at equilibrium when N
2
is 0.10 atm and H
2
is 0.15 atm?
Question 130
Multiple Choice
At a certain temperature,K
c
equals 1.4 × 10
2
for the reaction: 2 CO(g) + O
2
(g) ⇌ 2 CO
2
(g) . If a 3.00-L flask contains 0.400 mol of CO
2
and 0.100 mol of O
2
at equilibrium,how many moles of CO are also present in the flask?
Question 131
Multiple Choice
Picture (1) represents an equilibrium mixture of solid CaCO
3
,solid CaO,and gaseous CO
2
,obtained as a result of the endothermic decomposition of CaCO
3
.
-Which picture (2) -(4) represents the equilibrium mixture when more solid CaO is added?
Question 132
Multiple Choice
The equilibrium constant,K
p
,equals 3.40 for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene. If a flask initially contains 0.250 atm of cis-2-butene and 0.145 atm of trans-2-butene,what is the equilibrium pressure of each gas?
Question 133
Multiple Choice
The equilibrium constant,K
p
,equals 3.40 at 25°C for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene. If a flask initially contains 5.00 atm of each gas,in what direction will the system shift to reach equilibrium?
Question 134
Multiple Choice
Cyclohexane (C
6
H
12
) undergoes a molecular rearrangement in the presence of AlCl
3
to form methylcyclopentane (MCP) according to the equation: C
6
H
12
⇌ MCP If K
c
= 0.143 at 25°C for this reaction,predict the direction in which the system will shift if the initial concentrations of C
6
H
12
and MCP are 0.0400 M and 0.0200 M,respectively.The system
Question 135
Multiple Choice
For the isomerization reaction: Butane ⇌ isobutane K
p
equals 25 at 500°C.If the initial pressures of butane and isobutane are 20.atm and 0.0 atm,respectively,what are the pressures of the two gases at equilibrium?