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Chemistry
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General Chemistry Principles
Quiz 15: Principles of Chemical Equilibrium
Path 4
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Question 81
Multiple Choice
Consider the equilibrium system: N
2
O
4
(g) ⇌ 2 NO
2
(g) for which K
p
= 0.1134 at 25 °C and Δ
r
H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N
2
O
4
was present inside the container,compute
At equilibrium.
Question 82
Multiple Choice
Consider the following reaction: POCl
3
(g) ⇌ POCl(g) + Cl
2
(g) with K
c
= 0.450 A sample of pure POCl
3
(g) was placed in a reaction vessel and allowed to decompose according to the above reaction.At equilibrium,the concentrations of POCl(g) and Cl
2
(g) were each 0.150 M.What was the initial concentration of POCl
3
(g) ?
Question 83
Multiple Choice
A mixture,containing 0.0750 M HCl(g) and 0.0330 M O
2
(g) is allowed to come to equilibrium at 480 °C. 4 HCl(g) + O
2
(g) ⇌ 2 Cl
2
(g) + 2 H
2
O(g) At equilibrium [Cl
2
] = 0.030 M.What is the value of K
c
?
Question 84
Multiple Choice
A mixture containing 0.392 M A(g) and 0.452 M B(g) is allowed to come to equilibrium at 300 K.The reaction 3 A(g) + 2 B(g) ⇌ C(g) + D(g) occurs.At equilibrium,[C] = 0.00128 M.What is the value of K
c
?
Question 85
Multiple Choice
For the reaction: PCl
3
(g) + Cl
2
(g) ⇌ PCl
5
(g) at 85 °C,K
p
= 1.19 If one starts with 2.00 atm pressure of PCl
3
,1.00 atm pressure of Cl
2
and no PCl
5
,what is the partial pressure of PCl
5
(g) at equilibrium?
Question 86
Multiple Choice
Consider the equilibrium system: N
2
O
4
(g) ⇌ 2 NO
2
(g) for which K
p
= 0.1134 at 25 °C and Δ
r
H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N
2
O
4
was present inside the container,compute
At equilibrium.
Question 87
Multiple Choice
Consider the equilibrium system: N
2
O
4
(g) ⇌ 2 NO
2
(g) for which K
p
= 0.1134 at 25 °C and Δ
r
H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N
2
O
4
was present inside the container,compute
At equilibrium.
Question 88
Multiple Choice
At 35 °C,K
p
= 0.315 for the reaction N
2
O
4
(g) ⇌ 2 NO
2
(g) ,if the initial pressure of NO
2
(g) in a container is 3.00 atm,what is the equilibrium pressure of N
2
O
4
(g) ?
Question 89
Multiple Choice
For the decomposition of ammonium carbamate NH
4
(NH
2
CO
2
) (s) ⇌ 2 NH
3
(g) + CO
2
(g) K
p
= 0.0596 at a certain temperature.A solid sample of ammonium carbamate is introduced into an evacuated container and at equilibrium some solid remains in the container.What is the total pressure in the container?
Question 90
Multiple Choice
Consider the following reversible reaction: POCl
3
(g) ⇌ POCl(g) + Cl
2
(g) K
c
= 0.450 The following initial amounts of reactants and products were mixed: [POCl
3
] = 0.750 M,[POCl] = 0.550 M,and [Cl
2
] = 0.150 M.What is the equilibrium concentration of POCl?
Question 91
Multiple Choice
4.000 mol chlorine and 2.000 mol bromine were placed in a 50.0 L container and kept at 293 K until equilibrium was achieved for the reaction: Br
2
(l) + Cl
2
(g) ⇌ 2 BrCl(g) At the point of equilibrium there were 82.63 g of Br
2
(l) .Determine the total pressure in the 50.0 L container at equilibrium.
Question 92
Multiple Choice
Consider the following equilibrium. A(g) + 3 B(g) ⇌ 2 C(g) If the initial concentrations are [A] = 1.00 M,[B] = 3.00 M,and [C] = 0,at equilibrium it is found that [C] = 0.980 M.Calculate K
c
for this reaction.