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Chemistry
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Chemistry Study Set 4
Quiz 18: Electrochemistry
Path 4
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Question 201
Short Answer
The standard cell potential for the following galvanic cell is 1.21 V. Al(s)|Al
3+
(aq)||Fe
2+
(aq)|Fe(s) When [Al
3+
] = 0.10 M and [Fe
2+
] = 0.10 M,will the cell potential at 25°C be less than,the same as,or greater than 1.21 V?
Question 202
Essay
The two half-reactions that are used in the direct methanol fuel cell are shown below. I.2 CH
3
OH(aq)+ 2 H
2
O(l)→ 2 CO
2
(g)+ 12 H
+
(aq)+ 12 e
-
II.3 O
2
(g)+ 12 H
+
(aq)+ 12 e
-
→ 6 H
2
O(l) The electrode at which half-reaction I occurs is the ________ at which ________ is oxidized,and half-reaction II occurs at the ________ at which ________ is reduced.
Question 203
Short Answer
The standard reduction potential E° = -0.45 V for the half-reaction Fe
2+
+ 2 e
-
→ Fe.If the measured cell potential at 25°C is 0.35 V,the pH in the anode compartment of the following cell is ________. Pt(s)|H
2
(1 atm)|H
+
(? M)||Fe
2+
(1 M)|Fe(s)
Question 204
Short Answer
If a constant current of 1.50 × 10
8
A is passed through a molten mixture of aluminum oxide and cryolite for 4.00 hour ________ kg of aluminum can be produced.
Question 205
Short Answer
Based on the half-reactions and their respective standard reduction potentials below,the standard cell potential for the reaction that is expected to occur is ________ V. Ag
+
(aq)+ e
-
→ Ag(s)0.80 V 2 H
+
(aq)+ 2 e
-
→ H
2
(g)0.00 V Cd
2+
(aq)+ 2 e
-
→ Cd(s)-0.40 V
Question 206
Short Answer
The standard cell potential for the following galvanic cell is 0.71 V. Pb(s)|Pb
2+
(aq)||Al
3+
(aq)|Al This reaction has an equilibrium constant,K = ________.
Question 207
Short Answer
Reduction half-reactions with corresponding standard half-cell potentials are shown below. Zn
2+
(aq)+ 2 e
-
→ Zn(s)E° = - 0.76 V Al
3+
(aq)+ 3 e
-
→ Al(s)E° = - 1.66 V The standard potential for the galvanic cell that uses these two half-reactions is ________ V.
Question 208
Short Answer
For the hypothetical reaction 3 A + 2 B
x
→ 3 A
y
+ 2 B,E° = 0.85 V and G° = -495 kJ.For this reaction the values of x and y are ________ and ________.
Question 209
Short Answer
In order for a cell potential to be a standard cell potential,the concentration of all ions in solution must be ________ M,the partial pressures of all gaseous species must be ________ atm,and the temperature must be ________ K.