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It Has Been Suggested That the Decomposition of NO2 Occurs \rarr

Question 11

Multiple Choice

It has been suggested that the decomposition of NO2 occurs via the following mechanism:
NO2 \rarr NO + O (Rxn I)
O + NO2 \rarr 2NO + O2 (Rxn II)
Predict the rate determining step.


A) Rxn II; this reaction is bimolecular, bimolecular reactions are always slower than unimolecular reactions.
B) Rxn I; unimolecular reactions are always slower than bimolecular reactions.
C) Rxn I; O is highly reactive and thus Rxn II will be very fast.
D) Rxn II; NO2 is highly reactive and thus Rxn I will be very fast.
E) Rxn I and II are both elementary reactions and will proceed at equal rates.

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