Which is NOT true for solute retention?
A) Retention time,tr,is the elapsed time between injecting the sample to the arrival of a sample component at the detector minus the dwell time between the end of the column and the detector.
B) Adjusted retention time is tr' = tr - tm,where tr is the retention time and tm is the time for mobile phase or unretained solutes to pass through the column.
C) The relative retention, =
,is the ratio for the adjusted retention time for two components of the sample,where tr2' > tr1' so that > 1.
D) The retention factor,k =
,is the time,tr,required to elute a component minus the time,tm,for mobile phase to pass through the column divided by tm.
E) The relative retention, ,also equals
,where K2 and K1 are the partition coefficients for components 2 and 1.
Correct Answer:
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