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Chemistry
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General Chemistry The Essential Concepts
Quiz 19: Redox Reactions and Electrochemistry
Path 4
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Question 121
Short Answer
An electroplating solution is made up of nickel(II)sulfate. How much time would it take to deposit 0.500 g of metallic nickel on a custom car part using a current of 3.00 A?
Question 122
Essay
Consider the reaction Fe + Sn
2+
(1 * 10
-3
M)
→
\rarr
→
Fe
2+
(1.0 M)+ Sn. Sketch a diagram of such a cell. Be sure to label the anode and cathode, and show the direction of electron flow in the external circuit. Write the half-reactions occurring at the electrodes.
Question 123
Short Answer
You wish to electroplate a metal utensil with a surface area of 736 cm
2
with gold to give an average thickness of 0.025 mm over the entire surface. Starting with a solution of excess Au
3+
and applying a constant current of 14 A, how long will it take to electroplate the utensil? The density of gold is 19.3 g/cm
3
.
Question 124
True/False
When an aqueous solution of NaCl is electrolyzed, Na(l)is produced at the cathode, and Cl
2
(g)is evolved at the anode.
Question 125
Short Answer
A standard hydrogen electrode is immersed in an acetic acid solution. This electrode is connected by an external circuit to an iron nail dipping into 0.10 M FeCl
2
. If E
cell
is found to be 0.24 V, what is the pH of the acetic acid solution?
Question 126
Short Answer
Aluminum metal is formed by the electrolysis of Al
2
O
3
in molten cryolite. How many minutes are required to form 10.0 g of Al using a current of 30 A?
Question 127
Short Answer
Consider the reaction Fe + Sn
2+
(1 *10
-3
M)
→
\rarr
→
Fe
2+
(1.0 M)+ Sn. Calculate the voltage theoretically generated by the cell.
Question 128
Short Answer
Calculate the cell emf for the following reaction at 25°C: 2Ag
+
(0.010 M)+ H
2
(1 atm)
→
\rarr
→
2Ag(s)+ 2H
+
(pH = 6.0)
Question 129
Short Answer
Many different ways have been proposed to make batteries. One cell is set up with copper and lead electrodes in contact with CuSO
4
(aq)and Pb(NO
3
)
2
(aq), respectively. If the Pb
2+
and Cu
2+
concentrations are each 1.0 M, what is the overall cell potential? Pb
2+
+ 2e
-
→
\rarr
→
Pb E° = -0.22 V Cu
2+
+ 2e
-
→
\rarr
→
Cu E° = +0.34 V
Question 130
Short Answer
How many moles of silver metal are produced in 1.2 hours by the electrolysis of AgNO
3
(aq)using a current of 6.0 A?
Question 131
Essay
Consider the reaction Fe + Sn
2+
(1 * 10
-3
M)
→
\rarr
→
Fe
2+
(1.0 M)+ Sn. In what direction do the Cl
-
ions in the KCl salt bridge flow?
Question 132
Short Answer
What concentration of Ni
2+
ion remains in solution after electrolysis of 100. mL of 0.250 M NiSO
4
solution when using a current of 2.40 amperes for 30.0 minutes? Assume Ni metal is plated out.